Conditions | Yield |
---|---|
In ethanol Kinetics; shaking for 2-3 days;; | A 80% B n/a |
In ethanol Kinetics; at 100°C;; | A >99 B n/a |
A
(Cp3i)2Pb
B
potassium iodide
Conditions | Yield |
---|---|
In tetrahydrofuran KCp3i and PbI2 were added to THF and suspn. was stirred for 12 h; THF was removed under vac., residue was extd. with hexane, filtered andhexane was removed; | A 68% B n/a |
potassium hexafluorophosphate
[CpFe(dppe)(CN)]
methyl iodide
A
[CpFe(dppe)(η(1)-CNCH3)]PF6
B
potassium iodide
Conditions | Yield |
---|---|
In tetrahydrofuran addn. of KPF6 and MeI to soln. of Fe complex, stirring (room temp., 14 h), filtration, solvent removal (vac.); extn. into CH2Cl2, concn. (vac.), pptn. on Et2O addn., washing (Et2O); elem. anal.; | A 60% B n/a |
Conditions | Yield |
---|---|
potassium polymanganite(IV) In solid byproducts: O2; mixt. of KIO3 and potassium polymanganate heated (400-600°C, 2h, air); X-ray diffraction; | A 1% B n/a |
Conditions | Yield |
---|---|
With potassium hydroxide In not given evaporation of solvent then glowing, remainder of KOH neutralized with HI; | |
With potassium sulfite; potassium carbonate In not given byproducts: K2SO4, CO2; iodine containing activated charcoal and theoretic amounts of K2CO3 and K2SO3 used; filtration, evaporation of solvent; | |
With potassium hydroxide; hydrogen sulfide In not given soln. of KOH saturated with I2, then H2S introduced into soln. of iodide-iodite; |
Conditions | Yield |
---|---|
With potassium sulfide In water solid K2S used; evaporation of solvent; | |
With potassium sulfide In ethanol solid K2S used; evaporation of solvent; |
Conditions | Yield |
---|---|
With potassium carbonate In not given filtration and evaporation of solvent; |
Conditions | Yield |
---|---|
In not given on presence of water;; |
Conditions | Yield |
---|---|
luminous phenomenon and development of heat; | |
In neat (no solvent) 400 up to 500 °C;; | |
In neat (no solvent) 400 up to 500 °C;; |
Conditions | Yield |
---|---|
In neat (no solvent) primary reactn. in high dild. flames;; | |
In neat (no solvent) primary reactn. in high dild. flames;; |
Conditions | Yield |
---|---|
In ammonia byproducts: N2, H2; | |
In ammonia byproducts: N2, H2; NH3 (liquid); |
Conditions | Yield |
---|---|
With water neutralization of destillated HI with KHCO3, evaporation; product free from chloride, iodate and sulfate; |
Conditions | Yield |
---|---|
With potassium hydroxide In not given byproducts: iron oxide; Electrochem. Process; reduction in concd. soln. with iron and copper plates, during several days; pure product; | |
With potassium hydroxide In not given byproducts: iron oxide; complete reduction in warm; |
Conditions | Yield |
---|---|
With potassium carbonate In not given filtration and evaporation of solvent; |
Conditions | Yield |
---|---|
With potassium hydroxide In not given partial reduction; | |
With potassium hydroxide In not given Electrochem. Process; reduction in concd. soln. with zinc and coppper galvanic cell; pure product; |
Conditions | Yield |
---|---|
With potassium hydroxide In not given sufficient amount of Fe iodide used, heating; filtration, evaporation of solvent, product is free from iodate; | |
With potassium carbonate In ethanol introduction of I2 into soln. of K2CO3, then mixing with soln. of FeI2; | |
With potassium carbonate In not given introduction of I2 into soln. of K2CO3, then mixing with soln. of FeI2; |
Conditions | Yield |
---|---|
