Benzenemethanol,4-methyl-a-(4-methylphenyl)- supplier

Name
4,4'-DIMETHYLBENZHYDROL
EINECS
CAS No. 885-77-8
Article Data113
CAS DataBase
Density 1.063g/cm³
Solubility Insoluble in water.
Melting Point 71-73°C
Formula C₁₅H₁₆O
Boiling Point 352.7 °C at 760 mmHg
Molecular Weight 212.291
Flash Point 149.2 °C
Transport Information
Appearance
Safety 22-24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Benzhydrol,4,4'-dimethyl- (6CI,7CI,8CI);4,4'-Dimethylbenzhydrol;4-Methyl-a-(4-methylphenyl)benzenemethanol;Bis(4-methylphenyl)carbinol;Bis(4-methylphenyl)methanol;Di-p-tolylcarbinol;Di-p-tolylmethanol;NSC 129834;XA 100;
PSA 20.23000
LogP 3.38510

Synthetic route

: 611-97-2
bis(p-methylphenyl)-methanone

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With hydrogen In tetrahydrofuran at 60℃; under 760.051 Torr; for 45h;	98%
With sodium tetrahydroborate In isopropyl alcohol for 19h; Ambient temperature;	97%
With sodium tetrahydroborate In methanol; acetonitrile at 20℃; for 2h;	97%

: 5720-05-8
4-methylphenylboronic acid

: 104-87-0
4-methyl-benzaldehyde

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With Rh2(trifluoroacetate)4(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)2; potassium tert-butylate In methanol at 65℃; for 3h; Inert atmosphere;	98%
With sodium 2'‐(dicyclohexylphosphaneyl)‐2,6‐diisopropyl‐[1,1'‐biphenyl]‐3‐sulfonate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; sodium hydroxide In water at 80℃; for 2h; Inert atmosphere;	96.6%
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; tris(2,4-di-tert-butylphenyl)phosphite; potassium carbonate In 1,4-dioxane at 60℃; Glovebox; Inert atmosphere;	91%

: 201230-82-2
carbon monoxide

: 108-88-3
toluene

A: 611-97-2
bis(p-methylphenyl)-methanone

B: 885-77-8
4,4'-dimethylbenzhydrol

C: 104-87-0
4-methyl-benzaldehyde

D: 529-20-4
2-methylphenyl aldehyde

Conditions

Conditions	Yield
With hydrogen fluoride; boron trifluoride at 45℃; under 37503.8 - 60006 Torr; for 1h; Further byproducts.;	A n/a B n/a C 91% D 5%

...Expand

: 80731-92-6
(η2-4,4'-dimethylbenzophenone)zirconocene dimer

A: 1291-32-3
zirconocene dichloride

B: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With hydrogenchloride; silica gel In diethyl ether under Ar, suspn. of educt in ether stirred with 10% HCl and small amts.of silica gel for 2 h; washed with Na2CO3 soln., dried over Na2SO4, evapd., chromd. (silica, hexane/ether);	A 32% B 87%

: 107-31-3
Methyl formate

: 106-38-7
para-bromotoluene

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: Methyl formate In tetrahydrofuran; hexane at -78 - 20℃; for 4.16667h; Inert atmosphere;	85.2%
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: Methyl formate In tetrahydrofuran; Hexachlorobutadiene at -78℃; for 1h;	85.2%
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h; Inert atmosphere; Stage #2: Methyl formate In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere;	85.2%

: 5084-80-0
tri(4-tolyl)boroxine

: 104-87-0
4-methyl-benzaldehyde

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With C42H62ClO3PPd; sodium phosphate In toluene at 50℃; for 30h;	84%
Stage #1: tri(4-tolyl)boroxine; 4-methyl-benzaldehyde With [2,2]bipyridinyl; sodium acetate; copper(l) chloride In o-xylene at 135℃; for 6h; Stage #2: With hydrogenchloride In o-xylene; water	83%

: C19H23NOS

: 19226-36-9
3-phenyl-5H-1,4,2-dioxazol-5-one

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 7-methyl-2-phenyl-4-p-tolyl-quinazoline

Conditions

Conditions	Yield
Stage #1: C19H23NOS; 3-phenyl-5H-1,4,2-dioxazol-5-one With carbonyl(pentamethylcyclopentadienyl)cobalt diiodide; silver(I) triflimide In 1,2-dichloro-ethane at 120℃; for 16h; Inert atmosphere; Sealed tube; Stage #2: With sodium tetrahydroborate In methanol at 20℃; for 0.5h; Inert atmosphere; Sealed tube;	A n/a B 84%

