Conditions | Yield |
---|---|
In dichloromethane; water at 20℃; for 1h; Schlenk technique; Inert atmosphere; | A n/a B 98% |
Conditions | Yield |
---|---|
With sulfuric acid Reagent/catalyst; | 97.5% |
at 100°C for 48 h; | 50% |
at 20°C for 48 h; | 7% |
Conditions | Yield |
---|---|
With sulfuric acid | 97.1% |
lithium trifluoromethanesulfonate
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
With sulfuric acid | 96.8% |
Conditions | Yield |
---|---|
With C26H46ClO3Ru2S2(1+)*CF3O3S(1-); hydrogen In water at 20℃; under 760.051 Torr; for 1.2h; Catalytic behavior; Temperature; Reagent/catalyst; Inert atmosphere; Schlenk technique; | A 95% B n/a |
With [(pentamethylcyclopentadienyl)Ru{PhP(C6H4-o-S)2}Ru(pentamethylcyclopentadienyl)](OTf)2; hydrogen In water at 20℃; under 760.051 Torr; for 20h; | A 87% B 86% |
With [η5-C5Me5Ru(μ-SiPr)2Ru(OH2)-η5-C5Me5](OTf)2; hydrogen In methanol at 20℃; under 760.051 Torr; for 1.4h; Temperature; Reagent/catalyst; Solvent; Pressure; Schlenk technique; |
chloroform
Chlorine(I) trifluoromethanesulfonate
A
trifluorormethanesulfonic acid
B
trifluoromethylsulfonic anhydride
Conditions | Yield |
---|---|
at 22℃; for 1h; | A n/a B 92% |
(η5-C5H5)Re(NO)(PPh3)(COCH3)
trifluoromethylsulfonic anhydride
potassium tert-butylate
A
{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)
B
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In dichloromethane | A 88% B n/a |
2,2,6,6-tetramethyl-piperidine
(η5-C5H5)Re(NO)(PPh3)(COCH3)
trifluoromethylsulfonic anhydride
A
{(η5-C5H5)Re(NO)(PPh3)(vinylidene)}(CF3SO3)
B
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In dichloromethane (CF3SO2)2O added to a stirred soln. of CpRe(NO)(PPh3)(COCH3) in CH2Cl2 at -78°C, after 10 min addn. of TMP, stirring for 1 h at -78°C, (CF3SO2)2O added, after 10 min soln. warmed to room temp., filtration, solvent removed by rotary evapn.;; extn. (CHCl3), extract filtered, solvent removed by rotary evapn.; monitored by (1)H- and (31)P-NMR-spectroscopy (-80°C, CD2Cl2 or CH2Cl2, < 5 min);; | A 88% B n/a |
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 75% |
morpholine
1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
A
trifluorormethanesulfonic acid
B
1,2:3,4-di-O-isopropylidene-6-morpholino-α-D-galactopyranose
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 24h; Ambient temperature; | A n/a B 74% |
4-methylpiperidin
1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
A
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 24h; Ambient temperature; | A n/a B 67% |
2,2,6,6-tetramethyl-piperidine
(η5-C5H5)Re(NO)(PPh3)(COCH2(1-C10H7))
trifluoromethylsulfonic anhydride
sc-{(η5-C5H5)Re(NO)(PPh3)(CCH(1-C10H7))}(CF3SO3)
B
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In dichloromethane react. monitored by (1)H- and (31)P-NMR-spectroscopy (-80°C, CD2Cl2 or CH2Cl2, < 5 min); elem. anal.; sc/ac-ratio>99:1;; | A 63% B n/a |
N-(p-methoxybenzylidene)-p-toluidine
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 61% |
4-methoxy-N-[(1Z)-phenylmethylene]aniline
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 59% |
1-indoline
1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
A
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 24h; Ambient temperature; | A n/a B 57% |
1,2,3,4-tetrahydroisoquinoline
1,2:3,4-di-O-isopropylidene-6-O-trifluoromethanesulfonyl-α-D-galactopyranose
A
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide for 24h; Ambient temperature; | A n/a B 53% |
N-(3-phenyl-2-propenylidene)-4-methoxyaniline
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 52% |
