Product Name

  • Name

    trans-1,2-Dichloroethylene

  • EINECS 205-860-2
  • CAS No. 156-60-5
  • Article Data79
  • CAS DataBase
  • Density 1.243 g/cm3
  • Solubility Insoluble in water
  • Melting Point ?57 °C(lit.)
  • Formula C2H2Cl2
  • Boiling Point 47.7 °C at 760 mmHg
  • Molecular Weight 96.9439
  • Flash Point 6.1 °C
  • Transport Information UN 1150 3/PG 2
  • Appearance Clear liquid
  • Safety 7-16-29-61-45-36/37
  • Risk Codes 11-20-52/53-39/23/24/25-23/24/25
  • Molecular Structure Molecular Structure of 156-60-5 (trans-1,2-Dichloroethylene)
  • Hazard Symbols HarmfulXn, FlammableF, ToxicT
  • Synonyms Ethene,1,2-dichloro-, (E)-;Ethylene, 1,2-dichloro-, (E)- (8CI);Ethylene,1,2-dichloro-, trans- (5CI);(E)-1,2-Dichloroethene;(E)-1,2-Dichloroethylene;1,2-trans-Dichloroethene;Ethene, 1,2-dichloro-,(1E)-;HCC 1130t;NSC 60512;R1130t;trans-1,2-Dichloroethene;
  • PSA 0.00000
  • LogP 1.93520

Synthetic route

1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
100%
50%
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

Trichloroethylene
79-01-6

Trichloroethylene

Conditions
ConditionsYield
With methanol at 20℃; Inert atmosphere; UV-irradiation;A n/a
B n/a
C 43%
With Desulfomonile tiedjei DCB-1 In water at 35℃; Kinetics; Further Variations:; Reagents; time; concentration; Dehalogenation;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
at 100 - 250℃; Gleichgewicht der photochemischen Isomerisierung in der Gasphase im UV-Licht;
at 300℃; Gleichgewicht der thermischen Isomerisierung;
at 350℃; Gleichgewicht der thermischen Isomerisierung;
ethene
74-85-1

ethene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With oxygen; chlorine; copper(II) oxide at 375 - 425℃;
1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With copper chloride +pumice stone at 400 - 450℃;
With copper chloride; pumice stone at 400 - 450℃;
1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

Conditions
ConditionsYield
at 500℃; bei der thermischen Zersetzung;
at 500℃; Geschwindigkeit dieser Spaltung bei verschiedenen Temperaturen und Beschleunigung der Pyrolyse durch geringe Mengen Sauerstoff oder Chlor;
acetylene
74-86-2

acetylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With chlorine In solid at -213.1℃; Product distribution; Quantum yield; Mechanism; Irradiation; various temperatures;
With antimonypentachloride
With nitrosylchloride at 350℃;
acetylene
74-86-2

acetylene

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With aqueous CuCl2+CuCl+NH4Cl at 50 - 85℃;
With iron(III) chloride; ammonium chloride; copper(l) chloride at 50 - 85℃;
With hydrogenchloride; water; copper(l) chloride at 80 - 110℃;
acetylene
74-86-2

acetylene

A

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

B

1,1,1,2-tetrachoroethane
630-20-6

1,1,1,2-tetrachoroethane

Conditions
ConditionsYield
With chlorine; pyrographite at 40℃;
With chlorine; copper dichloride at 200 - 240℃;
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With sodium amalgam; water
With hydrogen; copper at 370 - 440℃;
With zinc In ethanol
1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

chloroethylene
75-01-4

chloroethylene

D

chloroacetylene
593-63-5

chloroacetylene

E

1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

F

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
under 0.2 Torr; Product distribution; Mechanism; Irradiation; laser photolysis, var. pressure, var. pulse energy, presence of var. gases;
1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

Ethyne; compound with chlorine
50835-27-3

Ethyne; compound with chlorine

D

Chloro-ethyne; hydrochloride
73787-86-7

Chloro-ethyne; hydrochloride

Conditions
ConditionsYield
With in Xe matrix at -261.2℃; Product distribution; Thermodynamic data; Irradiation; or with 1,1-dichloroethene-d2;
1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

