4-Biphenylcarboxaldehyde supplier

Name
4-Biphenylcarboxaldehyde
EINECS 221-742-3
CAS No. 3218-36-8
Article Data536
CAS DataBase
Density 1,107 g/cm³
Solubility 17mg/L at 20℃
Melting Point 57-59 °C(lit.)
Formula C₁₃H₁₀O
Boiling Point 326.6 °C at 760 mmHg
Molecular Weight 182.222
Flash Point 186.1 °C
Transport Information
Appearance off-white crystalline powder
Safety 26-36
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 4-Biphenylcarboxaldehyde(6CI,7CI,8CI);Benzaldehyde, p-phenyl- (3CI);4-Biphenylaldehyde;4-Formyl-1,1'-biphenyl;4-Formylbiphenyl;Biphenyl-4-carbaldehyde;NSC 46066;p-Biphenylaldehyde;p-Biphenylcarboxaldehyde;p-Phenylbenzaldehyde;
PSA 17.07000
LogP 3.16610

Synthetic route

: 104-88-1
4-chlorobenzaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate In methanol at 100℃; for 0.166667h; Suzuki-Miyaura Coupling; Microwave irradiation;	100%
With 2,2-bis-(N-2-morpholinethylbenzimidazolium)-ethylether dichloride; potassium tert-butylate; palladium diacetate In water; N,N-dimethyl-formamide at 50℃; for 3h; Reagent/catalyst; Suzuki Coupling;	100%
With caesium carbonate; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane for 1h; Suzuki-Miyaura coupling; Heating;	99%

: 1122-91-4
4-bromo-benzaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With sodium phosphate; palladium on activated charcoal In water; isopropyl alcohol at 20℃; for 6h; Suzuki-Miyaura reaction;	100%
With sodium carbonate; palladium on activated charcoal In ethanol at 20℃; for 5h; Suzuki-Miyaura cross-coupling;	100%
With potassium carbonate; bis(2-diphenylphosphinoxynaphthalen-1-yl)methane; palladium diacetate In methanol at 20℃; for 1h; Suzuki cross-coupling reaction;	100%

: 3597-91-9
biphenyl-4-yl methanol

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With n-butyltriphenylphosphonium permanganate In acetonitrile at 20℃; for 0.25h;	100%
With silica-supported Jones reagent In dichloromethane for 0.00269444h;	99.7%
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; N-methyl-N-[3-(4'-diacetoxyiodo)phenoxy-1-propyl]pyrrolidinium 4-methylbenzenesulfonate In dichloromethane at 20℃; for 6h;	99%

: 15164-44-0
p-(iodophenyl)carboxaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With [Pd(N-(naphthyl)-salicylaldimine(-2H))(triphenylphosphine)]; sodium hydroxide at 120℃; for 3h; Suzuki Coupling;	100%
With tetra-n-propylammonium bromide; sodium carbonate In water at 100℃; for 0.5h; Catalytic behavior; Suzuki-Miyaura Coupling;	100%
With potassium carbonate; palladium dichloride In water at 20 - 90℃; Suzuki coupling; Inert atmosphere;	99%

: 79913-05-6
1,1-diacetoxy-1-(4-biphenyl)methane

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
zeolite HSZ-360 for 0.333333h; Irradiation;	99%
With zirconium(IV) chloride In methanol at 20℃; for 0.05h;	96%
With 2,6-dicarboxypyridinium chlorochromate In acetonitrile at 20℃; for 0.5h;	70%

: 591-50-4
iodobenzene

: 87199-17-5
4-formylphenylboronic acid,

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With bis(1,1'-ethylene-3,3'-divinylimidazole-2,2'-diylidene)nickel(II) dibromide dihydrate; potassium carbonate In water; N,N-dimethyl-formamide at 100℃; for 8h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;	99%
With potassium carbonate In water; N,N-dimethyl-formamide at 30℃; for 4h; Suzuki-Miyaura Coupling; Irradiation; Inert atmosphere;	98%
With potassium phosphate In ethanol; water at 80℃; for 3h; Suzuki-Miyaura Coupling;	98%

