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Shandong Promise New Material Co., ltd.

We have the best quality of China,our product exports to all over the world. It is widely used in many different kinds of chemical area.We our quality means the best in China,even all over the world.We can export according to customers’ requir

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Metric Ton

FOB Price: $48000.0

Type:Trading Company

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

3-Bromofluorobenzene suppliers in China

Cas:1073-06-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality m-Fluorobromobenzene supplier in China

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Our Services 1. Certificate Of Analysis (COA) 2. Material Safety Data Sheet (MSDS) 3. Route of synthesis (ROS) 4. Method of Aanlysis (MOA)

1-Bromo-3-fluorobenzene

Cas:1073-06-9

Min.Order:1 Gram

FOB Price: $8.0

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

Good quality Good price Promptly delivery Appearance:white powder Storage:dry dondition Package:According to the demand of customer Application:intermediate Transportation:According to the demand of customer Port:shanghai

1073-06-9 3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1-bromo-3-fluorobenzene

Cas:1073-06-9

Min.Order:1

Negotiable

Type:Other

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 1073-06-9 3-Bromofluorobenzene Manufacturer

Cas:1073-06-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Kilogram

FOB Price: $8.0

Type:Manufacturers

inquiry

COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

3-bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

3-Bromofluorobenzene CAS 1073-06-9

Cas:1073-06-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFU-CHEM 1073-06-9 3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New product CAS 1073-06-9 with competitive price

Cas:1073-06-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS1073-06-9 3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Appearance:Clear colorless to light yellow liquid Storage:room temperature Package:200kg/Drum Application:Intermediates of Liquid Crystals Transportation:Express/Sea/Air Port:Any port in China

3-Bromofluorobenzene with high quality

Cas:1073-06-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best serv

3-Bromofluorobenzene 1073-06-9

Cas:1073-06-9

Min.Order:10 Gram

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzene,1-bromo-3-fluoro- 1073-06-9

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Kilogram

FOB Price: $85.0 / 100.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

3-Bromofluorobenzene CAS:1073-06-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inter

3-Bromofluorobenzene CAS:1073-06-9

Cas:1073-06-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzene,1-bromo-3-fluoro-

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Benzene,1-bromo-3-fluoro-/ LIDE PHARMA- Factory supply / Best price

Cas:1073-06-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1-bromo-3-fluoro-

Cas:1073-06-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

3-Bromofluorobenzene suppliers in China CAS NO.1073-06-9

Cas:1073-06-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 1073-06-9 cas 1073-06-9 3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Company Introduction 1. Established in 2005, with two independent business divisions: Fine chemicals division; Pharmaceutical division. 2. Main product: Optical brightener Textile auxiliary Dye stuff Pigments

3-BROMOFLUOROBENZENE

Cas:1073-06-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

3-Fluorobromobenzene

Cas:1073-06-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

3-Bromofluorobenzene

Cas:1073-06-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 1-Bromo-3-Fluorobenzene

Cas:1073-06-9

Min.Order:10 Gram

FOB Price: $10.0 / 100.0

Type:Lab/Research institutions

inquiry

Synthetic route

(3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate
1430342-19-0

(3-fluorophenyl)(mesityl)iodonium trifluoromethanesulfonate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Conditions
ConditionsYield
With copper(I) bromide In acetonitrile at 80℃; for 2h;91%
2-fluoro-4-bromoaniline sulfate

2-fluoro-4-bromoaniline sulfate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Conditions
ConditionsYield
With copper(I) oxide; sulfuric acid; sodium nitrite In water; isopropyl alcohol at -10 - 0℃; for 5h; Temperature; Reagent/catalyst; Solvent;82.7%
1,1,1-trifluoro-4-methyl-pent-3-en-2-one
400-31-7

