Sodium bisulfate monohydrate supplier

Name
Sodium bisulfate monohydrate
EINECS 231-665-7
CAS No. 10034-88-5
Article Data7
CAS DataBase
Density 2.103
Solubility 670 g/L in water
Melting Point 58 °C
Formula NaHSO₄^.H₂O
Boiling Point 330 °C at 760 mmHg
Molecular Weight 138.077
Flash Point
Transport Information UN 3260 8/PG 3
Appearance white adhering crystals
Safety 24-26
Risk Codes 41
Molecular Structure
Hazard Symbols Xi
Synonyms Sulfuricacid, monosodium salt, monohydrate (8CI,9CI);Sodium bisulfate hydrate;Sodium sulfate monohydrate;Sodium hydrogen sulfate hydrate (1:1:1);
PSA 95.04000
LogP 0.02110

Synthetic route

: 7664-93-9
sulfuric acid

: 7732-18-5
water

: 7647-14-5
sodium chloride

A: 10034-88-5
sodium hydrogensulfate monohydrate

: 7681-38-1
Na hydrogensulfate

Conditions

Conditions	Yield
In water Kinetics; exposure of powdered NaCl to H2SO4 soln. with compn. of NaCl:H2O:H2SO4 of 2:8:1 for 24 h at 85% rel. humidities; not isolated, detn. by Raman spectroscopy;

...Expand

: 7664-93-9
sulfuric acid

: 7732-18-5
water

: 7647-14-5
sodium chloride

A: 7647-01-0
hydrogenchloride

B: 10034-88-5
sodium hydrogensulfate monohydrate

Conditions

Conditions	Yield
In water Kinetics; exposure of powdered NaCl to H2SO4 soln. with compn. of NaCl:H2O:H2SO4 of 2:20:1 at 85% rel. humidities; not isolated, detn. by Raman spectroscopy;

...Expand

: 7664-93-9
sulfuric acid

: 7732-18-5
water

: 7647-14-5
sodium chloride

: 10034-88-5
sodium hydrogensulfate monohydrate

Conditions

Conditions	Yield
In sulfuric acid Kinetics; exposure of NaCl with 96 wt% H2SO4 (0.5:1 H2SO4:NaCl) in dry bag; storage in desiccator for several days; exposure to environment of 100% rel. humidities for 40 min; not isolated, detn. by Raman spectroscopy;

...Expand

: Glauber's salt

: oxalic acid

A: 10034-88-5
sodium hydrogensulfate monohydrate

B: 16009-94-2
sodium hydrogen oxalate monohydrate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O; mixing oxalic acid and Glauber's salt; completation of reaction after 24 h;;
In not given byproducts: H2O; reaction of Glauber's salt with oxalic acid;;
In neat (no solvent) byproducts: H2O; mixing oxalic acid and Glauber's salt; completation of reaction after 24 h;;

...Expand

: 7757-82-6
sodium sulfate

: 10034-88-5
sodium hydrogensulfate monohydrate

Conditions

Conditions	Yield
In water crystallization from an acidic aq. soln. of Na2SO4 at ambient temperature;;
In water crystallization from an acidic aq. soln. of Na2SO4 at ambient temperature;;

: 10034-88-5
sodium hydrogensulfate monohydrate

: 6737-42-4
1,3-bis-(diphenylphosphino)propane

: 7732-18-5
water

: 3375-31-3
palladium diacetate

: 874569-73-0
[Pd(SO4)(1,3-bis(diphenylphosphino)propane)]

Conditions

Conditions	Yield
In water; acetone acetone soln. of ligand added dropwise to soln. of Pd compd. (1:1), excess NaHSO4 in water added; pptd., stirred for 30 min, filtered off, washed (acetone/water=5/2, Et2O), dried (vac.), elem. anal.;	90%

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 16844-99-8
trimethylsilyl butyrate

: ammonium chloride

: 830-13-7
cyclododecanone

: 101-83-7
N-cyclohexyl-cyclohexanamine

: 78293-77-3, 79616-92-5
Cyclododecylene acetic acid

Conditions

Conditions	Yield
With hydrogenchloride In tetrahydrofuran; n-butyllithium	79%

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 1,11α,15S-tris(tetrahydropyran-2-yloxy)-9α-hydroxy-15-cyclopentyl-16,17,18,19,20-pentanorprost-trans-13-en-6-one

: 1,11α,15S-tris(tetrahydropyran-2-yloxy)-15-cyclopentyl-16,17,18,19,20-pentanorprost-trans-13-ene-6,9-dione

Conditions

Conditions	Yield
With pyridine In dichloromethane	62.6%

: 10034-88-5
sodium hydrogensulfate monohydrate

: 4447-60-3
Triisopropoxymethan

: 6831-82-9
potassium isopropoxide

: 120-92-3
cyclopentanone

: 1-isopropoxy-1-cyclopentene

Conditions

Conditions	Yield
In isopropyl alcohol	51%

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 62247-21-6
3-amino-3-(pyridin-3-yl)propanoic acid

