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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 1203-68-5 with competitive price

Cas:1203-68-5

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear Liquid Storage:2-8°C Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Any port in China

2-Biphenylcarboxaldehyde;2-FORMYL-BIPHENYL;(1,1’-biphenyl)-2-carboxaldehyde;

Cas:1203-68-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

[1,1'-Biphenyl]-2-carboxaldehyde

Cas:1203-68-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

[1,1'-Biphenyl]-2-carboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Biphenylcarboxylic acid

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

(1,1'-biphenyl)-2-carboxaldehyde;2-difenilaldeide;BIPHENYL-2-CARBALDEHYDE;BIPHENYL-2-CARBOXALDEHYDE;2-PHENYLBENZALDEHYDE;2-BIPHENYLCARBOXALDEHYDE;2-FORMYL-BIPHENYL;2-Formyl-1,1 '-biphenyl CAS No.: 1203-68-5 Molecular formula: C13H10O

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

2-Phenylbenzaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high qualityAppearance:white crystalline powder Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

(+)-2,3-O-BENZYLIDENE-D-THREITOL

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

2-Phenylbenzaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Phenylbenzaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-ForMyl-1,1'-biphenyl

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:Chemical intermediate

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-PHENYLBENZALDEHYDEAppearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-PHENYLBENZALDEHYDE

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Yuanye Bio-Technology Co., Ltd.

good quality, competitive price, thoughtful after sale serviceAppearance:white powder Storage:Keep it in dry,shady and cool place Package:1g Application:Pharma;Industry;Agricultural;chemical reaserch Transportation:by express or by sea Port:Any port

Biphenyl-2-carboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Other

inquiry

AstaTech ( Chengdu) BioPharmaceutical Corp.

Quality assurance, stable process and affordable priceAppearance:detailed see specifications Storage:enquiry Package:according to the clients requirement Application:Pharmaceutical intermediates Transportation:Normal Port:chengdu

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Bide Pharmatech Ltd

Our mission is to provide high-quality and innovative products to our customers. By offering a broad range of products, custom synthesis and personalized services, Bide can help scientists speeding up their research in the chemical and pharmaceutical

2-Phenylbenzaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Other

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer

Biphenyl-2-carboxaldehyde manufacturer

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Yinghao Pharm Co.,Ltd.

Yinghao Pharm products include: leader molecule, heterocyclic compounds,chiral compounds, photoelectric materials, biochemical reagents etc. For example:benzene, pyrimidine, boricacid,pyridine, pyrazole, imidazole, pyrrole, fluorine and other derivat

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1.Best service, high quality and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). ? 3. It's customers' right to choose the packing way for his products fro

Best price/ 2-ForMyl-1,1'-biphenyl CAS NO.1203-68-5

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ShiJiaZhuang Simaiou Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemical Technology Co.,LTD

1. Production capacity: we have three production base with high-tech production equipment and instruments, equipped with professional production personnel, meet your requirements.2. Quality assurance: we have a first-class testing equipment and testi

2-Biphenylcarboxaldehyde

Cas:1203-68-5

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2-biphenylmethanol
2928-43-0

2-biphenylmethanol

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With manganese(IV) oxide In chloroform for 5h; Oxidation; Heating;100%
With Celite; pyridinium chlorochromate In dichloromethane for 12h;90%
With manganese(IV) oxide In dichloromethane at 20℃; for 3h;87%
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

phenylboronic acid
98-80-6

phenylboronic acid

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethylene glycol at 80℃; for 3h; Suzuki-Miyaura Coupling;100%
With tetrabutylammomium bromide; potassium carbonate; cyclopalladated N-dodecylferrocenylimine In methanol; water at 20℃; for 5h; Suzuki-Miyaura cross-coupling reaction;99%
With potassium phosphate tribasic heptahydrate In tetrahydrofuran at 60℃; for 10h; Suzuki coupling; Inert atmosphere;99%
2-Bromobiphenyl
2052-07-5

