Dayang Chem (Hangzhou) Co.,Ltd.
As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch
Cas:1314-85-8
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryAlity Chemical Corporation
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Chemwill Asia Co., Ltd.
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:1314-85-8
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryZibo Hangyu Biotechnology Development Co., Ltd
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:1314-85-8
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryZibo Dorne chemical technology co. LTD
Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,
Cas:1314-85-8
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Dingyan Chem Co., Ltd
R & D enterprises have their own stock in stock Package:1kg Application:pharmaceutical intermediates
Henan Tianfu Chemical Co., Ltd.
Our advantage:Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientif
Cas:1314-85-8
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryAntimex Chemical Limied
Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
Cas:1314-85-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHubei Langyou International Trading Co., Ltd
TIANFU-CHEM PHOSPHORUS SESQUISULFIDE Application:TIANFU-CHEM PHOSPHORUS SESQUISULFIDE
Wuhan ZeShanCheng Biomedical Technology Co., Ltd.
1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl
Hunan Longxianng Runhui Trading Co.,Ltd
TIANFU-CHEM PHOSPHORUS SESQUISULFIDEAppearance:white powder Storage:room temperature Package:200KG Application:Industrial Grade Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LC
Cas:1314-85-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryShanghai united Scientific Co.,Ltd.
United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
Cas:1314-85-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryShanghai Run-Biotech Co., Ltd.
Shanghai, Run-Biotech Co., Ltd is a leading domestic pharmaceutical, biopharmaceutical, and health care products R & D outsourcing services company. As an innovation-driven and customer-focused company, Run Biotech provides a broad and integrated por
Hebei mingxing biotech co.,ltd
Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:yellow to white solid or po
Nanjing Raymon Biotech Co., Ltd.
Phosphorus sesquisulfideAppearance:Pls see the Details Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Po
Hebei Minshang Biotechnology Co., Ltd
TIANFU-CHEM PHOSPHORUS SESQUISULFIDE Application:Industrial Grade
Synova( Tianjin ) Chemical Technology Co,.Ltd
The company have effective management team, professional technical R & D personnel, the service spirit of customer oriented. We have long-term cooperation with famous domestic manufacturer, and excellent customer resources overseas. We are skilled in
Cas:1314-85-8
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryHangzhou Fenjun Chemical Co Ltd.
TIANFU-CHEM PHOSPHORUS SESQUISULFIDE Application:TIANFU-CHEM PHOSPHORUS SESQUISULFIDE
Cas:1314-85-8
Min.Order:0
Negotiable
Type:Trading Company
inquiryHebei Ruishun Trade Co.,Ltd
Supply top quality products with a reasonable price Application:api
Chemical Co.Ltd
Manufacturer,strong R&D,professional team Storage:Store in a cool, dry place. Store in a tightly closed container. Package:according to your requirement Application:ZhiShang Chemical is owned by ZhiShang Group, is a professional new-type chemicals en
Synthetic route
-
-
7704-34-9
sulfur
-
A
-
1314-85-8
phosphorus sulfide
-
-
131105-01-6
phosphorus sulfide
-
-
39350-99-7
tetraphosphorus tetrasulphide
-
E
-
12037-82-0
phosphorus sulfide
| Conditions | Yield |
|---|---|
| In melt vac., 10-100 mol% S, heating (1 week, 673 K); extraction (CS2), filtn.; followed by (31)P NMR; |
-
-
7704-34-9
sulfur
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
131105-01-6
phosphorous trisulfide
-
E
-
12037-82-0
phosphorus sulfide
| Conditions | Yield |
|---|---|
| In melt vac.,; 54 mol% S, heating (573-873 K), standing (5 weeks, room temp.); extraction (CS2), filtn.; followed by (31)P NMR; | |
| In melt vac.,; 54 mol% S, heating (573-873 K); extraction (CS2), filtn.; followed by (31)P NMR; |
-
-
7704-34-9
sulfur
-
A
-
15857-57-5
tetraphosphorus decasulfide
-
B
-
1314-85-8
phosphorus sulfide
-
C
-
12037-82-0
phosphorus sulfide
-
-
7719-09-7
thionyl chloride
-
-
7803-51-2
phosphan
-
A
-
7647-01-0
hydrogenchloride
-
B
-
3982-91-0
trichlorothiophosphine
-
D
-
1314-85-8
phosphorus sulfide
-
E
-
10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate
| Conditions | Yield |
|---|---|
| In neat (no solvent) room temp.;; further unidentified liquid products;; |
-
-
7719-09-7
thionyl chloride
-
-
7803-51-2
phosphan
-
A
-
7647-01-0
hydrogenchloride
-
C
-
1314-85-8
phosphorus sulfide
-
D
-
10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate
-
-
7783-06-4
hydrogen sulfide
-
-
7719-12-2, 52843-90-0
phosphorus trichloride
-
-
1314-85-8
phosphorus sulfide
| Conditions | Yield |
|---|---|
| With 2-methylpyridine In not given byproducts: CH3C5H4NH(PS2Cl2), CH3C5H4NH(Cl); |
-
-
7791-25-5
sulfuryl dichloride
-
-
7803-51-2
phosphan