: 108-86-1
bromobenzene

: 87199-17-5
4-formylphenylboronic acid,

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate In ethanol; water at 80℃; for 2h; Suzuki-Miyaura Coupling;	99%
With palladium diacetate In water; isopropyl alcohol at 27℃; for 1h; Suzuki-Miyaura Coupling;	96%
With C12H12Cl2N4O2Pd; caesium carbonate In water at 60℃; for 5h; Suzuki-Miyaura Coupling;	90%

: 143-66-8
sodium tetraphenyl borate

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With sodium hydroxide; palladium diacetate In water at 110℃; for 2h; Suzuki-type reaction;	99%
With sodium carbonate at 100℃; for 0.666667h; Suzuki Coupling;	97%
With sodium carbonate at 80℃; for 0.716667h; Catalytic behavior; Suzuki Coupling;	97%

: 24388-23-6
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

: 104-88-1
4-chlorobenzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate In water at 20℃; for 6h; Suzuki-Miyaura Coupling;	99%

: 40143-27-9
biphenyl-4-carbaldehyde oxime

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With 1-benzyl-4-aza-1-azoniabiyclo<2.2.2>octane peroxodisulfate In acetonitrile for 0.25h; Heating;	98%
With 1-benzyl-4-aza-1-azoniabiyclo<2.2.2>octane peroxodisulfate In acetonitrile for 0.25h; Oxidation; Heating;	98%
With tris[trinitratocerium(IV)] paraperiodate at 90℃; for 0.166667h;	95%
With Nitrogen dioxide In acetonitrile at 25℃; for 0.0833333h;

: 17763-69-8
4-(trifluormethanesulfonyloxy)benzaldehyde

: triethylammonium bis(1,2-benzenediolato)phenylsilicate

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With tetrabutyl ammonium fluoride; bis(dibenzylideneacetone)-palladium(0); CyJohnPhos In tetrahydrofuran for 6h; Heating;	98%

: 1122-91-4
4-bromo-benzaldehyde

: potassium phenyltrifluoborate

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With [Pd(N-(3-chloro-2-quinoxalinyl)-N'-(2,6-diisopropylphenyl)imidazolium)(PPh3)Cl2]; potassium carbonate In water at 70℃; for 3h; Catalytic behavior; Suzuki-Miyaura Coupling;	98%
With palladium diacetate; potassium carbonate In ethanol; water at 25℃; for 2h; Suzuki-Miyaura Coupling;	95%
With 5%-palladium/activated carbon; oxygen; potassium carbonate In ethanol; water at 80℃; for 0.416667h; Suzuki-Miyaura Coupling;	93%

: 960-16-7
tributylphenylstannane

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With cesium fluoride In water; N,N-dimethyl-formamide at 40℃; for 5h; Stille coupling;	98%
With [Pd{C6H2-(CH2CH2NH2)-(OMe)2-3,4}Br(PPh3)]; potassium carbonate In N,N-dimethyl-formamide at 90℃; for 0.0666667h; Stille coupling; Microwave irradiation;	95%
With C31H33INPPd In N,N-dimethyl-formamide at 80℃; for 24h; Stille coupling;	93%

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate In tetrahydrofuran; water at 25℃; Suzuki coupling;	98%

: 202264-90-2
4-(dibromomethyl)-1,1'-biphenyl

: 67-68-5
dimethyl sulfoxide

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
at 100℃; for 2h;	97%

: 1122-91-4
4-bromo-benzaldehyde

: 639-58-7
triphenyltin chloride

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With sodium carbonate at 80℃; for 3.16667h; Catalytic behavior; Stille Cross Coupling;	97%
With (2-methylacetatobenzyl)triphenylphosphonium hexabromodipalladate(II); potassium carbonate at 90℃; for 0.166667h; Stille Cross Coupling;	95%
With potassium carbonate for 0.4h; Stille Cross Coupling;	95%

: 87199-17-5
4-formylphenylboronic acid,

: 135654-49-8
diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With bis(tri-t-butylphosphine)palladium(0); sodium hydrogencarbonate In N,N-dimethyl-formamide at 60℃; for 6h; Suzuki-Miyaura Coupling; Inert atmosphere; Glovebox; Sealed tube;	97%

: 92-66-0
4-bromo-1,1'-biphenyl

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With samarium; copper(l) iodide at 20℃; for 4h; Inert atmosphere;	96%
Formylation;	88%
(i) nBuLi, Et2O, (ii) /BRN= 605365/; Multistep reaction;

