Conditions | Yield |
---|---|
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reaction in neutral and acid solutions complete;; |
Conditions | Yield |
---|---|
In water room temp.; X-ray diffraction, gravimetric anal.; | 99% |
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane
platinum
Conditions | Yield |
---|---|
With 1-decene; 1,1,3,3-tetramethyldisiloxane In toluene mixt. of tetramethyldisiloxane, 1-decene in unhyd. toluene stirred at room temp., evacuated, refilled with N2 three times, Pt-complex added, stirred at 100°C for 5 d; centrifuged, decanted, washed by toluene, centrifuged twice, dried indervac.; detd. by XRD, TEM; | 96% |
platinum
Conditions | Yield |
---|---|
With hydrogen In water Reagent/catalyst; Temperature; | 96% |
Irradiation (UV/VIS); photodeposition on NaInS2; | |
With aluminium In water 65 % surfactant contg. Pt-compd. soln., heating to 85 °C, coolingto room temp., heating to 80 °C, thermal aging was repeated 3 ti mes, Pt was deposited onto an Au/Ti/Si substrate with plating with Al; Pt film was washed with EtOH; |
platinum
Conditions | Yield |
---|---|
In ethanol; water Kinetics; Irradiation (UV/VIS); photoreduction of K2(Pt(NO2)4) in a suspension of anatase in H2O with 4 vol.-% C2H5OH at various temp. (pH: 3.6);; deposition of Pt on the TiO2 surface;; | 90% |
With hydrogenchloride; zinc In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;; | |
With HCl; Zn In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;; |
Conditions | Yield |
---|---|
In acetonitrile byproducts: H2O; suspn. of Pt complex and ligand (molar ratio 1:2) in MeCN stirred at room temp. for a few min; stored at room temp. overnight; filtered; Et2O added to filtrate; filtered; solid washed with Et2O; dried under vac.; dissolved in MeCN; crystd. by slow condensation of Et2O vapors; elem. anal.; | A 81% B 1% |
bis(η3-allyl)(tetracyanoethylene)platinum
A
CH2CHCH2C(CN)2C(CN)2CH2CHCH2
B
platinum
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2, mixt. was stirred for 2 h at room temp.; Pt metal was removed by filtration through Florisil, filtrate concd. and subjected to HLPC; | A 73% B n/a |
With triphenylphosphine In dichloromethane-d2 a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2; followed by (1)H and (31)P NMR; |
Conditions | Yield |
---|---|
With cinchonine In water byproducts: HCl; heating (140+/-5°C); filtn. (G4 filter), washing (aq. NaHCO3; H2O), freeze drying; | A n/a B 71% |
B
platinum
Conditions | Yield |
---|---|
With sodium acetate trihydrate In dimethyl sulfoxide byproducts: NaBr, acetic acid; PtBr2, Na salt and ligand (molar ratio 1:2:1) dissolved in DMSO; heated to 80°C for 2 h and then to 100°C for 1 h; cooled to room temp.; filtered; solvent evapd. from filtrate; washed with CH2Cl2; extd. with small amt. of H2O; residue washed with THF; dried under high vac.; elem. anal.; | A 64.2% B n/a |
B
(E)-2,3-dimethoxybut-2-ene
C
(Z)-2,3-dimethoxybut-2-ene
D
platinum
Conditions | Yield |
---|---|
With cobaltocene In dichloromethane-d2 | A n/a B n/a C 64% D n/a |
Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)
A
Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9
B
Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2
C
platinum
Conditions | Yield |
---|---|
In toluene N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.; | A n/a B 50% C n/a |
In dichloromethane N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.; | A n/a B 50% C n/a |
A
dichlorobis(triethylphosphine)platinum
B
methane
C
ethane
D
ethene
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A 48% B n/a C 2% D <1 E 43% |
trans-{PtCH3(CN)(PEt3)2}
B
methane
C
ethane
D
ethene
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A 48% B n/a C 2% D <1 E 43% |
A
methane
B
ethane
C
ethene
D
Pt(PEt3)2I2
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A n/a B 2% C <1 D 48% E 43% |
Conditions | Yield |
---|---|
