Conditions | Yield |
---|---|
With hydrogenchloride; sodium chloride In water at 25 - 27℃; for 19h; | 99.6% |
With hydrogenchloride; sodium chloride In water at 20 - 50℃; |
Conditions | Yield |
---|---|
In neat (no solvent) passing dry chlorine over dry iodine;; distillation in stream of chlorine at 100-101.5°C;; | A 85% B n/a |
In neat (no solvent) passing dry chlorine over dry iodine;; distillation at 100-101.5°C;; | A 35% B n/a |
In neat (no solvent) excess of iodine; | |
In neat (no solvent) |
iodine
1,3-dichloro-[1,3,5]triazinane-2,4,6-trione
A
cyanuric acid
B
triiodoisocyanuric acid
C
Iodine monochloride
Conditions | Yield |
---|---|
absence of moist, 24h, 180-230°C, every 30 min ICl removed,; removing of (HNCO)3: sublimation (220-230°C, 0.1 Torr), purity >99; | A n/a B 75.6% C n/a |
Conditions | Yield |
---|---|
beim Erwaermen ueber den Zersetzungspunkt; |
dichloroiodomethane
water
A
methylene chloride
B
Iodine monochloride
sulfuryl dichloride
iodine
A
Iodine monochloride
B
iodine trichloride
Conditions | Yield |
---|---|
In not given in presence of AlCl3;; |
tetrachloromethane
iodine
A
1,1,2,2-tetrachloroethylene
B
trichloroiodomethane
C
hexachloroethane
D
Iodine monochloride
Conditions | Yield |
---|---|
In tetrachloromethane other Radiation; γ-radiation of I2 soln. in CCl4; yield depends on concn. of I2 and on dose of radiation;; |
Conditions | Yield |
---|---|
In tetrachloromethane other Radiation; γ-radiation of I2 soln. in CCl4 saturated with air;; |
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
In water 6h heating to 250°C in sealed tube;; | |
In water 6h heating to 250°C in sealed tube;; | |
In not given at heating to 250°C in sealed tube; molar rate = 1:1;; |
Conditions | Yield |
---|---|
In gaseous matrix byproducts: CH3; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy; |
hydrogenchloride
A
sulfuric acid
B
Iodine monochloride
C
cadmium(II) chloride
Conditions | Yield |
---|---|
With potassium iodate In not given byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl;; | |
With KIO3 In not given byproducts: S, KCl, H2O; oxidation with KIO3 in presence of HCl;; |
Conditions | Yield |
---|---|
With hydrogenchloride; potassium iodate In not given byproducts: S, H2O; oxidation with KIO3; HCl-concentration: 65 vol.% HCl;; |
Conditions | Yield |
---|---|
With hydrogenchloride; potassium iodate In not given byproducts: S, H2O; oxidation with KIO3; HCl-concentration: < 15 vol.% HCl;; |
Conditions | Yield |
---|---|
In diethyl ether; water Electrochem. Process; |
iodide
Iodine monochloride
Conditions | Yield |
---|---|
With hydrogenchloride; cerium (IV) sulfate In hydrogenchloride strongly acidic solution;; | |
In hydrogenchloride |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: metal chloride; formation from metal iodides and liquid Cl2;; |
Conditions | Yield |
---|---|
In not given acidic soln.; ClO3(1-) : I(1-) = 1 : 3;; |
Conditions | Yield |
---|---|
In gaseous matrix byproducts: C2H5; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy; |
Conditions | Yield |
---|---|
In gaseous matrix byproducts: C3H7; reaction of in situ generated Cl atoms (by microwave discharge from Cl2/He or Cl2/Ne mixt., Cl atom beam velocity 1150-1950 m/s) with alkyl iodide according to: S. M. A. Hoffmann, D. J. Smith, R. Grice, Mol. Phys. 49 (1983) 621; mass spectroscopy; |
Conditions | Yield |
---|---|
In diethyl ether byproducts: C6H5I; | 100% |
In diethyl ether byproducts: C6H5I; | 100% |
byproducts: C6H5I; |
Conditions | Yield |
---|---|
evaporated, with excess of ICl; | 100% |
evaporated, with excess of ICl; | 100% |
tris(2,4-pentanedionato)ruthenium(III)
Iodine monochloride
Conditions | Yield |
---|---|
In benzene immediate reaction; | 100% |
In benzene | 100% |
Iodine monochloride
[5,6]fullerene-C70
Conditions | Yield |
---|---|
In chlorobenzene Kinetics; react. of C70 with ICl (250 equiv.) in PhCl for 7 min with intermediate formation of C70Cl6 and C70Cl8; HPLC; | 100% |
Iodine monochloride
(Me3Si)3C(SnMe2Cl)
trichloro(tris(trimethylsilyl)methyl)stannane
Conditions | Yield |
