Tetrahydrofurfuryl methacrylate supplier

Name
Tetrahydrofurfuryl methacrylate
EINECS 219-529-5
CAS No. 2455-24-5
Article Data7
CAS DataBase
Density 1.044
Solubility 18.99g/L at 20℃
Melting Point
Formula C9H14 O3
Boiling Point 52 °C0.4 mm Hg(lit.)
Molecular Weight 170.208
Flash Point 91 ºC
Transport Information 3272
Appearance
Safety 36
Risk Codes 10-36/37/38
Molecular Structure
Hazard Symbols R10:Flammable.; R36/37/38:Irritating to eyes, respiratory system and skin.;
Synonyms Methacrylicacid, tetrahydrofurfuryl ester (7CI,8CI); Furfuryl alcohol, tetrahydro-,methacrylate (8CI); Acryester THF; NSC 32634; SR 203; Sartomer SR 203;Tetrahydrofurfuryl methacrylate
PSA 35.53000
LogP 1.28470

Synthetic route

: 97-99-4
Tetrahydrofurfuryl alcohol

: 80-62-6
methacrylic acid methyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With 4-acetylamino-2,2,6,6-tetramethyl-1-piperidinoxy; di(n-butyl)tin oxide In 2-Methylpentane; cyclohexane at 85 - 100℃; for 12h; Temperature;	95%
2-methyl-propan-2-ol; lanthanum tri-tert-butylate at 25℃; for 2h;	32 %Chromat.
sodium ethanolate	15 %Chromat.
With sulfuric acid; benzene

: 97-99-4
Tetrahydrofurfuryl alcohol

: 97-63-2
methyl methacrylate

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With sulfuric acid

: 97-99-4
Tetrahydrofurfuryl alcohol

: 79-41-4
poly(methacrylic acid)

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

Conditions

Conditions	Yield
With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃;

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 829-85-6
diphenylphosphane

: C21H25O3P

Conditions

Conditions	Yield
In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction;	79%

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 66-99-9
β-naphthaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-(naphthalen-2-yl)-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	75%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 123-11-5
4-methoxy-benzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(4-methoxyphenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	74%

...Expand

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 34535-98-3
D,L-cis-phenylcyclopropylamine

: (tetrahydrofuran-2-yl)methyl-1-methyl-2-(phenylamino)cyclopentanecarboxylate

: (tetrahydrofuran-2-yl)methyl-1-methyl-2-(phenylamino)cyclopentanecarboxylate

Conditions

Conditions	Yield
With C60H100N4O12Rh2 In hexane at 20℃; for 18h; Schlenk technique; Inert atmosphere;	A 11% B 74%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 591-31-1
3-methoxy-benzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(3-methoxyphenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	73%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 100-52-7
benzaldehyde

: 1415690-09-3
(tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-phenylbutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	70%
With iron(II) chloride In decane; acetonitrile at 85℃; for 1h; Inert atmosphere;	61%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 459-57-4
4-fluorobenzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(4-fluorophenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	67%

...Expand

: 620-02-0
5-Methylfurfural

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-(5-methylfuran-2-yl)-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	61%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 6294-89-9
hydrazinecarboxylic acid methyl ester

: 4-methyl-1-((tetrahydrofuran-2-yl)methyl) 2-(tert-butylperoxy)-2-methylsuccinate

Conditions

Conditions	Yield
With iron(II) phthalocyanine In dichloromethane at 0℃; for 0.5h; Inert atmosphere;	60%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 66-77-3
1-naphthaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-(naphthalen-1-yl)-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	51%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 104-88-1
4-chlorobenzaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(4-chlorophenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	48%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 135-02-4
ortho-anisaldehyde

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-4-(2-methoxyphenyl)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	47%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 1203-68-5
2-Phenylbenzaldehyde

: (tetrahydrofuran-2-yl)methyl 4-([1,1'-biphenyl]-4-yl)-2-(tert-butylperoxy)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	47%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 455-19-6
4-Trifluoromethylbenzaldehyde

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: (tetrahydrofuran-2-yl)methyl 2-(tert-butylperoxy)-2-methyl-4-oxo-4-(4-(trifluoromethyl)phenyl)butanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	44%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 1122-91-4
4-bromo-benzaldehyde

: (tetrahydrofuran-2-yl)methyl 4-(4-bromophenyl)-2-(tert-butylperoxy)-2-methyl-4-oxobutanoate

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]} In decane; 1,2-dichloro-ethane at 20℃; for 6h; Inert atmosphere;	40%

...Expand

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: 1873-77-4
tris-(trimethylsilyl)silane

: (tetrahydrofuran-2-yl)methyl2-((1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilan-2-yl)methyl)acrylate

Conditions

Conditions	Yield
With Quinuclidine; pyridine; chloropyridinecobaloxime(III); (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile In acetonitrile at 25℃; Schlenk technique; Irradiation; Inert atmosphere;	40%

