SULFUR CHLORIDE PENTAFLUORIDE supplier

Name
SULPHUR CHLOROPENTAFLUORIDE
EINECS
CAS No. 13780-57-9
Article Data12
CAS DataBase
Density
Solubility
Melting Point -64°C
Formula ClF5 S
Boiling Point -21°C
Molecular Weight 162.511
Flash Point
Transport Information
Appearance
Safety Poison by inhalation. An irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Cl⁻, F⁻, and SO_x. See also FLUORIDES.
Risk Codes 23-34
Molecular Structure
Hazard Symbols
Synonyms Sulfurchloride fluoride (SClF5) (6CI,7CI); Chloropentafluorosulfur;Monochloropentafluorosulfur; Pentafluorosulfur chloride; Sulfur chloridepentafluoride; Sulfur monochloride pentafluoride; Sulfur pentafluoride chloride
PSA 25.30000
LogP 3.43870

Synthetic route

: 13997-90-5
chlorine fluorosulfate

: 7783-60-0
sulfur tetrafluoride

A: 13780-57-9
pentafluorosulfanyl chloride

B: 88548-61-2
trifluorosulfonium fluorosulfate

Conditions

Conditions	Yield
In neat (no solvent) ClOSO2F trasferred under vac. to FEP reactor fitted with stainless-steel valve and held at -196°C, SF4 condensed, reactor placed in bath at -90°C and allowed to warm to -40°C for 4 h; reactor cooled to -70°C, volatile materials(SF5Cl) removed, reactor warmed to -40°C and then - to 23°C and held under dynamic vac. for 10 min;	A 77% B 38%

...Expand

: 10544-50-0
sulfur

: potassium fluoride

: 87-90-1
trichloroisocyanuric acid

A: 640723-20-2, 2699-79-8, 12769-73-2
fluorosulfonyl fluoride

B: 13780-57-9
pentafluorosulfanyl chloride

C: 7783-42-8
thionyl fluoride

Conditions

Conditions	Yield
In acetonitrile at 20℃; Inert atmosphere; Darkness; Sealed tube;	A n/a B 47% C n/a

...Expand

: 7790-91-2
chlorine trifluoride

: 7783-60-0
sulfur tetrafluoride

: 13780-57-9
pentafluorosulfanyl chloride

Conditions

Conditions	Yield
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;;
In neat (no solvent) between 100 - 350°C under exclusion of water at 3 atm;;

: 7783-60-0
sulfur tetrafluoride

: 7790-89-8
chlorine monofluoride

: 13780-57-9
pentafluorosulfanyl chloride

Conditions

Conditions	Yield
In neat (no solvent) at 100 - 300°C and 3 atm;;
In gaseous matrix Kinetics; Irradiation (UV/VIS); photochemical reaction (Ar laser, mean power 10 mW, 450-500 nm, 100 Torr xenon as buffer gas); not isolated; IR monitoring;
In neat (no solvent) at 100 - 300°C and 3 atm;;

: 5714-22-7
disulfur decafluoride

: 13780-57-9
pentafluorosulfanyl chloride

Conditions

Conditions	Yield
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube at 350°C;;
With chlorine In neat (no solvent) passing Cl2 and S2F10 through tube under reduced pressure;;	>99

: 10025-67-9
disulfur dichloride

: 22650-46-0
F5SNCl2

A: 13780-57-9
pentafluorosulfanyl chloride

B: 25502-15-2
SF5N=SCl2

Conditions

Conditions	Yield
In further solvent(s) Cl2S2 is placed in a FEP-trap (dry-box), evacuated and cooled to -196°C, CFCl3 is condensed into trap, mixt. is warmed to room temp., into this mixt. Fe5SNCl2 is condensed (liquid N2), cooling to -100°C, mixt. is allowed to warm; mixt. is stirred under warming to -20°C for several hours, sepn.by fractional condensation in oil vac. in cold traps at -45, -50, -196°C, react. is followed by Raman-spectroscopy;

Yield

In further solvent(s) Cl2S2 is placed in a FEP-trap (dry-box), evacuated and cooled to -196°C, CFCl3 is condensed into trap, mixt. is warmed to room temp., into this mixt. Fe5SNCl2 is condensed (liquid N2), cooling to -100°C, mixt. is allowed to warm; mixt. is stirred under warming to -20°C for several hours, sepn.by fractional condensation in oil vac. in cold traps at -45, -50, -196°C, react. is followed by Raman-spectroscopy;

...Expand

: 60563-08-8
dichlorodithionitronium hexafluoroarsenate

: 7790-89-8
chlorine monofluoride

A: 13780-57-9
pentafluorosulfanyl chloride

B: 30313-36-1
{SF3}(1+)*{AsF6}(1-)=SF3AsF6

C: difluoro-dithionitronium hexafluoroarsenate(V)