: 24424-99-5
di-tert-butyl dicarbonate

: 3-[(tert-butoxy)carbonyl]amino-3-(3'-pyridyl)propionic acid

Conditions

Conditions	Yield
With sodium hydroxide; magnesium sulfate In tetrahydrofuran; water

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 7144-05-0
4-Aminomethylpiperidine

: 77445-06-8
1-acetyl-4-aminomethylpiperidine

Conditions

Conditions	Yield
With sodium hydroxide; acetic anhydride; benzaldehyde; triethylamine In water; benzene

: 10034-88-5
sodium hydrogensulfate monohydrate

: 141-52-6
sodium ethanolate

: 78-84-2
isobutyraldehyde

: 105-53-3
diethyl malonate

: 35113-48-5
2-isopropyl-5,5-bis(carboethoxy)-1,3-dioxane

Conditions

Conditions	Yield
With sulfuric acid; trimethyl orthoformate; paraformaldehyde In ethanol

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: methyl (1-hydroxymethyl-1,2,3,4-tetrahydronaphthalen-5-yl) oxyacetate

: 1333-82-0
chromium(VI) oxide

: Methyl (1-formyl-1,2,3,4-tetrahydronaphthalen-5-yl) oxyacetate

Conditions

Conditions	Yield
With pyridine In dichloromethane

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 109-87-5
Dimethoxymethane

: 123-72-8
butyraldehyde

: 699-25-2
3,5-diethylpyridine

Conditions

Conditions	Yield
In ammonium hydroxide; dichloromethane

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 74-79-3
L-arginine

: 24424-99-5
di-tert-butyl dicarbonate

: 13726-76-6
t-butyloxycarbonyl-L-arginine

Conditions

Conditions	Yield
With sodium hydroxide In 1,4-dioxane; water; butan-1-ol

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 61302-47-4
methyl 7-((1R,2S,3R,5S)-5-acetoxy-2-hydroxymethyl-3-((tetrahydro-2H-pyran-2-yl)oxy)cyclopentyl)heptanoate

: 61302-48-5
methyl 7-((1R,2R,3R,5S)-5-acetoxy-2-formyl-3-((tetrahydro-2H-pyran-2-yl)oxy)cyclopentyl)heptanoate

Conditions

Conditions	Yield
With pyridine In dichloromethane; ethyl acetate; benzene

: 10034-88-5
sodium hydrogensulfate monohydrate

: 61218-09-5
2α-(6-methoxycarbonyl-hex-cis-2-enyl)-3β-hydroxymethyl-4α-(2-tetrahydropyranyloxy)-cyclopentan-1α-ol

: 75-36-5
acetyl chloride

: 61218-11-9
2α-(6-methoxycarbonylhex-cis-2-enyl)-3β-acetoxymethyl-4α-(2-tetrahydropyranyloxy)cyclopentan-1α-ol

Conditions

Conditions	Yield
With pyridine In methanol; dichloromethane

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: Methyl 9α-hydroxy-11α,15 S-bis(2-tetrahydropyranyloxy)-15-(3-propylcyclopentyl)-16,17,18,19,20-pentanorprosta-cis-5,trans-13-dienoate

: Methyl 9-oxo-11α,15S-bis(2-tetrahydropyranyloxy)-15-(3-propylcyclopentyl)-16,17,18,19,20-pentanorprosta-cis-5, trans-13-dienoate

Conditions

Conditions	Yield
With pyridine In dichloromethane

: 10034-88-5
sodium hydrogensulfate monohydrate

: 14782-43-5
2-(Trimethylsilyl)butansaeure-ethylester

: 72277-17-9
(+/-)-ethyl 4-methyl-3-phenylpentanoate

Conditions

Conditions	Yield
With hydrogenchloride; lithium diisopropyl amide; palladium-carbon In tetrahydrofuran; methanol; ethyl acetate

: 10034-88-5
sodium hydrogensulfate monohydrate

: kaolin

: aluminium sodium sulfate

Conditions

Conditions	Yield
In solid byproducts: SiO2; investigation of solid state react. of kaolin and NaHSO4*H2O by DTA and thermogravimetry (up to 700 °C);; X-ray diffraction;

: 10034-88-5
sodium hydrogensulfate monohydrate

: kaolin

: aluminium sodium sulfate * 1.5 H2O

Conditions

Conditions	Yield
In solid byproducts: SiO2; investigation of solid state react. of kaolin and NaHSO4*H2O by DTA and thermogravimetry (closed vessel, low temp.);; X-ray diffraction;

: 10034-88-5
sodium hydrogensulfate monohydrate

: zirconium(IV) sulfate

: 4Na(1+)*Zr(4+)*4(SO4)(2-)*3H2O=Na4Zr(SO4)4*3H2O

Conditions

Conditions	Yield
In water addition of 30 g pure Zr sulfate under stirring to a solution of 57.95 g NaHSO4*H2O in 110 ml H2O at 30°C; increase of temperature to 43°C after 10 minutes, then decrease after 20 minutes to 37°C;; evacuation of the filtrate in vacuum, washing 3 times with 15 ml water at 10°C and drying on air; yield 29 g;;
In water addition of 30 g pure Zr sulfate under stirring to a solution of 57.95 g NaHSO4*H2O in 110 ml H2O at 30°C; increase of temperature to 43°C after 10 minutes, then decrease after 20 minutes to 37°C;; evacuation of the filtrate in vacuum, washing 3 times with 15 ml water at 10°C and drying on air; yield 29 g;;

