Stannous chloride dihydrate supplier

Name
Stannous chloride dihydrate
EINECS 231-868-0
CAS No. 10025-69-1
Article Data14
CAS DataBase
Density 2.71 g/cm³
Solubility Water: 1187 g/L (20 °C)
Melting Point 37-38 °C (dec.)(lit.)
Formula Cl₂H₄O₂Sn
Boiling Point 100 °C at 760 mmHg
Molecular Weight 225.647
Flash Point
Transport Information UN 3260 8/PG 3
Appearance Colorless to white, odorless solid
Safety 26-36/37/39-45
Risk Codes 22-34
Molecular Structure
Hazard Symbols C
Synonyms Stannous chloride;Stannouschloride dihydrate;Stannous dichloride dihydrate;Tin chloride dihydrate;Tindichloride dihydrate;Tin(II) chloridedihydrate;
PSA 18.46000
LogP 0.86960

Synthetic route

: 7646-78-8
tin(IV) chloride

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
With hydrogen In water byproducts: SnO, HCl; formation with SnO at effect of H2 at 270°C and 110 at on aq. SnCl4-soln. for 3.5 h;; evaporation of the HCl-satd. soln.;;	75%

: 7732-18-5
water

: tin(ll) chloride

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In water formation at dissolving of SnCl2 in H2O; obtaining at evaporation of the soln.;;
In hydrogenchloride pptn. at cooling down of a 80% SnCl2-soln. in aq. HCl;;
In hydrogenchloride pptn. at cooling down of a 80% SnCl2-soln. in aq. HCl;;

: 7647-01-0
hydrogenchloride

: 7440-31-5
tin

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In hydrogenchloride formation at dissolving of Sn in concd. HCl-soln.;;
In hydrogenchloride formation at effect of HCl on granulated Sn and evaporation of the cond. Sn-salt-soln. in Sn-pans with granulated Sn;;

: 7440-31-5
tin

: 7782-50-5
chlorine

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In not given formation at direct chlorination of granulated Sn with Cl2 in an app. of Cu and rustless steel; reduction of the formed SnCl4-soln. with metallic Sn at 90-100°C under stirring;; crystallisation and centrifugation at 15-20°C;;

: dichloro(acetylacetone)tin(II) dihydrate

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In ethanol soln. of SnHacacCl2*2H2O in ethanol evapd. and residue dried at 333 K; elem. anal.;
In neat (no solvent) compd. decompd. at 510-563 K; detn. by XRD;

: (x)Cl2Sn*(x)H2O

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
With hydrogen Electrochem. Process; under H2;

: 7647-01-0
hydrogenchloride

: tin

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In hydrogenchloride no formation at dissolving of pure α-Sn (99.997 %) in concd. HCl (37 %) at -17°C;;	0%

: 7647-01-0
hydrogenchloride

: tin

: 10025-69-1
tin(II) chloride dihdyrate

Conditions

Conditions	Yield
In hydrogenchloride formation at dissolving of pure β-Sn (99.997 %) in concd. HCl (37 %) at -17°C; crystallisation at 20°C;;

: 10025-69-1
tin(II) chloride dihdyrate

: ((CN(C6H4))C(C4H2N)C(C4H2NH)((C6H4)OCH3))2

: 1233863-52-9
SnCl2((CN(C6H4))C(C4H2N)C(C4H2N)((C6H4)OCH3))2

Conditions

Conditions	Yield
react. SnCl2*2H2O and ligand in pyridine;	100%

: 10025-69-1
tin(II) chloride dihdyrate

: 110452-48-7
5,10,15,20-tetrakis(p-tert-butylphenyl)porphyrin

: C60H60Cl2N4Sn

Conditions

Conditions	Yield
With pyridine for 3h; Reflux;	100%

: 10025-69-1
tin(II) chloride dihdyrate

: Rh7(3-)*16CO={Rh7(CO)16}(3-)

A: [Rh12(μ12-Sn)(CO)27](4-)

B: [Rh12(μ10-Sn)(CO)23(μ-Cl)2](4-)

