Product Name

  • Name

    Platinum

  • EINECS 231-116-1
  • CAS No. 7440-06-4
  • Article Data1514
  • CAS DataBase
  • Density 1.060 g/mL at 20 °C
  • Solubility Insoluble
  • Melting Point 1772 °C(lit.)
  • Formula Pt
  • Boiling Point 3827°C(lit.)
  • Molecular Weight 195.08
  • Flash Point 3825 °C
  • Transport Information
  • Appearance Black Powder
  • Safety 36-7/9-33-16-38-22-26-14-36/37/39-27-24/25
  • Risk Codes 11-37-20-36/37/38-36/37
  • Molecular Structure Molecular Structure of 7440-06-4 (Platinum)
  • Hazard Symbols FlammableF,IrritantXi,HarmfulXn
  • Synonyms A 3788A;C.I. 77795;Engelhard A 3788A;Furuuchi 8105;IASO;Liquid Bright Platinum;PR0;Platinum black;Platinum element;TP 1;TP 1 (metal);TPT 200;TR 706;
  • PSA 0.00000
  • LogP -0.00250

Synthetic route

platinum(IV) chloride
13454-96-1

platinum(IV) chloride

magnesium
7439-95-4

magnesium

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In water reduction with Mg in neutral or acidic soln.;100%
In water reduction with Mg in neutral or acidic soln.;100%
In water reaction in neutral and acid solutions complete;;
sodium octahydrotriborate tridioxanate

sodium octahydrotriborate tridioxanate

platinum(4+)

platinum(4+)

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In water room temp.; X-ray diffraction, gravimetric anal.;99%
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane
68478-92-2

platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With 1-decene; 1,1,3,3-tetramethyldisiloxane In toluene mixt. of tetramethyldisiloxane, 1-decene in unhyd. toluene stirred at room temp., evacuated, refilled with N2 three times, Pt-complex added, stirred at 100°C for 5 d; centrifuged, decanted, washed by toluene, centrifuged twice, dried indervac.; detd. by XRD, TEM;96%
dihydrogen hexachloroplatinate(IV) hexahydrate

dihydrogen hexachloroplatinate(IV) hexahydrate

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With hydrogen In water Reagent/catalyst; Temperature;96%
Irradiation (UV/VIS); photodeposition on NaInS2;
With aluminium In water 65 % surfactant contg. Pt-compd. soln., heating to 85 °C, coolingto room temp., heating to 80 °C, thermal aging was repeated 3 ti mes, Pt was deposited onto an Au/Ti/Si substrate with plating with Al; Pt film was washed with EtOH;
potassium tetranitroplatinate(IV)

potassium tetranitroplatinate(IV)

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In ethanol; water Kinetics; Irradiation (UV/VIS); photoreduction of K2(Pt(NO2)4) in a suspension of anatase in H2O with 4 vol.-% C2H5OH at various temp. (pH: 3.6);; deposition of Pt on the TiO2 surface;;90%
With hydrogenchloride; zinc In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;;
With HCl; Zn In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;;
1-MeCyt
1122-47-0

1-MeCyt

di(cis-[bis(dimethylphenylphosphane)(μ-hydroxo)platinum(II)]) nitrate

di(cis-[bis(dimethylphenylphosphane)(μ-hydroxo)platinum(II)]) nitrate

acetonitrile
75-05-8

acetonitrile

cis-[(PMe2Ph)2Pt(1-methylcytosinate-N(3),N(4)(1-))]3(NO3)3*H2O*(acetonitrile)

cis-[(PMe2Ph)2Pt(1-methylcytosinate-N(3),N(4)(1-))]3(NO3)3*H2O*(acetonitrile)

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In acetonitrile byproducts: H2O; suspn. of Pt complex and ligand (molar ratio 1:2) in MeCN stirred at room temp. for a few min; stored at room temp. overnight; filtered; Et2O added to filtrate; filtered; solid washed with Et2O; dried under vac.; dissolved in MeCN; crystd. by slow condensation of Et2O vapors; elem. anal.;A 81%
B 1%
bis(η3-allyl)(tetracyanoethylene)platinum
98689-94-2

bis(η3-allyl)(tetracyanoethylene)platinum

A

CH2CHCH2C(CN)2C(CN)2CH2CHCH2
98704-14-4

CH2CHCH2C(CN)2C(CN)2CH2CHCH2

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2, mixt. was stirred for 2 h at room temp.; Pt metal was removed by filtration through Florisil, filtrate concd. and subjected to HLPC;A 73%
B n/a
With triphenylphosphine In dichloromethane-d2 a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2; followed by (1)H and (31)P NMR;
formic acid
64-18-6