2-Bromobiphenyl

N,N-dimethyl-formamide
68-12-2, 33513-42-7

N,N-dimethyl-formamide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 2-Bromobiphenyl With tert.-butyl lithium In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran at -78 - 20℃;
100%
Stage #1: 2-Bromobiphenyl With n-butyllithium In tetrahydrofuran; hexane at -80℃; for 0.5h;
Stage #2: N,N-dimethyl-formamide In tetrahydrofuran; hexane at -80 - 20℃;
96%
phenylmagnesium bromide

phenylmagnesium bromide

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: phenylmagnesium bromide With indium(III) chloride In tetrahydrofuran at 25℃;
Stage #2: ortho-bromobenzaldehyde; tris-(dibenzylideneacetone)dipalladium(0); trifuran-2-yl-phosphane In tetrahydrofuran; water for 2h; Heating; Further stages.;
100%
Stage #1: phenylmagnesium bromide In tetrahydrofuran at -20℃; for 0.166667h;
Stage #2: ortho-bromobenzaldehyde With para-fluorostyrene; tetra-(n-butyl)ammonium iodide; cobalt acetylacetonate In tetrahydrofuran; 1,2-dimethoxyethane at 25℃; for 0.25h;
42%
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

phenylboronic acid
98-80-6

phenylboronic acid

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With caesium carbonate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 1h; Suzuki-Miyaura coupling; Heating;99%
With potassium phosphate; C50H63Cl2N3Pd In ethanol at 80℃; for 4h; Suzuki-Miyaura Coupling;98%
With potassium carbonate In water; isopropyl alcohol at 100℃; for 18h; Suzuki-Miyaura Coupling; Inert atmosphere;98%
1-(biphenyl-2-ylmethoxy)-2,2,6,6-tetramethyl-piperidine

1-(biphenyl-2-ylmethoxy)-2,2,6,6-tetramethyl-piperidine

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane for 0.5h; cooling;99%
2-iodobenzaldehyde
26260-02-6

2-iodobenzaldehyde

phenylboronic acid
98-80-6

phenylboronic acid

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In water at 20℃; for 0.5h; Suzuki-Miyaura Coupling;99%
With potassium carbonate In ethanol; water at 20℃; for 1h; Suzuki-Miyaura Coupling; Green chemistry;94%
With potassium phosphate In 1,4-dioxane at 70℃; for 1.5h; Suzuki-Miyaura Coupling;93%
iodobenzene
591-50-4

iodobenzene

2-formylbenzene boronic acid
40138-16-7

2-formylbenzene boronic acid

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In ethanol Suzuki-Miyaura Coupling; Schlenk technique; Heating;99%
With C43H54N2S; palladium diacetate; potassium carbonate In water; isopropyl alcohol at 100℃; for 3h; Suzuki-Miyaura coupling reaction; Aerobic condition; Sealed tube;93%
C20H25GeNO3

C20H25GeNO3

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; tetrabutyl ammonium fluoride In 2-methyltetrahydrofuran at 80℃; for 12h;98%
2,2'-sulfinylbis(4-methylphenol) phenylboronic ester

2,2'-sulfinylbis(4-methylphenol) phenylboronic ester

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); potassium phosphate; tert-butyldiphenylphosphine In tetrahydrofuran; water at 60℃; for 20h; Suzuki Coupling; Inert atmosphere;98%
N-(2-phenylbenzoyl)-N'-benzensulfonylhydrazine
154660-49-8

N-(2-phenylbenzoyl)-N'-benzensulfonylhydrazine

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With sodium carbonate In glycerol at 170℃; for 0.166667h;97%
With sodium carbonate; ethylene glycol
With sodium carbonate; glycerol Multistep reaction;
diethyl ether
60-29-7

diethyl ether

dichloromethane
75-09-2

dichloromethane

2-biphenylmethanol
2928-43-0

2-biphenylmethanol

water
7732-18-5

water

Dess-Martin periodane
87413-09-0

Dess-Martin periodane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With sodium hydroxide In tert-butyl alcohol97%
sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