Chloro-ethyne; hydrochloride
73787-86-7

Chloro-ethyne; hydrochloride

Conditions
ConditionsYield
With in Kr matrix at -261.2℃; Product distribution; Thermodynamic data; Irradiation;
acetylene
74-86-2

acetylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With chlorine at 21.9℃; under 700 Torr; for 0.00277778h; Product distribution; Mechanism; Irradiation; FTIR spectroscopic studies;
1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

chloroethylene
75-01-4

chloroethylene

D

chloroacetylene
593-63-5

chloroacetylene

E

1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

Conditions
ConditionsYield
With chloroethane; silicon tetrafluoride at 856.9 - 1076.9℃; Kinetics; Mechanism; Product distribution; Irradiation; also pyrolysis of 1,1,1-trichloroethane;A 15.6 % Chromat.
B 13.3 % Chromat.
C 1.58 % Chromat.
D 0.4 % Chromat.
E 0.44 % Chromat.
2,3-Dimethyl-2-butene
563-79-1

2,3-Dimethyl-2-butene

2-chloromethyl-3-chlorodiazirine

2-chloromethyl-3-chlorodiazirine

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

1-Chloro-1-chloromethyl-2,2,3,3-tetramethyl-cyclopropane

1-Chloro-1-chloromethyl-2,2,3,3-tetramethyl-cyclopropane

Conditions
ConditionsYield
at 30℃; Product distribution; Mechanism; Rate constant; Irradiation; other diazirines; var. temp.; also without irradiation; energy data: ΔHT;
dichloroethyne
7572-29-4

dichloroethyne

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With sodium chloride; zinc at 23℃; Kinetics; Reduction; anaerobic;
Trichloroethylene
79-01-6

Trichloroethylene

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
With sodium chloride; zinc at 23℃; Kinetics; Dehalogenation; anaerobic;
1,1,2,2-tetrachloroethylene
127-18-4

1,1,2,2-tetrachloroethylene

A

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

B

ethene
74-85-1

ethene

C

chloroethylene
75-01-4

chloroethylene

D

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With titanium(III) citrate; water; cyanocobalamin at 20℃; for 240h; Kinetics; Further Variations:; Reagents; Dehalogenation; β-elimination;
Trichloroethylene
79-01-6

Trichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

ethene
74-85-1

ethene

D

1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

Conditions
ConditionsYield
iron In water for 0.866667h; Dehalogenation;
Trichloroethylene
79-01-6

Trichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

ethene
74-85-1

ethene

D

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With vitamin B-12; titanium(III) citrate In water at 35℃; pH=7.05; Kinetics; Further Variations:; pH-values; Reagents; Reduction; dehalogenation;
Trichloroethylene
79-01-6

Trichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

1,1-Dichloroethylene
75-35-4

1,1-Dichloroethylene

D

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With titanium(III) citrate; water; cyanocobalamin at 20℃; for 280h; Kinetics; Further Variations:; Reagents; Dehalogenation; β-elimination;
1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

Trichloroethylene
79-01-6

Trichloroethylene

D

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With iron sulfide In water at 25℃; pH=8.3; Kinetics; Dehydrochlorination; dechlorination;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

bromine
7726-95-6

bromine

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
Kinetics; auch in Gegenwart von Antimonbromid;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

iodine
7553-56-2

iodine

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
at 185℃; Gleichgewicht der Isomerisierung in der Gasphase;
at 275℃; Gleichgewicht der Isomerisierung in der Gasphase;
at 150℃; under 7355.08 Torr; Rate constant; Isomerisierung;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

iodine
7553-56-2

iodine

benzene
71-43-2

benzene

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
at 100 - 120℃; Kinetics; photochemische Isomerisierung;
cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

platinum black

platinum black

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Conditions
ConditionsYield
at 180℃; Kinetics; Isomerisierung in der Gasphase;
water
7732-18-5

water

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

iron

iron

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

acetylene
74-86-2

acetylene

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

NiCl2

NiCl2

coal

coal

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

C

Trichloroethylene
79-01-6

Trichloroethylene

Conditions
ConditionsYield
at 350℃;
at 350℃;
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Chlorine(I) trifluoromethanesulfonate
65597-24-2

