Conditions | Yield |
---|---|
In diethyl ether; N,N-dimethyl acetamide; ethyl acetate (Ar); vapor diffusion of Et2O into a (CH3)2NCOCH3/EtOAc soln. of Co complex; | 100% |
In N,N-dimethyl acetamide; ethyl acetate (Ar); stirred for 2 h at room temp.; |
N,N-dimethyl acetamide
bis[(N'-isopropylureido)-N-ethyl]-N-methylamine
water
nickel diacetate
K[Ni(bis[(N'-isopropylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
B
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of urea deriv. in dimethylacetamide with 2 equiv. of KH at room temp., addn. of 1 equiv. of nickel compd. at room temp., filtration, addn. of 1 equiv. of KH, addn. of 1 equiv. of water; evapn., triturating with ether, isolation of ppt., IR and UV; | A n/a B 99% |
In N,N-dimethyl acetamide (Ar); treatment of soln. of urea deriv. in dimethylacetamide with 3 equiv. of KH at room temp., addn. of 1 equiv. of nickel compd. at room temp., stirring for 45 min, addn. of 1 equiv. of water, stirring for 20 min; filtration, diffusion of 1:1 ether/pentane vapour, isolation of crystals, elem. anal.; | A 64% B 98% |
N,N-dimethyl acetamide
3-(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-5-tert-butyl-1H-pyrazole
water
cobalt(II) acetate
B
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); a soln. of ligand treated with KH, Co salt added, stirred for 30 min, filtered, H2O added, stirred for 30 min; evapd. (vac., at room temp.), washed (Et2O), dried (vac.); elem. anal.; | A 83% B 98% |
K[Ni(bis[(N'-isopropylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
tetramethyl ammonium acetate
potassium hexamethylsilazane
C
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium amide deriv. at room temp., stirring for 30 min, addn.of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of 1:1 diethyl ether/pentane vapour into soln. in dimethylacetamide, elem. anal.; | A 0% B 94% C 98% |
K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
potassium tert-butylate
tetramethyl ammonium acetate
B
[tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(tert-butoxide)]
C
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium tert-butoxide at room temp., stirring for 30 min, addn. of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of diethyl ether vapour into soln. in dimethylacetamide, IR and UV; | A 0% B 78% C 96% |
K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
tetramethyl ammonium acetate
potassium hexamethylsilazane
B
[tetramethylammonium][Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(OSiMe3)]
C
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium amide deriv. at room temp., stirring for 30 min, addn.of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of 1:1 diethyl ether/pentane vapour into soln. in dimethylacetamide, IR and UV; | A 0% B 95% C n/a |
bis[(N'-isopropylureido)-N-ethyl]-N-methylamine
potassium tert-butylate
tetramethyl ammonium acetate
nickel diacetate
[tetramethylammonium][Ni(bis[(N'-isopropylureido)-N-ethyl]-N-methylamine(-2H))(tert-butoxide)]
B
potassium acetate
Conditions | Yield |
---|---|
With KH In N,N-dimethyl acetamide (vac. or Ar); treatment of soln. of urea deriv. in dimethylacetamide with KH, addn. of nickel compd., stirring for 45 min, addn. of potassium tert-butoxide, addn. of tetramethylammonium salt, stirring for 1 h; evapn. triturating with diethyl ether, isolation of ppt., elem. anal.; | A 91% B 89% |
K[Ni(bis[(N'-isopropylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
potassium tert-butylate
tetramethyl ammonium acetate
[tetramethylammonium][Ni(bis[(N'-isopropylureido)-N-ethyl]-N-methylamine(-2H))(tert-butoxide)]
C