: 853955-69-8
[2-(hydroxymethyl)phenyl](dimethyl)phenylsilane

: 15164-44-0
p-(iodophenyl)carboxaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate; N-cyclohexyl-1-[2-(diphenylphosphanyl)phenyl]methanimine; palladium dichloride In water; dimethyl sulfoxide at 50℃; for 27h;	96%

: phenyl(triphenyl-λ5-phosphanyl)gold

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With dichlorobis(tricyclohexylphosphine)nickel(II) In benzene at 25℃; for 1h;	96%

: phenylzinc iodide-lithium chloride complex

: 3446-89-7
4-(Methylthio)benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
Stage #1: phenylzinc iodide-lithium chloride complex With trans-[1,3-bis(2,6-diisopropylphenyl)imidazolin-2-ylidene]PdCl2(NC5H5) In tetrahydrofuran at 20℃; for 0.05h; Inert atmosphere; Stage #2: 4-(Methylthio)benzaldehyde In tetrahydrofuran; acetonitrile at 20℃; for 4h; Inert atmosphere;	96%

: 88654-54-0
4-formylbenzene-1-sulfonyl fluoride

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With palladium diacetate; diisopropylamine In ethanol; water at 25℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Temperature; Suzuki-Miyaura Coupling;	96%

: 2996-92-1
phenyl trimethylsiloxane

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With sodium hydroxide; PEG encapsulated palladium nanoparticle In water at 90℃; for 2.5h; Hiyama cross-coupling reaction;	95%
With sodium hydroxide In ethanol; water at 110℃; for 0.1h; Hiyama coupling; Microwave irradiation;	95%
With sodium hydroxide In ethylene glycol at 100℃; for 1h; Hiyama Coupling;	95%

: 17763-69-8
4-(trifluormethanesulfonyloxy)benzaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With sodium carbonate; palladium on activated charcoal In ethanol; water at 20℃; for 24h; Suzuki-Miyaura coupling reaction;	95%

: 4426-21-5
oxybis(diphenylborane)

: 104-88-1
4-chlorobenzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With triphenyl phosphite; potassium phosphate tribasic trihydrate; N,N′-bis(2,6-diisopropylphenyl)imidazol-2-ylidene hydrochloride; palladium diacetate In tert-butyl alcohol at 80℃; for 4h; Inert atmosphere;	95%

: 80459-48-9
4-tosyloxybenzaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With 1,1'-bis-(diphenylphosphino)ferrocene; (9-phenanthrenyl)Ni(II)(PPh3)2Cl; potassium carbonate In toluene at 110℃; for 20h; Suzuki Coupling; Inert atmosphere;	95%
With 2-hydroxy-3-(p-tolyl)-2,3-dihydroindan-1-one; palladium diacetate; potassium carbonate In ethanol for 2h; Reagent/catalyst; Solvent; Time; Suzuki-Miyaura Coupling; Reflux;	92%
With potassium phosphate; Ni(1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidene)[P(OPh)3]2 In tetrahydrofuran at 70℃; for 18h; Suzuki-Miyaura Coupling; Sealed tube;	22%

: 123-08-0
4-hydroxy-benzaldehyde

: 98-80-6
phenylboronic acid

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
Stage #1: 4-hydroxy-benzaldehyde With fluorosulfonyl fluoride; potassium carbonate In ethanol; water at 20℃; for 4h; Stage #2: phenylboronic acid With potassium carbonate; palladium dichloride In ethanol; water at 20℃; for 6h;	95%
With potassium phosphate; 1,3-bis[(diphenylphosphino)propane]dichloronickel(II); 4-methyl-N-phenyl-N-tosylbenzenesulfonamide In 1,4-dioxane at 110℃; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;	90%
Stage #1: 4-hydroxy-benzaldehyde With potassium phosphate; fluorosulfonyl fluoride In 1,4-dioxane at 20℃; for 48h; Stage #2: phenylboronic acid With bis(tricyclohexylphosphine)nickel(II) dichloride; tricyclohexylphosphine tetrafluoroborate In 1,4-dioxane at 80℃; for 15h;	40%