Chlorine(I) trifluoromethanesulfonate

Trifluoro-methanesulfonic acid 1,2,2-trichloro-ethyl ester
73323-79-2

Trifluoro-methanesulfonic acid 1,2,2-trichloro-ethyl ester

Conditions
ConditionsYield
In Dichlorodifluoromethane at -111 - -70℃; for 6h;100%
-111 to -70°C, 6 h;
-111 to -70°C, 6 h;
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Bromine(I) trifluoromethanesulfonate
70142-16-4

Bromine(I) trifluoromethanesulfonate

Trifluoro-methanesulfonic acid 2-bromo-1,2-dichloro-ethyl ester
73323-50-9

Trifluoro-methanesulfonic acid 2-bromo-1,2-dichloro-ethyl ester

Conditions
ConditionsYield
In Dichlorodifluoromethane at -111 - -100℃; for 1h;99%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

bis[bis(trimethylsilyl)methyl]germanium(II)
60111-69-5

bis[bis(trimethylsilyl)methyl]germanium(II)

[CHGeCl(CH(Si(CH3)3)2)2]2
182128-70-7

[CHGeCl(CH(Si(CH3)3)2)2]2

Conditions
ConditionsYield
In toluene 2 equiv. alkene, refluxing for 24 h; chromy. (SiO2, hexane); elem. anal.;99%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

hex-1-yne
693-02-7

hex-1-yne

(1E)-1-chloro-oct-1-en-3-yne
96251-51-3

(1E)-1-chloro-oct-1-en-3-yne

Conditions
ConditionsYield
98%
With triethylamine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 20℃; for 6h;94%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1-Phenyl-2-propyn-1-ol
4187-87-5

1-Phenyl-2-propyn-1-ol

(1E)-1-chloro-5-phenylpent-1-en-3-yn-5-ol
216689-47-3

(1E)-1-chloro-5-phenylpent-1-en-3-yn-5-ol

Conditions
ConditionsYield
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran for 1h; Ambient temperature;98%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

tris-iso-propylsilyl acetylene
89343-06-6

tris-iso-propylsilyl acetylene

(E)-(4-chlorobut-3-en-1-yn-1-yl)triisopropylsilane
402941-31-5

(E)-(4-chlorobut-3-en-1-yn-1-yl)triisopropylsilane

Conditions
ConditionsYield
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In diethyl ether at 20℃; for 5h; Inert atmosphere; Darkness;97%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine In tetrahydrofuran at 20℃; for 2h;91%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1-Heptyne
628-71-7

1-Heptyne

(E)-1-chloro-non-1-en-3-yne
77973-37-6

(E)-1-chloro-non-1-en-3-yne

Conditions
ConditionsYield
With iodine; N-butylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 6h; Ambient temperature;95%
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 20℃; for 2h;92%
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In diethyl ether for 4h; Ambient temperature;82%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1-Heptyne
628-71-7

1-Heptyne

(Z)-1-chloro-non-1-en-3-yne
77973-33-2

(Z)-1-chloro-non-1-en-3-yne

Conditions
ConditionsYield
With copper(l) iodide; N-butylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 5h; Ambient temperature;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

methyl propargyl sulphide
26842-65-9

methyl propargyl sulphide

(Z)-1-Chloro-5-methylsulfanyl-pent-1-en-3-yne
77973-36-5

(Z)-1-Chloro-5-methylsulfanyl-pent-1-en-3-yne

Conditions
ConditionsYield
With copper(l) iodide; N-butylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 5h; Ambient temperature;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

sodium isopropanethiolate
20607-43-6

sodium isopropanethiolate

2-{[(E)-2-(propan-2-ylsulfanyl)ethenyl]sulfanyl}propane
40588-88-3

2-{[(E)-2-(propan-2-ylsulfanyl)ethenyl]sulfanyl}propane

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide for 1h; Ambient temperature;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