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of nickel compd. in dimethylacetamide with 1 equiv. of potassium tert-butoxide at room temp., stirring for 30 min, addn. of tetramethylammonium salt at room temp., stirring for 1 h; filtration, evapn., triturating with diethyl ether, isolation of ppt., recrystn. by diffusion of 1:1 ether/pentane vapour into soln. in dimethylacetamide, IR and UV; | A 0% B 91% C 89% |
N,N-dimethyl acetamide
water
nickel diacetate
bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine
K[Ni(bis[(N'-tert-butylureido)-N-ethyl]-N-methylamine(-2H))(hydroxo)]*DMA
B
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide (Ar); treatment of soln. of urea deriv. in dimethylacetamide with 3 equiv. of KH at room temp., addn. of 1 equiv. of nickel compd. at room temp., stirring for 45 min, addn. of 1 equiv. of water, stirring for 20 min; filtration, diffusion of 1:1 ether/pentane vapour, isolation of crystals, elem. anal.; | A 87% B 84% |
Conditions | Yield |
---|---|
With water In melt byproducts: H2; 300°C, mixing, leading H2O vapor into the melt; | 83% |
With H2O In melt byproducts: H2; 300°C, mixing, leading H2O vapor into the melt; | 83% |
With air In water handling with air in presence of dild. aq. KOH in diffuse daylight at ambient temp.; | |
With air In water handling with air in presence of dild. aq. KOH in diffuse daylight at ambient temp.; |
acetic acid tert-butyl ester
potassium trimethylsilonate
potassium acetate
Conditions | Yield |
---|---|
77% |
Conditions | Yield |
---|---|
With C15H27Br2CoN3; potassium hydroxide In toluene at 140℃; for 16h; Cannizzaro Reaction; Inert atmosphere; Sealed tube; | 67% |
Conditions | Yield |
---|---|
at 100℃; |
Conditions | Yield |
---|---|
With potassium carbonate | |
Stage #1: acetic acid With potassium hydroxide Electric arc; Stage #2: at 40 - 250℃; |
4-acetoxy azetidinone
A
potassium acetate
Conditions | Yield |
---|---|
With potassium hydroxide at 25℃; Mechanism; Rate constant; |
vinyl crotonate
mercury(II) diacetate
A
(E)-but-2-enoic acid
B
potassium acetate
C
(formylmethyl)mercury chloride
Conditions | Yield |
---|---|
With potassium chloride 1.) water, 26 deg C; 2.) water; Yield given. Multistep reaction. Yields of byproduct given; |
2-hydroxyethyl vinyl ether
A
2-methyl-1,3-dioxolane
B
methane
C
ethane
D
propane
E
potassium acetate
F
acetylene
Conditions | Yield |
---|---|
With potassium hydroxide at 170℃; Product distribution; other hydroxides (Na, Li); |
potassium 4-nitrophenolate
acetic anhydride
A
potassium acetate
B
4-nitrophenol acetate
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile at 20℃; Rate constant; Equilibrium constant; | |
With 18-crown-6 ether In chlorobenzene at 25℃; Rate constant; Equilibrium constant; | |
In acetonitrile at 25℃; Kinetics; Equilibrium constant; |
potassium 2,4-dinitrophenolate
acetic anhydride
A
potassium acetate
B
2,4-dinitrophenyl acetate
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile at 20℃; Rate constant; Equilibrium constant; | |
With 18-crown-6 ether In chlorobenzene at 25℃; Rate constant; Equilibrium constant; |
acetic anhydride
4-hydroxybenzaldehyde potassium salt
A
4-formylphenyl acetate
B
potassium acetate
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile at 20℃; Rate constant; |
acetic anhydride
potassium salt of p-nitrosophenol
A
potassium acetate
B
Acetic acid 4-nitroso-phenyl ester
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile at 20℃; Rate constant; |
di(4-acetoxybenzyl) methylphosphonate
A
(4-hydroxyphenyl)methanol
B
potassium acetate
Conditions | Yield |
---|---|