2-formylphenyl triflate
84761-77-3

2-formylphenyl triflate

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With palladium diacetate; XPhos In toluene at 120℃; for 24h; Sealed tube; Inert atmosphere;97%
phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

N-tert-butyl-1-(2-methoxyphenyl)methanimine
82632-38-0

N-tert-butyl-1-(2-methoxyphenyl)methanimine

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: N-tert-butyl-1-(2-methoxyphenyl)methanimine With chromium dichloride In tetrahydrofuran at 25℃; for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: phenylmagnesium chloride In tetrahydrofuran at 25℃; for 5h; Schlenk technique; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 25℃; for 3h; Schlenk technique; Inert atmosphere;
96%
N-tert-butyl-1-(2-methoxyphenyl)methanimine
82632-38-0

N-tert-butyl-1-(2-methoxyphenyl)methanimine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: N-tert-butyl-1-(2-methoxyphenyl)methanimine With chromium dichloride In tetrahydrofuran at 25℃; for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: phenylmagnesium bromide In tetrahydrofuran at 25℃; for 5h; Schlenk technique; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 25℃; for 3h; Schlenk technique; Inert atmosphere;
96%
tributylphenylstannane
960-16-7

tributylphenylstannane

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium carbonate In water at 80℃; for 2h; Stille coupling;95%
With potassium carbonate In water at 90℃; for 3h; Stille Cross Coupling; Green chemistry;94%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; cesium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole In toluene at 60℃; for 10h; Stille coupling; Inert atmosphere;86%
With potassium carbonate In N,N-dimethyl-formamide at 110℃; for 16h; Stille coupling;84%
With cesium fluoride; palladium(II) trifluoroacetate In 1,4-dioxane at 100℃; for 10h; Stille cross-coupling;80%
phenyl trimethylsiloxane
2996-92-1

phenyl trimethylsiloxane

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With sodium hydroxide; PEG encapsulated palladium nanoparticle In water at 90℃; for 2.5h; Hiyama cross-coupling reaction;95%
With sodium hydroxide In water at 90℃; for 3h; Hiyama Coupling; Green chemistry;93%
With sodium hydroxide In ethylene glycol at 100℃; for 1h; Hiyama Coupling;93%
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; tetrabutyl ammonium fluoride; 3-tert-butyl-5-methyl-1-(2-(diphenylphosphino)phenyl)-1H-pyrazole In 1,4-dioxane at 55℃; for 10h; Hiyama coupling; Inert atmosphere;76%
2-iodobenzaldehyde
26260-02-6

2-iodobenzaldehyde

triphenylbismuthane
603-33-8

triphenylbismuthane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; caesium carbonate In N,N-dimethyl acetamide at 90℃; for 5h; Schlenk technique; Inert atmosphere;95%
2-((tert-butylimino)methyl)-N,N-dimethylaniline

2-((tert-butylimino)methyl)-N,N-dimethylaniline

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 2-[(tert-butylimino)methyl]-N,N-dimethylaniline With chromium dichloride In tetrahydrofuran at 20℃; for 0.0833333h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide In tetrahydrofuran at 20℃; for 15h; Inert atmosphere; Schlenk technique;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 20℃; for 3h; Reagent/catalyst; Time; Inert atmosphere; Schlenk technique;
95%
bromobenzene
108-86-1

bromobenzene

2-formylbenzene boronic acid
40138-16-7

2-formylbenzene boronic acid

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With palladium diacetate In water; isopropyl alcohol at 27℃; for 2h; Suzuki-Miyaura Coupling;94%
With C12H12Cl2N4O2Pd; caesium carbonate In water at 60℃; for 5h; Suzuki-Miyaura Coupling;88%
With sodium acetate In water Suzuki Coupling;80%
2-((tert-butylimino)methyl)-N,N-dimethylaniline