3-(tetrahydropyran-2'-yloxy)propyne
6089-04-9

3-(tetrahydropyran-2'-yloxy)propyne

(Z)-1-choro-5-<(2-tetrahydropyranyl)oxy>-1-penten-3-yne
77973-34-3

(Z)-1-choro-5-<(2-tetrahydropyranyl)oxy>-1-penten-3-yne

Conditions
ConditionsYield
With copper(l) iodide; N-butylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 5h; Ambient temperature;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(3aR,7aR)-2,2-Dimethyl-7-oxo-2,3,3a,4,7,7a-hexahydro-1H-indene-5-carboxylic acid methyl ester

(3aR,7aR)-2,2-Dimethyl-7-oxo-2,3,3a,4,7,7a-hexahydro-1H-indene-5-carboxylic acid methyl ester

(2aS,3aS,6aS,7aS)-1,2-Dichloro-5,5-dimethyl-7-oxo-decahydro-cyclobuta[f]indene-2a-carboxylic acid methyl ester

(2aS,3aS,6aS,7aS)-1,2-Dichloro-5,5-dimethyl-7-oxo-decahydro-cyclobuta[f]indene-2a-carboxylic acid methyl ester

Conditions
ConditionsYield
In benzene Irradiation;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(3aS,6aR)-3,5,5-Trimethyl-1-oxo-1,3a,4,5,6,6a-hexahydro-pentalene-2-carboxylic acid methyl ester
445307-65-3

(3aS,6aR)-3,5,5-Trimethyl-1-oxo-1,3a,4,5,6,6a-hexahydro-pentalene-2-carboxylic acid methyl ester

(2aR,2bS,5aR,6aR)-1,2-Dichloro-2a,4,4-trimethyl-6-oxo-octahydro-cyclobuta[a]pentalene-6a-carboxylic acid methyl ester
445307-74-4

(2aR,2bS,5aR,6aR)-1,2-Dichloro-2a,4,4-trimethyl-6-oxo-octahydro-cyclobuta[a]pentalene-6a-carboxylic acid methyl ester

Conditions
ConditionsYield
In cyclohexane at 20℃; for 6h; Irradiation;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

cinnarizine
298-57-7

cinnarizine

1-[(2E)-3-chloroprop-2-en-1-yl]-4-(diphenylmethyl)piperazine

1-[(2E)-3-chloroprop-2-en-1-yl]-4-(diphenylmethyl)piperazine

Conditions
ConditionsYield
With C56H65F5MoN2O In toluene; paraffin oil at 50℃; for 4h; diastereoselective reaction;95%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1,1,2,2-tetrachloroethane
79-34-5

1,1,2,2-tetrachloroethane

Conditions
ConditionsYield
With 2,3-dimethylbutane In benzene at 20℃; Irradiation;94%
With chlorine at 80 - 95℃; unter Ausschluss von Sauerstoff;
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(3aS,6aR)-3,5,5-Trimethyl-1-oxo-1,3a,4,5,6,6a-hexahydro-pentalene-2-carboxylic acid methyl ester

(3aS,6aR)-3,5,5-Trimethyl-1-oxo-1,3a,4,5,6,6a-hexahydro-pentalene-2-carboxylic acid methyl ester

(2aS,2bR,5aS,6aS)-1,2-Dichloro-2a,4,4-trimethyl-6-oxo-octahydro-cyclobuta[a]pentalene-6a-carboxylic acid methyl ester

(2aS,2bR,5aS,6aS)-1,2-Dichloro-2a,4,4-trimethyl-6-oxo-octahydro-cyclobuta[a]pentalene-6a-carboxylic acid methyl ester

Conditions
ConditionsYield
With pyrex In cyclohexane Irradiation;94%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(E)-1-octen-1-ylboronic acid
42599-16-6