Conditions

Conditions	Yield
In not given (N2);	A 99% B 99%

...Expand

: 10025-69-1
tin(II) chloride dihdyrate

: 2(CH3)(C6H5)3P(1+)*PtCl4(2-) = [(CH3)(C6H5)3P]2[PtCl4]

: methyltriphenylphosphonium cis-dichlorobis(trichlorostannato)platinate(II)

Conditions

Conditions	Yield
In acetone mixt. of Pt complex and SnCl2*2H2O covered with acetone, stood for 2 h at room temp.; soln. filtered, CCl4 added, recrystd. from MeOH; elem. anal.;	99%

: 148-24-3
8-quinolinol

: 10025-69-1
tin(II) chloride dihdyrate

: 12148-41-3
bis(8-hydroxyquinolinate)tin(II)

Conditions

Conditions	Yield
In ethanol N2-atmosphere; pptn. on dropwise addn. of SnCl2 to ligand (room temp., stirring); washing (EtOH, water), drying (vac., 1 h);	99%

: 10025-69-1
tin(II) chloride dihdyrate

: 149-30-4
2-Mercaptobenzothiazole

: 2C7H4NS2(1-)*Sn(2+)

Conditions

Conditions	Yield
In toluene Milling; Green chemistry;	99%

: 10025-69-1
tin(II) chloride dihdyrate

: 5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2(2)-(4-[(trimethylsilyl)ethynyl]phenyl)-2(1)H-imidazo[4,5-b]porphyrin

: dichloro[5,10,15,20-tetrakis(3,5-di-tert-butylphenyl)-2(2)-(4-[(trimethylsilyl)ethynyl]phenyl)-2(1)H-imidazo[4,5-b]porphyrinato]tin(IV)

Conditions

Conditions	Yield
With air In N,N-dimethyl-formamide a soln. of a ligand (0.184 mmol) and Sn(II)-contg. compd. (2.43 mmol) inN,N-dimethylformamide was heated at reflux for 5 h; the mixt. was cooled, H2O was added; the mixt. was left overnight; then it was filtered, the filtrate extd. with CH2Cl2; the org. phase was sepd., washed with water, dried over anhyd. Na2SO4, filtered, evapd.; extn. was repeated was repeated once more;	95%

Yield

With air In N,N-dimethyl-formamide a soln. of a ligand (0.184 mmol) and Sn(II)-contg. compd. (2.43 mmol) inN,N-dimethylformamide was heated at reflux for 5 h; the mixt. was cooled, H2O was added; the mixt. was left overnight; then it was filtered, the filtrate extd. with CH2Cl2; the org. phase was sepd., washed with water, dried over anhyd. Na2SO4, filtered, evapd.; extn. was repeated was repeated once more;

95%

: 124-43-6
sodium pyrophosphate

: 10025-69-1
tin(II) chloride dihdyrate

: tin(II) pyrophosphate

Conditions

Conditions	Yield
In water at 60℃; for 0.5h;	95%

: 10025-69-1
tin(II) chloride dihdyrate

: [5,5'10,10',15,15',20,20'-octakis(3,5-di-tert-butylphenyl)-4''H,8''H-1'',5''-methano[1'',5'']diazocino[2'',3''-b:6'',7''-b']bisporphyrinato]zinc(II)

: dichloro[5,5'10,10',15,15',20,20'-octakis(3,5-di-tert-butylphenyl)-4''H,8''H-1'',5''-methano[1'',5'']diazocino[2'',3''-b:6'',7''-b']bisporphyrinato]tin(IV)zinc(II)

Conditions

Conditions	Yield
With air In pyridine the mixt. of Sn(II)-contg. compd. (0.153 mmol) and Zn(II)-contg. compd. (0.163 mmol) in pyridine was heated at reflux for 3 h; water was added to ppt. the complex; it was collected by filtration and washed with water; the complex was dissolved in CH2Cl2 and dried over anhyd. Na2SO4, filtered and evapd.;	94%

