Tetrapropyl ammonium chloride supplier

Name
Tetrapropyl ammonium chloride
EINECS 227-375-5
CAS No. 5810-42-4
Density 1.41g/cm³
Solubility Soluble in water, acetone
Melting Point 240-242 °C(lit.)
Formula C₁₂H₂₈ClN
Boiling Point 358.03°C (rough estimate)
Molecular Weight 221.814
Flash Point
Transport Information
Appearance solid
Safety 26-36-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Tetra-n-propylammonium chloride;1-Propanaminium,N,N,N-tripropyl-, chloride (9CI);Ammonium, tetrapropyl-, chloride (8CI);Tetrapropylammonium chloride (6CI,7CI);N,N,N-Tripropyl-1-propanaminiumchloride;1-Propanaminium, N,N,N-tripropyl-, chloride;1-propanaminium, N,N,N-tripropyl-, chloride (1:1);n,n,n-tripropylpropan-1-aminium chloride;
PSA 0.00000
LogP 0.44720

Synthetic route

: 887280-10-6
3,5-bis(bis[(N'-tert-butylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7732-18-5
water

: 7646-79-9
cobalt(II) chloride

: tetrapropylammonium μ-hydroxo-μ-(3,5-bis(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl; (Ar); a soln. of ligand treated with KH, CoCl2 added, stirred for 30 min, H2O added, stirred for 30 min, N(C3H7)4Cl added, stirred for 1 h; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.); elem. anal.;	99%

...Expand

: 60-35-5
acetamide

: 887280-12-8
3,5-bis(bis[(N'-isopropylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7646-79-9
cobalt(II) chloride

: tetrapropylammonium μ-1,3-acetamido-μ-(3,5-bis(bis[(N'-isopropylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl; (Ar); a soln. of C3H2N2(CH2N(C2H4NHC(O)NHCH(CH3)2)2)2 treated with KH, CoCl2 added, stirred, acetamide added, stirred, N(C3H7)4Cl added, stirred; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.); elem. anal.;	99%

...Expand

: 60-35-5
acetamide

: 887280-10-6
3,5-bis(bis[(N'-tert-butylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7646-79-9
cobalt(II) chloride

: tetrapropylammonium μ-1,3-acetamido-μ-(3,5-bis(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl; (Ar); a soln. of C3H2N2(CH2N(C2H4NHC(O)NHC(CH3)3)2)2 treated with KH, CoCl2 added, stirred for 30 min, acetamide added, stirred for 30 min, N(C3H7)4Cl added, stirred for 1 h; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.);	99%

...Expand

: 127-19-5
N,N-dimethyl acetamide

: 887280-12-8
3,5-bis(bis[(N'-isopropylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: tetrapropylammonium μ-1,3-acetato-μ-(3,5-bis(bis[(N'-isopropylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II) N,N-dimethylacetamide adduct (1/1)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl, KCH3COO; (Ar); a soln. of C3H2N2(CH2N(C2H4NHC(O)NHC(CH3)3)2)2 treated with KH, Cosalt added, stirred, N(C3H7)4Cl added, stirred; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.); elem. anal.;	99%

...Expand

: 127-19-5
N,N-dimethyl acetamide

: 887280-10-6
3,5-bis(bis[(N'-tert-butylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: tetrapropylammonium μ-1,3-acetato-μ-(3,5-bis(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II) N,N-dimethylacetamide adduct (1/1)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl, KCH3COO; (Ar); a soln. of C3H2N2(CH2N(C2H4NHC(O)NHC(CH3)3)2)2 treated with KH, Cosalt added, stirred for 30 min, N(C3H7)4Cl added, stirred for 1 h; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.); elem. anal.;	99%

...Expand

: 75-09-2
dichloromethane

: 1000006-56-3
3-(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-5-tert-butyl-1H-pyrazole

: 5810-42-4
Tetrapropylammonium chloride

: 7732-18-5
water

: 71-48-7, 917-69-1, 5931-89-5, 55881-15-7, 68931-68-0, 68931-69-1, 93029-27-7
cobalt(II) acetate

: tetrapropylammonium 3-(bis[(N'-tert-butylureaylato)-N-ethyl]aminatomethyl)-5-tert-butyl-1H-pyrazolato(hydroxo)cobaltate(II) dichloromethane adduct (1/0.8)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl; (Ar); a soln. of ligand treated with KH, Co salt added, stirred, filtered, H2O added, stirred for 30 min, N(C3H7)4Cl added, stirred for 1 h; dissolved in CH2Cl2, filtered, evapd. (vac.), washed (Et2O/pentane), dried (vac.); elem. anal.;	95%

...Expand

: 1,10-bis(phenyliodonium)-closo-decaborate

: 5810-42-4
Tetrapropylammonium chloride

: B10H8I2(2-)*2C12H28N(1+)