2-((tert-butylimino)methyl)-N,N-dimethylaniline

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 2-[(tert-butylimino)methyl]-N,N-dimethylaniline; phenylmagnesium chloride With chromium dichloride In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;
Stage #2: With hydrogenchloride In water at 20℃; for 3h; Inert atmosphere;
93%
bromobenzene
108-86-1

bromobenzene

2-(2'-formylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
380151-85-9

2-(2'-formylphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With potassium phosphate; triphenylphosphine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 24h; Suzuki-Miyaura Coupling; Inert atmosphere; Sealed tube;93%
N-(2-phenoxybenzylidene)tert-butylamine

N-(2-phenoxybenzylidene)tert-butylamine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: N-(2-phenoxybenzylidene)tert-butylamine With chromium dichloride In tetrahydrofuran at 25℃; for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: phenylmagnesium bromide In tetrahydrofuran at 25℃; for 5h; Schlenk technique; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 25℃; for 3h; Schlenk technique; Inert atmosphere; chemoselective reaction;
92%
N-(2-ethoxybenzylidene)tert-butylamine

N-(2-ethoxybenzylidene)tert-butylamine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: N-(2-ethoxybenzylidene)tert-butylamine With chromium dichloride In tetrahydrofuran at 25℃; for 0.0833333h; Schlenk technique; Inert atmosphere;
Stage #2: phenylmagnesium bromide In tetrahydrofuran at 25℃; for 5h; Schlenk technique; Inert atmosphere;
Stage #3: With hydrogenchloride In tetrahydrofuran; water at 25℃; for 3h; Schlenk technique; Inert atmosphere; chemoselective reaction;
91%
2-methyl-N-[2-(pyrrolidin-1-yl)benzylidene]propan-2-amine

2-methyl-N-[2-(pyrrolidin-1-yl)benzylidene]propan-2-amine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 2-methyl-N-[2-(pyrrolidin-1-yl)benzylidene]propan-2-amine; phenylmagnesium bromide With chromium dichloride In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;
Stage #2: With hydrogenchloride In water Inert atmosphere;
91%
2-((tert-butylimino)methyl)-N,N-diethylaniline

2-((tert-butylimino)methyl)-N,N-diethylaniline

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
Stage #1: 2-((tert-butylimino)methyl)-N,N-diethylaniline; phenylmagnesium bromide With chromium dichloride In tetrahydrofuran at 20℃; for 15h; Inert atmosphere;
Stage #2: With hydrogenchloride In water Inert atmosphere;
90%
2-([1,1'-biphenyl]-2-yl)-1,3-dithiane

2-([1,1'-biphenyl]-2-yl)-1,3-dithiane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With iron(III)-acetylacetonate; dihydrogen peroxide; sodium iodide In water; ethyl acetate at 25℃; for 3h; Schlenk technique;90%
ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

potassium phenyltrifluoborate

potassium phenyltrifluoborate

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In methanol for 1h; Suzuki-Miyaura cross-coupling; Heating;89%
With potassium carbonate; palladium diacetate In methanol for 1h; Suzuki reaction; Heating;89%
N-(2-phenylbenzylidene)-4-methylbenzenesulfonamide
1292302-62-5

N-(2-phenylbenzylidene)-4-methylbenzenesulfonamide

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With hydrogenchloride; water In nitromethane at 100℃; for 10h;89%
triethoxyphenylsilane
780-69-8

triethoxyphenylsilane

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

Conditions
ConditionsYield
With sodium hydroxide; Pd(NH3)2Cl2 In water at 120℃; for 3h; Hiyama coupling;88%
With tetrabutyl ammonium fluoride; acetic acid In toluene at 100℃; for 24h; Hiyama Coupling;75%
With PdCl2{P(OC6H5)3}2; caesium carbonate In ethylene glycol at 80℃; for 2h; Hiyama coupling;100 %Chromat.
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

N-(2-phenylbenzylidene)-4-methylbenzenesulfonamide
1292302-62-5

N-(2-phenylbenzylidene)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With boron trichloride - methyl sulfide complex In toluene at 20℃; for 7.5h;100%
With copper diacetate In toluene Reflux;97%
With tetraethoxy orthosilicate Heating;47%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