...Expand

: 611-97-2
bis(p-methylphenyl)-methanone

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 913-86-0
tetra(4-methylphenyl)-1,2-ethanediol

Conditions

Conditions	Yield
With CdS(x)Se(1-x) x:0-1;; cesium acetate; para-thiocresol In toluene for 15h; Sealed tube; Inert atmosphere; Irradiation;	A 83% B 17%
With aluminium; sodium chloride In ammonia at 25℃; for 4h; Irradiation;	A 71% B 24%
With cyclohexylamine In acetonitrile; benzene Product distribution; Irradiation; influence of solvent on the course of photoreduction reaction; further solvents;	A 10 % Spectr. B 90 % Spectr.
With cyclohexylamine In acetonitrile; benzene Irradiation;	A 10 % Spectr. B 90 % Spectr.

: 624-31-7
4-tolyl iodide

: 104-87-0
4-methyl-benzaldehyde

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With diphenyl hydrogen phosphate; [Ni(dipy)(μ-Cl)2]; diisopropylamine; sodium iodide; zinc In hexane at 95℃; for 7h; Inert atmosphere; Sealed tube;	83%
Stage #1: 4-tolyl iodide With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: 4-methyl-benzaldehyde In tetrahydrofuran; hexane at -78℃; for 0.5h;	53%
Stage #1: 4-tolyl iodide With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: 4-methyl-benzaldehyde In tetrahydrofuran; hexane at -78℃; for 0.5h;	53%
Stage #1: 4-tolyl iodide With n-butyllithium In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere; Stage #2: 4-methyl-benzaldehyde In tetrahydrofuran at -78 - 20℃; Inert atmosphere;

: 106-38-7
para-bromotoluene

: 104-88-1
4-chlorobenzaldehyde

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
Stage #1: para-bromotoluene With magnesium In tetrahydrofuran for 1h; Inert atmosphere; Stage #2: 4-chlorobenzaldehyde In tetrahydrofuran at 20℃; for 2h; Inert atmosphere;	82%

: 2-(di-p-tolylmethoxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With silica gel at 25℃; Inert atmosphere; Glovebox;	74%
With water; silica gel In hexane; ethyl acetate at 25℃; Inert atmosphere; Glovebox;	191 mg
With sodium hydroxide In tetrahydrofuran; hexane; water for 0.5h;
With water; sodium hydroxide In tetrahydrofuran; water at 20℃; for 1h;	159 mg
With air In diethyl ether	108 mg

: 5720-05-8
4-methylphenylboronic acid

: 104-87-0
4-methyl-benzaldehyde

: 67-64-1
acetone

A: 611-97-2
bis(p-methylphenyl)-methanone

B: 885-77-8
4,4'-dimethylbenzhydrol

C: 4023-84-1, 3160-38-1
4-(p-tolyl)-3-buten-2-one

Conditions

Conditions	Yield
With potassium phosphate; platinacycle In toluene at 90 - 100℃; for 2h;	A n/a B n/a C 43%

...Expand

: 106-38-7
para-bromotoluene

: 109-94-4
formic acid ethyl ester

A: 94-08-6
4-methylbenzoic acid ethyl ester

B: 885-77-8
4,4'-dimethylbenzhydrol

C: 104-87-0
4-methyl-benzaldehyde

Conditions

Conditions	Yield
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h; Stage #2: formic acid ethyl ester In tetrahydrofuran; hexane at -78℃; for 3h; Stage #3: With ethanol; iodine; potassium carbonate In tetrahydrofuran; hexane at -78 - 20℃; for 14h;	A 12% B 41% C 27%

...Expand

: 913-86-0
tetra(4-methylphenyl)-1,2-ethanediol

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With sodium amalgam; diethyl ether; benzene

: 913-86-0
tetra(4-methylphenyl)-1,2-ethanediol

: 103-73-1
Phenetole

A: 611-97-2
bis(p-methylphenyl)-methanone

B: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
at 145℃; Kinetics; sowie bei 152grad;

...Expand

: 4294-57-9
para-methylphenylmagnesium bromide

: 109-94-4
formic acid ethyl ester

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With diethyl ether anschliessend Erwaermen;
In diethyl ether