formic acid

platinum(IV) chloride
13454-96-1

platinum(IV) chloride

A

carbon dioxide
124-38-9

carbon dioxide

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With cinchonine In water byproducts: HCl; heating (140+/-5°C); filtn. (G4 filter), washing (aq. NaHCO3; H2O), freeze drying;A n/a
B 71%
platinum(II) bromde

platinum(II) bromde

1,1'-dimethyl-3,3'-methylenediimidazolium bromide

1,1'-dimethyl-3,3'-methylenediimidazolium bromide

1,1′-di(methyl)-3,3′-methylene-4-diimidazolin-2,2′-diylideneplatinum(II) dibromide

1,1′-di(methyl)-3,3′-methylene-4-diimidazolin-2,2′-diylideneplatinum(II) dibromide

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With sodium acetate trihydrate In dimethyl sulfoxide byproducts: NaBr, acetic acid; PtBr2, Na salt and ligand (molar ratio 1:2:1) dissolved in DMSO; heated to 80°C for 2 h and then to 100°C for 1 h; cooled to room temp.; filtered; solvent evapd. from filtrate; washed with CH2Cl2; extd. with small amt. of H2O; residue washed with THF; dried under high vac.; elem. anal.;A 64.2%
B n/a
C6H12Br2O2Pt

C6H12Br2O2Pt

A

cobaltocenium bromide

cobaltocenium bromide

B

(E)-2,3-dimethoxybut-2-ene
41715-05-3

(E)-2,3-dimethoxybut-2-ene

C

(Z)-2,3-dimethoxybut-2-ene
41715-06-4

(Z)-2,3-dimethoxybut-2-ene

D

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With cobaltocene In dichloromethane-d2A n/a
B n/a
C 64%
D n/a
Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)
119593-13-4

Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)

A

Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9
57673-31-1

Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9

B

Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2
123857-98-7

Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2

C

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In toluene N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.;A n/a
B 50%
C n/a
In dichloromethane N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.;A n/a
B 50%
C n/a
trans-[PtCl(Me)(PEt3)2]

trans-[PtCl(Me)(PEt3)2]

A

dichlorobis(triethylphosphine)platinum
13965-02-1, 14177-93-6, 15692-07-6

dichlorobis(triethylphosphine)platinum

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A 48%
B n/a
C 2%
D <1
E 43%
trans-{PtCH3(CN)(PEt3)2}
22289-45-8

trans-{PtCH3(CN)(PEt3)2}

A

Pt(CN)2(P(C2H5)3)2

Pt(CN)2(P(C2H5)3)2

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A 48%
B n/a
C 2%
D <1
E 43%
trans-[Pt(Me)I(PEt3)2]

trans-[Pt(Me)I(PEt3)2]

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

ethene
74-85-1

ethene

D

Pt(PEt3)2I2
15692-97-4

Pt(PEt3)2I2

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A n/a
B 2%
C <1
D 48%
E 43%
platinum(IV) chloride
13454-96-1

platinum(IV) chloride

magnesium
7439-95-4

magnesium

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In water reduction with Mg in neutral or acidic soln.;100%
In water reduction with Mg in neutral or acidic soln.;100%
In water reaction in neutral and acid solutions complete;;
sodium octahydrotriborate tridioxanate

sodium octahydrotriborate tridioxanate

platinum(4+)

platinum(4+)

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In water room temp.; X-ray diffraction, gravimetric anal.;99%
platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane
68478-92-2

platinum 1,3-divinyl-1,1,3,3-tetramethyldisiloxane

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With 1-decene; 1,1,3,3-tetramethyldisiloxane In toluene mixt. of tetramethyldisiloxane, 1-decene in unhyd. toluene stirred at room temp., evacuated, refilled with N2 three times, Pt-complex added, stirred at 100°C for 5 d; centrifuged, decanted, washed by toluene, centrifuged twice, dried indervac.; detd. by XRD, TEM;96%
dihydrogen hexachloroplatinate(IV) hexahydrate

dihydrogen hexachloroplatinate(IV) hexahydrate

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With hydrogen In water Reagent/catalyst; Temperature;96%
Irradiation (UV/VIS); photodeposition on NaInS2;
With aluminium In water 65 % surfactant contg. Pt-compd. soln., heating to 85 °C, coolingto room temp., heating to 80 °C, thermal aging was repeated 3 ti mes, Pt was deposited onto an Au/Ti/Si substrate with plating with Al; Pt film was washed with EtOH;
potassium tetranitroplatinate(IV)

potassium tetranitroplatinate(IV)