(E)-1-octen-1-ylboronic acid

(1E,3E)-1-chloro-1,3-decadiene
96251-47-7

(1E,3E)-1-chloro-1,3-decadiene

Conditions
ConditionsYield
With cesium fluoride; tris-(dibenzylideneacetone)dipalladium(0); XPhos In 1,4-dioxane at 100℃; Suzuki coupling;94%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

tert-butyl(2,6-dimethyl-7-octen-2-yloxy)dimethylsilane

tert-butyl(2,6-dimethyl-7-octen-2-yloxy)dimethylsilane

tert-butyl((8-chloro-2,6-dimethyloct-7-en-2-yl)oxy)dimethylsilane

tert-butyl((8-chloro-2,6-dimethyloct-7-en-2-yl)oxy)dimethylsilane

Conditions
ConditionsYield
With C56H65F5MoN2O In benzene at 22℃; for 0.25h; Glovebox; Inert atmosphere;94%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

mesityldiazonium tetrakis(pentafluorophenyl)borate

mesityldiazonium tetrakis(pentafluorophenyl)borate

(E)-(2-chlorovinyl)(mesityl)[tetrakis(pentafluorophenyl)borato]-λ3-chlorane

(E)-(2-chlorovinyl)(mesityl)[tetrakis(pentafluorophenyl)borato]-λ3-chlorane

Conditions
ConditionsYield
at 30℃; for 16h; Temperature; Sealed tube;94%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1-butyn-4-ol
927-74-2

1-butyn-4-ol

(5E)-6-chlorohex-5-en-3-yn-1-ol
180787-04-6

(5E)-6-chlorohex-5-en-3-yn-1-ol

Conditions
ConditionsYield
With piperidine; bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide In diethyl ether at 15 - 20℃; for 4h;93%
1-Octyn-3-ol
818-72-4

1-Octyn-3-ol

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(1E)-1-chloro-5-hydroxy-dec-1-en-3-yne
127744-31-4

(1E)-1-chloro-5-hydroxy-dec-1-en-3-yne

Conditions
ConditionsYield
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 20℃; for 2h;92%
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In diethyl ether for 4h; Ambient temperature;85%
copper; palladium
With copper(l) iodide; N-butylamine; tetrakis(triphenylphosphine) palladium(0) In benzene for 4h; Ambient temperature;
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1,4,1',4'-tetrahydro-1,4:1',4'-di-o-benzeno-2,2'-binaphthyl
120524-15-4

1,4,1',4'-tetrahydro-1,4:1',4'-di-o-benzeno-2,2'-binaphthyl

6,7-dichloro-5,6,7,8,13,14-hexahydro-5,14:8,13-di-o-benzenopentaphene
120524-16-5

6,7-dichloro-5,6,7,8,13,14-hexahydro-5,14:8,13-di-o-benzenopentaphene

Conditions
ConditionsYield
at 190 - 195℃; for 24h;91%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Acetate de non-8-ynyle
152644-99-0

Acetate de non-8-ynyle

Acetate de (E)-11-chloroundec-10-en-8-ynyle
152645-03-9

Acetate de (E)-11-chloroundec-10-en-8-ynyle

Conditions
ConditionsYield
copper(l) iodide; tetrakis(triphenylphosphine) palladium(0); N-butylamine In benzene Ambient temperature;91%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

diphenylphosphane
829-85-6

diphenylphosphane

trans-1,2-bis(diphenylphosphino)ethylene
983-81-3

trans-1,2-bis(diphenylphosphino)ethylene

Conditions
ConditionsYield
With triethylamine; bis(triphenylphosphine)nickel(II) chloride In N,N-dimethyl-formamide at 120℃; for 7h;91%
With potassium hydroxide In dimethyl sulfoxide at 60℃; for 1h;68.5%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