: 107663-38-7
2-methylacrylic acid 2-(benzyloxycarbonylamino)ethyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): tetrahydrofurfuryl methacrylate; benzyl 2-(2-methylacryloyloxy)ethylcarbamate: polymer; monomer(s): tetrahydrofurfuryl methacrylate; benzyl 2-(2-methylacryloyloxy)ethylcarbamate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone UV-irradiation;

: 694483-26-6
2-methylacrylic acid 2-(benzylcarbamoyloxy)ethyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): tetrahydrofurfuryl methacrylate; 2-methylacrylic acid 2-(benzylcarbamoyloxy)ethyl ester: polymer; monomer(s): tetrahydrofurfuryl methacrylate; 2-methylacrylic acid 2-(benzylcarbamoyloxy)ethyl ester

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone UV-irradiation;

: 110782-91-7
2-methylacrylic acid 2-(3-benzylureido)ethyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): tetrahydrofurfuryl methacrylate; 2-methylacrylic acid 2-(3-benzylureido)ethyl ester: polymer; monomer(s): tetrahydrofurfuryl methacrylate; 2-methylacrylic acid 2-(3-benzylureido)ethyl ester

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone UV-irradiation;

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): tetrahydrofurfuryl methacrylate: polymer; monomer(s): tetrahydrofurfuryl methacrylate

Conditions

Conditions	Yield
With 2,2-dimethoxy-2-phenylacetophenone UV-irradiation;

: 868-77-9
2-methyl-2-propenoic acid 2-hydroxyethyl ester

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): 2-hydroxyethyl methacrylate; tetrahydrofurfuryl methacrylate: polymer; monomer(s): 2-hydroxyethyl methacrylate; tetrahydrofurfuryl methacrylate

Conditions

Conditions	Yield
With dibenzoyl peroxide at 49.85 - 79.85℃; for 22h;

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

polymer; monomer(s): tetrahydrofurfur-2-yl methacrylate: polymer; monomer(s): tetrahydrofurfur-2-yl methacrylate

Conditions

Conditions	Yield
With methanesulfonic acid; 2,2-dimethoxy-2-phenylacetophenone at 25℃; for 0.0833333h; UV-irradiation;

: 4271-95-8
2-methyl-1,4,5,6-tetrahydropyrimidine

: 2455-24-5
(tetrahydrofuran-2-yl)methyl 2-methylprop-2-enoate

: tetrahydrofurfuryl 3-(2-methyl-1,4,5,6-tetrahydropyrimidin-1-yl)-2-methylpropionate

Conditions

Conditions	Yield
at 100℃; for 5h;

Tetrahydrofurfuryl methacrylate Chemical Properties

Molecular Structure of Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5):

Molecular Formula: C₉H₁₄O₃
Molecular Weight:
CAS No: 2455-24-5
H bond acceptors: 3
H bond donors: 0
Freely Rotating Bonds: 4
Polar Surface Area: 35.53 Å²
Index of Refraction: 1.452
Molar Refractivity: 44.62 cm³
Molar Volume: 165.2 cm³
Surface Tension: 33.7 dyne/cm
Density: 1.03 g/cm³
Flash Point: 105.6 °C
Enthalpy of Vaporization: 50.29 kJ/mol
Boiling Point: 265 °C at 760 mmHg
Vapour Pressure: 0.0094 mmHg at 25°C
IUPAC Name: Oxolan-2-ylmethyl 2-methylprop-2-enoate
InChI: InChI=1/C₉H₁₄O₃/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
InChIKey: LCXXNKZQVOXMEH-UHFFFAOYAZ
Std. InChI: InChI=1S/C₉H₁₄O₃/c1-7(2)9(10)12-6-8-4-3-5-11-8/h8H,1,3-6H2,2H3
Std. InChIKey: LCXXNKZQVOXMEH-UHFFFAOYSA-N
Product Categories: FuransMonomers;Acrylic Monomers;Building Blocks;Heterocyclic Building Blocks;Methacrylate

Tetrahydrofurfuryl methacrylate Safety Profile

Risk Statements: 10-36/37/38
R10:Flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 36
S36:Wear suitable protective clothing.
RIDADR: 3272
WGK Germany: 1
HazardClass: 3
PackingGroup: III
Hazardous Substances Data: 2455-24-5

Tetrahydrofurfuryl methacrylate Specification

Tetrahydrofurfuryl methacrylate (CAS No.2455-24-5), its synonyms are 2-Propenoic acid, 2-methyl-, (tetrahydro-2-furanyl)methyl ester ; Methacrylic acid, tetrahydrofurfuryl ester (8CI) ; Tetrahydro-2-furanylmethyl methacrylate ; Tetrahydrofuran-2-ylmethyl 2-methylprop-2-enoate ; Tetrahydrofuran-2-ylmethyl methacrylate ; 2-Methyl-acrylic acid tetrahydro-furan-2-ylmethyl ester .

Product Name

Tetrahydrofurfuryl methacrylate

Synthetic route

Tetrahydrofurfuryl methacrylate Chemical Properties

Tetrahydrofurfuryl methacrylate Safety Profile

Tetrahydrofurfuryl methacrylate Specification

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