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In ethanol; water Kinetics; Irradiation (UV/VIS); photoreduction of K2(Pt(NO2)4) in a suspension of anatase in H2O with 4 vol.-% C2H5OH at various temp. (pH: 3.6);; deposition of Pt on the TiO2 surface;;90%
With hydrogenchloride; zinc In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;;
With HCl; Zn In water byproducts: KCl, ZnCl2; aq. K2(Pt(NO2)4) soln., at elevated temp. or in coldness;;
1-MeCyt
1122-47-0

1-MeCyt

di(cis-[bis(dimethylphenylphosphane)(μ-hydroxo)platinum(II)]) nitrate

di(cis-[bis(dimethylphenylphosphane)(μ-hydroxo)platinum(II)]) nitrate

acetonitrile
75-05-8

acetonitrile

cis-[(PMe2Ph)2Pt(1-methylcytosinate-N(3),N(4)(1-))]3(NO3)3*H2O*(acetonitrile)

cis-[(PMe2Ph)2Pt(1-methylcytosinate-N(3),N(4)(1-))]3(NO3)3*H2O*(acetonitrile)

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In acetonitrile byproducts: H2O; suspn. of Pt complex and ligand (molar ratio 1:2) in MeCN stirred at room temp. for a few min; stored at room temp. overnight; filtered; Et2O added to filtrate; filtered; solid washed with Et2O; dried under vac.; dissolved in MeCN; crystd. by slow condensation of Et2O vapors; elem. anal.;A 81%
B 1%
bis(η3-allyl)(tetracyanoethylene)platinum
98689-94-2

bis(η3-allyl)(tetracyanoethylene)platinum

A

CH2CHCH2C(CN)2C(CN)2CH2CHCH2
98704-14-4

CH2CHCH2C(CN)2C(CN)2CH2CHCH2

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With triphenylphosphine In dichloromethane a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2, mixt. was stirred for 2 h at room temp.; Pt metal was removed by filtration through Florisil, filtrate concd. and subjected to HLPC;A 73%
B n/a
With triphenylphosphine In dichloromethane-d2 a soln. PPh3 in CH2Cl2 was added dropwise with stirring to a CH2Cl2 soln. of Pt-complex under N2; followed by (1)H and (31)P NMR;
formic acid
64-18-6

formic acid

platinum(IV) chloride
13454-96-1

platinum(IV) chloride

A

carbon dioxide
124-38-9

carbon dioxide

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With cinchonine In water byproducts: HCl; heating (140+/-5°C); filtn. (G4 filter), washing (aq. NaHCO3; H2O), freeze drying;A n/a
B 71%
platinum(II) bromde

platinum(II) bromde

1,1'-dimethyl-3,3'-methylenediimidazolium bromide

1,1'-dimethyl-3,3'-methylenediimidazolium bromide

1,1′-di(methyl)-3,3′-methylene-4-diimidazolin-2,2′-diylideneplatinum(II) dibromide

1,1′-di(methyl)-3,3′-methylene-4-diimidazolin-2,2′-diylideneplatinum(II) dibromide

B

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With sodium acetate trihydrate In dimethyl sulfoxide byproducts: NaBr, acetic acid; PtBr2, Na salt and ligand (molar ratio 1:2:1) dissolved in DMSO; heated to 80°C for 2 h and then to 100°C for 1 h; cooled to room temp.; filtered; solvent evapd. from filtrate; washed with CH2Cl2; extd. with small amt. of H2O; residue washed with THF; dried under high vac.; elem. anal.;A 64.2%
B n/a
C6H12Br2O2Pt

C6H12Br2O2Pt

A

cobaltocenium bromide

cobaltocenium bromide

B

(E)-2,3-dimethoxybut-2-ene
41715-05-3

(E)-2,3-dimethoxybut-2-ene

C

(Z)-2,3-dimethoxybut-2-ene
41715-06-4

(Z)-2,3-dimethoxybut-2-ene

D

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With cobaltocene In dichloromethane-d2A n/a
B n/a
C 64%
D n/a
Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)
119593-13-4

Ru3Pt(μ-H)(μ4-η2-CC(t-Bu))(CO)9(cycloocta-1,5-diene)