: 4294-57-9
para-methylphenylmagnesium bromide

: 109-94-4
formic acid ethyl ester

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 40673-57-2
1,1,2,2-tetra(p-tolyl)ethane

Conditions

Conditions	Yield
With diethyl ether

...Expand

: 64-17-5
ethanol

: 73689-62-0
Di(p-tolyl)methyl-p-nitrobenzoat

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 68240-81-3
C17H20O

Conditions

Conditions	Yield
With pyridine; water at 60℃; Mechanism; Product distribution; different rates of solvents;

...Expand

: 64-17-5
ethanol

: 21573-83-1
3,5-dinitro-benzoic acid benzhydryl ester

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 68240-81-3
C17H20O

Conditions

Conditions	Yield
With pyridine; water at 100℃; Mechanism; Product distribution; different rates of solvents;

...Expand

: 106-38-7
para-bromotoluene

: 104-87-0
4-methyl-benzaldehyde

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With magnesium 1.) diethyl ether, 2.) 0.5 h; Yield given. Multistep reaction;
Grignard reaction;
Stage #1: para-bromotoluene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.333333h; Inert atmosphere; Stage #2: 4-methyl-benzaldehyde In tetrahydrofuran; hexane for 0.333333h; Inert atmosphere; Stage #3: With water In tetrahydrofuran; hexane Inert atmosphere;
Stage #1: para-bromotoluene; 4-methyl-benzaldehyde With magnesium In tetrahydrofuran at 20 - 85℃; for 2h; Stage #2: In tetrahydrofuran at 0 - 20℃; Inert atmosphere;
Stage #1: para-bromotoluene With magnesium In diethyl ether at 20℃; for 2h; Inert atmosphere; Stage #2: 4-methyl-benzaldehyde In diethyl ether at 20℃; for 2h; Inert atmosphere;

: 104-87-0
4-methyl-benzaldehyde

: 4294-57-9
para-methylphenylmagnesium bromide

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
In tetrahydrofuran for 2h; Heating; Yield given;
In diethyl ether for 144h; Reflux;
In diethyl ether
In tetrahydrofuran at 0 - 20℃;
In tetrahydrofuran at 20℃; Inert atmosphere;

: 64-17-5
ethanol

: 1143-91-5
bis(4-methylphenyl)diazomethane

: 62-23-7
4-nitro-benzoic acid

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 73689-62-0
Di(p-tolyl)methyl-p-nitrobenzoat

C: 68240-81-3
C17H20O

Conditions

Conditions	Yield
With pyridine; water at 25℃; Mechanism; Product distribution; different rates of solvents;	A n/a B 53.6 % Chromat. C n/a

...Expand

: 1143-91-5
bis(4-methylphenyl)diazomethane

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With water In tetrahydrofuran Heating;

: 58493-75-7
bis(4-methyldiphenyl)methylium

: 885-77-8
4,4'-dimethylbenzhydrol

Conditions

Conditions	Yield
With water In sulfuric acid; acetic acid Equilibrium constant;
With water In acetonitrile at 20℃; Kinetics;

: 611-97-2
bis(p-methylphenyl)-methanone

: 64-17-5
ethanol

sodium amalgam: sodium amalgam

: 885-77-8
4,4'-dimethylbenzhydrol

...Expand

: 611-97-2
bis(p-methylphenyl)-methanone

: 7664-41-7
ammonia

zinc dust: zinc dust

: 885-77-8
4,4'-dimethylbenzhydrol

...Expand

: 611-97-2
bis(p-methylphenyl)-methanone

: 64-17-5
ethanol

aluminium amalgam: aluminium amalgam

A: 885-77-8
4,4'-dimethylbenzhydrol

B: 913-86-0
tetra(4-methylphenyl)-1,2-ethanediol

...Expand

: 60-29-7
diethyl ether

: 913-86-0
tetra(4-methylphenyl)-1,2-ethanediol

: 71-43-2
benzene

sodium-amalgam: sodium-amalgam

: 885-77-8
4,4'-dimethylbenzhydrol

...Expand

: 13389-70-3
bis(4-methylphenyl)methyl chloride

: 71-43-2
benzene

fine-dispersed silver: fine-dispersed silver

A: 611-97-2
bis(p-methylphenyl)-methanone

B: 885-77-8
4,4'-dimethylbenzhydrol

C: 40673-57-2
1,1,2,2-tetra(p-tolyl)ethane

D: 37858-01-8
bis[bis(p-tolyl)methyl] ether

Conditions

Conditions	Yield
in Gegenwart von Sauerstoff;