Conditions

Conditions	Yield
Stage #1: 1,10-bis(phenyliodonium)-closo-decaborate With n-butyllithium In tetrahydrofuran; hexane at -10 - -5℃; for 1h; Inert atmosphere; Stage #2: Tetrapropylammonium chloride Inert atmosphere;	95%

: 75-09-2
dichloromethane

: 887280-12-8
3,5-bis(bis[(N'-isopropylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7732-18-5
water

: 7646-79-9
cobalt(II) chloride

: tetrapropylammonium μ-hydroxo-μ-(3,5-bis(bis[(N'-isopropylureaylato)-N-ethyl]aminatomethyl)-1H-pyrazolato)dicobaltate(II) dichloromethane adduct (10/1)

Conditions

Conditions	Yield
With KH In N,N-dimethyl acetamide byproducts: KCl; (Ar); a soln. of ligand treated with KH, CoCl2 added, stirred, H2O added, stirred, N(C3H7)4Cl added, stirred; evapd. (vac., at room temp.), washed (Et2O), dried (vac.), dissolved in CH2Cl2, filtered, evapd. (vac.); elem. anal.;	94%

...Expand

: potassium hexacyanocobaltate(III)

: 1066-45-1
trimethyltin(IV)chloride

: 5810-42-4
Tetrapropylammonium chloride

: (C3H7)4N(1+)*2Sn(CH3)3(1+)*Co(CN)6(3-)*2H2O=N(C3H7)4(Sn(CH3)3)2Co(CN)6*2H2O

Conditions

Conditions	Yield
In water K3Co(CN)6 in H2O was added under stirring to soln. of ligand and Sn-complex in H2O, 15 min; filtered, washed with H2O, dried at room temp. for ca. 10 h; elem. anal.;	90%

...Expand

: [(Me3Sn)3Fe(CN)6]n

: 5810-42-4
Tetrapropylammonium chloride

: (C3H7)4N(1+)*2Sn(CH3)3(1+)*Fe(CN)6(3-)*2H2O=N(C3H7)4(Sn(CH3)3)2Fe(CN)6*2H2O

Conditions

Conditions	Yield
In water SnFe-complex was reacted with ligand in H2O, stirred for 12 h; filtered, washed with H2O, dried; elem. anal.;	90%

: sodium hexachlororhodate(III)

: 5810-42-4
Tetrapropylammonium chloride

: 66197-27-1
tetra(n-propyl)ammonium dicarbonyldichlororhodate(I)

Conditions

Conditions	Yield
With CO; HCl In hydrogenchloride stirring Rh-complex (in concd. HCl) under CO for 2 d, addn. of Pr4NCl (in CH2Cl2), shaking; sepn. of org. layer, drying (MgSO4), crystn. on Et2O addn.; elem. anal.;	90%

: 7719-09-7
thionyl chloride

: Nb6(14+)*14Cl(1-)*8H2O

: 5810-42-4
Tetrapropylammonium chloride

: [tetrapropylammonium]2[Nb6Cl18]

Conditions

Conditions	Yield
for 6h; Reflux;	90%

...Expand

: 5810-42-4
Tetrapropylammonium chloride

: 7722-84-1
dihydrogen peroxide

: ortho-tungstic acid

: 1447968-67-3
ClH2O6W(1-)*C12H28N(1+)

Conditions

Conditions	Yield
Stage #1: dihydrogen peroxide; ortho-tungstic acid In water at 31.84℃; for 0.5h; Stage #2: Tetrapropylammonium chloride With hydrogenchloride In water at -0.16℃; for 0.666667h;	88%

...Expand

: 5810-42-4
Tetrapropylammonium chloride

: 10025-91-9
antimony(III) chloride

: tetrapropylammonium tetrachloroantimonate(III)

Conditions

Conditions	Yield
In further solvent(s) solvent: 1.2-C2H4Cl2; dropwise addn. of SbCl3 soln. at room temp. with stirring; 1 h; filtration; crystn. from 1.2-C2H4Cl2 or EtOH; elem. anal.;	85%

: [Mo3S4Br3((2-aminoethyl)diphenylphosphine)3]Br

: 5810-42-4
Tetrapropylammonium chloride

: [W3S4Cl3((2-aminoethyl)diphenylphosphine)3]Br

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 1h; Inert atmosphere; Schlenk technique; Reflux;	82%

: 5810-42-4
Tetrapropylammonium chloride

: 2695-37-6
sodium 4-styrenesulfonate

: C8H7O3S(1-)*C12H28N(1+)