1,1,1-trifluoro-4-methyl-pent-3-en-2-one

2-bromo-4-fluoro-1-iodobenzene

2-bromo-4-fluoro-1-iodobenzene

A

2,2′-dibromo-4,4′-difluorobiphenyl
124445-98-3

2,2′-dibromo-4,4′-difluorobiphenyl

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

4-(2-bromo-4-fluorophenyl)-1,1,1-trifluoro-4-methylpentan-2-one
1198785-52-2

4-(2-bromo-4-fluorophenyl)-1,1,1-trifluoro-4-methylpentan-2-one

D

2-(2-bromo-4-fluorophenyl)-1,1,1-trifluoro-4-methylpent-3-en-2-ol
1429053-26-8

2-(2-bromo-4-fluorophenyl)-1,1,1-trifluoro-4-methylpent-3-en-2-ol

E

2-bromo-4-fluoro-phenol
496-69-5

2-bromo-4-fluoro-phenol

Conditions
ConditionsYield
Stage #1: 2-bromo-4-fluoro-1-iodobenzene With isopropylmagnesium chloride In tetrahydrofuran at -30 - -25℃; for 0.5h; Inert atmosphere; Large scale;
Stage #2: 1,1,1-trifluoro-4-methyl-pent-3-en-2-one With copper(l) iodide In tetrahydrofuran at -30 - -25℃; for 4h; Inert atmosphere; Large scale;
A 0.5%
B 16%
C 75%
D 5%
E 0.5%
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With fluorine In trichlorofluoromethane at -78℃; for 1h;A 23 % Chromat.
B 17 % Chromat.
C 60 % Chromat.
With fluorine In trichlorofluoromethane at -78℃; for 1h; Rate constant; Product distribution; competitive reaction with benzene;A 23 % Chromat.
B 17 % Chromat.
C 60 % Chromat.
With xenon difluoride; boron trifluoride diethyl etherate In acetonitrile at -35 - 20℃; for 2.5h; Inert atmosphere; Overall yield = 56 %;
3-chlorofluorobenzene
625-98-9

3-chlorofluorobenzene

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Conditions
ConditionsYield
With bromobenzene; Cu-HZSM-5 zeolite at 399.9℃; Mechanism; various catalysts;14.3 % Chromat.
carbon disulfide
75-15-0

carbon disulfide

fluorobenzene
462-06-6

fluorobenzene

bromine
7726-95-6

bromine

aluminium

aluminium

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
at 55℃; Product distribution;
tetrachloromethane
56-23-5

tetrachloromethane

fluorobenzene
462-06-6

fluorobenzene

iodo monobromide

iodo monobromide

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

D

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
Product distribution;
fluorobenzene
462-06-6

fluorobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

D

HBr

HBr

Conditions
ConditionsYield
With bromine at 25℃; for 16h; Irradiation; Yield given;
3-bromo-benzenediazonium-(1)-tetrafluoroborate

3-bromo-benzenediazonium-(1)-tetrafluoroborate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

fluorobenzene
462-06-6

fluorobenzene

A

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

B

2-fluoro-1-bromo-benzene; 4-fluoro-1-bromo-benzene

2-fluoro-1-bromo-benzene; 4-fluoro-1-bromo-benzene

Conditions
ConditionsYield
With bromine at 400 - 700℃;
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2-bromo-1-oxypentafluorosulfanylbenzene
1000995-64-1

2-bromo-1-oxypentafluorosulfanylbenzene

C

4-bromo-1-oxypentafluorosulfanylbenzene
344455-90-9

4-bromo-1-oxypentafluorosulfanylbenzene

D

3-bromo-1-oxypentafluorosulfanylbenzene

3-bromo-1-oxypentafluorosulfanylbenzene

E

C6H3FBrOSF5

C6H3FBrOSF5

F

C6H3FBrOSF5

C6H3FBrOSF5

G

C6H3FBrOSF5

C6H3FBrOSF5

H

C6H3FBrOSF5

C6H3FBrOSF5

I

C6H3FBrOSF5

C6H3FBrOSF5

J

C6H3FBrOSF5

C6H3FBrOSF5

K

C6H3FBrOSF5

C6H3FBrOSF5

L

C6H3FBrOSF5

C6H3FBrOSF5

M

C6H3FBrOSF5

C6H3FBrOSF5

N

C6H3FBrOSF5

C6H3FBrOSF5

O

C6H4(OSF5)2

C6H4(OSF5)2

P

C6H4(OSF5)2

C6H4(OSF5)2

Q

C6H4(OSF5)2

C6H4(OSF5)2

R

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

S

1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

T

1.4-dibromobenzene
106-37-6

1.4-dibromobenzene

U

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

V

1,2-dibromobenzene
583-53-9

1,2-dibromobenzene

Conditions
ConditionsYield
With bis(pentafluorosulfur) peroxide at 100℃; for 17h;
1-Fluoro-3-iodobenzene
1121-86-4