A

Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9
57673-31-1

Ru3(μ-H)(μ3-η2-CC(t-Bu))(CO)9

B

Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2
123857-98-7

Pt{Ru3(μ-H)(μ4-η2-CC(t-Bu))(CO)9}2

C

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In toluene N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.;A n/a
B 50%
C n/a
In dichloromethane N2-atmosphere; ambient temp., 5 days (crystn.); washing (petroleum ether); elem. anal.;A n/a
B 50%
C n/a
trans-[PtCl(Me)(PEt3)2]

trans-[PtCl(Me)(PEt3)2]

A

dichlorobis(triethylphosphine)platinum
13965-02-1, 14177-93-6, 15692-07-6

dichlorobis(triethylphosphine)platinum

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A 48%
B n/a
C 2%
D <1
E 43%
trans-{PtCH3(CN)(PEt3)2}
22289-45-8

trans-{PtCH3(CN)(PEt3)2}

A

Pt(CN)2(P(C2H5)3)2

Pt(CN)2(P(C2H5)3)2

B

methane
34557-54-5

methane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A 48%
B n/a
C 2%
D <1
E 43%
trans-[Pt(Me)I(PEt3)2]

trans-[Pt(Me)I(PEt3)2]

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

ethene
74-85-1

ethene

D

Pt(PEt3)2I2
15692-97-4

Pt(PEt3)2I2

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A n/a
B 2%
C <1
D 48%
E 43%
trans-(triethylphosphine)2PtMeBr
15691-67-5, 22289-47-0

trans-(triethylphosphine)2PtMeBr

A

methane
34557-54-5

methane

B

ethane
74-84-0

ethane

C

ethene
74-85-1

ethene

D

[PtBr2(P(CH2CH3)3)2]
15636-78-9, 15692-84-9, 13985-90-5

[PtBr2(P(CH2CH3)3)2]

E

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In decalin Kinetics; Pt complex was heated in decalin under Ar at 170 and 200°C; rateconst for decompn. at 200°C is given; Pt was filtered off, light petroleum was added to the concd. soln., crystals were collected, gas. products were detd. by GLS;A n/a
B 2%
C <1
D 48%
E 43%
platinum(II) acetylacetonate

platinum(II) acetylacetonate

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With 1-butanol; oleylamine; acetic acid In toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (185°C, 16 h); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH;45%
With 1-butanol; oleylamine; acetic acid In N,N-dimethyl-formamide; toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (185°C, 16 h); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH;45%
With 1-butanol; oleylamine; acetic acid In N,N-dimethyl-formamide; toluene High Pressure; mixt. of 10 mM Pt(acac)2 (2 ml), 80 mM CH3COOH (0.5 ml) and 0.1 M oleylamine (1 ml) in toluene, 1-butanol (1 ml) and DMF (2.5 ml) heated in autoclave (145°C); cooled naturally to room temp.; centrifuged; ppt. washed with EtOH;
Pt(PPh3)2(N2O2)

Pt(PPh3)2(N2O2)

iodine
7553-56-2

iodine

trans-diiodobis(triphenylphosphane)platinum(II)
35085-00-8, 23523-31-1, 35085-01-9

trans-diiodobis(triphenylphosphane)platinum(II)

B

platinum
7440-06-4

platinum

C

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
With Et3N In dichloromethane byproducts: PPh3O; Pt-compd. and Et3N were dissolved in CH2Cl2, cooling to -78 °C, 2equiv. of I2 was added, warming to room temp. over 1 h; ppt. was filtered off;A 45%
B n/a
C n/a
trans-chlorohydridobis(triethylphosphine)platinum(II)
16842-17-4, 20436-52-6, 89254-73-9

trans-chlorohydridobis(triethylphosphine)platinum(II)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

A

1-butylene
106-98-9

1-butylene

trans-{PtH(CH2CN)(PEt3)2}
118831-46-2

trans-{PtH(CH2CN)(PEt3)2}

C

tributyl-amine
102-82-9

tributyl-amine

D

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In acetonitrile; benzene byproducts: H2; Electrolysis; electrochemically reducing trans-(PtH(Cl)(PEt3)2) at -2.1 V vs Ag/AgCl in CH3CN/C6H6 (5/2, v/v), terminating electrolysis at constancy of current; 36% of hydrido complex recovered; 31P NMR;A n/a
B 38%
C n/a
D n/a
platinum(IV) oxide
1314-15-4

platinum(IV) oxide

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With hydrogen In acetic acid under 760.051 Torr; for 1.5h;
With hydrogenchloride; hydrogen In hydrogenchloride bubbling of H2 through suspn. of PtO2 in aq. HCl for 20 min;
With hydrogen In water react. of PtO2 with H2 (50 psi) in water at room temp. for 30 min;
dihydrogen hexachloroplatinate