Conditions

Conditions	Yield
In dichloromethane; water	81%

: Re6Se5Cl8

: 5810-42-4
Tetrapropylammonium chloride

: N(CH2CH2CH3)4(1+)*Re6Se5Cl9(1-)={N(CH2CH2CH3)4}{Re6Se5Cl9}

Conditions

Conditions	Yield
In N,N-dimethyl-formamide (N2); mixture in DMF is heated at 60°C for 18 h; filtration, addn. of ether to the filtrate, after 3 d solid is washed (acetonitrile, ether), recrystn. (hot acetonitrile), elem. anal.;	80%

: W6Cl18

: 5810-42-4
Tetrapropylammonium chloride

: 2N(CH2CH2CH3)4(1+)*W6Cl18(2-)=(N(CH2CH2CH3)4)2W6Cl18

Conditions

Conditions	Yield
With methanol In methanol addn. of a soln. of ammonium salt in methanol to a soln. of W6Cl18 in methanol; sepn. of ppt.;	80%

: Re6Se6Cl6

: 5810-42-4
Tetrapropylammonium chloride

: 2N(CH2CH2CH3)4(1+)*Re6Se6Cl8(2-)={N(CH2CH2CH3)4}2{Re6Se6Cl8}

Conditions

Conditions	Yield
In acetonitrile (N2); mixture in acetonitrile is refluxed for 24 h; addn. of ether, solid is collected, recrystd. by ether diffusion into a soln. of DMF, after 5 d solid is collected, washed (ether), dried, elem. anal.;	78%

: sodium polyselenide

: 5810-42-4
Tetrapropylammonium chloride

: silver nitrate

: 2(CH3CH2CH2)4N(1+)*{Ag4(Se4)3}(2-) = {(CH3CH2CH2)4N}2{Ag4(Se4)3}

Conditions

Conditions	Yield
In N,N-dimethyl-formamide filtering, addn. of ether, elem. anal.;	75%

...Expand

: 1.5(CH3)2Sn(CH2)3Sn(CH3)2(2+)*Co(CN)6(3-)=[((CH3)2Sn(CH2)3Sn(CH3)2)1.5Co(CN)6]

: 5810-42-4
Tetrapropylammonium chloride

A: 129732-09-8
(CH3)3Sn(H2O)(1+)

: (C3H7)4N(1+)*((CH3)2Sn(H2O)(CH2)3Sn(CH3)2(H2O))Co(CN)6(1-)=[(C3H7)4N][((CH3)2Sn(H2O)(CH2)3Sn(CH3)2(H2O))Co(CN)6]

Conditions

Conditions	Yield
In water; acetonitrile (Me2Sn(CH2)3SnMe)1.5Co(CN)6 suspended in soln. of (n-Pr)4NCl in H2O (plus a few drops of MeCN; stirred for 24 h; filtered; washed (cold H2O); dried; elem. anal.;	A n/a B 75%

...Expand

: 33861-17-5
phenyl trimethylsilyl selenide

: 5810-42-4
Tetrapropylammonium chloride

: 10108-64-2
cadmium(II) chloride

: 2N(C3H7)4(1+)*Cd4(SeC6H5)6Cl4(2-)=(N(C3H7)4)2Cd4(SeC6H5)6Cl4

Conditions

Conditions	Yield
In dichloromethane CdCl2, N(nPr)4Cl were dissolved in CH2Cl2, ligand was added, stirred overnight, Et2O was added; elem. anal.;	70%

...Expand

: 5810-42-4
Tetrapropylammonium chloride

: 7440-66-6
zinc

: 73104-38-8
[(C3H7)4N](1+)*[C6H5ZnCl2](1-)=[(C3H7)4N][C6H5ZnCl2]

Conditions

Conditions	Yield
With C6H5Cl In acetonitrile; benzene Electrolysis; (N2); electrolysis of soln. of arylhalogenide and Pr4NBr in MeCN/benzene with Zn anode during 6 h; filtered soln. was pptd. by addn. of Et2O, ppt. washed with PE and dried; elem. anal.;	69%

: Re6Se4Cl10

: 5810-42-4
Tetrapropylammonium chloride

: 2N(CH2CH2CH3)4(1+)*Re6Se4O2Cl8(2-)={N(CH2CH2CH3)4}2{Re6Se4O2Cl8}

Conditions

Conditions	Yield
With H2O In N,N-dimethyl-formamide (N2); mixture in DMF containing water is heated at 60°C for 18 h; filtration, addn. of ether, obtained oil is washed (acetonitrile, ether), obtained powder is dissolved in DMF, ether is diffused for 7 d, crystals are washed (ether);	66%

: Re4Se4(TeCl2)4Cl8

: 5810-42-4
Tetrapropylammonium chloride

: 7732-18-5
water

: 75-05-8
acetonitrile

: [N(C3H7)4]2[Re4Se4(acetamido)2Cl8]