With potassium carbonate In not given I2 dissolved in FeI2 then KI precipitated with K2CO3; filtration of Fe3O4, neutralization of strong alkaline remainder with HI; |
Conditions | Yield |
---|---|
In potassium hydroxide byproducts: O2; dissolving I2 in KOH soln., evaporation; melting KI-KIO3 mixture;; | |
In neat (no solvent) byproducts: H2O, O; reactn. of iodine with KOH only at red-heat;; | |
In neat (no solvent) byproducts: H2O, O; reactn. of iodine with KOH only at red-heat;; | |
In potassium hydroxide byproducts: O2; aq. KOH; dissolving I2 in KOH soln., evaporation; melting KI-KIO3 mixture;; |
Conditions | Yield |
---|---|
In ethanol burnt, free from sulfide, pulverized antimonyl potassium tartrate used; pure product; |
Conditions | Yield |
---|---|
glowing; | <99 |
Conditions | Yield |
---|---|
heating; | |
glowing; | <99 |
heating; |
Conditions | Yield |
---|---|
equilibrium reaction; above m.p. of mixt reaction complete; |
Conditions | Yield |
---|---|
With hydrogen sulfide; potassium carbonate In not given melting; | |
With potassium carbonate melting; | |
With potassium sulfide; potassium carbonate In not given melting; |
Conditions | Yield |
---|---|
equilibrium reaction; above m.p. of mixt reaction complete; |
Conditions | Yield |
---|---|
equilibrium reaction; above m.p. of mixt. reaction complete; |
Conditions | Yield |
---|---|
at 100 ° C; |
Conditions | Yield |
---|---|
With potassium hydroxide byproducts: Cu2O, H2O; boiling; filtration, precipitation of Cu2O, reminder of Cu treated with Mg pulver, excess of KOH neutralized with H2SO4 or HI, crystallization; | |
With hydrogen sulfide; potassium carbonate In not given | |
With potassium carbonate In not given byproducts: Cu2O, CO2; free from chloride soln. of CuI used; filtration, remainder of Cu precipitated with H2S, crystallization; | |
With H2S; K2CO3 | |
With K2CO3 |
Conditions | Yield |
---|---|
With carbon dioxide; potassium carbonate In water from sea-weed extracted NaI used; | |
With K2CO3; CO2 In water |
Conditions | Yield |
---|---|
In neat (no solvent) wall reactn. in high dild. flames;; | |
In gaseous matrix Kinetics; He matrix; resonance fluorescence spectroscopic monitoring; | |
In neat (no solvent) wall reactn. in high dild. flames;; |
potassium tetrachloroplatinate(II)
potassium iodide
Conditions | Yield |
---|---|
In water at 50℃; for 0.0833333h; Darkness; | 100% |
In water at 30℃; for 0.5h; | |
In water for 0.5h; |
Conditions | Yield |
---|---|
In water for 0.0833333h; Darkness; Heating; | 100% |
In water | |
In water for 0.25h; |
Conditions | Yield |
---|---|
100% | |
100% | |
Reactivity of KI depends on moisture content of Cl2.; | |
Reactivity of KI depends on moisture content of Cl2.; |
potassium iodide
bisbiphenylchromium iodide
Conditions | Yield |
---|---|
In chloroform; water | 100% |
In chloroform; water | 100% |
Conditions | Yield |
---|---|
In not given byproducts: iodine; weakly acidic, warm soln.,; | 100% |
In not given byproducts: iodine; weakly acidic, warm soln.,; | 100% |
Conditions | Yield |
---|---|
In acetone large excess of KI; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In acetone large excess of KBr; elem. anal.; | 100% |
PtCl2(CH3SCH2CH2SC6F5)2
potassium iodide
PtI2(CH3SCH2CH2SC6F5)2
Conditions | Yield |
---|---|
In acetone large excess of KI; elem. anal.; | 100% |
cis-dichloro[1,2-bis(methylthio)1,1-difluoro-ethane] platinum(II)
potassium iodide
PtI2(CH3SCF2CH2SCH3)
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
cis-[3,4-bis(trifluoromethyl)-2,5-dithiahexane]dichloroplatinum(II)
potassium iodide
PtI2(CH3SCH(CF3)CH(CF3)SCH3)