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reduction with Mg in neutral or acidic soln.; | 100% |
In water reaction in neutral and acid solutions complete;; |
Conditions | Yield |
---|---|
In water room temp.; X-ray diffraction, gravimetric anal.; | 99% |
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane
platinum
Conditions | Yield |
---|---|
With 1-decene; 1,1,3,3-tetramethyldisiloxane In toluene mixt. of tetramethyldisiloxane, 1-decene in unhyd. toluene stirred at room temp., evacuated, refilled with N2 three times, Pt-complex added, stirred at 100°C for 5 d; centrifuged, decanted, washed by toluene, centrifuged twice, dried indervac.; detd. by XRD, TEM; | 96% |
platinum
Conditions | Yield |
---|---|
With hydrogen In water Reagent/catalyst; Temperature; | 96% |
Irradiation (UV/VIS); photodeposition on NaInS2; | |
With aluminium In water 65 % surfactant contg. Pt-compd. soln., heating to 85 °C, coolingto room temp., heating to 80 °C, thermal aging was repeated 3 ti mes, Pt was deposited onto an Au/Ti/Si substrate with plating with Al; Pt film was washed with EtOH; |
platinum
Conditions | Yield |
---|---|
In ethanol; water Kinetics; Irradiation (UV/VIS); photoreduction of K2(Pt(NO2)4) in a suspension of anatase in H2O with 4 vol.-% C2H5OH at various temp. (pH: 3.6);; deposition of Pt on the TiO2 surface;; | 90% |
With hydrogenchloride; zinc In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;; | |
With HCl; Zn In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;; |
Conditions | Yield |
---|---|
In acetonitrile byproducts: H2O; suspn. of Pt complex and ligand (molar ratio 1:2) in MeCN stirred at room temp. for a few min; stored at room temp. overnight; filtered; Et2O added to filtrate; filtered; solid washed with Et2O; dried under vac.; dissolved in MeCN; crystd. by slow condensation of Et2O vapors; elem. anal.; | A 81% B 1% |
bis(η3-allyl)(tetracyanoethylene)platinum
A
CH2CHCH2C(CN)2C(CN)2CH2CHCH2
B
platinum
Conditions | Yield |
---|---|
With triphenylphosphine In dichloromethane a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2, mixt. was stirred for 2 h at room temp.; Pt metal was removed by filtration through Florisil, filtrate concd. and subjected to HLPC; | A 73% B n/a |
With triphenylphosphine In dichloromethane-d2 a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2; followed by (1)H and (31)P NMR; |
Conditions | Yield |
---|---|
With cinchonine In water byproducts: HCl; heating (140+/-5°C); filtn. (G4 filter), washing (aq. NaHCO3; H2O), freeze drying; | A n/a B 71% |
B
platinum
Conditions | Yield |
---|---|
With sodium acetate trihydrate In dimethyl sulfoxide byproducts: NaBr, acetic acid; PtBr2, Na salt and ligand (molar ratio 1:2:1) dissolved in DMSO; heated to 80°C for 2 h and then to 100°C for 1 h; cooled to room temp.; filtered; solvent evapd. from filtrate; washed with CH2Cl2; extd. with small amt. of H2O; residue washed with THF; dried under high vac.; elem. anal.; | A 64.2% B n/a |
B
(E)-2,3-dimethoxybut-2-ene
C
(Z)-2,3-dimethoxybut-2-ene
D
platinum
Conditions | Yield |
---|---|
With cobaltocene In dichloromethane-d2 | A n/a B n/a C 64% D n/a |
Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)
A
Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9
B
Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2
C
platinum
Conditions | Yield |
---|---|
In toluene N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.; | A n/a B 50% C n/a |
In dichloromethane N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.; | A n/a B 50% C n/a |
A
dichlorobis(triethylphosphine)platinum
B
methane
C
ethane
D
ethene
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A 48% B n/a C 2% D <1 E 43% |
trans-{PtCH3(CN)(PEt3)2}
B
methane
C
ethane
D
ethene
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A 48% B n/a C 2% D <1 E 43% |
A
methane
B
ethane
C
ethene
D
Pt(PEt3)2I2
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A n/a B 2% C <1 D 48% E 43% |