1-octyn-3-ol
32556-71-1

1-octyn-3-ol

(S)-(E)-1-chlorodec-1-en-3-yn-5-ol
246856-34-8

(S)-(E)-1-chlorodec-1-en-3-yn-5-ol

Conditions
ConditionsYield
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 20℃; for 3h; cross-coupling;91%
Stage #1: trans-1,2-dichloroethylene With copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 20℃; for 0.05h; Schlenk technique; Inert atmosphere;
Stage #2: 1-octyn-3-ol With triethylamine at 20℃; Schlenk technique; Inert atmosphere;
85%
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In benzene at 0 - 20℃; for 6h; Inert atmosphere;85%
1-decyne
764-93-2

1-decyne

trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

(E)-1-Chloro-dodec-1-en-3-yne
593288-35-8

(E)-1-Chloro-dodec-1-en-3-yne

Conditions
ConditionsYield
With piperidine; copper(l) iodide; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃;91%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

benzaldehyde
100-52-7

benzaldehyde

1-phenyl-3-trimethylsilylprop-2-yn-1-ol
89530-34-7

1-phenyl-3-trimethylsilylprop-2-yn-1-ol

Conditions
ConditionsYield
Stage #1: trans-1,2-dichloroethylene With n-butyllithium In tetrahydrofuran; hexane at 0℃;
Stage #2: benzaldehyde In tetrahydrofuran; hexane at 0℃;
Stage #3: trimethylsilyl trifluoromethanesulfonate Further stages;
91%
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

anthracene
120-12-7

anthracene

trans-7,8-dichloro-2,3:5,6-dibenzobicyclo<2.2.2>octa-2,5-diene
6476-15-9

trans-7,8-dichloro-2,3:5,6-dibenzobicyclo<2.2.2>octa-2,5-diene

Conditions
ConditionsYield
at 215℃; for 30h;90%
at 198 - 202℃;
trans-1,2-dichloroethylene
156-60-5

trans-1,2-dichloroethylene

Bicyclo [5.3.1]undec-10-en-9-one
73274-32-5

Bicyclo [5.3.1]undec-10-en-9-one

(1S,4S,7S)-2,3-Dichloro-tricyclo[5.5.1.01,4]tridecan-5-one
115025-24-6

(1S,4S,7S)-2,3-Dichloro-tricyclo[5.5.1.01,4]tridecan-5-one

Conditions
ConditionsYield
for 19h; Irradiation;90%

trans-1,2-Dichloroethylene Chemical Properties

IUPAC Name: (E)-1,2-Dichloroethene 
Molecular Weight: 96.94328 g/mol
Molecular Formula: C2H2Cl2 
Density: 1.243 g/cm3 
Melting Point: −57 °C(lit.)
Boiling Point: 47.7 °C at 760 mmHg 
Flash Point: 6.1 °C
Index of Refraction: 1.453
Molar Refractivity: 21.07 cm3
Molar Volume: 77.9 cm3
Surface Tension: 25.9 dyne/cm 
Enthalpy of Vaporization: 27.93 kJ/mol
Vapour Pressure: 333 mmHg at 25 °C 
Exact Mass: 95.953355
EINECS: 205-860-2 
Properties: colourless liquid 
Product categories: Organics ; Analytical Chemistry ; Standard Solution of Volatile Organic Compounds for Water , Soil Analysis ; Standard Solutions (VOC) ; Alpha Sort ; D ; DAlphabetic ; DIA - DIC ; Volatiles/ Semivolatiles 
Mmolecular structure of  trans-1,2-Dichloroethylene (CAS NO.156-60-5):

trans-1,2-Dichloroethylene Toxicity Data With Reference

1.    

skn-rbt 500 mg/24H MOD

    JACTDZ    Journal of the American College of Toxicology. 1 (1990),11.
2.    

eye-rbt 10 mg MOD

    JACTDZ    Journal of the American College of Toxicology. 1 (1990),11.
3.    

mma-smc 80 mmol/L

    TCMUD8    Teratogenesis, Carcinogenesis, and Mutagenesis. 4 (1984),365.
4.    

ihl-rat TCLo:12,000 ppm/6H (female 7-16D post):REP

    FAATDF    Fundamental and Applied Toxicology. 20 (1993),225.
5.    