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
PdCl2(CH3SCH(CF3)CH(CF3)SCH3)
potassium iodide
PdI2(CH3SCH(CF3)CH(CF3)SCH3)
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
cis-dichloro{1,1,1-trifluoro-2,3-bis(methylthio)propane}platinum(II)
potassium iodide
PtI2(CH3SCH(CF3)CH2SCH3)
Conditions | Yield |
---|---|
In acetone elem. anal.; | 100% |
2,2'-bipyridine(2,2':6',2''-terpyridine)chlororuthenium(II) hexafluorophosphate
potassium iodide
[Ru(2,2':3'2''-terpyridine)(2,2'-bipyridine)I]PF6
Conditions | Yield |
---|---|
In water; acetone a mixt. of complex and KI in acetone and water was refluxed overnight, NH4PF6 in min water was added; ppt. was collected while it was hot, washed with water, dried; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 18h; | 100% |
bis(1,5-cyclooctadiene)diiridium(I) dichloride
potassium iodide
Conditions | Yield |
---|---|
In acetone at 20℃; for 3h; | 100% |
Conditions | Yield |
---|---|
Stage #1: copper(l) iodide; lead(II) nitrate; potassium iodide In water for 2h; Stage #2: at 620℃; for 72h; Sealed tube; | 100% |
potassium iodide
Conditions | Yield |
---|---|
With potassium hexamethylsilazane In tetrahydrofuran at 20℃; for 18h; Inert atmosphere; Glovebox; Darkness; | 100% |
potassium tetrachloroplatinate(II)
potassium iodide
μ-iodo(μ-1,1'-[(1H-pyrazole-1-ido-3,5-diyl)bis(methylene)]bis(2-methoxyethylamino))diiododiplatinum(II)
Conditions | Yield |
---|---|
With sodium hydroxide In water to stirred aq. soln. K2PtCl4 in water KI was added, soln. ligand in water and NaOH were added dropwise, stirred dor 28 h at room temp.; ppt. was filtered, washed with water and dried at 60°C in high vac.; elem. anal.; | 99.7% |
Conditions | Yield |
---|---|
In methanol; water methanol soln. of org. compd. addn. to soln. of I- and Au-compds. in methanol-water; ppt. filtration off, washing, drying (in darkness); elem. anal.; | 99% |
potassium tetrachloropalladate(II)
iodine
potassium iodide
1,10-dimethyl-4,7,13,16-tetraoxa-1,10-dithiacyclooctadecane hexaiodopalladate(IV)
Conditions | Yield |
---|---|
In methanol; water methanol soln. of org. compd. addn. to soln. of I- and Pd compds. in methanol-water; ppt. filtration off, washing, drying (in darkness); elem. anal.; | 99% |
potassium iodide
Conditions | Yield |
---|---|
In dichloromethane under N2; large excess of KI added to soln. of Pt complex in CH2Cl2; stirred for 4 h; ppt. removed by filtration; solvent removed under reduced pressure; | 99% |
potassium iodide
Conditions | Yield |
---|---|
In not given Ar; 4 equiv. of KI, 24 h at 60°C; | 99% |
(η(5)-1-ethylindenyl)Ni(PPh3)Cl
potassium iodide
(η(3)-1-ethylindenyl)Ni(PPh3)I
Conditions | Yield |
---|---|
In tetrahydrofuran; acetone 1.2 equiv. of KI in acetone was added to THF soln. of Ni-compd., under Ar, stirring at 50 °C for 12 h; soln. was evapd. to dryness, extn. with Et2O, evapn., elem. anal.; | 99% |
chloro(trimethylamine-isocyanoborane)gold(I)
1,2-dichloro-ethane
potassium iodide
Conditions | Yield |
---|---|
In dichloromethane; water (Ar); a soln. of Au complex in CH2Cl2 poured into an aq. soln. of KI, stirred for 18 h; phases sepd., the aq. phase extd. (CH2Cl2), the org. exts. combined, recrystd. (1,2-dichloroethane and pentane); elem. anal.; | 99% |
potassium iodide
Conditions | Yield |
---|---|
In dichloromethane 1) KI (excess), 2) (Cp2Fe)PF6 (2 equiv), room temp.; | 99% |
potassium iodide
Conditions | Yield |
---|---|
In dichloromethane under N2; large excess of KI added to soln. of Pd complex in CH2Cl2; stirred for 4 h; ppt. removed by filtration; solvent removed under reduced pressure; | 99% |
