Product Name

  • Name

    Trifluoromethanesulfonic acid

  • EINECS 216-087-5
  • CAS No. 1493-13-6
  • Article Data90
  • CAS DataBase
  • Density 1.877 g/cm3
  • Solubility soluble in water
  • Melting Point -40 °C
  • Formula CHF3O3S
  • Boiling Point 161.999 °C at 760 mmHg
  • Molecular Weight 150.078
  • Flash Point None
  • Transport Information UN 3265 8/PG 2
  • Appearance Colourless liquid with a pungent odour
  • Safety 26-36/37/39-45
  • Risk Codes 21/22-35-10
  • Molecular Structure Molecular Structure of 1493-13-6 (Trifluoromethanesulfonic acid)
  • Hazard Symbols CorrosiveC
  • Synonyms Trifluoromethane sulfonic acid;Methanesulfonicacid, trifluoro- (6CI,7CI,8CI,9CI);Fluorad FC 24;Perfluoromethanesulfonicacid;Triflic acid;Trimsylate;
  • PSA 62.75000
  • LogP 1.47480

Synthetic route

[η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2

[η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2

hydrogen
1333-74-0

hydrogen

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

C26H45Ru2S2(1+)*CF3O3S(1-)

C26H45Ru2S2(1+)*CF3O3S(1-)

Conditions
ConditionsYield
In dichloromethane; water at 20℃; for 1h; Schlenk technique; Inert atmosphere;A n/a
B 98%
Trifluoromethanesulfonyl fluoride
335-05-7

Trifluoromethanesulfonyl fluoride

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
With sulfuric acid Reagent/catalyst;97.5%
at 100°C for 48 h;50%
at 20°C for 48 h;7%
sodium triflate
2926-30-9

sodium triflate

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
With sulfuric acid97.1%
lithium trifluoromethanesulfonate
33454-82-9

lithium trifluoromethanesulfonate

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
With sulfuric acid96.8%
ferrocenium trifluoromethanesulfonate

ferrocenium trifluoromethanesulfonate

A

ferrocene
102-54-5

ferrocene

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In water at 20℃; under 760.051 Torr; for 1.2h; Catalytic behavior; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique;A 95%
B n/a
With [(pentamethylcyclopentadienyl)Ru{PhP(C6H4-o-S)2}Ru(pentamethylcyclopentadienyl)](OTf)2; hydrogen In water at 20℃; under 760.051 Torr; for 20h;A 87%
B 86%
With [η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2; hydrogen In methanol at 20℃; under 760.051 Torr; for 1.4h; Temperature; Reagent/catalyst; Solvent; Pressure; Schlenk technique;
chloroform
67-66-3

chloroform

Chlorine(I) trifluoromethanesulfonate
65597-24-2

Chlorine(I) trifluoromethanesulfonate

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

Conditions
ConditionsYield
at 22℃; for 1h;A n/a
B 92%
(η5-C5H5)Re(NO)(PPh3)(COCH3)
82582-46-5

(η5-C5H5)Re(NO)(PPh3)(COCH3)

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

potassium tert-butylate
865-47-4

potassium tert-butylate

A

{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)
82582-34-1

{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
In dichloromethaneA 88%
B n/a
2,2,6,6-tetramethyl-piperidine
768-66-1

2,2,6,6-tetramethyl-piperidine

(η5-C5H5)Re(NO)(PPh3)(COCH3)
82582-46-5

(η5-C5H5)Re(NO)(PPh3)(COCH3)

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

A

{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)
82582-34-1

{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
In dichloromethane (CF3SO2)2O added to a stirred soln. of CpRe(NO)(PPh3)(COCH3) in CH2Cl2 at -78°C, after 10 min addn. of TMP, stirring for 1 h at -78°C, (CF3SO2)2O added, after 10 min soln. warmed to room temp., filtration, solvent removed by rotary evapn.;; extn. (CHCl3), extract filtered, solvent removed by rotary evapn.; monitored by (1)H- and (31)P-NMR-spectroscopy (-80°C, CD2Cl2 or CH2Cl2, < 5 min);;A 88%
B n/a
(E)-1-(4-chlorophenyl)-N-(4-methoxyphenyl)methanimine