...Expand

: 885-77-8
4,4'-dimethylbenzhydrol

: 13389-70-3
bis(4-methylphenyl)methyl chloride

Conditions

Conditions	Yield
With hydrogenchloride; calcium chloride In dichloromethane	100%
With hydrogenchloride In dichloromethane; water at 20℃; for 120h;	88%
With hydrogenchloride; diethyl ether; calcium chloride; Petroleum ether

: 885-77-8
4,4'-dimethylbenzhydrol

: 4957-14-6
4,4'-dimethyldiphenylmethane

Conditions

Conditions	Yield
With iodine; hypophosphorous acid In acetic acid at 60℃; for 24h;	100%
With o-benzenedisulfonimide; isopropyl alcohol at 80℃; for 5h;	100%
With palladium dichloride In methanol at 40℃; for 18h; Inert atmosphere; Green chemistry; chemoselective reaction;	89%

: 885-77-8
4,4'-dimethylbenzhydrol

: 70-55-3
toluene-4-sulfonamide

A: 37858-01-8
bis[bis(p-tolyl)methyl] ether

B: 1581274-94-3
C22H23NO2S

Conditions

Conditions	Yield
With acidic mesoporous zeolite β-catalyst In 1,2-dichloro-ethane at 80℃; for 6h; Sealed tube; Inert atmosphere;	A n/a B 100%

...Expand

: 885-77-8
4,4'-dimethylbenzhydrol

: 100-51-6
benzyl alcohol

: 1224874-55-8
bis(4-tolyl)methyl benzyl ether

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In 1,2-dichloro-ethane at 60℃; for 12h; Green chemistry;	99%
With platinum on carbon at 130℃; for 1h; Neat (no solvent);	82%

: 875928-76-0
1-(2-methyl-1-phenyl-3-(2,2-diphenylvinylidene)cyclopropyl)benzene

: 885-77-8
4,4'-dimethylbenzhydrol

: 1233195-49-7
C45H38

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In 1,2-dichloro-ethane at 20℃; for 0.0833333h; Intramolecular Friedel-Crafts reaction; Inert atmosphere;	99%

: 696-63-9
4-Methoxybenzenethiol

: 885-77-8
4,4'-dimethylbenzhydrol

: [di(p-tolyl)methyl](4-methoxyphenyl)sulfane

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.0166667h;	99%

: 885-77-8
4,4'-dimethylbenzhydrol

: 100-53-8
phenylmethanethiol

: benzyl[di(p-tolyl)methyl]sulfane

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.0166667h; Reagent/catalyst;	99%

: 885-77-8
4,4'-dimethylbenzhydrol

: 108-94-1
cyclohexanone

A: 502-44-3
hexahydro-2H-oxepin-2-one

B: 611-97-2
bis(p-methylphenyl)-methanone

Conditions

Conditions	Yield
Stage #1: 4,4'-dimethylbenzhydrol; cyclohexanone With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen In ethyl acetate at 75℃; for 8h; Stage #2: With bis(3-trifluoromethyl) diselenide In 2,2,2-trifluoroethanol; ethyl acetate at 30℃; for 6h; Baeyer-Villiger Ketone Oxidation;	A 99% B 99%
Stage #1: 4,4'-dimethylbenzhydrol; cyclohexanone With N-hydroxyphthalimide; 2,2'-azobis(isobutyronitrile); oxygen In ethyl acetate at 75℃; for 22h; Baeyer-Villiger Ketone Oxidation; Stage #2: With ammonium cerium (IV) nitrate; 1,1,1,3',3',3'-hexafluoro-propanol In ethyl acetate at 45℃; for 10h; Baeyer-Villiger Ketone Oxidation;

...Expand

: 885-77-8
4,4'-dimethylbenzhydrol

: 37858-01-8
bis[bis(p-tolyl)methyl] ether

Conditions

Conditions	Yield
With iodine In dichloromethane at 25℃; for 1.5h;	98%
(i) nPrCaI, THF, (ii) (CO2Et)2; Multistep reaction;

: 885-77-8
4,4'-dimethylbenzhydrol

: 611-97-2
bis(p-methylphenyl)-methanone

Conditions

Conditions	Yield
With diisopropyl-carbodiimide In toluene at 120℃; for 24h; Inert atmosphere; Sealed tube;	98%
With dimanganese decacarbonyl In toluene at 120℃; Sealed tube;	97%
With tert.-butylhydroperoxide; bismuth(III) oxide In water; ethyl acetate for 4h; Kinetics; Concentration; Reflux; chemoselective reaction;	92%