1-Fluoro-3-iodobenzene

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 3-chloro-benzenecarboperoxoic acid
2: copper(I) bromide / acetonitrile / 2 h / 80 °C
View Scheme
bromobenzene
108-86-1

bromobenzene

A

o-fluorobromobenzene
1072-85-1

o-fluorobromobenzene

B

2-bromo-1,4-difluorobenzene
399-94-0

2-bromo-1,4-difluorobenzene

C

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

D

1-bromo-3,4-difluorobenzene
348-61-8

1-bromo-3,4-difluorobenzene

E

1-Bromo-4-fluorobenzene
460-00-4

1-Bromo-4-fluorobenzene

Conditions
ConditionsYield
With xenon difluoride; boron trifluoride diethyl etherate at 0 - 25℃; Cooling with ice;A 0.06 mmol
B 0.01 mmol
C 0.03 mmol
D 0.004 mmol
E 0.16 mmol
1-bromo-3-fluoro-2-(dimethylsilyl)-benzene

1-bromo-3-fluoro-2-(dimethylsilyl)-benzene

benzaldehyde
100-52-7

benzaldehyde

A

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

B

(2-bromo-6-fluorophenyl)(phenyl)methanol

(2-bromo-6-fluorophenyl)(phenyl)methanol

C

benzoic acid
65-85-0

benzoic acid

D

benzyl alcohol
100-51-6

benzyl alcohol

Conditions
ConditionsYield
With sodium hydroxide In tetrahydrofuran at 40℃; for 1h;
1-bromo-3-fluoro-2-(dimethylsilyl)-benzene

1-bromo-3-fluoro-2-(dimethylsilyl)-benzene

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Conditions
ConditionsYield
With water; sodium hydroxide In tetrahydrofuran at 40℃; for 1h;
2-Fluoroaniline
348-54-9

2-Fluoroaniline

A

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

B

1,3-dibromo-5-fluorobenzene
1435-51-4

1,3-dibromo-5-fluorobenzene

Conditions
ConditionsYield
Stage #1: 2-Fluoroaniline With sulfuric acid; dihydrogen peroxide; bromine at 10 - 15℃; for 0.5h;
Stage #2: With nitrosylsulfuric acid at 5℃; for 2h; Overall yield = 80.8 %;
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

formic acid ethyl ester
109-94-4

formic acid ethyl ester

bis(3-fluorophenyl)methanol
98586-21-1

bis(3-fluorophenyl)methanol

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With magnesium In tetrahydrofuran
Stage #2: formic acid ethyl ester In tetrahydrofuran at 0 - 20℃;
100%
With magnesium In diethyl ether for 18h; Heating;95%
Stage #1: 3-fluorobromobenzene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: formic acid ethyl ester In tetrahydrofuran at -78 - 0℃; for 1h; Further stages.;
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

N-methyl-N-phenylformamide
93-61-8

N-methyl-N-phenylformamide

2-bromo-6-fluorobenzaldehyde
360575-28-6

2-bromo-6-fluorobenzaldehyde

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With hydrogenchloride; n-butyllithium; diisopropylamine In tetrahydrofuran; hexanes at -78 - -70℃; for 2.5h;
Stage #2: N-methyl-N-phenylformamide In tetrahydrofuran; hexanes at -78 - -70℃; for 2h;
100%
(R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate
884510-86-5

(R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

(R)-tert-butyl 3-(3-fluorobenzoyl)piperidine-1-carboxylate
942142-91-8

(R)-tert-butyl 3-(3-fluorobenzoyl)piperidine-1-carboxylate

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With magnesium In tetrahydrofuran at 50 - 60℃; for 1h;
Stage #2: (R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate In tetrahydrofuran at -78 - 20℃; for 1.5h;
Stage #3: With water; ammonium chloride In tetrahydrofuran
100%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

3-fluorobiphenyl
2367-22-8

3-fluorobiphenyl

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene; phenylboronic acid With potassium phosphate In isopropyl alcohol at 20℃; for 4h; Suzuki Coupling;
Stage #2: [Pd2(μ-Cl)2{{(C2F5)2O}2H}2] In isopropyl alcohol at 20℃; for 20h; Suzuki Coupling;
100%
Stage #1: 3-fluorobromobenzene; phenylboronic acid With potassium phosphate In isopropyl alcohol at 20℃; for 2h; Suzuki coupling; Inert atmosphere;
Stage #2: With Juliphos In isopropyl alcohol at 20℃; for 20h; Suzuki coupling; Inert atmosphere;
100%
With potassium phosphate tribasic trihydrate; 1-(tert-butyl)-2-(diphenylphosphaneyl)-1H-imidazole; palladium dichloride In ethanol at 60℃; for 1h; Suzuki Coupling; Inert atmosphere; Schlenk technique;97%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