(E)-1-(4-chlorophenyl)-N-(4-methoxyphenyl)methanimine

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

4-(4-chlorophenyl)-1-(4-methoxyphenyl)-3-phenoxyazetidin-2-one

4-(4-chlorophenyl)-1-(4-methoxyphenyl)-3-phenoxyazetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 75%
morpholine
110-91-8

morpholine

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
71001-09-7

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

1,2:3,4-di-O-isopropylidene-6-morpholino-α-D-galactopyranose
98979-39-6

1,2:3,4-di-O-isopropylidene-6-morpholino-α-D-galactopyranose

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 24h; Ambient temperature;A n/a
B 74%
4-methylpiperidin
626-58-4

4-methylpiperidin

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
71001-09-7

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

1,2:3,4-di-O-isopropylidene-6-(4-methylpiperidino)-α-D-galactopyranose

1,2:3,4-di-O-isopropylidene-6-(4-methylpiperidino)-α-D-galactopyranose

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 24h; Ambient temperature;A n/a
B 67%
2,2,6,6-tetramethyl-piperidine
768-66-1

2,2,6,6-tetramethyl-piperidine

(η5-C5H5)Re(NO)(PPh3)(COCH2(1-C10H7))
115365-02-1

(η5-C5H5)Re(NO)(PPh3)(COCH2(1-C10H7))

trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

sc-{(η5-C5H5)Re(NO)(PPh3)(CCH(1-C10H7))}(CF3SO3)
115365-04-3

sc-{(η5-C5H5)Re(NO)(PPh3)(CCH(1-C10H7))}(CF3SO3)

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
In dichloromethane react. monitored by (1)H- and (31)P-NMR-spectroscopy (-80°C, CD2Cl2 or CH2Cl2, < 5 min); elem. anal.; sc/ac-ratio>99:1;;A 63%
B n/a
N-(p-methoxybenzylidene)-p-toluidine
83306-66-5

N-(p-methoxybenzylidene)-p-toluidine

C21H20O3P(1+)*CF3O3S(1-)

C21H20O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-3-Methoxy-4-(4-methoxy-phenyl)-1-p-tolyl-azetidin-2-one

(3S,4R)-3-Methoxy-4-(4-methoxy-phenyl)-1-p-tolyl-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 61%
4-methoxy-N-[(1Z)-phenylmethylene]aniline
40339-42-2

4-methoxy-N-[(1Z)-phenylmethylene]aniline

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-1-(4-Methoxy-phenyl)-3-phenoxy-4-phenyl-azetidin-2-one

(3S,4R)-1-(4-Methoxy-phenyl)-3-phenoxy-4-phenyl-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 59%
1-indoline
496-15-1

1-indoline

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
71001-09-7

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

1,2:3,4-di-O-isopropylidene-6-(indolino)-α-D-galactopyranose

1,2:3,4-di-O-isopropylidene-6-(indolino)-α-D-galactopyranose

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 24h; Ambient temperature;A n/a
B 57%
1,2,3,4-tetrahydroisoquinoline
91-21-4

1,2,3,4-tetrahydroisoquinoline

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
71001-09-7

1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

1,2:3,4-di-O-isopropylidene-6-(1,2,3,4-tetrahydroisoquinoline)-α-D-galactopyranose

1,2:3,4-di-O-isopropylidene-6-(1,2,3,4-tetrahydroisoquinoline)-α-D-galactopyranose

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 24h; Ambient temperature;A n/a
B 53%
N-(3-phenyl-2-propenylidene)-4-methoxyaniline
123525-44-0

N-(3-phenyl-2-propenylidene)-4-methoxyaniline

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-1-(4-Methoxy-phenyl)-3-phenoxy-4-((E)-styryl)-azetidin-2-one

(3S,4R)-1-(4-Methoxy-phenyl)-3-phenoxy-4-((E)-styryl)-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 52%
p-methoxyphenylcarboxaldehyde N-(p-methoxyphenyl)imine
83306-67-6

p-methoxyphenylcarboxaldehyde N-(p-methoxyphenyl)imine

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-1,4-Bis-(4-methoxy-phenyl)-3-phenoxy-azetidin-2-one

(3S,4R)-1,4-Bis-(4-methoxy-phenyl)-3-phenoxy-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 46%
N-(2-methyl-3-phenylprop-2-enylidene)-p-anisidine
94612-45-0, 100239-15-4, 106318-92-7, 108908-63-0

N-(2-methyl-3-phenylprop-2-enylidene)-p-anisidine

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-1-(4-Methoxy-phenyl)-4-((E)-1-methyl-2-phenyl-vinyl)-3-phenoxy-azetidin-2-one

(3S,4R)-1-(4-Methoxy-phenyl)-4-((E)-1-methyl-2-phenyl-vinyl)-3-phenoxy-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 45%
N-(p-methoxybenzylidene)-p-toluidine
83306-66-5