: 10034-88-5
sodium hydrogensulfate monohydrate

: 7757-82-6
sodium sulfate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: H2O; transition point 58.54 °C;;
In neat (no solvent) byproducts: H2O; transition point 58.54 °C;;

: 10034-88-5
sodium hydrogensulfate monohydrate

: 7664-41-7
ammonia

A: ammonium sulfate

B: 7757-82-6
sodium sulfate

Conditions

Conditions	Yield
In melt
In melt

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: zirconium(IV) sulfate

: 4Na(1+)*4SO4(2-)*Zr(4+)*11H2O=2Na2SO4*Zr(SO4)2*11H2O

Conditions

Conditions	Yield
In water evaporation of a solution of 10 g Zr sulfate and 16.8 g NaHSO4 in 40 ml H2O at room temperature over H2SO4 with formation of a transparent syrup;; solidifying on scrapeing with a glass stick; drying on air;;

: 10034-88-5
sodium hydrogensulfate monohydrate

: hydrous zirconium oxide

: 4Na(1+)*4SO4(2-)*Zr(4+)*4H2O=2Na2SO4*Zr(SO4)2*4H2O

Conditions

Conditions	Yield
In not given addition of freshly precipitated Zr dioxide hydrate to a boiling concentrated solution of NaHSO4;; precipitation on cooling down of Zr sulfate, then of Na-Zr-sulfate, finally precipitation of the excess of hydrogensulfate;;
In not given addition of freshly precipitated Zr dioxide hydrate to a boiling concentrated solution of NaHSO4;; precipitation on cooling down of Zr sulfate, then of Na-Zr-sulfate, finally precipitation of the excess of hydrogensulfate;;

: 10034-88-5
sodium hydrogensulfate monohydrate

: 7681-38-1
Na hydrogensulfate

Conditions

Conditions	Yield
In neat (no solvent) heating NaHSO4*H2O to 120°C for 48 h;
In neat (no solvent, solid phase) NaHSO4*H2O heated at 420-440 K for 24 h;

: 10034-88-5
sodium hydrogensulfate monohydrate

: 11113-50-1
boric acid

: 5Na(1+)*BO16S4(5-)

Conditions

Conditions	Yield
at 399.84℃; for 12h;

: boron trioxide

: 10034-88-5
sodium hydrogensulfate monohydrate

: fuming sulphuric acid

: BNaO14S4

Conditions

Conditions	Yield
at 20℃;

...Expand

: 10034-88-5
sodium hydrogensulfate monohydrate

: 112926-00-8, 7631-86-9
silica gel

: Na(1+)*HSO4(1-)*SiO2 = NaHSO4*SiO2

Conditions

Conditions	Yield
In water Heating; Inert atmosphere;
at 20℃; for 0.25h;

Sodium bisulfate monohydrate Specification

The Sodium bisulfate monohydrate, with the CAS registry number 10034-88-5 and EINECS registry number 231-665-7, has the systematic name of sodium hydrogen sulfate hydrate (1:1:1). It is a kind of white adhering crystals which is sensitive to moisture. And the molecular formula of this chemical is NaHSO₄^.H₂O.

The physical properties of Sodium bisulfate monohydrate are as followings: (1)ACD/LogP: -1.03; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -5.53; (4)ACD/LogD (pH 7.4): -5.53; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)#H bond acceptors: 4; (8)#H bond donors: 2; (9)#Freely Rotating Bonds: 0; (10)Polar Surface Area: 71.98 Å²; (11)Enthalpy of Vaporization: 62.94 kJ/mol; (12)Boiling Point: 330 °C at 760 mmHg; (13)Vapour Pressure: 3.35E-05 mmHg at 25°C.

Preparation of Sodium bisulfate monohydrate: Thenardite reacts with sulphuric acid, and after a series of Filtration, crystallization, separation, drying, you can get the Sodium hydrogen sulfate monohydrae.
Na₂SO₄+H₂SO₄→2NaHSO₄

Applications of Sodium bisulfate monohydrate: It is usually used as dyeing auxiliaries for acid dye in printing and dyeing industry, fluxing agent for mineral decomposition in metallurgy industry, and disinfectants & detergents in medical industry.

You should be cautious while dealing with this chemical. It may cause serious damage to eyes. Therefore, you had better take the following instructions: Avoid contact with skin, and in case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Na+].[O-]S(=O)(=O)O.O
(2)InChI: InChI=1/Na.H2O4S.H2O/c;1-5(2,3)4;/h;(H2,1,2,3,4);1H2/q+1;;/p-1
(3)InChIKey: JXHZRQHZVYDRGX-REWHXWOFAC

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	193mg/kg (193mg/kg)		Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 257, Pg. 791, 1963.

Product Name

Sodium bisulfate monohydrate

Synthetic route

Sodium bisulfate monohydrate Specification

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