Conditions

Conditions	Yield
In acetonitrile reflux (1 h); filtration, concn. (in air, room temperature), dissolution (CH3CN), recrystn. (CH3CN/toluene), filtration, washing (MeOH and ether), drying; elem. anal.;	66%

...Expand

: 335-05-7
Trifluoromethanesulfonyl fluoride

: 5810-42-4
Tetrapropylammonium chloride

: 676-58-4
methylmagnesium chloride

: 227098-73-9
tetrapropylammonium tris(trifluoromethanesulfonyl)methide

Conditions

Conditions	Yield
Stage #1: Trifluoromethanesulfonyl fluoride; methylmagnesium chloride In tetrahydrofuran at 0 - 50℃; Inert atmosphere; Stage #2: Tetrapropylammonium chloride In tetrahydrofuran; water	62%

...Expand

: 110-89-4
piperidine

: 5810-42-4
Tetrapropylammonium chloride

: platinum(II) chloride

: 817163-84-1
piperidinium (2,7-dimethoxy-9H-fluoren-9-ylidine)methanedithioate

: [NPr4]2[Pt(2,7-dimethoxyfluoren-9-ylidene)methanedithiolato)2]

Conditions

Conditions	Yield
In dichloromethane byproducts: colloidal Pt, piperidinium chloride; room temp.; to a suspn. of PtCl2 in CH2Cl2 were added piperidine and ammonium-compound, the soln. was filtered through Celite, dithioate was added, the mixt. was stirred for 1 h; partially evapd., the solid was filtered off, washed with CH2Cl2 and methanol, vac.-dried; elem. anal.;	60%

...Expand

: 887280-12-8
3,5-bis(bis[(N'-isopropylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7646-79-9
cobalt(II) chloride

: [nPr4N]2[Co(II)2H4P(iPr)buam(μ-Cl)]

Conditions

Conditions	Yield
With potassium hydride In N,N-dimethyl acetamide byproducts: KCl; (under Ar); KH in N,N-dimethylacetamide added to ligand at room temp., CoCl2 added at room temp., (CH3CH2CH2)4NCl added;	60%

...Expand

: 887280-10-6
3,5-bis(bis[(N'-tert-butylureayl)-N-ethyl]aminomethyl)-1H-pyraze

: 5810-42-4
Tetrapropylammonium chloride

: 7646-79-9
cobalt(II) chloride

: [nPr4N]2[Co(II)2H4P(tBu)buam(μ-Cl)]

Conditions

Conditions	Yield
With potassium hydride In N,N-dimethyl acetamide byproducts: KCl; (under Ar); KH in N,N-dimethylacetamide added to ligand at room temp., CoCl2 added at room temp., (CH3CH2CH2)4NCl added;	60%

...Expand

: 12136-60-6
lithium selenide

: N(CH2CH2CH3)4(1+)*Re6Se5Cl9(1-)={N(CH2CH2CH3)4}{Re6Se5Cl9}

: 5810-42-4
Tetrapropylammonium chloride

: 2N(CH2CH2CH3)4(1+)*Re6Se6Cl8(2-)={N(CH2CH2CH3)4}2{Re6Se6Cl8}

Conditions

Conditions	Yield
In tetrahydrofuran (N2); mixture is stirred for 30 min; ppt. is collected, dissolved in DMF, slow diffusion of ether for 3 d, crystals are collected;	57%

...Expand

Tetrapropyl ammonium chloride Specification

The Tetrapropyl ammonium chloride, with the CAS registry number 5810-42-4 and EINECS registry number 227-375-5, has the systematic name of N,N,N-tripropylpropan-1-aminium chloride. And the molecular formula of this chemical is C₁₂H₂₈ClN. It is a kind of hygroscopic solid, and belongs to the following product categories: Quarternary ammonium salts; Ammonium Chlorides (Quaternary); Quaternary Ammonium Compounds; Ammonium Salts; Greener Alternatives: Catalysis; Phase Transfer Catalysts.

The physical properties of Tetrapropyl ammonium chloride are as following: (1)ACD/LogP: -2.64; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -2.64; (4)ACD/LogD (pH 7.4): -2.64; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 8; (12)Polar Surface Area: 0 Å².

You should be cautious while dealing with this chemical. It irritates eyes, respiratory system and skin. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [Cl-].C(C[N+](CCC)(CCC)CCC)C
(2)InChI: InChI=1/C12H28N.ClH/c1-5-9-13(10-6-2,11-7-3)12-8-4;/h5-12H2,1-4H3;1H/q+1;/p-1
(3)InChIKey: FBEVECUEMUUFKM-REWHXWOFAR

Product Name

Tetrapropyl ammonium chloride

Synthetic route

Tetrapropyl ammonium chloride Specification

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