In [D3]acetonitrile; water-d2 at 36.4℃; Mechanism; Rate constant; potassium phosphate buffer; half-live; also in the presence of porcine liver carboxyesterase; |
potassium 4-nitrophenolate
acetic acid
A
4-nitro-phenol
B
potassium acetate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; Equilibrium constant; Further equilibria; | |
In acetonitrile Equilibrium constant; |
potassium salt of p-nitrosophenol
acetic acid
A
p-nitrosophenol
B
potassium acetate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; Equilibrium constant; Further equilibria; |
di(4-acetoxybenzyl) methoxycarbonylmethylphosphonate
A
(4-hydroxyphenyl)methanol
B
potassium acetate
Conditions | Yield |
---|---|
In [D3]acetonitrile; water-d2 at 37℃; Mechanism; potassium phosphate buffer, porcine liver carboxyesterase; half-live; also with human plasma; |
A
(4-hydroxyphenyl)methanol
B
potassium acetate
C
dipotassium methylphosphonate
Conditions | Yield |
---|---|
In [D3]acetonitrile; water-d2 at 36.4℃; Mechanism; Rate constant; potassium phosphate buffer; half-live; also in the presence of porcine liver carboxyesterase; |
lithium 4-acetoxybenzyl methoxycarbonylmethylphosphonate
A
(4-hydroxyphenyl)methanol
B
potassium acetate
C
C3H5O5P(2-)*2K(1+)
Conditions | Yield |
---|---|
In [D3]acetonitrile; water-d2 at 37℃; Mechanism; potassium phosphate buffer, porcine liver carboxyesterase; half-live; also with human plasma and with S9 fraction of porcine brain; also without any enzyme (velocity constant); |
Conditions | Yield |
---|---|
With 18-crown-6 ether In acetonitrile at 15℃; Equilibrium constant; Thermodynamic data; ΔH(excit.), ΔS(excit.), ΔG(excit.); |
acetic anhydride
potassium salt of 2,3,5-trichlorophenol
A
potassium acetate
B
2,3,5-trichlorophenol acetate
Conditions | Yield |
---|---|
With 18-crown-6 ether In chlorobenzene at 25℃; Rate constant; Equilibrium constant; | |
In acetonitrile at 25℃; Kinetics; Equilibrium constant; |
Conditions | Yield |
---|---|
With 18-crown-6 ether In chlorobenzene at 25℃; Rate constant; Equilibrium constant; | |
In acetonitrile at 25℃; Kinetics; Equilibrium constant; |
Conditions | Yield |
---|---|
Amberlyst A27 In toluene at 95℃; for 20h; | 100% |
With dicyclohexano-18-crown-6 In acetonitrile at 60℃; for 0.5h; Product distribution; further reagents; | 85.4% |
With zirconium (benzyldiethylammoniomethylphosphonate chloride) phosphate In water; toluene at 88℃; for 15h; | 82.5% |
Conditions | Yield |
---|---|
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane at 40℃; for 24h; | 100% |
5,11,17,23,29,35-Hexa-p-tert-butyl-37,38,39,40,41,42-hexakis-(3,6,9-trioxadecyloxy)calix<6>arene In dichloromethane; water at 40℃; for 24h; | 100% |
"octopus-type" calixarene 1 In dichloromethane; water at 40℃; for 24h; Product distribution; other catalysts, content of water, other carboxylates; | 100% |
With ethanol | |
5,11,17,23,29,35-hexa-....-calix<6>arene In dichloromethane at 40℃; for 24h; influence of other catalysts; |
Conditions | Yield |
---|---|
With dipotassium peroxodisulfate; copper diacetate In acetic acid for 2h; Heating; | 100% |
Conditions | Yield |
---|---|
Sucrose-ethyleneoxide adducts In acetonitrile at 83℃; for 24h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O; | 100% |
With aluminum oxide at 196℃; for 0.0333333h; Irradiation; other long chain halides; | 99% |
With aluminum oxide at 196℃; for 0.0333333h; Irradiation; | 99% |
(S)-2,2'-bis(bromomethyl)-1,1'-binaphthyl
potassium acetate
(S)-2,2'-Bis-1,1'-binaphthyl
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 80℃; for 20h; | 100% |
With tetrabutylammomium bromide In N,N-dimethyl-formamide at 80℃; |