: 7677-24-9
trimethylsilyl cyanide

: 885-77-8
4,4'-dimethylbenzhydrol

: 92962-16-8
bis(4-methylphenyl)acetonitrile

Conditions

Conditions	Yield
With indium(III) bromide In dichloromethane at 20℃; Inert atmosphere;	98%
With indium(III) bromide In dichloromethane at 20℃; Inert atmosphere;	98%
With zinc trifluoromethanesulfonate In nitromethane at 100℃; for 16h; Inert atmosphere;	79%
With indium(III) chloride In dichloromethane at 20℃; for 13h; Inert atmosphere;
Stage #1: 4,4'-dimethylbenzhydrol With molybdenum(V) chloride In dichloromethane at 23℃; for 0.25h; Stage #2: trimethylsilyl cyanide In dichloromethane at 23℃; for 3h;

: 128-39-2
2,6-di-tert-butylphenol

: 885-77-8
4,4'-dimethylbenzhydrol

: 3,5-ditertiary-butyl-4-hydroxyphenyldi-p-tolylmethane

Conditions

Conditions	Yield
With tris(pentafluorophenyl)borate In 1,2-dichloro-ethane at 60℃; for 4h; Green chemistry;	98%
With sulfuric acid; acetic acid

: 1569-69-3
Cyclohexanethiol

: 885-77-8
4,4'-dimethylbenzhydrol

: cyclohexyl[di(p-tolyl)methyl]sulfane

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.0166667h;	98%

: 3770-50-1
2-carbethoxyindole

: 885-77-8
4,4'-dimethylbenzhydrol

: 187535-49-5
ethyl 3-[bis(4-methylphenyl)methyl]-indole-2-carboxylate

Conditions

Conditions	Yield
	97%
	97%

: 885-77-8
4,4'-dimethylbenzhydrol

: 75-36-5
acetyl chloride

: 285129-99-9
di-p-tolylmethyl acetate

Conditions

Conditions	Yield
With triethylamine In diethyl ether at 0 - 25℃; for 2.08333h; Inert atmosphere;	97%

: 885-77-8
4,4'-dimethylbenzhydrol

: 108-98-5
thiophenol

: 53700-31-5
[di(p-tolyl)methyl](phenyl)sulfane

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.0166667h;	96%

: 111-70-6
n-heptan1ol

: 885-77-8
4,4'-dimethylbenzhydrol

: bis(4-tolyl)methyl heptyl ether

Conditions

Conditions	Yield
platinum on activated charcoal at 130℃; for 3h;	95%

: 885-77-8
4,4'-dimethylbenzhydrol

: 78-84-2
isobutyraldehyde

: 1353001-16-7
C19H22O

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In dibutyl ether at 50℃; for 24h;	95%

: 885-77-8
4,4'-dimethylbenzhydrol

: 824-46-4
methoxyhydroquinone

: 2-(di-p-tolylmethyl)-5-methoxybenzene-1,4-diol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In water at 40℃; for 1h; Green chemistry;	95%

: 292638-84-7
styrene

: 885-77-8
4,4'-dimethylbenzhydrol

: 1352552-60-3
(E)-4,4'-(3-phenylprop-2-ene-1,1-diyl)bis(methylbenzene)

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid In ethylene dibromide at 60℃; Air atmosphere; stereoselective reaction;	94%

: 885-77-8
4,4'-dimethylbenzhydrol

: 106-49-0
p-toluidine

: 1421841-88-4
2,6-bis(bis(p-methylphenyl)methyl)-4-methylaniline

Conditions

Conditions	Yield
With hydrogenchloride; zinc(II) chloride at 160℃;	93%
With hydrogenchloride; zinc(II) chloride at 160℃; for 1.5h;	89%
With hydrogenchloride; zinc(II) chloride In water at 120 - 160℃; for 0.5h;	74%

: 885-77-8
4,4'-dimethylbenzhydrol

: 3-(trifluoromethyl)imidazo[1,5-a]pyridine

: 3-(trifluoromethyl)-1-(dip-tolylmethyl)H-imidazo[1,5-a]pyridine

Conditions

Conditions	Yield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In toluene at 90℃; for 14h;	93%