D: 7783-60-0
sulfur tetrafluoride

E: 7783-42-8
thionyl fluoride

Conditions

Conditions	Yield
With fluorosulfonylchloride In not given SO2ClF and ClF were condensed onto (SCl)2NAsF6, mixt. was warmed to room temp. with srirring, 5 h; volatiles were removed, products were not isolated; products were analized by IR;	A n/a B n/a C 0% D n/a E <1

...Expand

: potassium fluoride

: 87-90-1
trichloroisocyanuric acid

: 7704-34-9
sulfur

: 13780-57-9
pentafluorosulfanyl chloride

Conditions

Conditions	Yield
With trifluoroacetic acid In acetonitrile at 20℃; for 14h; Inert atmosphere;

...Expand

: 13780-57-9
pentafluorosulfanyl chloride

: 22650-46-0
F5SNCl2

: 100312-09-2
tris(pentafluorosulfanyl)amine

Conditions

Conditions	Yield
In water at 20℃; under 1.50015 Torr; for 3.5h; UV-irradiation;	94%

: 13780-57-9
pentafluorosulfanyl chloride

: 22675-70-3
pentafuorosulfanyl hypochlorite

: 42310-84-9
bis(pentafluorosulfur)oxide

Conditions

Conditions	Yield
byproducts: SO2F2, SOF4, SF6; Irradiation (UV/VIS); irradn. for 4 h at 22°C; collection in a -196°C trap (dynamic vacuum); fractional condensation; SF5OSF5 and SF5O2SF5 in -111°C trap; mixt. heated in copper reactor at 237°C for 2.5 h;; fractional condensation yielded SF5OSF5 in a -118°C trap; further compounds (from decompn. of SF5O2SF5) in -196°C trap;;	72%

: 13780-57-9
pentafluorosulfanyl chloride

: 25246-37-1
N-Chlor-N-trifluormethyl-pentafluoraethylamin

: 25246-38-2
N,N'-bis(perfluoroethyl)-N,N'-bis(trifluoromethyl)-hydrazine

Conditions

Conditions	Yield
In gas Irradiation (UV/VIS); irradiation with PRK-2 lamp in silica flask at 20°C (45 h);	70%
In neat (no solvent, gas phase) Irradiation (UV/VIS); irradiation with PRK-2 lamp in silica flask at 20°C (45 h);	70%

: 375-00-8
heptafluorobutyronitrile

: 13780-57-9
pentafluorosulfanyl chloride

: 2261-34-9
sulfur pentafluoride (1-chloro-heptafluorobutylidene)amide

Conditions

Conditions	Yield
Irradiation (UV/VIS); 20°C, 17.7 h;	45%

: 13780-57-9
pentafluorosulfanyl chloride

: 25246-37-1
N-Chlor-N-trifluormethyl-pentafluoraethylamin

: 26981-28-2
sulfur pentafluoride pentafluoroethyl(trifluoromethyl)amide

Conditions

Conditions	Yield
Irradiation (UV/VIS); in quartz flask, 20°C, 45 h, with PKR UV lamps;	43%
Irradiation (UV/VIS); in quartz flask, 20°C, 45 h, with PKR UV lamps;	43%

: 13780-57-9
pentafluorosulfanyl chloride

: 353-85-5
trifluoroacetonitrile

: 2375-40-8
sulfur pentafluoride (1-chloro-2,2,2-trifluoroethylidene)amide

Conditions

Conditions	Yield
Irradiation (UV/VIS); 20°C, 14.5 h;	32%

: 13780-57-9
pentafluorosulfanyl chloride

: 22650-46-0
F5SNCl2

: tetrakis(pentafluorosulfanyl)hydrazine

Conditions

Conditions	Yield
In neat (no solvent) byproducts: S2F10, (SF5)2NCl, Cl2; Irradiation (UV/VIS); SF5NCl2 and SF5Cl were loaded into a Pyrex flask to give a pressure of about 1 atm at room temp., mixt. was irradiated for 4.5 to 5 h with an internal medium-pressure Hg lamp; by-products included S2F10, Cl2, N2, and (SF5)2NCl; isolated by repeated trap-to-trap distn. of the volatile products (in the -30°C trap); elem. anal.;	20%