potassium acetate
methyl <1S-<1α,2α(Z),3α,4α>>-7-<3-<(tosyloxy)methyl>-7-oxabicyclo<2.2.1>hept-2-yl>-5-heptanoate
Methyl <1S-<1α,2α(Z),3α,4α>>-7-<3-<<(2-Oxo-2-ethyl)thio>methyl>-7-oxabicyclo<2.2.1>hept-2-yl>-5-heptenoate
Conditions | Yield |
---|---|
In tetrahydrofuran; dimethyl sulfoxide at 75℃; for 1.25h; | 100% |
potassium acetate
Conditions | Yield |
---|---|
With acetic anhydride for 96h; Yields of byproduct given; | A 100% B n/a |
With acetic anhydride In acetic acid at 25℃; for 72h; Yield given. Yields of byproduct given; |
Conditions | Yield |
---|---|
In acetone for 1h; | 100% |
Conditions | Yield |
---|---|
Sucrose-ethyleneoxide adducts In acetonitrile at 20℃; for 8h; Product distribution; further catalysts: PEG, DB18K6; further objects of study: phase-transfer catalysis; further solvents: toluene/H2O; | 100% |
With ammonium salt In neat (no solvent) for 2h; Ambient temperature; | 99% |
With tetradecane; potassium acetate; magnetic nanoparticle-supported crown ether In toluene at 80℃; for 8h; | 96% |
1,4-bis(decyloxy)benzene
potassium acetate
Acetic acid 4-acetoxymethyl-2,5-bis-decyloxy-benzyl ester
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In chloroform; acetonitrile Heating; | 100% |
potassium acetate
3-bromo-7-hydroxymethyl-9-fluorenone
Conditions | Yield |
---|---|
With sodium methylate In tetrahydrofuran; methanol for 1.25h; Ambient temperature; | 100% |
potassium acetate
D-3-O-trifluoromethanesulfonyl-1,2:4,5-di-O-isopropylidene-myo-inositol
1L-1-O-acetyl-2,3:5,6-di-O-isopropylidene-chiro-inositol
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide at 70℃; | 100% |
potassium acetate
D-3,6-di-O-trifluoromethanesulfonyl-1,2:4,5-di-O-isopropylidene-myo-inositol
(D)-2,5-di-O-acetyl-1,6:3,4-di-O-isopropylidene-allo-inositol
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide at 70℃; | 100% |
potassium acetate
(3Z)-3-(chloromethyl)-4-(4-chlorophenyl)but-3-en-2-one
Conditions | Yield |
---|---|
With 1-n-butyl-methylimidazolium tetrafluoroborate at 45 - 50℃; for 2h; | 100% |
potassium acetate
Conditions | Yield |
---|---|
With 1-n-butyl-methylimidazolium tetrafluoroborate at 45 - 50℃; for 2h; | 100% |
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl acetamide at 70℃; | 100% |
potassium acetate
Conditions | Yield |
---|---|
In acetone; acetonitrile for 0.75h; | 100% |
3-bromo-2-(bromomethyl)-1-nitrobenzene
potassium acetate
2-bromo-6-nitrobenzyl acetate
Conditions | Yield |
---|---|
In DMF (N,N-dimethyl-formamide) at 70℃; for 1h; | 100% |
In N,N-dimethyl-formamide at 70℃; for 1h; | |
In N,N-dimethyl-formamide at 80℃; for 4h; | 14.5 g |
1-(5-(bromomethyl)-1-methyl-1H-pyrazol-4-yl)ethanone
potassium acetate
(4-acetyl-1-methyl-1H-pyrazol-5-yl)methyl acetate
Conditions | Yield |
---|---|
18-crown-6 ether In acetonitrile at 20℃; for 20h; | 100% |
5-bromo-7-(bromomethyl)-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-indazole
potassium acetate
(5-bromo-1-((2-(trimethylsilyl)ethoxy)methyl)-1H-indazol-7-yl)methyl acetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20 - 40℃; for 1.16667h; | 100% |
tetrabutyl-ammonium chloride
potassium acetate
tetrabutylammonium acetate
Conditions | Yield |
---|---|
In methanol | 100% |
In methanol for 24h; Inert atmosphere; | |
In methanol for 24h; Inert atmosphere; |
2-(1-chloroethyl)-5-(3-chlorophenyl)-1,3,4-oxadiazole
potassium acetate
1-[5-(3-chlorophenyl)-1,3,4-oxadiazol-2-yl]ethyl acetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 24h; | 100% |
Conditions | Yield |
---|---|
In water at 20℃; for 12h; | 100% |
Conditions | Yield |
---|---|
