Conditions | Yield |
---|---|
With potassium hydroxide In water at 70℃; Electrolysis; | 99.8% |
Conditions | Yield |
---|---|
With potassium hydroxide In water at 70℃; Temperature; Concentration; Electrolysis; | 98.8% |
Conditions | Yield |
---|---|
In melt melting 1 mol KI/ 1.5 mol KClO4;; | 91% |
melting; |
potassium iodate
Conditions | Yield |
---|---|
With potassium iodide molar ratio of KI:KClO4 = 1:1.5; | 91% |
With KI molar ratio of KI:KClO4 = 1:1.5; | 91% |
Conditions | Yield |
---|---|
With oxygen High Pressure; at 410 °C, at 1200 atm., at higher temp. with I2-elimination, 5- 6 h; | 90% |
With O2 High Pressure; at 410 °C, at 1200 atm., at higher temp. with I2-elimination, 5- 6 h; | 90% |
With ozone In ethanol |
Conditions | Yield |
---|---|
With water In water MoO3 and KIO4 were loaded in Parr 4749 PTFE-lined autoclave, water was added, the mixt. was heated for 3 d at 180°C; the autoclave was cooled at a rate of 9°C/h to 23°C, the mother liquors were decanted from crystalline products that were subsequently washed with methanol, the colorless plates of KMoO3(IO3) were sepd.from colorless cubes of KIO3; | A n/a B 90% |
Conditions | Yield |
---|---|
In melt melting 1 mol KI/ 1.5 mol KBrO3;; | 87% |
melting; |
Conditions | Yield |
---|---|
With potassium iodide molar ratio of KI:KBrO3 = 1:1.5; | 87% |
With KI molar ratio of KI:KBrO3 = 1:1.5; | 87% |
With water; iodine byproducts: Br2; first heating, than cooling to cryst. KIO3; | |
With I2; H2O byproducts: Br2; first heating, than cooling to cryst. KIO3; |
oxygen
potassium iodide
A
potassium iodate
B
potassium metaperiodate
Conditions | Yield |
---|---|
In water dissolving 80g KI and 40g KOH in 500ml H2O; 24h at 250°C with O2 pressure of 90 - 100 atm;; product mixture;; | A 82.3% B 25.4% |
In water dissolving 80g KI and 40g KOH in 500ml H2O; 36h at 250°C with O2 pressure of 90 - 100 atm;; product mixture;; | A 82.5% B 24.5% |
In water dissolving 80g KI and 40g KOH in 500ml H2O; 24h at 250°C with O2 pressure of 90 - 100 atm;; product mixture;; | A 82.3% B 25.4% |
Conditions | Yield |
---|---|
In water dissolving 80g KI and 40g KOH in 1000ml H2O; 48h at 250°C with O2 pressure of 90 - 100 atm;; | 76.6% |
In water dissolving 80g KI and 40g KOH in 1000ml H2O; 48h at 250°C with O2 pressure of 90 - 100 atm;; | 76.6% |
In melt melting KOH and KI (3:1) at 400°C in O2-atmosphere at 5-15atm.;; | |
In melt melting KOH and KI (3:1) at 400°C in O2-atmosphere at 5-15atm.;; |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: O2; 1.5 mol KI/ mol KClO3; start at 350-400°C; violent reaction under formation of O2; mechanism discussed;; product mixture;; | A 65% B n/a |
Conditions | Yield |
---|---|
With potassium iodide molar ratio of KI:KIO3 = 1.5:1; | 65% |
With KI molar ratio of KI:KIO3 = 1.5:1; | 65% |
With iodine In water heating an aq. suspension of I2 with KClO3 and some drops concd. HNO3; |
Conditions | Yield |
---|---|
In neat (no solvent) at ambient temp.;; | |
In neat (no solvent) | |
In neat (no solvent) | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In water | |
In neat (no solvent) reaction by influence of O3 on KI;; | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In melt on melting KI in CO2-stream;; residue containing some KIO3;; | |
In melt on melting KI in CO2-stream;; residue containing some KIO3;; |
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) dry KI heated to 400-450°C in a sealed tube;; | |
In neat (no solvent) |
Conditions | Yield |
---|---|
In potassium hydroxide byproducts: KI3, O2; Electrochem. Process; oscillation reaction for electro-oxidation of iodide in alkaline soln.; | |
With air; aluminum oxide In melt reaction at 500°C in air stream;; | |
With air; aluminum oxide In melt reaction at 500°C in air stream;; |
Conditions | Yield |
---|---|
melting; |
Conditions | Yield |
---|---|
In water heated to 200°C in sealed vessel;; KIO3 precipitated at cooling;; | |
In water heated to 200°C in sealed vessel;; KIO3 precipitated at cooling;; |
potassium iodate
Conditions | Yield |
---|---|
With ethanol; hydrogen iodide In further solvent(s) addn. of few ethanol to K2Cr2O7/ concd. HI mixt. at ambient temp.; pptn.;; |
iodine isocyanate
A
potassium cyanate
B
potassium iodate
C
water
D
potassium iodide
Conditions | Yield |
---|---|