: 24388-23-6
2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole

: 1122-91-4
4-bromo-benzaldehyde

: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With potassium carbonate In ethanol; water at 20℃; Suzuki-Miyaura Coupling; Green chemistry;	95%
With dichloro bis(acetonitrile) palladium(II); potassium phosphate; 1,1'-bis(di-tertbutylphosphino)ferrocene In tetrahydrofuran; water at 60℃; for 20h; Suzuki Coupling; Inert atmosphere;	88%
With potassium hydroxide In water; isopropyl alcohol at 80℃; for 6h; Reagent/catalyst; Suzuki-Miyaura Coupling; Schlenk technique; Green chemistry;

: 595-90-4
tetraphenyltin(IV)

: 1122-91-4
4-bromo-benzaldehyde

A: 92-52-4
biphenyl

B: 3218-36-8
4-Phenylbenzaldehyde

Conditions

Conditions	Yield
With dmap; palladium dichloride for 0.333333h; Stille Cross Coupling; Microwave irradiation;	A 3% B 95%

...Expand

: 2408-36-8
lithium cyanide

: 98-88-4
benzoyl chloride

: 3218-36-8
4-Phenylbenzaldehyde

: 108583-45-5
α-Benzoyloxy-α-(4-biphenylyl)acetonitrile

Conditions

Conditions	Yield
In tetrahydrofuran for 0.5h; Ambient temperature;	100%

...Expand

: 609-20-1
2,6-dichloro-p-phenylenediamine

: 3218-36-8
4-Phenylbenzaldehyde

: 84562-39-0
N'-[1-Biphenyl-4-yl-meth-(E)-ylidene]-2,6-dichloro-benzene-1,4-diamine

Conditions

Conditions	Yield
In ethanol for 1.5h; Heating;	100%

: 3218-36-8
4-Phenylbenzaldehyde

: 210686-44-5
4-(thiomorpholinomethyl)aniline

: [1-Biphenyl-4-yl-meth-(E)-ylidene]-(4-thiomorpholin-4-ylmethyl-phenyl)-amine

Conditions

Conditions	Yield
With acetic acid	100%
With acid Condensation;	93%

: 870-46-2
t-butoxycarbonylhydrazine

: 3218-36-8
4-Phenylbenzaldehyde

: N'-[1-Biphenyl-4-yl-meth-(E)-ylidene]-hydrazinecarboxylic acid tert-butyl ester

Conditions

Conditions	Yield
In ethanol for 4h; Heating;	100%

: 3218-36-8
4-Phenylbenzaldehyde

: 204126-54-5
N2-[2R-isobutyl-3S-(9-fluorenylmethoxycarbonylamino)-4-hydroxysuccinyl]-L-tert-leucine-N1-methylamide

: 2-[(biphenyl-4-ylmethyl)-amino]-N4-(2,2-dimethyl-1-methylcarbamoyl-propyl)-N1-hydroxy-3-isobutyl-succinamide

Conditions

Conditions	Yield
Multistep reaction;	100%

: 339-59-3
4-(trifluoromethyl)benzoic acid hydrazide

: 3218-36-8
4-Phenylbenzaldehyde

: 868842-52-8
4-trifluoromethylbenzoyl acid biphenyl-4-yl-methylene hydrazide

Conditions

Conditions	Yield
In methanol for 3h; Heating / reflux;	100%

: 3218-36-8
4-Phenylbenzaldehyde

: 57260-71-6
1-t-Butoxycarbonylpiperazine

: 1322768-09-1
tert-butyl 4-([1,1'-biphenyl]-4-ylmethyl)piperazine-1-carboxylate

Conditions

Conditions	Yield
With triethylamine; trimethyl orthoformate In dichloromethane at 20℃; for 1h;	100%
With sodium tris(acetoxy)borohydride; acetic acid In methanol for 15h; Inert atmosphere;

: 3218-36-8
4-Phenylbenzaldehyde

: 74-89-5
methylamine

: C14H13N

Conditions

Conditions	Yield
With magnesium sulfate In dichloromethane for 2h; Reflux;	100%

: 3218-36-8
4-Phenylbenzaldehyde

: 98-80-6
phenylboronic acid

: 613-37-6
4-methoxylbiphenyl

Conditions

Conditions	Yield
With [Pd(N-(naphthyl)-4-methoxy-salicylaldimine(-2H))(triphenylphosphine)]; sodium hydroxide at 120℃; for 4h; Reagent/catalyst; Suzuki Coupling;	100%