In acetonitrile | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 1h; | 100% |
potassium acetate
1,4-bis(bromomethyl)-2,5-bis-(dodecyloxy)benzene
2,5-bis(acetyl methyl)-1,4-bis(dodecyloxy)benzene
Conditions | Yield |
---|---|
With N-butylammonium bromide In chloroform; acetonitrile for 2h; Reflux; | 100% |
With tetrabutylammomium bromide In chloroform; acetonitrile for 12h; Reflux; | 88% |
Conditions | Yield |
---|---|
In acetonitrile Reflux; | 100% |
potassium acetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 20℃; for 0.333333h; | 100% |
potassium acetate
Conditions | Yield |
---|---|
In dimethyl sulfoxide at 80℃; for 2h; | 100% |
Molecular Structure of Potassium Acetate (CAS NO.127-08-2):
IUPAC Name: potassium acetate
Empirical Formula: C2H3KO2
Molecular Weight: 98.1423
H bond acceptors: 2
H bond donors: 1
Freely Rotating Bonds: 0
Polar Surface Area: 37.3Å2
Flash Point: 40 °C
Enthalpy of Vaporization: 23.7 kJ/mol
Density: 1.57 g/cm3 at 25 °C(lit.)
Boiling Point: 117.1 °C at 760 mmHg
Vapour Pressure: 13.9 mmHg at 25°C
CAS Registry Number: 127-08-2
EINECS: 204-822-2
FEMA: 2920
Storage temp: Store at RT.
Melting point: 292°C
Water solubility: 2694 g/L (25°C)
Sensitive: Hygroscopic
Merck: 14,7605
BRN: 3595449
InChI
InChI=1/C2H4O2.K/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
Smiles
C(C)(=O)[O-].[K+]
Stability: Stability Deliquescent. Stable. Incompatible with strong oxidizing agents.
Product Categories: AlphabeticalMolecular Biology;Biological Buffers;BioUltra Buffers;BioUltraBiological Buffers;Buffer SolutionsProtein Structural Analysis;Molecular Biology Reagents;Optimization Reagents;X-Ray Crystallography;Alphabetical Listings;Flavors and Fragrances;O-P
Potassium Acetate (CAS NO.127-08-2) can be used as a deicer instead of chloride salts like calcium chloride or magnesium chloride. Potassium acetate offers the advantage of being less aggressive on soils and much less corrosive, and for this reason is preferred for airport runways. It is, however, more expensive. Potassium acetate is used as part of replacement protocols in the treatment of diabetic ketoacidosis because of its ability to break down into bicarbonate and help neutralize the acidotic state. It is the extinguishing agent used in class K fire extinguishers because of its ability to cool and form a crust over the burning oils. Besides used as a food additive (preservative, acidity regulator) found on food labels in the European Union.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LD50 | oral | 3250mg/kg (3250mg/kg) | American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969. |
Reported in EPA TSCA Inventory.
Moderately toxic by ingestion. When heated to decomposition it emits toxic fumes of K2O.
Hazard Codes of Potassium Acetate (CAS NO.127-08-2): Xi,T
Risk Statements: 36/37/38-25-23/24/25-21
R36/37/38:Irritating to eyes, respiratory system and skin.
R25 :Toxic if swallowed.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R21:Harmful in contact with skin.
Safety Statements: 26-36-24/25-45-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36:Wear suitable protective clothing.
S24/25:Avoid contact with skin and eyes.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
WGK Germany: 1
RTECS: AJ3325000
Hazard Note: Hygroscopic
TSCA: Yes
Potassium Acetate , with CAS number of 127-08-2, can be called Polycat 46 ; Acetic acid,compounds,potassium salt ; Catacyst LB ; Kaliumazetat ; Potassium acetate (TN) ; Potassium Acetate, Granular, U.S.P ; Potassium acetate ; Acetic acid, potassium salt . It is a colourless crystals or white powder.
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