: 885-77-8
4,4'-dimethylbenzhydrol

: 135-19-3
β-naphthol

: 1-(di-p-tolylmethyl)naphthalen-2-ol

Conditions

Conditions	Yield
With stannic bromide In dichloromethane at 20℃; for 24h; Friedel-Crafts Alkylation; Inert atmosphere;	92%

: 885-77-8
4,4'-dimethylbenzhydrol

: 56866-32-1
2-[(E/Z)-3-phenylprop-2-enyl]-2,3-dihydro-1H-isoindole-1,3-dione

: 2-((5-methyl-3-phenyl-1-(p-tolyl)-2,3-dihydro-1H-inden-2-yl)methyl)isoindoline-1,3-dione

Conditions

Conditions	Yield
With iron(III) chloride hexahydrate In 1,2-dichloro-ethane at 120℃; for 2h; Inert atmosphere; stereoselective reaction;	92%

: 885-77-8
4,4'-dimethylbenzhydrol

: 95-71-6
2-methylbenzene-1,4-diol

: 2-(di-p-tolylmethyl)-5-methylbenzene-1,4-diol

Conditions

Conditions	Yield
With toluene-4-sulfonic acid In water at 40℃; for 1h; Solvent; Temperature; Green chemistry;	92%

: 885-77-8
4,4'-dimethylbenzhydrol

: bis(4-methylphenyl)methyl nitrite

Conditions

Conditions	Yield
With nitrosylchloride; triethylamine In dichloromethane at -78 - -30℃; for 0.5h;	91%

: 885-77-8
4,4'-dimethylbenzhydrol

: 71-36-3
butan-1-ol

: 4,4'-(butoxymethylene)bis(methylbenzene)

Conditions

Conditions	Yield
With iron(III) chloride In 1,2-dichloro-ethane at 70℃; for 10h;	91%

Benzenemethanol,4-methyl-a-(4-methylphenyl)- Specification

The Benzenemethanol,4-methyl-a-(4-methylphenyl)-, with CAS registry number 885-77-8, belongs to the following product category: Benzhydrols, Benzyl & Special Alcohols. It has the systematic name of bis(4-methylphenyl)methanol. When use this chemical, do not breathe dust and avoid contact with skin and eyes. And the chemical formula of this chemical is C₁₅H₁₆O.

Physical properties of Benzenemethanol,4-methyl-a-(4-methylphenyl)-: (1)ACD/LogP: 3.66; (2)# of Rule of 5 Violations: 0; (3)#H bond acceptors: 1; (4)#H bond donors: 1; (5)#Freely Rotating Bonds: 3; (6)Polar Surface Area: 9.23 Å²; (7)Index of Refraction: 1.583; (8)Molar Refractivity: 66.75 cm³; (9)Molar Volume: 199.6 cm³; (10)Polarizability: 26.46×10^-24cm³; (11)Surface Tension: 42.2 dyne/cm; (12)Density: 1.063 g/cm³; (13)Flash Point: 149.2 °C; (14)Enthalpy of Vaporization: 63.05 kJ/mol; (15)Boiling Point: 352.7 °C at 760 mmHg; (16)Vapour Pressure: 1.4E-05 mmHg at 25°C.

Preparation: this chemical can be prepared by 4,4'-dimethyl-benzophenone. This reaction will need reagents Zn, NaOH.

Uses of Benzenemethanol,4-methyl-a-(4-methylphenyl)-: it can be used to produce 4,4'-dimethyl-benzophenone. This reaction will need reagent pyridinium chlorochromate and solvent CH₂Cl₂. The reaction time is 30 min. The yield is about 86%.

You can still convert the following datas into molecular structure:
(1)SMILES: OC(c1ccc(cc1)C)c2ccc(cc2)C
(2)InChI: InChI=1/C15H16O/c1-11-3-7-13(8-4-11)15(16)14-9-5-12(2)6-10-14/h3-10,15-16H,1-2H3
(3)InChIKey: RGYZQSCFKFDECZ-UHFFFAOYAR
(4)Std. InChI: InChI=1S/C15H16O/c1-11-3-7-13(8-4-11)15(16)14-9-5-12(2)6-10-14/h3-10,15-16H,1-2H3
(5)Std. InChIKey: RGYZQSCFKFDECZ-UHFFFAOYSA-N

Product Name

4,4'-DIMETHYLBENZHYDROL

Synthetic route

Benzenemethanol,4-methyl-a-(4-methylphenyl)- Specification

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