dihydrogen hexachloroplatinate

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With poly(1-vinyl-2-pyrrolidone) In ethanol; water at 100℃; for 14.5h; Heating / reflux;
With J-0381V; L-10D; ethanol; sodium hydrogencarbonate In water at 70℃;
With ethanol; sodium hydrogencarbonate; polysorbate 80 In water at 70℃;
hexachloroplatinic acid

hexachloroplatinic acid

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In 1-ethenyl-2-pyrrolidinone; ethanol; water at 100℃; for 2.66667h; Product distribution / selectivity; Heating / reflux;
In poly(sodium acrylate); ethanol; water at 100℃; for 2.66667h; Product distribution / selectivity; Heating / reflux;
dihydrogen hexachloroplatinate

dihydrogen hexachloroplatinate

formic acid
64-18-6

formic acid

platinum
7440-06-4

platinum

Conditions
ConditionsYield
With sodium carbonate In not given heating;
With Na2CO3 In not given heating;
sodium hexachloroplatinate

sodium hexachloroplatinate

formic acid
64-18-6

formic acid

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In ammonia Electrochem. Process; solution of {Pt(NH3)2Cl2} in aq. NH3, 90°C;;
With NaB(C2H5)3H In tetrahydrofuran byproducts: NaCl, B(C2H5)3, H2; 23°C, 2 h; Washing with H2O to separate alkali halogenide from metal powder.;
In ammonia Electrochem. Process; no pptn. of Pt out of a satd. soln. of {Pt(NH3)2(CNS)2} in aq. NH3, evolution of H2 at the cathode;;0%
In ammonia Electrochem. Process; solution of {Pt(NH3)2Cl2} in aq. NH3, 90°C;;
Co(NH3)5(NO2)(2+)*Pt(NO2)4(2-)*1.5H2O=(Co(NH3)5(NO2))(Pt(NO2)4)*1.5H2O

Co(NH3)5(NO2)(2+)*Pt(NO2)4(2-)*1.5H2O=(Co(NH3)5(NO2))(Pt(NO2)4)*1.5H2O

ammonium chloride

ammonium chloride

A

Co0.40Pt0.60

Co0.40Pt0.60

B

Co0.10Pt0.90

Co0.10Pt0.90

C

Pt0.75Co0.25

Pt0.75Co0.25

D

platinum
7440-06-4

platinum

E

cobalt(II) chloride
7646-79-9

cobalt(II) chloride

Conditions
ConditionsYield
In neat (no solvent) under He; mixt. of Co-Pt complex and NH4Cl (1:10 wt/wt) heated to 500°C; detd. by X-ray powder diffraction;
platinum tetrabromide
68938-92-1

platinum tetrabromide

platinum
7440-06-4

platinum

Conditions
ConditionsYield
In water Electrochem. Process; pptn. from a concd. aq. soln. of PtBr4 (bunsen cell);;
With alc. In not given heating;
With diethyl ether In not given heating;
bismuth
7440-69-9

bismuth

aqueous H2 O2

aqueous H2 O2

sulfuric acid
7664-93-9

sulfuric acid

pyrographite
7440-44-0

pyrographite

2-butyl-5-hydroxymethyl-1H-imidazole
68283-19-2

2-butyl-5-hydroxymethyl-1H-imidazole

platinum
7440-06-4

platinum

2-butyl-1H-imidazole-5-carboxaldehyde
68282-49-5

2-butyl-1H-imidazole-5-carboxaldehyde

Conditions
ConditionsYield
With sodium hydroxide In water100%
With sodium hydroxide In water98.2%
With sodium hydroxide In methanol; water94.5%
2-(cyanomethyl)cyclohexanone
42185-27-3

2-(cyanomethyl)cyclohexanone

platinum
7440-06-4

platinum

indole
120-72-9

indole

Conditions
ConditionsYield
With hydrogen100%
bis(diethoxyphosphoryl)disulphide
2901-90-8

bis(diethoxyphosphoryl)disulphide

platinum
7440-06-4

platinum

bis(O,O'-diethyldithiophosphato-S,S')platinum(II)
37583-01-0

bis(O,O'-diethyldithiophosphato-S,S')platinum(II)

Conditions
ConditionsYield
In styrene at 20℃; for 0.333333h; Product distribution / selectivity;100%
calcium
7440-70-2

calcium

platinum
7440-06-4

platinum

cadmium
7440-43-9

cadmium

Ca6PtCd11

Ca6PtCd11

Conditions
ConditionsYield
In neat (no solvent) at 600 - 950℃; for 111h; Sealed tube; Schlenk technique; Inert atmosphere; Glovebox;100%
hydrogenchloride
7647-01-0

hydrogenchloride

CYANAMID
420-04-2

CYANAMID

platinum
7440-06-4

platinum

Cl6Pt(2-)*2CH4ClN2(1+)