In not given in alkalin soln.; |
Conditions | Yield |
---|---|
With potassium hydroxide neutralization in cold; | |
With potassium carbonate neutralization in warm; | |
With K2CO3 neutralization in warm; | |
With KOH neutralization in cold; |
Conditions | Yield |
---|---|
With potassium hydroxide In not given byproducts: KI; | |
With potassium permanganate | |
With potassium permanganate; water byproducts: KOH, MnO2; |
Conditions | Yield |
---|---|
In further solvent(s) Kinetics; soln. of I2 in tributylphosphate (TBP) quickly added to soln. of KMnO4 in TBP at 20°C and stirred (magnetic stirrer); reaction stopped by quickly vacuum-filtering the mixt. in Mohr's salt and octane, solid products remain in filter; |
Conditions | Yield |
---|---|
In potassium hydroxide byproducts: MnO2; addn. of KMnO4 to hot concd. I2-soln. in small amount of KOH soln.; boiling;; decantation, filtration of MnO2; evapn. and crystn. of KIO3;; |
potassium chlorate
iodine
A
potassium iodate
B
Iodine monochloride
Conditions | Yield |
---|---|
With nitric acid In water at higher concn.; KClO3/I2 ratio is 2:1 mol;; |
potassium chlorate
iodine
A
potassium iodate
C
potassium iodide
Conditions | Yield |
---|---|
In water Irradiation (UV/VIS); | A n/a B n/a C 0% |
Conditions | Yield |
---|---|
With potassium hydroxide; nitric acid In water 1000g KClO3, 1150 - 1250g I2, 30 - 40ml HCl (d 1.2), 2.5 - 3l H2O; in acidic soln. because of acceleration of reaction by formed Cl2; filtration of KIO3*HIO3, neutralization with KOH; mechanism discussed;; | A 90-95 B n/a |
With nitric acid In water mechanism discussed;; |
potassium chlorate
iodine
A
potassium iodate
B
potassium iodide
Conditions | Yield |
---|---|
In water heating in the dark;; |
Conditions | Yield |
---|---|
heating an aq. suspension of I2 with KClO3 and some drops of concd. HNO3; | A 0% B n/a |
heating an aq. suspension of I2 with KClO3 and some drops of concd. HNO3; | A 0% B n/a |
Conditions | Yield |
---|---|
With potassium hydroxide In not given equiv. amt. of KOH is 4-5, Cl2 intoduction between mixing,cooling, lightly acidify with H2SO4; washing, drying; | 95% |
With KOH In not given equiv. amt. of KOH is 4-5, Cl2 intoduction between mixing,cooling, lightly acidify with H2SO4; washing, drying; | 95% |
With fluorine In water strongly alkaline solution, about 2n with KOH; after taking samples for analysis, some concd. KOH soln. is added again;; | 48.5% |
potassium iodate
Conditions | Yield |
---|---|
With H2SO4; KBrO3; NaOH In water solid KBrO3 added to suspn. of ligand in H2O, acidified with H2SO4 to pH=0-1, treated with Cu salt, filtered, treated with NaOH to pH=5 at 0°C; washed (water); | 90% |
Conditions | Yield |
---|---|
With sulfuric acid In not given | 75% |
Conditions | Yield |
---|---|
With NaOH In water aq. Cu complex treated with solid KJO3 with stirring, pH adjusted to 6.0(aq.NaOH); filtered, dried, elem. anal.; | 70% |
potassium iodate
Conditions | Yield |
---|---|
In water High Pressure; mixt. of K salt and Mg salt in H2O was heated at 100°C for 5 d inautoclave; cooled at rate 0.04°C/min to room temp.; | 70% |
Conditions | Yield |
---|---|
With sulfuric acid at 230℃; for 72h; Autoclave; High pressure; | 70% |
Conditions | Yield |
---|---|
In water at 235℃; for 72h; Autoclave; | 65% |
Conditions | Yield |
---|---|
In water at 235℃; for 30h; Autoclave; | 63% |
Conditions | Yield |
---|---|
In water High Pressure; mixt. of K salt and Zn salt in H2O was heated at 100°C for 5 d inautoclave; cooled at rate 0.04°C/min to room temp.; | 50% |
Conditions | Yield |
---|---|
In not given KIO4 decompd. with the formed H2O2, in concd. KOH soln.; | 48.5% |
In not given KIO4 decompd. with the formed H2O2, in concd. KOH soln.; | 48.5% |
potassium iodate
Conditions | Yield |
---|---|
In water High Pressure; mixt. of K salt and Co salt in H2O was heated at 100°C for 5 d inautoclave; cooled at rate 0.04°C/min to room temp.; | 33.4% |
Conditions | Yield |
---|---|
potassium polymanganite(IV) In solid byproducts: O2; mixt. of KIO3 and potassium polymanganate heated (400-600°C, 2h, air); X-ray diffraction; | A 1% B n/a |
Conditions | Yield |
---|---|
Product distribution / selectivity; |
Conditions | Yield |
---|---|
In water in 0.1 n HCl soln.; | >99 |
In water in 0.1 n HCl soln.; | >99 |
Reported in EPA TSCA Inventory.