3-[2-(trimethylsilylethynyl)]phenol
388061-72-1

3-[2-(trimethylsilylethynyl)]phenol

3-((3-fluorophenyl)ethynyl)phenol

3-((3-fluorophenyl)ethynyl)phenol

Conditions
ConditionsYield
Stage #1: 3-[2-(trimethylsilylethynyl)]phenol With tetrabutyl ammonium fluoride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: 3-fluorobromobenzene With bis-triphenylphosphine-palladium(II) chloride In tetrahydrofuran at 80℃; for 24h;
100%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

ammonium chloride

ammonium chloride

formic acid ethyl ester
109-94-4

formic acid ethyl ester

bis(3-fluorophenyl)methanol
98586-21-1

bis(3-fluorophenyl)methanol

Conditions
ConditionsYield
With magnesium In tetrahydrofuran; water99%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

phenylboronic acid
98-80-6

phenylboronic acid

2-fluorobiphenyl
321-60-8

2-fluorobiphenyl

Conditions
ConditionsYield
With N-[2-(pyrazol-1-yl)phenyl]-N'-benzylimidazol-2-ylidene palladium chloride; caesium carbonate In water; isopropyl alcohol Reagent/catalyst; Suzuki-Miyaura Coupling;99%
styrene
292638-84-7

styrene

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

1-Fluoro-3-((E)-styryl)-benzene
88741-06-4

1-Fluoro-3-((E)-styryl)-benzene

Conditions
ConditionsYield
With N-[2-(3,5-dimethylpyrazol-1-yl)phenyl]-N'-benzylimidazol-2-ylidene palladium chloride; potassium carbonate In water; N,N-dimethyl-formamide Reagent/catalyst; Heck Reaction;99%
With potassium phosphate; C34H46Br4N8Pd2 In N,N-dimethyl-formamide at 110℃; for 4h; Heck Reaction;82%
With C74H61Cl2N3Pd; triethylamine In 1,4-dioxane for 10h; Heck Reaction;77%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

2-(3-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(3-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
With 10H-phenothiazine; caesium carbonate In acetonitrile for 48h; Irradiation; Sealed tube; Inert atmosphere;99%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In dimethyl sulfoxide at 80℃; for 48h; Inert atmosphere;31%
With {meso-1,3-bis(1-methylethyl)-4,5-(9,10-dihydroanthraceno)imidazolin-2-ylidene}copper(I) chloride; potassium tert-butylate In tert-butyl methyl ether at 25℃; for 4h; Inert atmosphere;63 %Spectr.
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane at 110℃; for 0.166667h; Miyaura Borylation Reaction; Microwave irradiation;
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

o-(phenylethynyl)trifluoroacetanilide
143360-89-8

o-(phenylethynyl)trifluoroacetanilide

3-(3-fluorophenyl)-2-phenyl-1H-indole

3-(3-fluorophenyl)-2-phenyl-1H-indole

Conditions
ConditionsYield
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 100℃; for 0.5h;98%
With caesium carbonate; tetrakis(triphenylphosphine) palladium(0) In acetonitrile at 100℃; for 3h;98%
quinoline-2-carbonitrile
1436-43-7

quinoline-2-carbonitrile

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

(3-fluorophenyl)(quinolin-2-yl)methanone
1177408-13-7

(3-fluorophenyl)(quinolin-2-yl)methanone

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With magnesium In tetrahydrofuran Inert atmosphere;
Stage #2: quinoline-2-carbonitrile In tetrahydrofuran; toluene at 0 - 20℃; Inert atmosphere;
Stage #3: With hydrogenchloride; water In diethyl ether for 0.333333h; Inert atmosphere;
98%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

2-(3-fluorophenyl)cyclohexane-1,3-dione

2-(3-fluorophenyl)cyclohexane-1,3-dione

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; di-tert-butyl (2'-methyl-[1,1'-biphenyl]-2-yl)phosphine In 1,4-dioxane; tert-Amyl alcohol Inert atmosphere; Reflux;98%
With potassium phosphate; palladium diacetate; di-tert-butyl (2'-methyl-[1,1'-biphenyl]-2-yl)phosphine In 1,4-dioxane; tert-Amyl alcohol Inert atmosphere; Reflux;98%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