: 10025-69-1
tin(II) chloride dihdyrate

: C29H31ClIrN4OPS

: C29H31Cl3IrN4OPSSn

Conditions

Conditions	Yield
In dichloromethane for 3h; Reflux; Schlenk technique;	94%

: 10025-69-1
tin(II) chloride dihdyrate

: 27147-03-1
5-(phenylazo)salicylaldehyde

: (C6H5NNC6H3(OH)CHO)SnCl2*2H2O

Conditions

Conditions	Yield
In acetone stirring a soln. of SnCl2 and ligand in acetone for 4 h, pptn.; filtn., washing with acetone, followed by hexane, drying in vacuo, elem. anal.;	93%

: 7782-49-2
selenium

: 10025-69-1
tin(II) chloride dihdyrate

: cobalt(II) chloride hexahydrate

: 111-40-0
1,5-diamino-3-azapentane

: [Co(diethylenetriamine)2]2Sn2Se6

Conditions

Conditions	Yield
at 160℃; for 168h; High pressure; Autoclave;	93%

...Expand

: 10025-69-1
tin(II) chloride dihdyrate

: 63-91-2
L-phenylalanine

: C18H18N2O4Sn

Conditions

Conditions	Yield
Stage #1: L-phenylalanine With triethylamine In methanol at 60℃; for 1h; Inert atmosphere; Stage #2: tin(II) chloride dihdyrate In methanol at 60℃; for 5.5h; Inert atmosphere;	92.68%

: 10025-69-1
tin(II) chloride dihdyrate

: cobalt(II) chloride hexahydrate

: 67-68-5
dimethyl sulfoxide

: 947538-62-7
[Co(dimethylsulfoxide)6][SnCl6]

Conditions

Conditions	Yield
With (CH3)2C(OCH3)2 In dimethyl sulfoxide dissolution of SnCl22H2O and CoCl26H2O in DMSO, filtration, addn. of Me2C(OMe)2, heating under Ar at 100-120 °C for 3-4 h; cooling to room temp., addn. of ether, vacuum filtration, washing with ether, drying in vac., elem. anal.;	92%
With (CH3CNOH)2 In dimethyl sulfoxide elem. anal.;

...Expand

: 10025-69-1
tin(II) chloride dihdyrate

: 92-44-4
2,3-naphthalenediol

: 1767-81-3
2,3-NaphthalindioxyzinnII

Conditions

Conditions	Yield
With hydrogenchloride In hydrogenchloride; water aq. solnn of SnCl2*2H2O contg. HCl is added with stirring in inert atm.to aq. 2,3-dihydroxynaphthalene; 1 M KOH is added until a pH 2 is reached; filtration, washing with hot H2O, drying in vac. at 60°C; elem. anal.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: 154-85-8
orotic acid sodium salt

: 2Sn(2+)*2Sn(4+)*12C4H3N2O2(COO)(1-)*2H2O={Sn2Sn2(H2N2C4HO2COO)12}*2H2O

Conditions

Conditions	Yield
In ethanol; water addn. of SnCl2 in EtOH to stirred soln. of org. compd. in hot water, stirring (15 min, 60-70°C); filtration, washing (H2O, EtOH, Et2O), drying over silica (vac.); elem. anal.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: C19H9N4(C6F5)3(SO2OH)2

: Sn(C19H6N4(C6F5)3(SO2OH)2)Cl

Conditions

Conditions	Yield
In N,N-dimethyl-formamide mixt. heated to reflux for 30 min; solvent evapd.; CH2Cl2 added to the residue; filtered; solvent evapd.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: 68494-08-6
4,5-bis(benzoylthio)-1,3-dithiole-2-thione

: 1.5(C2H5)4N(1+)*Sn(S5C3)2(1.5-)=[(C2H5)4N]1.5[Sn(S5C3)2]

Conditions

Conditions	Yield
With cetylpyridinium halide; Na In methanol thione dissoln. in MeOH containing Na, stirring for 30 min at room temp., metal salt soln. addn., pptn. on tetraalkylammonium halide soln. addn.; ppt. filtration, washing (water, MeOH), vac. drying, recrystn. from acetone; elem. anal.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: 2,3,6,7,12,13,16,17-octaethylporphycene