: 36062-19-8
1,3-diaminoguanidine hydrochloride

: 3218-36-8
4-Phenylbenzaldehyde

: 2,2′-bis[(1,1'-biphenyl-4-yl)methylene]carbonimidic dihydrazide monohydrochloride

Conditions

Conditions	Yield
In ethanol for 16h; Reflux;	100%
In ethanol at 100℃; for 0.166667h; Microwave irradiation;	81%

: 1560-56-1
(methyl-d3)triphenylphosphonium iodide

: 3218-36-8
4-Phenylbenzaldehyde

: 57204-39-4
4-(vinyl-β,β-d2)-1,1'-biphenyl

Conditions

Conditions	Yield
With sodium hydride In tetrahydrofuran; mineral oil at 20℃; for 16h; Cooling;	100%

: 540-63-6
ethane-1,2-dithiol

: 3218-36-8
4-Phenylbenzaldehyde

: 134261-69-1
2-biphenyl-4-yl-1,3-dithiolane

Conditions

Conditions	Yield
With amberlyst-15 In acetonitrile for 1h;	99.97%
With zeolite HSZ-360 In dichloromethane for 15h; Ambient temperature;	88%

: 3218-36-8
4-Phenylbenzaldehyde

: 109-77-3
malononitrile

: 26089-09-8
2-([1,1’-biphenyl]-4-ylmethylene)malononitrile

Conditions

Conditions	Yield
In ethanol; water for 23h; Knoevenagel condensation;	99%
With potassium carbonate In ethanol at 70℃; under 750.075 Torr; for 2.5h; Inert atmosphere;	99.9%
With [Cd(2,4,5-tris(pyridin-4-yl)imidazole)(naphthalene-1,5-disulfonate)]n In neat (no solvent) at 20℃; for 24h; Knoevenagel Condensation; Green chemistry;	97%

: 109-80-8
1.3-propanedithiol

: 3218-36-8
4-Phenylbenzaldehyde

: 54527-55-8
2-([1,1'-biphenyl]-4-yl)-1,3-dithiane

Conditions

Conditions	Yield
With amberlyst-15 In acetonitrile for 1h;	99.06%
With hydrogenchloride In benzene Heating;
With hydrogenchloride In chloroform for 0.583333h;
With boron trifluoride diethyl etherate In dichloromethane Inert atmosphere;
With boron trifluoride diethyl etherate In dichloromethane at 0 - 25℃;

: 3218-36-8
4-Phenylbenzaldehyde

: 40143-27-9
biphenyl-4-carbaldehyde oxime

Conditions

Conditions	Yield
With hydroxylamine hydrochloride; sodium carbonate In methanol; water at 20℃; for 3h;	99%
With sodium hydroxide; hydroxylamine hydrochloride In ethanol; water at 25 - 30℃; for 1h;	98%
With hydroxylamine hydrochloride; sodium acetate In tetrahydrofuran; ethanol; water at 20℃; for 72h;	98%

: 3218-36-8
4-Phenylbenzaldehyde

: 108-46-3
recorcinol

: 118600-31-0, 118711-37-8, 181231-13-0
C76H56O8

Conditions

Conditions	Yield
With hydrogenchloride In ethanol at 80℃; for 48h;	99%

: 3218-36-8
4-Phenylbenzaldehyde

: 2920-38-9
4-cyano-1,1'-biphenyl

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid; O-benzenesulfonyl-acetohydroxamic acid ethyl ester In dichloromethane at 23℃; for 24h; Inert atmosphere;	99%
With ammonium sulfate; sodium carbonate; sulfur In dimethyl sulfoxide at 120℃; for 10h; Sealed tube;	99%
With trifluorormethanesulfonic acid; trimethylsilylazide In acetonitrile at 25℃; for 0.00277778h; Schmidt Reaction; Flow reactor;	98%