Cl6Pt(2-)*2CH4ClN2(1+)

Conditions
ConditionsYield
Stage #1: platinum With hydrogenchloride; dihydrogen peroxide In water
Stage #2: hydrogenchloride In water
Stage #3: CYANAMID With hydrogenchloride In water
100%
acetic acid-(5-chloro-2-hydroxy-3-nitro-anilide)
156016-33-0

acetic acid-(5-chloro-2-hydroxy-3-nitro-anilide)

platinum
7440-06-4

platinum

7-acetamino-5-chloro-2-mercaptobenzoxazole

7-acetamino-5-chloro-2-mercaptobenzoxazole

Conditions
ConditionsYield
With carbon disulfide; potassium hydroxide In ethanol; ethyl acetate99%
rac.-N-[1-(5-chloro-1H-benzoimidazol-2-yl)-ethyl]-3-ethynyl-4-(pyrrolidine-1-carbonyl)-benzamide
713138-43-3

rac.-N-[1-(5-chloro-1H-benzoimidazol-2-yl)-ethyl]-3-ethynyl-4-(pyrrolidine-1-carbonyl)-benzamide

platinum
7440-06-4

platinum

N-[1-(5-chloro-1H-benzimidazol-2-yl)-ethyl]-3-ethyl-4-(pyrrolidin-1-yl-carbonyl)-benzamide

N-[1-(5-chloro-1H-benzimidazol-2-yl)-ethyl]-3-ethyl-4-(pyrrolidin-1-yl-carbonyl)-benzamide

Conditions
ConditionsYield
With hydrogen In 1,4-dioxane; water99%
2,4-diamino-5-nitroso-6-hydroxypyrimidine
2387-48-6

2,4-diamino-5-nitroso-6-hydroxypyrimidine

platinum
7440-06-4

platinum

2-amino-1,9-dihydro-6H-purin-6-one
73-40-5

2-amino-1,9-dihydro-6H-purin-6-one

Conditions
ConditionsYield
98.9%
allyl methacrylate
96-05-9

allyl methacrylate

platinum
7440-06-4

platinum

γ-methacryloxypropyltrichlorosilane

γ-methacryloxypropyltrichlorosilane

Conditions
ConditionsYield
With trichlorosilane; [SG]-S-Pt In hexane98%
2,6-diisopropylcyclohexanol
95299-24-4

2,6-diisopropylcyclohexanol

platinum
7440-06-4

platinum

2,6-diisopropylphenol
2078-54-8

2,6-diisopropylphenol

Conditions
ConditionsYield
96.5%
ethyl 2-methyl-4,4,4-trifluoroacetoacetate
344-00-3

ethyl 2-methyl-4,4,4-trifluoroacetoacetate

platinum
7440-06-4

platinum

ethyl 3-hydroxy-2-methyl-4,4,4-trifluorobutanoate
91600-33-8

ethyl 3-hydroxy-2-methyl-4,4,4-trifluorobutanoate

Conditions
ConditionsYield
With nitrogen; hydrogen; triethylamine; Pt/C96%
platinum
7440-06-4

platinum

isopropyl 4,4,4-trifluoro-3-oxobutanoate

isopropyl 4,4,4-trifluoro-3-oxobutanoate

isopropyl 4,4,4-trifluoro-3-hydroxybutanoate

isopropyl 4,4,4-trifluoro-3-hydroxybutanoate

Conditions
ConditionsYield
With nitrogen; hydrogen; triethylamine; Pt/C96%
ethyl 4,4,4-trifluoroacetoacetate
372-31-6

ethyl 4,4,4-trifluoroacetoacetate

platinum
7440-06-4

platinum

ethyl 3-hydroxy-4,4,4-trifluorobutyrate
372-30-5

ethyl 3-hydroxy-4,4,4-trifluorobutyrate

Conditions
ConditionsYield
With nitrogen; hydrogen; triethylamine; Pt/C96%
With nitrogen; hydrogen; triethylamine; Pt/C96%
With nitrogen; hydrogen; triethylamine; Pt/C96%
With nitrogen; hydrogen; triethylamine96%
With methanesulfonic acid; nitrogen; hydrogen; Pt/C50%
2-(2-carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(p-nitrobenzyl)-1H-imidazole
178980-69-3