Yield

In neat (no solvent) byproducts: S2F10, (SF5)2NCl, Cl2; Irradiation (UV/VIS); SF5NCl2 and SF5Cl were loaded into a Pyrex flask to give a pressure of about 1 atm at room temp., mixt. was irradiated for 4.5 to 5 h with an internal medium-pressure Hg lamp; by-products included S2F10, Cl2, N2, and (SF5)2NCl; isolated by repeated trap-to-trap distn. of the volatile products (in the -30°C trap); elem. anal.;

20%

: 13780-57-9
pentafluorosulfanyl chloride

: 7446-09-5
sulfur dioxide

A: 7791-25-5
sulfuryl dichloride

B: 640723-20-2, 2699-79-8, 12769-73-2
fluorosulfonyl fluoride

C: 5714-22-7
disulfur decafluoride

D: 81439-35-2
pentafluorosulfur fluorosulfonate

E: 7783-42-8
thionyl fluoride

Conditions

Conditions	Yield
byproducts: SiF4; other Radiation; photochemical reaction with 253.7 nm radiation, 48 h, in glass vessel;	A n/a B n/a C <1 D n/a E n/a

...Expand

: phosphorus

: 13780-57-9
pentafluorosulfanyl chloride

: 7647-19-0, 874483-74-6
phosphorus pentafluoride

Conditions

Conditions	Yield
In not given byproducts: SF4; react. of P with SF5Cl;;
In not given byproducts: SF4; react. of P with SF5Cl;;

: 75-77-4
chloro-trimethyl-silane

: 13780-57-9
pentafluorosulfanyl chloride

: 10545-99-0
sulfur dichloride

Conditions

Conditions	Yield
byproducts: Cl2, (CH3)3SiF; a mixt. of SF5Cl and (CH3)3SiCl is held at 0°C for 2 h; distn.;

: 13780-57-9
pentafluorosulfanyl chloride

A: 353-50-4
Carbonyl fluoride

B: 353-49-1
fluoroformyl chloride

C: 7783-60-0
sulfur tetrafluoride

D: 2551-62-4
sulfur(VI) hexafluoride

Conditions

Conditions	Yield
With carbon monoxide byproducts: S2F10, COS, SO2F2; Irradiation (UV/VIS);

...Expand

: 13780-57-9
pentafluorosulfanyl chloride

A: 807261-54-7
FCl(1-)

B: 141248-49-9
SF5Cl(1-)

C: fluoride

D: 16887-00-6
chloride

E: F5S(1-)

Conditions

Conditions	Yield
In gas other Radiation; electron attachment by SF5Cl in the energy range 0-20 eV studied in a beam experiment at room temp.; only a weak signal of SF5Cl(1-) is observed;

...Expand

: 13780-57-9
pentafluorosulfanyl chloride

: 5714-22-7
disulfur decafluoride

Conditions

Conditions	Yield
With hydrogen In neat (no solvent) other Radiation; photochemical reduction;;
In neat (no solvent)

: 13780-57-9
pentafluorosulfanyl chloride

: 1630-79-1
tetrakis(dimethylamido)diborane

: 10294-34-5
boron trichloride

Conditions

Conditions	Yield
byproducts: Cl2, SF4; excess SF5Cl;
byproducts: Cl2, SF4; excess SF5Cl;

: 13780-57-9
pentafluorosulfanyl chloride

: 40779-99-5
Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate

A: 1494-06-0
bis(pentafluorophenyl) disulfide

B: 52082-75-4
bis(pentafluorophenyl)trisulfane

...Expand

: 13780-57-9
pentafluorosulfanyl chloride

: 65844-06-6
Li(1+)*CF3S(1-)=LiSCF3

: 372-06-5
bis(trifluoromethyl)trisulfide

: 13780-57-9
pentafluorosulfanyl chloride

: 65844-06-6
Li(1+)*CF3S(1-)=LiSCF3

: 372-64-5
Bis(trifluoromethyl)disulfid

Conditions

Conditions	Yield
In diethyl ether -78°C, among other products;
In diethyl ether -78°C, among other products;

: 13780-57-9
pentafluorosulfanyl chloride

: 42310-84-9
bis(pentafluorosulfur)oxide

Conditions

Conditions	Yield
With oxygen In neat (no solvent) Irradiation (UV/VIS); photochemical oxidation;;
With oxygen In neat (no solvent) Irradiation (UV/VIS); photochemical oxidation;;

: 13780-57-9
pentafluorosulfanyl chloride

: 12395-41-4
bis(pentafluorosulfur) peroxide

Conditions

Conditions	Yield
With oxygen In neat (no solvent) Irradiation (UV/VIS); photochemical oxidation;;
With oxygen In neat (no solvent) Irradiation (UV/VIS); photochemical oxidation;;

: 13780-57-9
pentafluorosulfanyl chloride

: 79-38-9
Chlorotrifluoroethylene

: 3830-75-9
(2,2-dichlorotrifluoroethyl)pentafluorosulfur(VI)