---|---|
In tetrachloromethane Ar-atmosphere; dropwise addn. of excess ICl to Sn-compd., stirring for 1h; solvent removal, recrystn. (hexane); | 99% |
Conditions | Yield |
---|---|
In dichloromethane for 0.0833333h; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
In tetrachloromethane; dichloromethane solution of ICl (1.32 mmol) in CCl4 was added dropwise (0,5 h) to a stirred solution of tin compound (1.26 mmol) in 1/4 CH2Cl2/CCl4 at room temperature; reaction was monitored by (1)H-NMR spectroscopy; solvent was removed under reduced pressure; pink residue kept under vacuum for 3 h; product was identified by comparison of its spectra with an authentic sample; | 98% |
Conditions | Yield |
---|---|
In tetrachloromethane solution of ICl (2.5 mmol) in CCl4 was added (stirring) to a solution of tin compound (1.02 mmol); progress of reaction was monitored by (1)H-NMR spectroscopy;; solvent was removed, residue kept under vacuum for 3 h;; | 98% |
Iodine monochloride
caesium 3,3'-commo-bis(decahydro-8-iodo-1,2-dicarba-3-cobalta-closo-dodecaborate)(1-)
Conditions | Yield |
---|---|
In ethanol under N2 atm. ICl was added to soln. Cs(3,3'-Co(1,2-C2B9H11)2) in EtOH and refluxed for 10 h; Na2SO3 in water was added and refluxed for 5 min, soln. was concd., ppt.was filtered off, washed with water andpetroleum ether, and dried in va cuo; elem. anal.; | 98% |
Iodine monochloride
(Me3Si)3C(SnMe2Cl)
dichloro(methyl)(tris(trimethylsilyl)methyl)stannane
Conditions | Yield |
---|---|
In tetrachloromethane Ar-atmosphere; dropwise addn. of ICl to equimolar amt. of Sn-compd.; solvent removal (after 30 min), recrystn. (hexane); | 98% |
Iodine monochloride
Conditions | Yield |
---|---|
In 1,1,2,2-tetrachloroethane at 150℃; for 72h; Inert atmosphere; Schlenk technique; | 98% |
Iodine monochloride
Conditions | Yield |
---|---|
In chloroform at 50℃; for 4h; Inert atmosphere; | 98% |
In chloroform Inert atmosphere; Heating; | 98% |
Conditions | Yield |
---|---|
In dichloromethane for 0.166667h; Inert atmosphere; | 98% |
Conditions | Yield |
---|---|
Stage #1: C27H27BN2OSi; Iodine monochloride In dichloromethane at -78℃; for 18h; Inert atmosphere; Stage #2: With 2-methyl-but-2-ene In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere; | 98% |
ethoxy(dimethyl)(tris(dimethylphenylsilyl)methyl)stannane
Iodine monochloride
chloro(dimethyl)(tris(dimethylphenylsilyl)methyl)stannane
Conditions | Yield |
---|---|
In tetrachloromethane Ar-atmosphere; dropwise addn. of ICl to equimolar amt. of Sn-compd., stirring for 1 h; solvent removal, recrystn. (hexane); | 96% |
trimethyl(trifluorsilyl)stannane
Iodine monochloride
A
chlorotrifluorosilane
B
trimethylstannyl iodide
Conditions | Yield |
---|---|
A 96% B n/a |
chloro(diphenyl)(tris(trimethylsilyl)methyl)stannane
Iodine monochloride
trichloro(tris(trimethylsilyl)methyl)stannane
Conditions | Yield |
---|---|
In tetrachloromethane Ar-atmosphere; addn. of slight excess of ICl to Sn-compd., stirring overnight; solvent removal, recrystn. (hexane); | 96% |
Iodine monochloride
Conditions | Yield |
---|---|
In dichloromethane for 0.0833333h; Inert atmosphere; | 96% |
ethoxy(dimethyl)(tris(dimethylphenylsilyl)methyl)stannane
Iodine monochloride
dichloro(methyl)(tris(dimethylphenylsilyl)methyl)stannane
Conditions | Yield |
---|---|
In tetrachloromethane Ar-atmosphere; dropwise addn. of excess ICl to Sn-compd., stirring for 3h; solvent removal, recrystn. (hexane); | 95% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 3h; | 95% |
Conditions | Yield |
---|---|
In dichloromethane for 0.0833333h; Inert atmosphere; | 95% |
Conditions | Yield |
---|---|
Stage #1: tetramethylammonium ammine-undecahydro-closo-doedecaborate; iodine In dichloromethane at 20 - 80℃; for 3h; Sealed tube; Stage #2: Iodine monochloride In dichloromethane at 300℃; for 5h; Sealed tube; Stage #3: tetramethlyammonium chloride In water | 95% |
Conditions | Yield |
---|---|