N-(p-methoxybenzylidene)-p-toluidine

C26H22O3P(1+)*CF3O3S(1-)

C26H22O3P(1+)*CF3O3S(1-)

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

Triphenylphosphine oxide
791-28-6

Triphenylphosphine oxide

(3S,4R)-4-(4-Methoxy-phenyl)-3-phenoxy-1-p-tolyl-azetidin-2-one

(3S,4R)-4-(4-Methoxy-phenyl)-3-phenoxy-1-p-tolyl-azetidin-2-one

Conditions
ConditionsYield
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition;A n/a
B n/a
C 41%
Trifluoromethylsulfenyl chloride
421-17-0

Trifluoromethylsulfenyl chloride

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

A

Bis(trifluoromethyl)disulfid
372-64-5

Bis(trifluoromethyl)disulfid

B

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C

trifluoromethane sulfonyl chloride
421-83-0

trifluoromethane sulfonyl chloride

Conditions
ConditionsYield
35% H2O2 soln.;A 35%
B 7%
C 40%
35% H2O2 soln.;A 35%
B 7%
C 40%
trifluoromethanesulfonic acid ethyl ester
425-75-2

trifluoromethanesulfonic acid ethyl ester

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
at 150℃; Pyrolysis;
diethyl ether
60-29-7

diethyl ether

methyl trifluoromethanesulfonate
333-27-7

methyl trifluoromethanesulfonate

A

ethyl methyl ether
540-67-0

ethyl methyl ether

B

trifluoromethanesulfonic acid ethyl ester
425-75-2

trifluoromethanesulfonic acid ethyl ester

C

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

Conditions
ConditionsYield
at 80℃; unter Luftausschluss;
trifluoromethanesulfonic acid ethyl ester
425-75-2

trifluoromethanesulfonic acid ethyl ester

benzene
71-43-2

benzene

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

B

ethylbenzene
100-41-4

ethylbenzene

C

ortho-diethylbenzene
253185-02-3

ortho-diethylbenzene

D

9,10-dimethylanthracene
781-43-1

9,10-dimethylanthracene

3-methyl-4-penten-1-ol
51174-44-8

3-methyl-4-penten-1-ol

phenylselenyl triflate
112238-64-9

phenylselenyl triflate

A

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

(2S,3R)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan
109065-98-7

(2S,3R)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan

(2S,3S)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan
109065-97-6

(2S,3S)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan

Conditions
ConditionsYield
In dichloromethane at 0℃; for 0.25h; Mechanism; Product distribution;
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

trifluoromethyl trifluoromethanesulfonate
3582-05-6

trifluoromethyl trifluoromethanesulfonate

Conditions
ConditionsYield
With pentafluoroethanesulfonic acid anhydride at 60℃; for 4h;100%
With phosphorus pentoxide In neat (no solvent) at 80 - 180℃; Inert atmosphere;66%
With phosphorus pentoxide at -78 - 110℃; Inert atmosphere;56%
bis(diethylamino)dimethylsilane
4669-59-4

bis(diethylamino)dimethylsilane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

(diethylamino)dimethylsilyl-triflat
155166-24-8

(diethylamino)dimethylsilyl-triflat

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
bis(diethylamino)chloromethylsilane
17891-70-2

bis(diethylamino)chloromethylsilane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C6H13ClF3NO3SSi

C6H13ClF3NO3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
bis(diethylamino)dichlorosilane
18881-64-6

bis(diethylamino)dichlorosilane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C5H10Cl2F3NO3SSi

C5H10Cl2F3NO3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
tetrakis(dimethylamino)silane
1624-01-7

tetrakis(dimethylamino)silane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

tris(dimethylamino)silyl triflate
155166-32-8

tris(dimethylamino)silyl triflate

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
In toluene for 0.5h; Ambient temperature;
tris(diethylamino)silane
15730-66-2

tris(diethylamino)silane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C9H21F3N2O3SSi

C9H21F3N2O3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
methyl-tris(diethylamino)silane
18418-65-0

methyl-tris(diethylamino)silane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C10H23F3N2O3SSi
154922-03-9

C10H23F3N2O3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
In diethyl ether at 0℃; for 0.25h;
SiCl(NEt2)3
15730-69-5

SiCl(NEt2)3

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C9H20ClF3N2O3SSi

C9H20ClF3N2O3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

tetraphenylsilane
1048-08-4

tetraphenylsilane

Diphenylsilicium-bis(trifluormethansulfonat)
27607-80-3

Diphenylsilicium-bis(trifluormethansulfonat)