4-cyclobutenylbenzeneboronic acid

4-cyclobutenylbenzeneboronic acid

4'-cyclobutenyl-3-fluorobiphenyl

4'-cyclobutenyl-3-fluorobiphenyl

Conditions
ConditionsYield
With 18-crown-6 ether; palladium diacetate; potassium carbonate In ethanol; water at 40 - 72℃; for 4h; Inert atmosphere;98%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C17H15F3O7S

C17H15F3O7S

C22H19FO4

C22H19FO4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In tetrahydrofuran; water at 80℃; for 10h; Inert atmosphere;98%
3,6-dioxa-1,8-diaminooctane
929-59-9

3,6-dioxa-1,8-diaminooctane

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

C18H22F2N2O2

C18H22F2N2O2

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; bis(dibenzylideneacetone)-palladium(0) In 1,4-dioxane Inert atmosphere;
Stage #2: 3,6-dioxa-1,8-diaminooctane With sodium t-butanolate In 1,4-dioxane for 8h; Reflux;
98%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

Propiolic acid
471-25-0

Propiolic acid

1,2-bis(3-fluorophenyl)ethyne
23349-16-8

1,2-bis(3-fluorophenyl)ethyne

Conditions
ConditionsYield
With Na2{PdCl2(Ph2P(m-C6H4SO3))2}; sodium 3-(diphenylphosphanyl)benzenesulfonate; trimethyloctadecylammonium chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene In water for 20h; Heating;97%
With bis-triphenylphosphine-palladium(II) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene; 1,4-di(diphenylphosphino)-butane In dimethyl sulfoxide at 80℃; for 16h; Inert atmosphere;
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

1-(S-phenylsulfonimidoyl)piperidine
1523523-71-8

1-(S-phenylsulfonimidoyl)piperidine

1-[N-(3-fluorophenyl)-S-phenylsulfonimidoyl]piperidine

1-[N-(3-fluorophenyl)-S-phenylsulfonimidoyl]piperidine

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In toluene at 20 - 100℃; Inert atmosphere;97%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

6-(6-(2,2,2-trifluoroethyl)thieno[2,3-d]pyrimidin-4-yl)-6-azaspiro[3.4]octan-2-amine trifluoroacetate

6-(6-(2,2,2-trifluoroethyl)thieno[2,3-d]pyrimidin-4-yl)-6-azaspiro[3.4]octan-2-amine trifluoroacetate

C21H20F4N4S

C21H20F4N4S

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; sodium t-butanolate In 1,4-dioxane at 110℃; for 2h; Inert atmosphere;96%
acetic acid tert-butyl ester
540-88-5

acetic acid tert-butyl ester

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

tert-butyl α-(3-fluorophenyl)acetate
476429-07-9

tert-butyl α-(3-fluorophenyl)acetate

Conditions
ConditionsYield
With tri-tert-butyl phosphine; lithium dicyclohexylamide; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; for 15h;95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

diisopropylmagnesium
3536-97-8

diisopropylmagnesium

C9H11FMg

C9H11FMg

Conditions
ConditionsYield
at 20℃; for 3h;95%
2-methylquinoline
91-63-4

2-methylquinoline

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

2-(3-fluorobenzyl)quinoline
1334723-87-3

2-(3-fluorobenzyl)quinoline

Conditions
ConditionsYield
Stage #1: 2-methylquinoline With zinc chloride-2,2,6,6-tetramethylpiperidin-1-ide lithium chloride complex In tetrahydrofuran at 25℃; for 1h; Inert atmosphere;
Stage #2: 3-fluorobromobenzene With palladium diacetate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 50℃; for 1h; Inert atmosphere;
95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

cyclohexylmagnesium bromide
931-50-0

cyclohexylmagnesium bromide

1-cyclohexyl-3-fluorobenzene
1717-83-5

1-cyclohexyl-3-fluorobenzene

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II) In tetrahydrofuran for 0.0833333h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;
Stage #2: cyclohexylmagnesium bromide With lithium bromide In tetrahydrofuran at 20℃; for 24h; Reagent/catalyst; Inert atmosphere; Schlenk technique;
95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