Method One: It is obtained from potassium hydroxide and iodine direct reaction.
Method Two: In dilute nitric acid medium, it can be obtained from direct oxidation of potassium chlorate and iodine.
The Potassium iodate, with the CAS registry number 7758-05-6, is also known as Iodic acid potassium salt. It belongs to the product categories of Inorganics; Reagent Grade; Synthetic Reagents; Analytical Reagents for General Use; Titrimetry; Titrimetry CRMs; Alphabetic; Application CRMs; Metal and Ceramic Science; Potassium Salts; Salts; Halogenated Solutions Volumetric Solutions; Salt Solutions; Titration; Volumetric Solutions; ACS Grade Synthetic Reagents; Essential Chemicals; Inorganic Salts; Routine Reagents; Reference Material Sodium thiosulfate Titration; By Reference Material; Materials Science. Its EINECS number is 231-831-9. This chemical's molecular formula is IKO3 and molecular weight is 214.00. What's more, its systematic name is Potassium iodate. Its classification codes are: (1)Anti-Infective Agents; (2)Antifungal agents. Potassium iodate is an oxidizing agent and as such it can cause fires if in contact with combustible materials or reducing agents. Potassium iodate is sometimes used for iodination of table salt. In other countries, potassium iodate is used as source for iodine. It is also an ingredient in baby formula milk. Like potassium bromate, potassium iodate is occasionally used as a maturing agent in baking.
Physical properties of Potassium iodate are: (1)#H bond acceptors: 3; (2)#H bond donors: 1; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 54.37 Å2.
Preparation: it can be prepared by reacting a potassium-containing base such as potassium hydroxide with iodic acid. It can also be prepared by adding iodine to a hot, concentrated solution of potassium hydroxide. Or by fusing potassium iodide with potassium chlorate, bromate or perchlorate, the melt is extracted with water and potassium iodate is isolated from the solution by crystallization.
HIO3 + KOH → KIO3 + H2O
3 I2 + 6 KOH → KIO3 + 5 KI + 3 H2O
KI + KClO3 → KIO3 + KCl
When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When contact with combustible material, it may cause fire, so you should keep it away from combustible material. It is harmful by inhalation, in contact with skin and if swallowed and cause harm to the unborn child. You should not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) and should not breathe dust. When using it, you need wear suitable protective clothing, gloves and eye/face protection and you must avoid contact with skin and eyes. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). It should be avoided exposure, and you should obtain special instructions before use.
You can still convert the following datas into molecular structure:
(1)SMILES: [K+].[O-]I(=O)=O
(2)Std. InChI: InChI=1S/HIO3.K/c2-1(3)4;/h(H,2,3,4);/q;+1/p-1
(3)Std. InChIKey: JLKDVMWYMMLWTI-UHFFFAOYSA-M
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
dog | LDLo | oral | 200mg/kg (200mg/kg) | BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: FOOD INTAKE (ANIMAL) | Toxicology and Applied Pharmacology. Vol. 8, Pg. 185, 1966. |
mouse | LD50 | intraperitoneal | 136mg/kg (136mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES BEHAVIORAL: EXCITEMENT | Journal of Pharmacology and Experimental Therapeutics. Vol. 120, Pg. 171, 1957. |
mouse | LDLo | oral | 531mg/kg (531mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Journal of Pharmacology and Experimental Therapeutics. Vol. 120, Pg. 171, 1957. |
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