potassium iodide
Conditions | Yield |
---|---|
In not given according to J.G Erdman, V.G. Ramsey, N.W. Kalenda, W.E. Hanson, J. Am. Chem. Soc. 78 (1956) 5844; porphyrin (0.14 mmol) reacted with VOSO4 (1.84 mmol); cooled; evapd. (vac.); pptd. with KI soln.; filtered; dried (vac.) to const. wt.; | 99% |
Conditions | Yield |
---|---|
In water hot soln. KI in water was added to hot aq. soln. AgNO3 and ethylenethiourea; ppt. was filtered while warm and washed with water; elem. anal.; | 99% |
Potassium iodide , with CAS number of 7681-11-0, can be called AI3-52931; Asmofug E; Dipotassium diiodide; Iodure de potassium; Potassium monoiodide; Thyro-Block; Potide; Tripotassium triiodide. Potassium iodide is an inorganic compound with the chemical formula KI. KI is also used as a fluorescence quenching agent in biomedical research because of collisional quenching by its iodide ion. Potassium iodide is used medicinally in tablets.Potassium iodide is an inorganic compound with formula KI.
Properties about Potassium iodide are: (1)mp:113 °C(lit.); (2)bp: 184 °C(lit.); (3)density: 1.32 g/mL at 25 °C; (4)vapor density: 9 (vs air); (5)vapor pressure: 0.31 mm Hg ( 25 °C); (6)refractive index: 1.677; (7)Fp: 1330°C; (8)storage temp. : Store at RT.; (9)solubility H2O: 1 M at 20 °C, clear, colorless; (10)Water Solubility: 1.43 kg/L; (11)Merck: 14,7643
Preparation of Potassium iodide: Potassium iodide is ionic, K+I−. It crystallises in the sodium chloride structure. It is produced industrially by treating KOH with iodine.
Uses of Potassium iodide: Potassium iodide is used to loosen and break up mucus in the airways. This helps you cough up the mucus so you can breathe more easily if you have long-term lung problems (e.g., asthma, chronic bronchitis, emphysema). This medication is known as an expectorant.
Potassium iodide is also used along with antithyroid medicines to prepare the thyroid gland for surgical removal, to treat certain overactive thyroid conditions (hyperthyroidism), and to protect the thyroid in a radiation exposure emergency. It works by shrinking the size of the thyroid gland and decreasing the amount of thyroid hormones produced.
When you are using this chemical, please be cautious about it as the following:
1. Avoid contact with skin and eyes;
2. Wear suitable protective clothing;
3. In case of accident or if you feel unwell, seek medical advice immediately (show label where possible);
4. Wear suitable protective clothing, gloves and eye/face protection;
You can still convert the following datas into molecular structure:
(1)InChI=1S/HI.K/h1H;/q;+1/p-1;
(2)InChIKey=NLKNQRATVPKPDG-UHFFFAOYSA-M;
(3)Smiles[K+].[I-];
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LDLo | intraperitoneal | 1117mg/kg (1117mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES | Journal of Pharmacology and Experimental Therapeutics. Vol. 120, Pg. 171, 1957. |
mouse | LDLo | oral | 1862mg/kg (1862mg/kg) | BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Journal of Pharmacology and Experimental Therapeutics. Vol. 120, Pg. 171, 1957. |
rabbit | LDLo | oral | 916mg/kg (916mg/kg) | Journal of Pharmacology and Experimental Therapeutics. Vol. 30, Pg. 407, 1927. | |
rat | LDLo | intravenous | 167mg/kg (167mg/kg) | BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD | Archiv fuer Experimentelle Pathologie und Pharmakologie. Vol. 96, Pg. 292, 1923. |
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