Conditions
ConditionsYield
In chloroform at 0℃;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

bis(diethylamino)(methyl)(vinyl)silane
18023-34-2

bis(diethylamino)(methyl)(vinyl)silane

C8H16F3NO3SSi

C8H16F3NO3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

diphenylsilane
775-12-2

diphenylsilane

phenylsilanyl trifluoromethanesulfonate
127808-36-0

phenylsilanyl trifluoromethanesulfonate

Conditions
ConditionsYield
at 20℃;100%
In toluene at 0℃; for 0.25h;78%
In chloroform at 0℃; for 0.166667h; Yield given;
In dichloromethane at 0 - 20℃; for 0.5h;
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

bis(diethylamino)(methyl)(phenyl)silane
1023-81-0

bis(diethylamino)(methyl)(phenyl)silane

CH3C6H5Si(C2H5)2NCF3SO3
154922-06-2

CH3C6H5Si(C2H5)2NCF3SO3

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
In diethyl ether at 0℃; for 0.25h;
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

N-benzoyl-N-(α-benzoylbenzyl)aniline
81640-85-9

N-benzoyl-N-(α-benzoylbenzyl)aniline

2,3,4,5-tetraphenyloxazolium trifluoromethanesulphonate
81640-37-1

2,3,4,5-tetraphenyloxazolium trifluoromethanesulphonate

Conditions
ConditionsYield
100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

vinyl-tris(diethylamino)silane
61423-53-8

vinyl-tris(diethylamino)silane

C11H23F3N2O3SSi

C11H23F3N2O3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

benzenetellurinic acid anhydride
94971-86-5

benzenetellurinic acid anhydride

benzenetellurinyl trifluoromethanesulfonate
122745-21-5

benzenetellurinyl trifluoromethanesulfonate

Conditions
ConditionsYield
In dichloromethane for 0.5h; Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

(E)-2-(3-oxo-1,3-diphenylpropylidene)-3,4-dihydronaphthalen-1(2H)-one
35339-16-3

(E)-2-(3-oxo-1,3-diphenylpropylidene)-3,4-dihydronaphthalen-1(2H)-one

2,4-diphenyl-5,6-dihydro-7,8-benzochromenylium trifluoromethanesulphonate
76017-15-7

2,4-diphenyl-5,6-dihydro-7,8-benzochromenylium trifluoromethanesulphonate

Conditions
ConditionsYield
In ethanol 1.) 60 deg C, 4 h, 2.) 25 deg C, 12 h;100%
In ethanol Heating;
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

1,1,2,2-tetraphenyl-1,2-di-tert-butyl-1,2-disilane
122131-73-1

1,1,2,2-tetraphenyl-1,2-di-tert-butyl-1,2-disilane

1,2-di-tert-butyl-1,2-diphenyldisilane-1,2-bis(triflate)
155166-11-3

1,2-di-tert-butyl-1,2-diphenyldisilane-1,2-bis(triflate)

Conditions
ConditionsYield
In toluene Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C10H23F3N2O3SSi
154922-03-9

C10H23F3N2O3SSi

C7H13F6NO6S2Si
155166-33-9

C7H13F6NO6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

(Allyl-bis-diethylamino-silanyl)-diethyl-amine

(Allyl-bis-diethylamino-silanyl)-diethyl-amine

C12H25F3N2O3SSi

C12H25F3N2O3SSi

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C9H21F3N2O3SSi

C9H21F3N2O3SSi

C6H11F6NO6S2Si

C6H11F6NO6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

tris(dimethylamino)silyl triflate
155166-32-8

tris(dimethylamino)silyl triflate

C6H12F6N2O6S2Si

C6H12F6N2O6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C9H20ClF3N2O3SSi

C9H20ClF3N2O3SSi

C6H10ClF6NO6S2Si

C6H10ClF6NO6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C12H25F3N2O3SSi

C12H25F3N2O3SSi

C9H15F6NO6S2Si

C9H15F6NO6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

C11H23F3N2O3SSi

C11H23F3N2O3SSi

C8H13F6NO6S2Si

C8H13F6NO6S2Si

Conditions
ConditionsYield
In diethyl ether Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