Conditions

Conditions	Yield
In trichlorofluoromethane 100°C , 10 h;
90°C , 10 h ,in presence of dibenzoylperoxide;
In trichlorofluoromethane 100°C , 10 h;
90°C , 10 h ,in presence of dibenzoylperoxide;

: 13780-57-9
pentafluorosulfanyl chloride

: 79-38-9
Chlorotrifluoroethylene

: 22687-89-4
(1,2-dichlorotrifluoroethyl)pentafluorosulfur(VI)

Conditions

Conditions	Yield
Irradiation (UV/VIS); 5 h;
Irradiation (UV/VIS); 5 h;

: 13780-57-9
pentafluorosulfanyl chloride

: 431-94-7
N-chlorobistrifluoromethylamine

: 13888-13-6
sulfur pentafluoride bis(trifluoromethylamide)

Conditions

Conditions	Yield
Irradiation (UV/VIS); irradiation 44 h and heating to 200°C, 2 h;
Irradiation (UV/VIS); irradiation 44 h and heating to 200°C, 2 h;

: 13780-57-9
pentafluorosulfanyl chloride

: 1076-44-4
pentafluorophenyl lithium

: 26346-84-9
bis(pentafluorophenyl) sulfoxide

Conditions

Conditions	Yield
In diethyl ether -78°C, 5 h;	50-60

: 13780-57-9
pentafluorosulfanyl chloride

: 61097-18-5
lithium S,S-bis(trifluoromethyl)sulfimide

: 371-78-8
bis-(trifluoromethyl)sulfide

Conditions

Conditions	Yield
byproducts: LiCl; educts condensed at -196°C, followed by warming to room temp., decomposition products formed, too;
byproducts: LiCl; educts condensed at -196°C, followed by warming to room temp., decomposition products formed, too;

: 13780-57-9
pentafluorosulfanyl chloride

: 40779-99-5
Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate

A: 27918-31-6
pentafluorobenzenesulfenyl chloride

B: 1494-06-0
bis(pentafluorophenyl) disulfide

C: 52082-75-4
bis(pentafluorophenyl)trisulfane

Conditions

Conditions	Yield
In diethyl ether molar ratio 3 : 1 to 4 : 1, -78.degre;
In diethyl ether molar ratio 3 : 1 to 4 : 1, -78.degre;

...Expand

SULFUR CHLORIDE PENTAFLUORIDE Chemical Properties

Product Name: Sulphur chloropentafluoride
Synonyms:Chloropentafluorosulfur ; Monochloropentafluorosulfur ; Pentafluorosulfurchloride ; SClF₅; SF₅Cl ; Silfur chloropentafluoride ; Sulfur chloride fluoride ; Sulfur chloride fluoride (SClF₅).
CAS: 13780-57-9
Molecular Formula of Sulphur chloropentafluoride (13780-57-9) : ClF₅S
Molecular Weight of Sulphur chloropentafluoride (13780-57-9) : 162.51
Molecular Struture of Sulphur chloropentafluoride (13780-57-9) :
EINECS: 237-431-0
Product Categories:
Mol File: 13780-57-9.mol
Melting point: -64°C
Boiling point: -21°C

SULFUR CHLORIDE PENTAFLUORIDE Toxicity Data With Reference

ihl-rat LCLo:100 ppm/1H

BJIMAG British Journal of Industrial Medicine. 27 (1970),1.

SULFUR CHLORIDE PENTAFLUORIDE Safety Profile

Hazard Codes T
Risk Statements 23-34
23: Toxic by inhalation
34: Sulphur chloropentafluoride (13780-57-9) causes burns
Safety Statements 26-36/37/39-45
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR 3308
Hazard Note Toxic

SULFUR CHLORIDE PENTAFLUORIDE Standards and Recommendations

OSHA PEL: TWA 2.5 mg(F)/m³
ACGIH TLV: TWA 2.5 mg(F)/m³; BEI: 3 mg/g creatinine of fluorides in urine prior to shift; 10 mg/g creatinine of fluorides in urine at end of shift.
NIOSH REL: (Inorganic Fluorides) TWA 2.5 mg(F)/m³

Product Name

SULPHUR CHLOROPENTAFLUORIDE

Synthetic route

SULFUR CHLORIDE PENTAFLUORIDE Chemical Properties

SULFUR CHLORIDE PENTAFLUORIDE Toxicity Data With Reference

SULFUR CHLORIDE PENTAFLUORIDE Safety Profile

SULFUR CHLORIDE PENTAFLUORIDE Standards and Recommendations

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