: 1192350-55-2
trans-dichloro(2,3,6,7,12,13,16,17-octaethylporphycenato)tin(IV)

Conditions

Conditions	Yield
In decalin refluxing mixt. of tin compd. and porphycene deriv. in dry decalin at 200°C for 0.5 h under N2; cooling to room temp. in air, filtration, evapn. in vac., extn. (CHCl3),wshing with aq. HCl, drying with Na2SO4, evapn., recrystn. (CHCl3/benze ne), elem. anal.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: calix[4]arene-bis(β-octaalkylporphyrin)

: calix[4]arene-bis(trans-dichloro-β-octaalkylporphyrinatotin(IV))

Conditions

Conditions	Yield
In pyridine dissolving of (C20H4N4(CH3)4(C2H5)4(C6H5))2(CH2CH2O)5O(CH2C6H2CH2C6H3OCH3)2 in pyridine, addn. of 1.5-fold excess of SnCl2*2H2O, reflux for 8 h; cooling, filtration, vac. distn., recrystn. from a CH2Cl2-hexane (2:1) mixt.; elem. anal.;	92%

: 10025-69-1
tin(II) chloride dihdyrate

: (Z)-2-(9-benzyl-8,9-dihydropyrazolo[4,3-b]carbazol-6(1H,5H,7H)-ylidene) semicarbazone

: [Sn((Z)-2-(9-benzyl-8,9-dihydropyrazolo[4,3-b]carbazol-6(1H,5H,7H)-ylidene) semicarbazone)2Cl2]*2H2O

Conditions

Conditions	Yield
In methanol for 0.0666667h; Reflux; Microwave irradiation;	92%

Stannous chloride dihydrate Specification

The Stannous chloride dihydrate with CAS registry number of 10025-69-1 is also known as Stannous dichloride dihydrate. The IUPAC name is Dichlorotin dihydrate. It belongs to classification codes of Mutation Data; Pharmaceutic Aid; Reproductive Effect. Its EINECS registry number is 231-868-0. In addition, the formula is Cl₂H₄O₂Sn and the molecular weight is 225.63. This chemical is a colorless to white, odorless solid and soluble in water, alcohol, acetic acid, alkali solution. What's more, it should be sealed in ventilated and dry place without light.

Physical properties about Stannous chloride dihydrate are:
(1)ACD/LogP: -1.38; (2) Enthalpy of Vaporization: 40.65 kJ/mol; (3)Boiling Point: 100 °C at 760 mmHg; (4)Vapour Pressure: 24.5 mmHg at 25 °C.

Preparation of Stannous chloride dihydrate:
it is prepared by reaction of tin with hydrochloric acid with a certain ratio. Product is obtained by cooling, crystallization and centrifugal separation.
Sn + 2 HCl → SnC1₂+ H₂↑

Uses of Stannous chloride dihydrate:
it can be used as analytical reagents, reducing agents, stabilizers, bleach and oil stain agent. This chemical also can be used for electroplating and can be used as raw materials for organic synthesis, pesticide herbicide.

Safety information of Stannous chloride dihydrate:
When you are using this chemical, please be cautious about it. As a chemical, it is harmful if swallowed and it causes burns. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. If accident happens or you feel unwell seek medical advice immediately.

You can still convert the following datas into molecular structure:
1. Canonical SMILES: O.O.Cl[Sn]Cl
2. InChI: InChI=1S/2ClH.2H2O.Sn/h2*1H;2*1H2;/q;;;;+2/p-2
3. InChIKey: FWPIDFUJEMBDLS-UHFFFAOYSA-L

The toxicity data of Stannous chloride dihydrate is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LDLo	intravenous	20mg/kg (20mg/kg)		"Handbook of Toxicology," 4 vols., Philadelphia, W.B. Saunders Co., 1956-59Vol. 1, Pg. 282, 1955.
rat	LD50	intravenous	7830ug/kg (7.83mg/kg)		Acta Physiologica Polonica. Vol. 32, Pg. 193, 1981.

Product Name

Stannous chloride dihydrate

Synthetic route

Stannous chloride dihydrate Specification

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