2-(2-carbamoyloxyethyl)-5-(3,5-dichlorophenylthio)-4-isopropyl-1-(p-nitrobenzyl)-1H-imidazole

platinum
7440-06-4

platinum

1-(4-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole
178980-34-2

1-(4-Aminobenzyl)-5-(3,5-dichlorophenylthio)-2-(2-carbamoyloxyethyl)-4-isopropyl-1H-imidazole

Conditions
ConditionsYield
In ethyl acetate95%
2,5-dichlorophenyl-1-sulfochloride

2,5-dichlorophenyl-1-sulfochloride

platinum
7440-06-4

platinum

2,5-dichlorbenzenethiol
5858-18-4

2,5-dichlorbenzenethiol

Conditions
ConditionsYield
In water; toluene95%
hydrogenchloride
7647-01-0

hydrogenchloride

platinum
7440-06-4

platinum

1,5-dicyclooctadiene
5259-72-3, 10060-40-9, 111-78-4

1,5-dicyclooctadiene

dichloro(1,5-cyclooctadiene)platinum(ll)
12080-32-9

dichloro(1,5-cyclooctadiene)platinum(ll)

Conditions
ConditionsYield
With HNO3; SnCl2*2H2O In further solvent(s) byproducts: nitrogen oxides; N2-atmosphere; dissoln. of Pt in aqua regia by stirring overnight at 60°C, concn., addn. of concd. HCl, evapn., dissoln. in H2O/PrOH=4:3,addn. of excess COD and slight excess SnCl2, stirring (12°C, 7 d , pptn.); filtration, washing (H2O), drying (SiO2); elem. anal.;95%
rubidium hydride

rubidium hydride

hydrogen
1333-74-0

hydrogen

platinum
7440-06-4

platinum

rubidium [hydridoplatinate(II)]

rubidium [hydridoplatinate(II)]

Conditions
ConditionsYield
In neat (no solvent) loading and unloading carried out in inert gas; RbH and Pt with a molar ratio of 2.1:1 mixed and filled in molybdenum boat; transferred into a low pressure autoclave; evacuated; filled with H2 up to 1 bar; heated at 620 K for 6 h; unloaded in the glove box;95%
rubidium hydride

rubidium hydride

hydrogen
1333-74-0

hydrogen

platinum
7440-06-4

platinum

rubidium hydride [hydridoplatinate(II)]

rubidium hydride [hydridoplatinate(II)]

Conditions
ConditionsYield
In neat (no solvent) loading and unloading carried out in inert gas; RbH and Pt with a molar ratio of 3.1:1 mixed and filled in molybdenum boat; transferred into a low pressure autoclave; evacuated; filled with H2 up to 1 bar; heated at 620 K for 6 h; unloaded in the glove box;95%
1-(4-diphenyl)3,3-dimethyl-1-(1-imidazolyl)-5-hexen-2-ol

1-(4-diphenyl)3,3-dimethyl-1-(1-imidazolyl)-5-hexen-2-ol

pyrographite
7440-44-0

pyrographite

platinum
7440-06-4

platinum

1-(4-Diphenyl)-3,3-dimethyl-1-(1-imidazolyl)-2-hexanol

1-(4-Diphenyl)-3,3-dimethyl-1-(1-imidazolyl)-2-hexanol

Conditions
ConditionsYield
With hydrogen In methanol93.7%
sulfuryl dichloride
7791-25-5

sulfuryl dichloride

carbon monoxide
201230-82-2

carbon monoxide

platinum
7440-06-4

platinum

cis-dicarbonyldichloroplatinum(II)
25478-60-8, 15020-32-3, 62841-60-5

cis-dicarbonyldichloroplatinum(II)

Conditions
ConditionsYield
In thionyl chloride addn. of platinum black to soln. of SO2Cl2 in SOCl2 under CO; after 150h soln. evapd. and residue dissolved in toluene; detn. by IR;92%
With platinum In thionyl chloride soln. of SO2Cl2 in SOCl2 under CO (1 atm) and platinum black sealed in tube; suspn. stirred 30 h at temp. 60°C; not isolated; detn. by IR;