1-phenyl-1-butyne
622-76-4

1-phenyl-1-butyne

C16H15F

C16H15F

Conditions
ConditionsYield
With chloro[1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene]copper(I); 4,4,5,5-tetramethyl-2-(4,4,5,5-tetramethyl-1,3-dioxolan-2-yl)-1,3,2-dioxaborolane; [PdCl2(N,N’-bis-[2,6-(diisopropyl)phenyl]imidazolidin-2-ylidene){P(N,N’-bis-[2,6-(diisopropyl)phenyl]imidazol-2-ylidene)3}]; potassium 2-methylbutan-2-olate In ethanol at 80℃; for 20h; Glovebox; regioselective reaction;95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

3'-fluoro[1,1'-biphenyl]-4-carbaldehyde
400750-63-2

3'-fluoro[1,1'-biphenyl]-4-carbaldehyde

Conditions
ConditionsYield
With C5H6N2*Pd(2+)*2Cl(1-); potassium carbonate In ethanol; water for 0.166667h; Suzuki-Miyaura Coupling; Reflux; Schlenk technique;95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

2-bromo-4-methylbenzaldehyde
824-54-4

2-bromo-4-methylbenzaldehyde

(2-bromo-4-methylphenyl)(3-fluorophenyl)methanol

(2-bromo-4-methylphenyl)(3-fluorophenyl)methanol

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: 2-bromo-4-methylbenzaldehyde In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere; Schlenk technique;
95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

phenyl[(2-phenylsulfanyl)phenyl]methanone
52252-61-6

phenyl[(2-phenylsulfanyl)phenyl]methanone

C25H19FOS

C25H19FOS

Conditions
ConditionsYield
Stage #1: 3-fluorobromobenzene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.0833333h; Inert atmosphere;
Stage #2: phenyl[(2-phenylsulfanyl)phenyl]methanone In tetrahydrofuran; hexane at -78℃; Inert atmosphere;
95%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

2-(3-bromo-5-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1357266-25-1

2-(3-bromo-5-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions
ConditionsYield
Stage #1: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer In tetrahydrofuran at 20℃; Glovebox; Inert atmosphere;
Stage #2: With 2,2'-methylenebis( N,N)-dimethylpyridin-4-amine In tetrahydrofuran at 20℃; for 0.25h; Glovebox; Inert atmosphere;
Stage #3: 3-fluorobromobenzene In tetrahydrofuran at 20℃; for 5h; Glovebox; Inert atmosphere; regioselective reaction;
95%
methyl cyclohexylcarboxylate
4630-82-4

methyl cyclohexylcarboxylate

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

methyl α-(3-fluorophenyl)cyclohexanecarboxylate

methyl α-(3-fluorophenyl)cyclohexanecarboxylate

Conditions
ConditionsYield
With tri-tert-butyl phosphine; lithium dicyclohexylamide; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; for 24h;94%
3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

phenylacetylene
536-74-3

phenylacetylene

1-fluoro-3-(2-phenylethynyl)benzene
29778-28-7

1-fluoro-3-(2-phenylethynyl)benzene

Conditions
ConditionsYield
With tetrabutylammomium bromide; sodium acetate In dimethyl sulfoxide at 110℃; for 35h; Sonogashira Cross-Coupling; Inert atmosphere;94%
With potassium phosphate; C30H37Br2N3Pd(2-) In dimethyl sulfoxide at 100℃; for 1h; Sonogashira Cross-Coupling;84%
With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; diisopropylamine; tri tert-butylphosphoniumtetrafluoroborate In 1,4-dioxane at 20℃; Schlenk technique; Inert atmosphere;83%
With C34H40Br2N3Pd; potassium carbonate In dimethyl sulfoxide at 100℃; for 1h; Sonogashira coupling;59%
With Sonogashira catalyst CMX-1 In HN(iPr)2 at 80℃; Sonogashira coupling;
3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione
58-08-2

3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione

3-fluorobromobenzene
1073-06-9

3-fluorobromobenzene

1,3,7-trimethyl-8-(m-fluorophenyl)-xanthine
1161823-22-8

1,3,7-trimethyl-8-(m-fluorophenyl)-xanthine

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; 1,10-Phenanthroline In 5,5-dimethyl-1,3-cyclohexadiene; N,N-dimethyl-formamide at 20 - 140℃; for 36.1667h; Inert atmosphere; regioselective reaction;94%

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