N-(9H-fluoren-9-yl)-4-methylbenzenesulfonamide
94623-63-9

N-(9H-fluoren-9-yl)-4-methylbenzenesulfonamide

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In toluene at 20℃; for 0.333333h; aza-Friedel-Crafts reaction;99%
With aluminum (III) chloride In nitromethane at 100℃; for 8h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature;81%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

N-methoxylamine hydrochloride
593-56-6

N-methoxylamine hydrochloride

biphenyl-2-carbaldehyde O-methyl oxime
1109233-26-2

biphenyl-2-carbaldehyde O-methyl oxime

Conditions
ConditionsYield
With sodium hydroxide In ethanol; water at 85℃; for 1.5h;99%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

2-biphenylmethanol
2928-43-0

2-biphenylmethanol

Conditions
ConditionsYield
With CdS(x)Se(1-x) x:0-1;; cesium acetate; para-thiocresol In toluene Sealed tube; Inert atmosphere; Irradiation;98%
Stage #1: 2-Phenylbenzaldehyde With polymethylhydrosiloxane; iron(II) acetate; tricyclohexylphosphine In tetrahydrofuran at 65℃; for 16h;
Stage #2: With sodium hydrogencarbonate In tetrahydrofuran; methanol at 0 - 20℃; Further stages.;
96%
Stage #1: 2-Phenylbenzaldehyde With 1-Methylpyrrolidine; 2-chloro-5-fluorophenylboronic acid; phenylsilane at 20℃; for 16h; Inert atmosphere;
Stage #2: With sodium hydroxide In water at 20℃; for 2h; chemoselective reaction;
95%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

toluene-4-sulfonic acid hydrazide
1576-35-8

toluene-4-sulfonic acid hydrazide

N′-(biphenyl-2-ylmethylene)-4-methylbenzenesulfonohydrazide
84648-90-8

N′-(biphenyl-2-ylmethylene)-4-methylbenzenesulfonohydrazide

Conditions
ConditionsYield
In methanol at 60℃; Inert atmosphere; Schlenk technique;98%
In ethanol Heating;67%
In methanol at 60℃; Inert atmosphere;
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate
90965-06-3

dimethyl 1-(1-diazo-2-oxopropyl)phosphonate

2-ethynyl-1,1'-biphenyl
52889-62-0

2-ethynyl-1,1'-biphenyl

Conditions
ConditionsYield
With potassium carbonate In methanol at 20℃; for 3h; Inert atmosphere;98%
With potassium carbonate In methanol at 20℃;92%
With caesium carbonate In ethanol at 0 - 20℃; for 12h; Inert atmosphere;
With potassium carbonate In methanol at 0 - 20℃; for 16h;829.4 mg
1,2,3-trimethoxybenzene
621-23-8

1,2,3-trimethoxybenzene

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

9-(2,4,6-trimethoxyphenyl)-9H-fluorene
1597444-14-8

9-(2,4,6-trimethoxyphenyl)-9H-fluorene

Conditions
ConditionsYield
With iron(III) chloride; Tosyl isocyanate In 1,2-dichloro-ethane at 80℃; for 2h;98%
With trifluorormethanesulfonic acid; acetic anhydride In 1,2-dichloro-ethane at 20℃; Green chemistry;63%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

9-(2,4,6-trimethylphenyl)-9H-fluorene
18153-40-7

9-(2,4,6-trimethylphenyl)-9H-fluorene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid; acetic anhydride In 1,2-dichloro-ethane at 20℃; Solvent; Reagent/catalyst; Green chemistry;98%
With iron(III) chloride; Tosyl isocyanate at 80℃; for 1h;98%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

4,5-dimethyl-1,2-phenylenediamine
3171-45-7

4,5-dimethyl-1,2-phenylenediamine

2-([1,1′-biphenyl]-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

2-([1,1′-biphenyl]-2-yl)-5,6-dimethyl-1H-benzo[d]imidazole

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃; for 8h;98%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