trans-(triethylphosphine)2PtMeBr
A
methane
B
ethane
C
ethene
D
[PtBr2(P(CH2CH3)3)2]
E
platinum
Conditions | Yield |
---|---|
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS; | A n/a B 2% C <1 D 48% E 43% |
platinum
Conditions | Yield |
---|---|
With 1-butanol; oleylamine; acetic acid In toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (185°C, 16 h); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH; | 45% |
With 1-butanol; oleylamine; acetic acid In N,N-dimethyl-formamide; toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (185°C, 16 h); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH; | 45% |
With 1-butanol; oleylamine; acetic acid In N,N-dimethyl-formamide; toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (145°C); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH; |
iodine
trans-diiodobis(triphenylphosphane)platinum(II)
B
platinum
C
dinitrogen monoxide
Conditions | Yield |
---|---|
With Et3N In dichloromethane byproducts: PPh3O; Pt-compd. and Et3N were dissolved in CH2Cl2, cooling to -78 °C, 2equiv. of I2 was added, warming to room temp. over 1 h; ppt. was filtered off; | A 45% B n/a C n/a |
trans-chlorohydridobis(triethylphosphine)platinum(II)
tetrabutylammonium perchlorate
A
1-butylene
trans-{PtH(CH2CN)(PEt3)2}
C
tributyl-amine
D
platinum
Conditions | Yield |
---|---|
In acetonitrile; benzene byproducts: H2; Electrolysis; electrochemically reducing trans-(PtH(Cl)(PEt3)2) at -2.1 V vs Ag/AgCl in CH3CN/C6H6 (5/2, v/v), terminating electrolysis at constancy of current; 36% of hydrido complex recovered; 31P NMR; | A n/a B 38% C n/a D n/a |
Conditions | Yield |
---|---|
With hydrogen In acetic acid under 760.051 Torr; for 1.5h; | |
With hydrogenchloride; hydrogen In hydrogenchloride bubbling of H2 through suspn. of PtO2 in aq. HCl for 20 min; | |
With hydrogen In water react. of PtO2 with H2 (50 psi) in water at room temp. for 30 min; |
platinum
Conditions | Yield |
---|---|
With poly(1-vinyl-2-pyrrolidone) In ethanol; water at 100℃; for 14.5h; Heating / reflux; | |
With J-0381V; L-10D; ethanol; sodium hydrogencarbonate In water at 70℃; | |
With ethanol; sodium hydrogencarbonate; polysorbate 80 In water at 70℃; |
platinum
Conditions | Yield |
---|---|
In 1-ethenyl-2-pyrrolidinone; ethanol; water at 100℃; for 2.66667h; Product distribution / selectivity; Heating / reflux; | |
In poly(sodium acrylate); ethanol; water at 100℃; for 2.66667h; Product distribution / selectivity; Heating / reflux; |
Conditions | Yield |
---|---|
With sodium carbonate In not given heating; | |
With Na2CO3 In not given heating; |
cisplatine
platinum
Conditions | Yield |
---|---|
In ammonia Electrochem. Process; solution of {Pt(NH3)2Cl2} in aq. NH3, 90°C;; | |
With NaB(C2H5)3H In tetrahydrofuran byproducts: NaCl, B(C2H5)3, H2; 23°C, 2 h; Washing with H2O to separate alkali halogenide from metal powder.; | |
In ammonia Electrochem. Process; no pptn. of Pt out of a satd. soln. of {Pt(NH3)2(CNS)2} in aq. NH3, evolution of H2 at the cathode;; | 0% |
In ammonia Electrochem. Process; solution of {Pt(NH3)2Cl2} in aq. NH3, 90°C;; |
Conditions | Yield |
---|---|
In neat (no solvent) under He; mixt. of Co-Pt complex and NH4Cl (1:10 wt/wt) heated to 500°C; detd. by X-ray powder diffraction; |
platinum tetrabromide
platinum
Conditions | Yield |
---|---|
In water Electrochem. Process; pptn. from a concd. aq. soln. of PtBr4 (bunsen cell);; | |
With alc. In not given heating; | |
With diethyl ether In not given heating; |
bismuth
sulfuric acid
pyrographite
2-butyl-5-hydroxymethyl-1H-imidazole
platinum
2-butyl-1H-imidazole-5-carboxaldehyde
Conditions | Yield |
---|---|
With sodium hydroxide In water | 100% |
With sodium hydroxide In water | 98.2% |
With sodium hydroxide In methanol; water | 94.5% |
Conditions | Yield |
---|---|
With hydrogen | 100% |
bis(diethoxyphosphoryl)disulphide
platinum