ihl-hmn TCLo:4800 mg/m3/10M:CNS

    AHBAAM    Archiv fuer Hygiene und Bakteriologie. 116 (1936),131.
6.    

orl-rat LD50:1235 mg/kg

    TXCYAC    Toxicology. 7 (1977),141.
7.    

ipr-rat LD50:7411 mg/kg

    TXCYAC    Toxicology. 7 (1977),141.
8.    

orl-mus LD50:2122 mg/kg

    DCTODJ    Drug and Chemical Toxicology. 8 (1985),373.
9.    

ipr-rat LD50:7536 mg/kg

    TXCYAC    Toxicology. 7 (2)(1977),141.
10.    

ihl-mus LCLo:75,000 mg/m3/2H

    AHBAAM    Archiv fuer Hygiene und Bakteriologie. 116 (1936),131.
11.    

 

trans-1,2-Dichloroethylene Consensus Reports

Reported in EPA TSCA Inventory.

trans-1,2-Dichloroethylene Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. Human systemic effects by inhalation: sleep, hallucinations, and distorted perceptions. Experimental reproductive effects. A skin and eye irritant. Mutation data reported. Exposure to high vapor concentration can cause nausea, vomiting, weakness, tremor, and cramps. Recovery is usually prompt following removal from exposure. Dermatitis may result from defatting action on skin. Dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderate explosion hazard in the form of vapor when exposed to flame. Violent reaction with difluoromethylene dihypofluorite. Forms shock-sensitive explosive mixtures with dinitrogen tetraoxide. Reaction with solid caustic alkalies or their concentrated solutions produces chloracetylene gas that ignites spontaneously in air. Reacts violently with N2O4, KOH, Na, NaOH. Moderate explosion hazard in the form of vapor when exposed to flame. Can react vigorously with oxidizing materials. To fight fire, use water spray, foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl. See also CHLORIDES; CHLORINATED HYDROCARBONS, ALIPHATIC; and ACETYLENE COMPOUNDS and ALKYNES.
Hazard Codes: FlammableF, HarmfulXn, ToxicT
Risk Statements: 11-20-52/53-39/23/24/25-23/24/25 
R11: Highly flammable. 
R20: Harmful by inhalation. 
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R39: Danger of very serious irreversible effects. 
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed.
Safety Statements: 7-16-29-61-45-36/37 
S7: Keep container tightly closed. 
S16: Keep away from sources of ignition. 
S29: Do not empty into drains. 
S61: Avoid release to the environment. Refer to special instructions / safety data sheets. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37: Wear suitable protective clothing and gloves.
RIDADR: UN 1150 3/PG 2
WGK Germany: 2
RTECS: KV9400000
HazardClass: 3
PackingGroup: II

trans-1,2-Dichloroethylene Standards and Recommendations

DFG MAK: 200 ppm (800 mg/m3)

trans-1,2-Dichloroethylene Specification

The chemical synonyms of trans-1,2-Dichloroethylene (CAS NO.156-60-5) are (E)-1,2-Dichloroethene ; (E)-1,2-Dichloroethylene ; 4-01-00-00709 (Beilstein Handbook Reference) ; AI3-28786 ; BRN 1420761 ; CCRIS 2505 ; Ethylene, 1,2-dichloro-, trans- ; HCC 1130t ; HSDB 6361 ; NSC 60512 ; R 1130t ; RCRA waste number U079 ; trans-Acetylene dichloride ; trans-Dichloroethylene . It is highly flammable. Oxidizes in air to form unstable peroxides that may explode spontaneously. Avoid contact with copper and copper alloys. trans-1,2-Dichloroethylene reacts with alkalis, difluoromethylene, dihypofluorite, and nitrogen tetraoxide. Contact with solid alkalis or their concentrated solutions will cause formation of chloroacetylene, which ignites in air. Corrosive to metals unless an inhibitor has been added. Oxidation in the presence of concentrated sulfuric acid or a free radical initiator gives chloroacetyl chloride via epoxide intermediates. It is incompatible with organic peroxides.

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