: 3218-36-8
4-Phenylbenzaldehyde

: 3597-91-9
biphenyl-4-yl methanol

Conditions

Conditions	Yield
Stage #1: 4-Phenylbenzaldehyde With zinc diacetate In tetrahydrofuran at 65℃; for 0.166667h; Stage #2: With methyl-di(n-propoxy)silane In tetrahydrofuran at 65℃; for 24h; Stage #3: With hydrogenchloride; water at 0℃; for 1h;	99%
With iron(II) fluoro{tris[2-(diphenylphosphino)phenyl]phospino}tetrafluoroborate; hydrogen; trifluoroacetic acid In isopropyl alcohol at 120℃; under 15001.5 Torr; for 2h; Inert atmosphere; Autoclave; chemoselective reaction;	99%
With C46H49CoN3P4(2+)*2BF4(1-); hydrogen; potassium hydroxide In ethanol; acetonitrile at 60℃; under 22801.5 Torr; for 24h; Autoclave; Glovebox; chemoselective reaction;	99%

: 3218-36-8
4-Phenylbenzaldehyde

: 1,1'-biphenyl-4-carbaldehyde oxime

Conditions

Conditions	Yield
With pyridine; hydroxylamine hydrochloride In ethanol at 150℃; for 2.5h;	99%
With hydroxylamine hydrochloride; sodium acetate In methanol for 0.5h; Heating; Yield given;

: 3218-36-8
4-Phenylbenzaldehyde

: 237432-14-3
2-thiomorpholin-4-ylmethyl-phenylamine

: [1-Biphenyl-4-yl-meth-(E)-ylidene]-(2-thiomorpholin-4-ylmethyl-phenyl)-amine

Conditions

Conditions	Yield
With acid Condensation;	99%

: 3218-36-8
4-Phenylbenzaldehyde

: 98-80-6
phenylboronic acid

: 7598-80-3
4-phenylbenzhydrol

Conditions

Conditions	Yield
With potassium tert-butylate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; dirhodium(II) tetrakis(perfluorobutyrate) In tert-Amyl alcohol at 60℃; for 1h;	99%
With [(quinone)Rh(COD)]-*K+; water at 75℃; for 3h;	93%
BF4(1-)C14H16O2Rh(1-)2K(1+) In water at 75℃; for 3h; Conversion of starting material;	93%
With potassium phosphate monohydrate; nickel(II) perchlorate hexahydrate In isopropyl alcohol at 80℃; Inert atmosphere;	89%

4-Biphenylcarboxaldehyde Chemical Properties

The molecular formula of 4-Biphenylcarboxaldehyde(3218-36-8) is C₁₃H₁₀O and its formula weight is 182.22.
The density of 4-Biphenylcarboxaldehyde(3218-36-8) is 1.107 g/cm³ and it has a melting point of 57-59 °C(lit.). The boiling point is 184 °C11 mm Hg(lit.). Its flash point is 172°C.
The chemical synonyms of 4-Biphenylcarboxaldehyde(3218-36-8) are P-PHENYLBENZALDEHYDE;P-BIPHENYLCARBOXALDEHYDE;P-DIPHENYLALDEHYDE;P-DIPHENYLCARBOXALDEHYDE;[1,1'-BIPHENYL]-4-CARBALDEHYDE;(1,1'-BIPHENYL)-4-CARBOXALDEHYDE;4-PHENYLBENZALDEHYDE;4-BIPHENYLALDEHYDE
The molecular structure of 4-Biphenylcarboxaldehyde(3218-36-8):

4-Biphenylcarboxaldehyde Toxicity Data With Reference

RTECS#: CAS# 3218-36-8: DV1767000
LD50/LC50: RTECS: Not available.
Carcinogenicity: 4-BIPHENYLCARBOXALDEHYDE, 99% - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: See actual entry in RTECS for complete information.

4-Biphenylcarboxaldehyde Safety Profile

Hazard Codes Xi
Risk Statements 36/37/38
Safety Statements 26-36
WGK Germany 1
RTECS DV1767000
F 10-23
Hazard Note Irritant

4-Biphenylcarboxaldehyde Specification

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials Strong oxidizing agents, strong bases.
Hazardous Decomposition Products Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization Has not been reported.

Product Name

4-Biphenylcarboxaldehyde

Synthetic route

4-Biphenylcarboxaldehyde Chemical Properties

4-Biphenylcarboxaldehyde Toxicity Data With Reference

4-Biphenylcarboxaldehyde Safety Profile

4-Biphenylcarboxaldehyde Specification

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