bis(O,O'-diethyldithiophosphato-S,S')platinum(II)
Conditions | Yield |
---|---|
In styrene at 20℃; for 0.333333h; Product distribution / selectivity; | 100% |
Conditions | Yield |
---|---|
In neat (no solvent) at 600 - 950℃; for 111h; Sealed tube; Schlenk technique; Inert atmosphere; Glovebox; | 100% |
Conditions | Yield |
---|---|
Stage #1: platinum With hydrogenchloride; dihydrogen peroxide In water Stage #2: hydrogenchloride In water Stage #3: CYANAMID With hydrogenchloride In water | 100% |
acetic acid-(5-chloro-2-hydroxy-3-nitro-anilide)
platinum
Conditions | Yield |
---|---|
With carbon disulfide; potassium hydroxide In ethanol; ethyl acetate | 99% |
rac.-N-[1-(5-chloro-1H-benzoimidazol-2-yl)-ethyl]-3-ethynyl-4-(pyrrolidine-1-carbonyl)-benzamide
platinum
Conditions | Yield |
---|---|
With hydrogen In 1,4-dioxane; water | 99% |
2,4-diamino-5-nitroso-6-hydroxypyrimidine
platinum
2-amino-1,9-dihydro-6H-purin-6-one
Conditions | Yield |
---|---|
98.9% |
Conditions | Yield |
---|---|
With trichlorosilane; [SG]-S-Pt In hexane | 98% |
Conditions | Yield |
---|---|
96.5% |
ethyl 2-methyl-4,4,4-trifluoroacetoacetate
platinum
ethyl 3-hydroxy-2-methyl-4,4,4-trifluorobutanoate
Conditions | Yield |
---|---|
With nitrogen; hydrogen; triethylamine; Pt/C | 96% |
platinum
Conditions | Yield |
---|---|
With nitrogen; hydrogen; triethylamine; Pt/C | 96% |
ethyl 4,4,4-trifluoroacetoacetate
platinum
ethyl 3-hydroxy-4,4,4-trifluorobutyrate
Conditions | Yield |
---|---|
With nitrogen; hydrogen; triethylamine; Pt/C | 96% |
With nitrogen; hydrogen; triethylamine; Pt/C | 96% |
With nitrogen; hydrogen; triethylamine; Pt/C | 96% |
With nitrogen; hydrogen; triethylamine | 96% |
With methanesulfonic acid; nitrogen; hydrogen; Pt/C | 50% |
2-(2-carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(p-nitrobenzyl)-1H-imidazole
platinum
1-(4-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
Conditions | Yield |
---|---|
In ethyl acetate | 95% |
Conditions | Yield |
---|---|
In water; toluene | 95% |
hydrogenchloride
platinum
1,5-dicyclooctadiene
dichloro(1,5-cyclooctadiene)platinum(ll)
Conditions | Yield |
---|---|
With HNO3; SnCl2*2H2O In further solvent(s) byproducts: nitrogen oxides; N2-atmosphere; dissoln. of Pt in aqua regia by stirring overnight at 60°C, concn., addn. of concd. HCl, evapn., dissoln. in H2O/PrOH=4:3,addn. of excess COD and slight excess SnCl2, stirring (12°C, 7 d , pptn.); filtration, washing (H2O), drying (SiO2); elem. anal.; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) loading and unloading carried out in inert gas; RbH and Pt with a molar ratio of 2.1:1 mixed and filled in molybdenum boat; transferred into a low pressure autoclave; evacuated; filled with H2 up to 1 bar; heated at 620 K for 6 h; unloaded in the glove box; | 95% |
Conditions | Yield |
---|---|
In neat (no solvent) loading and unloading carried out in inert gas; RbH and Pt with a molar ratio of 3.1:1 mixed and filled in molybdenum boat; transferred into a low pressure autoclave; evacuated; filled with H2 up to 1 bar; heated at 620 K for 6 h; unloaded in the glove box; | 95% |
Conditions | Yield |
---|---|
With hydrogen In methanol | 93.7% |
sulfuryl dichloride
carbon monoxide
platinum
cis-dicarbonyldichloroplatinum(II)
Conditions | Yield |
---|---|
In thionyl chloride addn. of platinum black to soln. of SO2Cl2 in SOCl2 under CO; after 150h soln. evapd. and residue dissolved in toluene; detn. by IR; | 92% |
With platinum In thionyl chloride soln. of SO2Cl2 in SOCl2 under CO (1 atm) and platinum black sealed in tube; suspn. stirred 30 h at temp. 60°C; not isolated; detn. by IR; |
Platinum (CAS NO.7440-06-4) occurs naturally in the alluvial sands of various rivers, though there is little evidence of its use by ancient peoples. However, the metal was used by pre-Columbian Americans near modern-day Esmeraldas, Ecuador to produce artifacts of a white gold-platinum alloy.
