In this work, the contribution of mediated oxidation mechanisms in the electrolytic degradation of cyanuric acid using boron-doped diamond (BDD) anodes was investigated in different electrolytes. A complete mineralization of cyanuric acid was obtained in NaCl; however lower degrees of mineraliza...
7-hydroxyisoflavone has been crystallized, identified, and characterized as 2 solvent-free conformational polymorphs and 5 solvates, which differ from each other in the mode of packing and in molecular conformation. All the 7 crystal structures were previously unreported. The conformational poly...
Objectives. Several urinary calculi were submitted to our institution for compositional analysis. The typical techniques of analysis, polarized light microscopy, electron microprobe analysis, and infrared spectroscopy proved inadequate for a definitive identification. As a result, a more detaile...
An acidic metabolite of glyceryl guaiacolate was isolated from human urine by solvent extraction and column chromatography. Combined GLC-mass spectrometry of the trimethylsilyl and trimethylsilyl-d9 derivatives of the metabolite and mass spectrometry of the underivatized metabolite have demonstr...
The effects of the membrane perturbing reagents linoleic acid and benzyl alcohol on the activities of four rat liver Golgi membrane enzymes, N-acetylglucosaminyl-, N-acetylgalactosaminyl-, galactosyl-, and sialytransferases and several soluble glycosyltransferases, bovine milk galactosyl- and N-...
(1) The effects of changes in the intramitochondrial volume, benzyl alcohol treatment and calcium-induced mitochondrial aging on the behaviour of liver mitochondria from control and glucagon-treated rats are reported. (2) The stimulatory effects of glucagon on mitochondrial respiration, pyruvate...
This study extends previous work on Cabernet Sauvignon wines of lowered alcohol concentrations produced by pre-fermentatively substituting proportions of juice from an overripe crop with “green harvest wine” or water to adjust initial sugar concentrations. Resulting wines were assessed for the...
We present a base free method for amide bond construction via oxidative coupling of alcohols with amines catalyzed by Silver(I) N-heterocyclic carbenes (Ag(I)-NHCs) and mediated by tert-butyl hydroperoxide (TBHP) in ethanol. The results of controlled experiments suggest that the oxidative coupli...
Bi(OTf)3 catalyzed disproportionation reaction of cinnamyl alcohols provides chalcones and benzyl styrenes. The use of various metal triflates is investigated herein for facile and efficient redox transformation. A plausible mechanism has been proposed.
Benzyl alcohol caused a rather complete and selective inhibition of the methylamine sensitive (i.e., the putative lysosomal) pathway of protein degradation in isolated rat hepatocytes. The effect was found to be entirely reversible within 30 min of removing the agent. A morphometric examination ...
One-dimensional (1D) TiO2 nanostructures can be used as the support of metal particles to form the heterostructures, which can prevent the metal agglomeration and enhance the activity of metal in various applications. Here, well-dispersed Ru nanoparticles (NPs) supported on 1D TiO2 nanobelts (NB...
Four supported catalysts with the same tungsten loading were prepared by depositing decatungstate species W10O4−32, through wet impregnation, on the surface of γ-alumina and silica at different pH values. The prepared samples were characterized using BET measurements as well as XRD, UV–vis DR,...
Based on energy band matching between RuO2 and TiO2, the RuO2/TiO2 nanobelt heterostructures are designed and fabricated. The formed heterostructures can efficiently enhance the separation of photogenerated electron-hole pairs and accelerate the transport of charges. Thanks to above-mentioned ad...
Benzyl alcohol (BnOH) is widely used as a component of foods, cosmetics, household products and medical products. It is generally considered to be safe for human use, however, it has been connected to a number of adverse effects, including hypersensitivity reactions and neonatal deaths. BnOH is ...
BackgroundOne of the serious postoperative complications associated with joint replacement is bacterial infection. In our recent investigations, iodine supported titanium implants demonstrated antibacterial activity in both in vitro and in vivo studies. The surfaces of the implants have porous a...
Exosomes are extracellular nanovesicles that play an important role in cellular communication. The modulatory effects of bone morphogenetic protein 2 (BMP2) on macrophages have encouraged the functionalization of scaffolds through the integration of the exosomes from the BMP2-stimulated macropha...
The goal of this study is to reveal mechanism of preparing high quality modified starch by advanced equipment in well-known modified starch enterprises. Corn starch was used as raw material to prepare starch acetate with low degree of substitution under grinding, and the effect of grinding on th...
During the last two decades metal injection molding (MIM) of titanium and titanium alloys developed to an established alternative technology to produce complex titanium parts with sound or even excellent properties. However, there are still concerns about supposed high costs and insufficient mec...
The thermal stability of membranes is currently a cause of major concern, keeping their competence for industrial application and high temperature cleaning in perspective. The present study explores the degree of membrane performance enhancement accomplished by the alterations introduced in memb...
Iron-titanium binary oxides were synthesized by template-assisted hydrothermal method. The effect of the variation in the Fe/Ti ratio and the temperature of hydrothermal treatment on the phase composition, structural, textural and redox characteristics of thus obtained materials was studied by N...
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