In dichloromethane under N2; Co complex dissolved in dry CH2Cl2 at 0°C, ICl in CH2Cl2 added dropwise, stirred at 0°C for 2 h, then at room temp. for 4 h; satd. aq. soln. of sodium thiosulfate added, aq. layer sepd., washed with CH2Cl2, the combined org. materials washed with concd. aq. NaCl, driedover MgSO4, evapd.; elem. anal.; | 94% |
3-iodo-1,2-dicarba-closo-dodecaborane
Iodine monochloride
3,4,5,7,8,9,10,11,12-nonaiodo-1,2-dicarba-closo-dodecaborane
Conditions | Yield |
---|---|
With NaHSO3; Zn; triflic acid In further solvent(s) N2, triflic acid, ICl, borane heated at 90°C for 3 d, allowed to cool to room temp., cold water, aq. NaHSO3 added, ppt. filtered, dissolved (ethyl acetate), Zn added; filtered, solvent evapd. (vac.), recrystd. (ethyl acetate); elem. anal.; | 94% |
2-methoxy-3-(trimethylsilyl)phenylboronic acid
Iodine monochloride
3-iodo-2-methoxyphenylboronic acid
Conditions | Yield |
---|---|
In chloroform (Ar); stirring stoich. mixt. of boronic acid deriv. and ICl in CHCl3 at 0°C for 12 h; concg., addn. of diethyl ether, addn. of aq. Na2S2O3, separating organicphase, evapn., filtration, washing with CHCl3, elem. anal.; | 94% |
iron pentacarbonyl
Iodine monochloride
benzyltrimethylammonium iodide
sulfur
Conditions | Yield |
---|---|
Stage #1: iron pentacarbonyl; Iodine monochloride; benzyltrimethylammonium iodide; sulfur In tetrahydrofuran at -60℃; Inert atmosphere; Schlenk technique; Stage #2: In tetrahydrofuran for 23h; Inert atmosphere; Schlenk technique; Reflux; | 94% |
Conditions | Yield |
---|---|
Stage #1: C35H43BN2O3Si; Iodine monochloride In dichloromethane at -78℃; for 18h; Inert atmosphere; Stage #2: With 2-methyl-but-2-ene In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
Stage #1: Cs(1+)*C5H25B22N2(1-); Iodine monochloride With trifluorormethanesulfonic acid at 50℃; for 24h; Stage #2: trimethylamine hydrochloride In water for 12h; | 94% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 5h; Inert atmosphere; | 94% |
This product is an organic compound with the formula ClI. The systematic name of this chemical is Iodine monochloride. It belongs to the product category of Inorganics. Its EINECS number is 232-236-7. With the CAS registry number 7790-99-0, it is also named as Iodochlorine. In addition, the molecular weight is 162.36. Its storage temperature is 2 - 8 °C. It is used as an iodine value determination regent. It is a useful reagent in organic synthesis, and it can also be used as strong oxidizing agents.
Physical properties of Iodine monochloride are: (1)ACD/LogP: 2.51; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 2.51; (4)ACD/LogD (pH 7.4): 2.51; (5)ACD/BCF (pH 5.5): 47.19; (6)ACD/BCF (pH 7.4): 47.19; (7)#H bond acceptors: 0; (8)#H bond donors: 0; (9)#Freely Rotating Bonds: 0; (10)Index of Refraction: 1.591; (11)Molar Refractivity: 19.86 cm3; (12)Molar Volume: 58.7 cm3; (13)Polarizability: 7.87×10-24cm3; (14)Surface Tension: 36.6 dyne/cm; (15)Density: 2.763 g/cm3; (16)Enthalpy of Vaporization: 36.62 kJ/mol; (17)Boiling Point: 97.4 °C at 760 mmHg; (18)Vapour Pressure: 31.4 mmHg at 25°C.
Preparation of Iodine monochloride: this reaction entails simply combining the halogens in a 1:1 molar ratio, according to the following equation. When chlorine gas is passed through iodine crystals, the brown vapor of iodine monochloride is observed. Dark brown iodine monochloride liquid is collected.
I2 + Cl2 → 2 ICl
When you are using this chemical, please be cautious about it as the following:
This chemical is flammable and can cause severe burns. It has a limited evidence of a carcinogenic effect and may cause sensitisation by inhalation. You should not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer). In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible).
You can still convert the following datas into molecular structure:
(1)SMILES: ClI
(2)Std. InChI: InChI=1S/ClI/c1-2
(3)Std. InChIKey: QZRGKCOWNLSUDK-UHFFFAOYSA-N
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rat | LDLo | oral | 50mg/kg (50mg/kg) | Kodak Company Reports. Vol. 21MAY1971. | |
rat | LDLo | skin | 500mg/kg (500mg/kg) | Kodak Company Reports. Vol. 21MAY1971. |
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