The first European reference to platinum appears in 1557 in the writings of the Italian humanist Julius Caesar Scaliger as a description of an unknown noble metal found between Darién and Mexico, "which no fire nor any Spanish artifice has yet been able to liquefy."
In 1750, after studying the platinum sent to him by Wood, Brownrigg presented a detailed account of the metal to the Royal Society, mentioning that he had seen no mention of it in any previous accounts of known minerals. Brownrigg also made note of platinum's extremely high melting point and refractoriness toward borax. Other chemists across Europe soon began studying platinum, including Torbern Bergman, J?ns Jakob Berzelius, William Lewis, and Pierre Macquer. In 1752, Henrik Scheffer published a detailed scientific description of the metal, which he referred to as "white gold", including an account of how he succeeded in fusing platinum ore with the aid of arsenic. Scheffer described platinum as being less pliable than gold, but with similar resistance to corrosion.
Carl von Sickingen researched platinum extensively in 1772. He succeeded in making malleable platinum by alloying it with gold, dissolving the alloy in aqua regia, precipitating the platinum with ammonium chloride, igniting the ammonium chloroplatinate, and hammering the resulting finely divided platinum to make it cohere. Franz Karl Achard made the first platinum crucible in 1784. He worked with the platinum by fusing it with arsenic, then later volatilizing the arsenic.
In 1786, Charles III of Spain provided a library and laboratory to Pierre-Fran?ois Chabaneau to aid in his research of platinum. Chabaneau succeeded in removing various impurities from the ore, including gold, mercury, lead, copper, and iron. This led him to believe that he was working with a single metal, but in truth the ore still contained the yet-undiscovered platinum group metals.
From 1875 to 1960 the SI unit of length was defined as the distance between two lines on a standard bar of an alloy of ninety percent platinum and ten percent iridium, measured at 0 degrees Celsius.
In 2007 Gerhard Ertl won the Nobel Prize in Chemistry for determining the detailed molecular mechanisms of the catalytic oxidation of carbon monoxide over platinum.
Reported in EPA TSCA Inventory.
OSHA PEL: TWA (metal) 1 mg/m3; (soluble salts as Pt) 0.002 mg/m3
ACGIH TLV: TWA (metal) 1 mg/m3; (soluble salts as Pt) 0.002 mg/m3
DFG MAK: 0.002 mg/m3
NIOSH REL: (Platinum (as Pt), metal) TWA 1 mg/m3; (Platinum (as Pt), soluble salts): TWA 0.002 mg/m3
For occupational chemical analysis use NIOSH: Elements (ICP) 7300; Metals in Urine (ICP) 8310.
The Platinum, with the CAS registry number 7440-06-4, is also known as Platinum, metal. It belongs to the product categories of Inorganics; Electrode Materials Metal and Ceramic Science; Alternative Energy; Metal and Ceramic Science; Metals; Platinum; Nanoparticles: Metals and Metal AlloysChemical Synthesis; PlatinumNanomaterials; Catalysis and Inorganic Chemistry; Materials Science; Nanomaterials; Nanopowders and Nanoparticle Dispersions; Chemical Synthesis; Fuel Cell Catalysts Chemical Synthesis; Chloride Alphabetic; PER - POLASpectroscopy; AA Standard Solutions Spectroscopy; AAS; Matrix Selection; P; Reference/Calibration Standards; Single Solution; Standard Solutions; Fuel Cell Catalysts. Its EINECS registry number is 231-116-1. Its IUPAC name is called platinum. This chemical's classification code is Tumor data.
Physical properties of Platinum: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 194.964774; (5)MonoIsotopic Mass: 194.964774; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 1; (8)Formal Charge: 0; (9)Complexity: 0; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 1.
Preparation: this chemical can be prepared by platinum ore by dry in industry. This reaction will need copper, nickel sulfide ores and NH4Cl.
Uses of Platinum: it can be used to make jewelry, wire, laboratory containers, thermocouples, resistance to corrosion of equipment, dental materials. Besides, platinum powder can be used as catalyst. It can also be used as catalyst, oxidizer and gas absorbent. Platinum is used in catalytic converters, laboratory equipment, electrical contacts and electrodes, platinum resistance thermometers, dentistry equipment, and jewelry.
When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes and may cause damage to health. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Pt]
(2)InChI: InChI=1S/Pt
(3)InChIKey: BASFCYQUMIYNBI-UHFFFAOYSA-N
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