p-methoxyphenylcarboxaldehyde N-(p-methoxyphenyl)imine
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 46% |
N-(2-methyl-3-phenylprop-2-enylidene)-p-anisidine
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 45% |
N-(p-methoxybenzylidene)-p-toluidine
A
trifluorormethanesulfonic acid
B
Triphenylphosphine oxide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 0℃; for 0.5h; Cyclization; decomposition; | A n/a B n/a C 41% |
Trifluoromethylsulfenyl chloride
dihydrogen peroxide
A
Bis(trifluoromethyl)disulfid
B
trifluorormethanesulfonic acid
C
trifluoromethane sulfonyl chloride
Conditions | Yield |
---|---|
35% H2O2 soln.; | A 35% B 7% C 40% |
35% H2O2 soln.; | A 35% B 7% C 40% |
Conditions | Yield |
---|---|
at 150℃; Pyrolysis; |
diethyl ether
methyl trifluoromethanesulfonate
A
ethyl methyl ether
B
trifluoromethanesulfonic acid ethyl ester
C
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
at 80℃; unter Luftausschluss; |
trifluoromethanesulfonic acid ethyl ester
benzene
A
trifluorormethanesulfonic acid
B
ethylbenzene
C
ortho-diethylbenzene
D
9,10-dimethylanthracene
3-methyl-4-penten-1-ol
phenylselenyl triflate
A
trifluorormethanesulfonic acid
(2S,3R)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan
(2S,3S)-3-Methyl-2-phenylselanylmethyl-tetrahydro-furan
Conditions | Yield |
---|---|
In dichloromethane at 0℃; for 0.25h; Mechanism; Product distribution; |
Conditions | Yield |
---|---|
With pentafluoroethanesulfonic acid anhydride at 60℃; for 4h; | 100% |
With phosphorus pentoxide In neat (no solvent) at 80 - 180℃; Inert atmosphere; | 66% |
With phosphorus pentoxide at -78 - 110℃; Inert atmosphere; | 56% |
bis(diethylamino)dimethylsilane
trifluorormethanesulfonic acid
(diethylamino)dimethylsilyl-triflat
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
bis(diethylamino)chloromethylsilane
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
bis(diethylamino)dichlorosilane
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
tetrakis(dimethylamino)silane
trifluorormethanesulfonic acid
tris(dimethylamino)silyl triflate
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
In toluene for 0.5h; Ambient temperature; |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
methyl-tris(diethylamino)silane
trifluorormethanesulfonic acid
C10H23F3N2O3SSi
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
In diethyl ether at 0℃; for 0.25h; |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
tetraphenylsilane
Diphenylsilicium-bis(trifluormethansulfonat)
Conditions | Yield |
---|---|
In chloroform at 0℃; | 100% |
trifluorormethanesulfonic acid
bis(diethylamino)(methyl)(vinyl)silane
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
diphenylsilane
phenylsilanyl trifluoromethanesulfonate
Conditions | Yield |
---|---|
at 20℃; | 100% |
In toluene at 0℃; for 0.25h; | 78% |
In chloroform at 0℃; for 0.166667h; Yield given; | |
In dichloromethane at 0 - 20℃; for 0.5h; |
trifluorormethanesulfonic acid
bis(diethylamino)(methyl)(phenyl)silane
CH3C6H5Si(C2H5)2NCF3SO3
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
In diethyl ether at 0℃; for 0.25h; |
trifluorormethanesulfonic acid
N-benzoyl-N-(α-benzoylbenzyl)aniline
2,3,4,5-tetraphenyloxazolium trifluoromethanesulphonate
Conditions | Yield |
---|---|
100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
benzenetellurinic acid anhydride
benzenetellurinyl trifluoromethanesulfonate
Conditions | Yield |
---|---|
In dichloromethane for 0.5h; Ambient temperature; | 100% |
trifluorormethanesulfonic acid
