Hazard Codes | C |
Risk Statements | 34 |
Safety Statements | 26-36/37/39-45 |
RIDADR | UN 3261 8/PG 2 |
WGK Germany | 3 |
F | 3-9-21 |
Hazard Note | Corrosive/Moisture Sensitive |
HazardClass | 8 |
PackingGroup | II |
Conditions | Yield |
---|---|
With trimethylsilyl N,N-dimesylamidosulfonate In dichloromethane at 0℃; | 95% |
With chlorosulphuric acid; chloroform |
trimethylsilyl N,N-dimesylamidosulfonate
trimethylamine
A
trimethylsilyldimesylamine
B
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In dichloromethane at 0℃; Product distribution; other Lewis bases; | A n/a B 95% |
Conditions | Yield |
---|---|
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;; | |
In neat (no solvent) react. of SO3-vapor (dild. with N2 as carrier gas) with dry (CH3)3N-vapor;; crystn.;; |
sulfur trioxide trimethylamine complex
2,3,4,6-tetra-O-benzyl-α-D-mannopyranoside
Conditions | Yield |
---|---|
In acetonitrile for 48h; Heating; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 100% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; | 100% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 80℃; for 0.5h; Inert atmosphere; | 98.1% |
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 72h; | 96% |
2-(N-benzyloxycarbonyl)aminoethyl 2,3,4-tri-O-(4-methylbenzoyl)-6-O-(2-naphthylmethyl)-β-D-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranosyl-(1→3)-2,4-di-O-(4-methyl)benzoyl-6-O-(2-naphthylmethyl)-β-D-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-β-D-glucopyranoside
sulfur trioxide trimethylamine complex
2-(N-benzyloxycarbonyl)aminoethyl 2,3,4-tri-O-(4-methylbenzoyl)-6-O-(2-naphthylmethyl)-β-D-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-6-O-sulfo-β-D-glucopyranosyl-(1→3)-2,4-di-O-(4-methyl)benzoyl-6-O-(2-naphthylmethyl)-β-d-galactopyranosyl-(1→4)-3-O-benzyl-2-deoxy-2-phthalimido-6-O-sulfo-β-D-glucopyranoside
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 26h; Inert atmosphere; | 96% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 90℃; for 0.333333h; Inert atmosphere; | 95.2% |
4-methylphenyl 6-O-acetyl-2-O-benzoyl-3-O-benzyl-1-thio-β-D-glucopyranoside
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In acetonitrile at 60℃; for 2h; Solvent; Temperature; Reagent/catalyst; | 95% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In toluene at 80℃; for 0.833333h; Inert atmosphere; | 93.8% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 100℃; for 1h; Microwave irradiation; | 93.7% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 40 - 50℃; for 111h; | 92% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 40 - 50℃; for 144h; | 92% |
7-methoxy-2-naphthyl O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-(1->3)-(2,4-di-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 1h; | 91% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide; toluene at 80℃; for 48h; | 90.3% |
7-methoxy-2-naphthyl O-(2,3,4-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-2,3-di-O-acetyl-β-D-xylopyranoside
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 1h; | 90% |
7-methoxy-2-naphthyl O-(2,3,4,6-tetra-O-benzoyl-β-D-galactopyranosyl)-(1->3)-(2,4-di-O-benzoyl-β-D-galactopyranosyl)-(1->4)-3-O-acetyl-2-O-dibenzyloxyphosphinyl-β-D-xylopyranoside
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 1h; | 90% |
calenduladiol
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
Stage #1: calenduladiol; sulfur trioxide trimethylamine complex In N,N-dimethyl-formamide at 90℃; for 18h; Inert atmosphere; Stage #2: With Amberlite CG-120 (Na+ form) In methanol; N,N-dimethyl-formamide Inert atmosphere; | 90% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 90% |
sulfur trioxide trimethylamine complex
N-(9H-fluoren-9-ylmethoxycarbonyl)-L-serine
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In ethyl acetate at 80℃; for 0.416667h; Inert atmosphere; | 89.1% |
7-methoxy-2-naphthyl O-(2,3,4-tri-O-benzoyl-β-D-galactopyranosyl)-(1->4)-3-O-acetyl-2-O-dibenzyloxyphosphinyl-β-D-xylopyranoside
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; for 1h; | 89% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 50℃; for 48h; Schlenk technique; Inert atmosphere; | 89% |
sulfur trioxide trimethylamine complex
methyl (methyl 3,4-di-O-pivaloyl-α-L-idopyranosyluroate)-(1->4)-2-azido-3-O-benzyl-2-deoxy-6-O-pivaloyl-α-D-glucopyranoside
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; | 88% |
sulfur trioxide trimethylamine complex
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; Inert atmosphere; | 88% |
sulfur trioxide trimethylamine complex
methyl (2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranosyl)-(1->4)-(methyl 3-O-pivaloyl-α-L-idopyranosyluronate)-(1->4)-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 60℃; | 86% |
Conditions | Yield |
---|---|
In acetonitrile at 0 - 22℃; for 0.5h; Inert atmosphere; | 86% |
Conditions | Yield |
---|---|
With N,N-dimethyl-formamide In 1,2-dichloro-ethane at 80℃; for 0.416667h; Inert atmosphere; | 85.8% |
IUPAC Name: N,N-Dimethylmethanamine; sulfur trioxide
Empirical Formula: C3H9NO3S
Molecular Weight: 139.1735
Einecs: 221-614-7
Melting point: 232 °C
Polar Surface Area: 3.24 Å2
Enthalpy of Vaporization: 22.94 kJ/mol
Boiling Point: 2.8 °C at 760 mmHg
Vapour Pressure: 1720 mmHg at 25°C
The Cas Register Number of Sulfur trioxide trimethylamine complex is 3162-58-1.The chemical synonyms of Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) are Sulphur trioxide trimethylamine (1:1) .The molecular structure of Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is
.
Sulfur trioxide trimethylamine complex (CAS NO.3162-58-1) is used in organic synthesis.
Hazard Codes: C
Risk Statements: 34
R34: Causes burns.
Safety Statements: 26-36/37/39-45
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
F: 3-9-21
Hazard Note: Corrosive/Moisture Sensitive
HazardClass: 8
PackingGroup: II
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