2,3-dihydro-2-(p-methoxybenzylthio)-1H-indolizinium chloride

2,3-dihydro-2-(p-methoxybenzylthio)-1H-indolizinium chloride

2,3-dihydro-2-metcapto-1H-indolizinium trifluoromethanesulfonate

2,3-dihydro-2-metcapto-1H-indolizinium trifluoromethanesulfonate

Conditions
ConditionsYield
With trifluoroacetic acid In various solvent(s) for 1h; Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

2,3-dihydro-1-(p-methoxybenzylthio)-1H-indolizinium p-toluenesulfonate

2,3-dihydro-1-(p-methoxybenzylthio)-1H-indolizinium p-toluenesulfonate

2,3-dihydro-1-metcapto-1H-indolizinium trifluoromethanesulfonate

2,3-dihydro-1-metcapto-1H-indolizinium trifluoromethanesulfonate

Conditions
ConditionsYield
With trifluoroacetic acid In various solvent(s) for 1h; Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

1H-2,4,6-tri-isopropyl-1,3,5-triazinium triflate
86774-69-8

1H-2,4,6-tri-isopropyl-1,3,5-triazinium triflate

1,3-Dimethoxybenzene
151-10-0

1,3-Dimethoxybenzene

2-(2,4-dimethoxyphenyl)-2,4,6-tri-isopropyl-1,2-dihydro-1,3,5-triazinium triflate
86774-78-9

2-(2,4-dimethoxyphenyl)-2,4,6-tri-isopropyl-1,2-dihydro-1,3,5-triazinium triflate

Conditions
ConditionsYield
In benzene for 1.5h; Ambient temperature;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

1,1,2,2,3,3-hexaphenyltrisilane
18816-18-7

1,1,2,2,3,3-hexaphenyltrisilane

1,2,3-triphenyl-1,2,3-tris(trifluoromethansulfonyloxy)trisilan

1,2,3-triphenyl-1,2,3-tris(trifluoromethansulfonyloxy)trisilan

Conditions
ConditionsYield
In toluene at 0℃; for 2h;100%
1,4-diaza-bicyclo[2.2.2]octane
280-57-9

1,4-diaza-bicyclo[2.2.2]octane

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

N,N'-difluoro-1,4-diazoniabicyclo<2.2.2>octane bis(triflate)

N,N'-difluoro-1,4-diazoniabicyclo<2.2.2>octane bis(triflate)

Conditions
ConditionsYield
With fluorine In various solvent(s)100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

1,3-Dibromo-1,3-di-p-tolyl-[1,3]disiletane

1,3-Dibromo-1,3-di-p-tolyl-[1,3]disiletane

Trifluoro-methanesulfonic acid 1,3-dibromo-3-trifluoromethanesulfonyloxy-[1,3]disiletan-1-yl ester

Trifluoro-methanesulfonic acid 1,3-dibromo-3-trifluoromethanesulfonyloxy-[1,3]disiletan-1-yl ester

Conditions
ConditionsYield
In diethyl ether; toluene for 1h; Ambient temperature;100%

Trifluoromethanesulfonic acid Chemical Properties

Empirical Formula: CHF3O3S
Molecular Weight: 150.077 g/mol
EINECS: 216-087-5
Index of Refraction: 1.354
Density: 1.876 g/cm3
Boiling Point: 162 °C at 760 mmHg
Vapour Pressure: 1.14 mmHg at 25 °C
Melting point: -40 °C
Storage tempreture: -20 °C
Sensitive: Hygroscopic
Appearance: Clear very light yellow liquid
Structure of Trifluoromethanesulfonic acid (CAS NO.1493-13-6):
             
Product Category of Trifluoromethanesulfonic acid (CAS NO.1493-13-6): straight chain compounds;Organic Fluorides;Organic AcidsVolumetric Solutions;Synthetic Reagents;Titration;Volumetric Solutions

Trifluoromethanesulfonic acid Toxicity Data With Reference

 p-Tolualdehyde (CAS NO.620-23-5) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated.

Trifluoromethanesulfonic acid Safety Profile

Hazard Codes:  C
Risk Statements:
10:  Flammable 
35:  Causes severe burns 
21/22:  Harmful in contact with skin and if swallowed 
Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible) 
36/37/39:  Wear suitable protective clothing, gloves and eye/face protection 

Trifluoromethanesulfonic acid Specification

 Trifluoromethanesulfonic acid , its cas register number is 1493-13-6. It also can be called Methanesulfonic acid, 1,1,1-trifluoro- ; and Triflic acid . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, p-Tolualdehyde (CAS NO.620-23-5) could be stable under normal temperatures and pressures. It absorbs moisture or water from the air, and is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas.

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