(E)-2-(3-oxo-1,3-diphenylpropylidene)-3,4-dihydronaphthalen-1(2H)-one
2,4-diphenyl-5,6-dihydro-7,8-benzochromenylium trifluoromethanesulphonate
Conditions | Yield |
---|---|
In ethanol 1.) 60 deg C, 4 h, 2.) 25 deg C, 12 h; | 100% |
In ethanol Heating; |
trifluorormethanesulfonic acid
1,1,2,2-tetraphenyl-1,2-di-tert-butyl-1,2-disilane
1,2-di-tert-butyl-1,2-diphenyldisilane-1,2-bis(triflate)
Conditions | Yield |
---|---|
In toluene Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
tris(dimethylamino)silyl triflate
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
Conditions | Yield |
---|---|
In diethyl ether Ambient temperature; | 100% |
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid In various solvent(s) for 1h; Ambient temperature; | 100% |
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
With trifluoroacetic acid In various solvent(s) for 1h; Ambient temperature; | 100% |
trifluorormethanesulfonic acid
1H-2,4,6-tri-isopropyl-1,3,5-triazinium triflate
1,3-Dimethoxybenzene
2-(2,4-dimethoxyphenyl)-2,4,6-tri-isopropyl-1,2-dihydro-1,3,5-triazinium triflate
Conditions | Yield |
---|---|
In benzene for 1.5h; Ambient temperature; | 100% |
trifluorormethanesulfonic acid
1,1,2,2,3,3-hexaphenyltrisilane
Conditions | Yield |
---|---|
In toluene at 0℃; for 2h; | 100% |
Conditions | Yield |
---|---|
With fluorine In various solvent(s) | 100% |
trifluorormethanesulfonic acid
Conditions | Yield |
---|---|
In diethyl ether; toluene for 1h; Ambient temperature; | 100% |
Empirical Formula: CHF3O3S
Molecular Weight: 150.077 g/mol
EINECS: 216-087-5
Index of Refraction: 1.354
Density: 1.876 g/cm3
Boiling Point: 162 °C at 760 mmHg
Vapour Pressure: 1.14 mmHg at 25 °C
Melting point: -40 °C
Storage tempreture: -20 °C
Sensitive: Hygroscopic
Appearance: Clear very light yellow liquid
Structure of Trifluoromethanesulfonic acid (CAS NO.1493-13-6):
Product Category of Trifluoromethanesulfonic acid (CAS NO.1493-13-6): straight chain compounds;Organic Fluorides;Organic AcidsVolumetric Solutions;Synthetic Reagents;Titration;Volumetric Solutions
p-Tolualdehyde (CAS NO.620-23-5) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65. And the toxicological properties have not been fully investigated.
Hazard Codes: C
Risk Statements:
10: Flammable
35: Causes severe burns
21/22: Harmful in contact with skin and if swallowed
Safety Statements:
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
Trifluoromethanesulfonic acid , its cas register number is 1493-13-6. It also can be called Methanesulfonic acid, 1,1,1-trifluoro- ; and Triflic acid . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: first, should flush skin with plenty of water immediately for at least 15 minutes while removing contaminated clothing. Secondly, get medical aid. Or in the eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Then get medical aid soon. While, it's inhaled: Remove from exposure and move to fresh air immediately. Give artificial respiration while not breathing. When breathing is difficult, give oxygen. And as soon as to get medical aid. Then you have the ingesting of the product: Wash mouth out with water, and get medical aid immediately. Notes to physician: Treat supportively and symptomatically.
In addition, p-Tolualdehyde (CAS NO.620-23-5) could be stable under normal temperatures and pressures. It absorbs moisture or water from the air, and is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: carbon monoxide, oxides of sulfur, carbon dioxide, hydrogen fluoride gas.
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