Platinum History

 Platinum (CAS NO.7440-06-4) occurs naturally in the alluvial sands of various rivers, though there is little evidence of its use by ancient peoples. However, the metal was used by pre-Columbian Americans near modern-day Esmeraldas, Ecuador to produce artifacts of a white gold-platinum alloy.
The first European reference to platinum appears in 1557 in the writings of the Italian humanist Julius Caesar Scaliger as a description of an unknown noble metal found between Darién and Mexico, "which no fire nor any Spanish artifice has yet been able to liquefy."
In 1750, after studying the platinum sent to him by Wood, Brownrigg presented a detailed account of the metal to the Royal Society, mentioning that he had seen no mention of it in any previous accounts of known minerals. Brownrigg also made note of platinum's extremely high melting point and refractoriness toward borax. Other chemists across Europe soon began studying platinum, including Torbern Bergman, J?ns Jakob Berzelius, William Lewis, and Pierre Macquer. In 1752, Henrik Scheffer published a detailed scientific description of the metal, which he referred to as "white gold", including an account of how he succeeded in fusing platinum ore with the aid of arsenic. Scheffer described platinum as being less pliable than gold, but with similar resistance to corrosion.
Carl von Sickingen researched platinum extensively in 1772. He succeeded in making malleable platinum by alloying it with gold, dissolving the alloy in aqua regia, precipitating the platinum with ammonium chloride, igniting the ammonium chloroplatinate, and hammering the resulting finely divided platinum to make it cohere. Franz Karl Achard made the first platinum crucible in 1784. He worked with the platinum by fusing it with arsenic, then later volatilizing the arsenic.
In 1786, Charles III of Spain provided a library and laboratory to Pierre-Fran?ois Chabaneau to aid in his research of platinum. Chabaneau succeeded in removing various impurities from the ore, including gold, mercury, lead, copper, and iron. This led him to believe that he was working with a single metal, but in truth the ore still contained the yet-undiscovered platinum group metals.
From 1875 to 1960 the SI unit of length was defined as the distance between two lines on a standard bar of an alloy of ninety percent platinum and ten percent iridium, measured at 0 degrees Celsius.
In 2007 Gerhard Ertl won the Nobel Prize in Chemistry for determining the detailed molecular mechanisms of the catalytic oxidation of carbon monoxide over platinum.

Platinum Consensus Reports

Reported in EPA TSCA Inventory.

Platinum Standards and Recommendations

OSHA PEL: TWA (metal) 1 mg/m3; (soluble salts as Pt) 0.002 mg/m3
ACGIH TLV: TWA (metal) 1 mg/m3; (soluble salts as Pt) 0.002 mg/m3
DFG MAK: 0.002 mg/m3
NIOSH REL: (Platinum (as Pt), metal) TWA 1 mg/m3; (Platinum (as Pt), soluble salts): TWA 0.002 mg/m3

Platinum Analytical Methods

For occupational chemical analysis use NIOSH: Elements (ICP) 7300; Metals in Urine (ICP) 8310.

Platinum Specification

The Platinum, with the CAS registry number 7440-06-4, is also known as Platinum, metal. It belongs to the product categories of Inorganics; Electrode Materials Metal and Ceramic Science; Alternative Energy; Metal and Ceramic Science; Metals; Platinum; Nanoparticles: Metals and Metal AlloysChemical Synthesis; PlatinumNanomaterials; Catalysis and Inorganic Chemistry; Materials Science; Nanomaterials; Nanopowders and Nanoparticle Dispersions; Chemical Synthesis; Fuel Cell Catalysts Chemical Synthesis; Chloride Alphabetic; PER - POLASpectroscopy; AA Standard Solutions Spectroscopy; AAS; Matrix Selection; P; Reference/Calibration Standards; Single Solution; Standard Solutions; Fuel Cell Catalysts. Its EINECS registry number is 231-116-1. Its IUPAC name is called platinum. This chemical's classification code is Tumor data.

Physical properties of Platinum: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 0; (3)Rotatable Bond Count: 0; (4)Exact Mass: 194.964774; (5)MonoIsotopic Mass: 194.964774; (6)Topological Polar Surface Area: 0; (7)Heavy Atom Count: 1; (8)Formal Charge: 0; (9)Complexity: 0; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 1.

Preparation: this chemical can be prepared by platinum ore by dry in industry. This reaction will need copper, nickel sulfide ores and NH4Cl.

Uses of Platinum: it can be used to make jewelry, wire, laboratory containers, thermocouples, resistance to corrosion of equipment, dental materials. Besides, platinum powder can be used as catalyst. It can also be used as catalyst, oxidizer and gas absorbent. Platinum is used in catalytic converters, laboratory equipment, electrical contacts and electrodes, platinum resistance thermometers, dentistry equipment, and jewelry.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes and may cause damage to health. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Pt]
(2)InChI: InChI=1S/Pt
(3)InChIKey: BASFCYQUMIYNBI-UHFFFAOYSA-N

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