(S)-2-methylpropane-2-sulfinamide
343338-28-3

(S)-2-methylpropane-2-sulfinamide

(S)-N-(biphenyl-2-ylmethylene)-2-methylpropane-2-sulfinamide

(S)-N-(biphenyl-2-ylmethylene)-2-methylpropane-2-sulfinamide

Conditions
ConditionsYield
With titanium(IV) tetraethanolate In tetrahydrofuran at 80℃; for 6h;97%
With titanium(IV) tetraethanolate In tetrahydrofuran at 80℃; for 6h; Temperature; Concentration;97.4%
4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

(biphenyl-4-yl)(biphenyl-2-yl)methanol
1065544-02-6

(biphenyl-4-yl)(biphenyl-2-yl)methanol

Conditions
ConditionsYield
Stage #1: 4-bromo-1,1'-biphenyl With magnesium In tetrahydrofuran
Stage #2: 2-Phenylbenzaldehyde In tetrahydrofuran at 20℃; for 1h; Grignard addition; Further stages.;
97%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

9-phenanthrylmagnesium bromide
71112-64-6

9-phenanthrylmagnesium bromide

(biphenyl-2-yl)(phenanthren-9-yl)methanol
1065544-06-0

(biphenyl-2-yl)(phenanthren-9-yl)methanol

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Grignard addition; Heating;97%
In tetrahydrofuran
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

methyl (triphenylphosphoranylidene)acetate
21204-67-1

methyl (triphenylphosphoranylidene)acetate

(E)-3-([1,1'-biphenyl]-2-yl)acrylic acid methyl ester

(E)-3-([1,1'-biphenyl]-2-yl)acrylic acid methyl ester

Conditions
ConditionsYield
In tetrahydrofuran for 24h; Reflux; Inert atmosphere;97%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

[(dibromomethylene)(2,4,6-tri-tertbutylphenyl)phosphine]
100281-23-0

[(dibromomethylene)(2,4,6-tri-tertbutylphenyl)phosphine]

C35H48BrOPSi

C35H48BrOPSi

Conditions
ConditionsYield
Stage #1: [(dibromomethylene)(2,4,6-tri-tertbutylphenyl)phosphine] With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere; Schlenk technique;
Stage #2: 2-Phenylbenzaldehyde In tetrahydrofuran; hexane at -78℃; for 0.25h; Inert atmosphere; Schlenk technique;
Stage #3: chloro-trimethyl-silane In tetrahydrofuran; hexane at 0 - 40℃; for 3h; Inert atmosphere; Schlenk technique;
97%
2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

1-([1,1’-biphenyl]-2-yl)-3-(trimethylsilyl)prop-2-yn-1-ol
1370723-58-2

1-([1,1’-biphenyl]-2-yl)-3-(trimethylsilyl)prop-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
Stage #2: 2-Phenylbenzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
96%
Stage #1: trimethylsilylacetylene With n-butyllithium In tetrahydrofuran; hexane at -5℃; for 0.25h; Inert atmosphere;
Stage #2: 2-Phenylbenzaldehyde In tetrahydrofuran; hexane at 0℃; for 3h; Inert atmosphere;
55%
nitromethane
75-52-5

nitromethane

2-Phenylbenzaldehyde
1203-68-5

2-Phenylbenzaldehyde

(+)-1-(biphenyl-2-yl)-2-nitroethanol

(+)-1-(biphenyl-2-yl)-2-nitroethanol

Conditions
ConditionsYield
Stage #1: nitromethane With C36H46Cu2N2O4 In tert-butyl alcohol at 20℃; under 760.051 Torr; for 3h; Henry Nitro Aldol Condensation;
Stage #2: 2-Phenylbenzaldehyde In tert-butyl alcohol at 20℃; for 86h; Henry Nitro Aldol Condensation; enantioselective reaction;
96%
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