-
A
-
7647-01-0
hydrogenchloride
-
C
-
1314-85-8
phosphorus sulfide
-
D
-
10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate
| Conditions | Yield |
|---|---|
| With sulfur with pured and dried PH3 in vacuum; at 450°C; equilibrium reaction 3-4.5 mol S for two mol PH3; | |
| With S with pured and dried PH3 in vacuum; at 450°C; equilibrium reaction 3-4.5 mol S for two mol PH3; |
| Conditions | Yield |
|---|---|
| With sulfuryl dichloride In neat (no solvent) react. of SO2Cl2 with dry PH3; formation of HCl, P4S3, red P, POCl3 and P2O3;; | |
| With thionyl chloride In neat (no solvent) react. of SOCl2 with dry PH3; formation of HCl, P4S3 and red P;; |
-
-
7791-27-7
pyrosulfuryl chloride
-
A
-
7647-01-0
hydrogenchloride
-
B
-
7790-94-5
chlorosulfonic acid
-
D
-
1314-85-8
phosphorus sulfide
-
E
-
7446-09-5
sulfur dioxide
| Conditions | Yield |
|---|---|
| With hydrogen phosphide In neat (no solvent) 10°C;; |
| Conditions | Yield |
|---|---|
| In not given byproducts: HCl, SO2; |
-
A
-
15857-57-5
tetraphosphorus decasulfide
-
B
-
1314-85-8
phosphorus sulfide
-
C
-
12037-82-0
phosphorus sulfide
-
D
-
25070-46-6
tetraphosphorus nonasulfide
-
E
-
7704-34-9
sulfur
| Conditions | Yield |
|---|---|
| In neat (no solvent) heating (dehydration at 500-550°C, 13-130 Pa, 10 min, open quartz ampoule), sealing of ampoule and heating again (1000-1050°C); mixt. of products not sepd.; (31)P-NMR spectroscopy; |
| Conditions | Yield |
|---|---|
| In melt melting together P and S in a glycerine bath at 170°C;; recrystn. from CS2;; | |
| With phosphoric acid In melt formation from P and S in the melt, with less than 1% H3PO4; stirring in a cast iron vessel;; distn. first at atm. pressure, then in vac.;; | |
| In neat (no solvent) continuous prepn. by heating P and S at 313-318°C under CO2-atmosphere;; |
| Conditions | Yield |
|---|---|
| In melt stoich. amts. of reagents are reacted in a quartz tube under vac.; recrystn. from CS2; |
-
-
7719-09-7
thionyl chloride
-
-
7803-51-2
phosphan
-
A
-
3982-91-0
trichlorothiophosphine
-
B
-
1314-85-8
phosphorus sulfide
-
C
-
7446-09-5
sulfur dioxide
-
D
-
10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate
| Conditions | Yield |
|---|---|
| In not given react. of SOCl2 with PH3;; | |
| In not given react. of SOCl2 with PH3;; |
| Conditions | Yield |
|---|---|
| In not given react. of PH3 with SOCl2 at ambient temp.;; |
| Conditions | Yield |
|---|---|
| In not given | |
| In neat (no solvent) heating P4 with S at 165°C;; extraction with CS2 or PCl3;; | |
| In further solvent(s) slow addn. of a soln. of S in αchloronaphthalene heated to 150°C to a boiling soln. of P4 in αchloronaphthalene under CO2-atmosphere; boiling for 1 h;; filtn. and washing with CCl4;; |
-
-
12185-10-3
phosphorus
-
-
7704-34-9
sulfur
-
A
-
15857-57-5
tetraphosphorus decasulfide
-
B
-
1314-85-8
phosphorus sulfide
-
-
37295-14-0
P4S8, I
-
D
-
12037-82-0
phosphorus sulfide
-
E
-
25070-46-6
tetraphosphorus nonasulfide
| Conditions | Yield |
|---|---|
| In carbon disulfide vac.; several months, room temp., light; followed by (31)P NMR; |
-
-
12185-10-3
phosphorus
-
-
7704-34-9
sulfur
-
A
-
1314-85-8
phosphorus sulfide
-
-
169833-95-8
P4S8, II
-
-
169833-94-7
P4S7, III
| Conditions | Yield |
|---|---|
| In carbon disulfide vac.; several months, room temp., light; followed by (31)P NMR; |
-
-
12185-10-3
phosphorus
-
-
7704-34-9
sulfur
-
A
-
15857-57-5
tetraphosphorus decasulfide
-
B
-
1314-85-8
phosphorus sulfide
-
C
-
12037-82-0
phosphorus sulfide
-
D
-
25070-46-6
tetraphosphorus nonasulfide
| Conditions | Yield |
|---|---|
| In melt vac.; 15-79 mol% S, heating (363 K, 10-30 d); extraction (CS2), fitln., followed by (31)P NMR; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) byproducts: P, H2S; react. of PH3 with S above 320°C (ratio: 2:3);; |
| Conditions | Yield |
|---|---|
| In neat (no solvent) heating red P with powdered S at 100°C under CO2 atmosphere or in a evacuated react.-tube;; distn. by further heating; extraction with CS2; distn. under CO2-atmosphere;; | |
| iodine In not given formation from red P and S with I2 as catalyst;; | |
| In neat (no solvent) formation from red P and S at 250-330°C in a stream of CO2;; |
-
-
15578-54-8
tetraphosphorus pentasulphide
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
12037-82-0
phosphorus sulfide
| Conditions | Yield |
|---|---|
| In neat (no solvent) reversible react. at higher temp.;; | |
| In not given formation from P4S5 at higher temp.;; |
-
-
15578-54-8
tetraphosphorus pentasulphide
-
-
3937-40-4
triphenyl arsine sulfide
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
12037-82-0
phosphorus sulfide
-
C
-
189556-96-5
γ-P4S6
-
D
-
169833-95-8
β-P4S8
-
E
-
189556-95-4
α-P4S6
| Conditions | Yield |
|---|---|
| In carbon disulfide absence of air and moisture; molar ratio P4S5:Ph3AsS=1:1, stirring for 2h; product mixt. not sepd., detd by (31)P-NMR spectroscopy; |
-
-
15578-54-8
tetraphosphorus pentasulphide
-
-
3937-40-4
triphenyl arsine sulfide
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
12037-82-0
phosphorus sulfide
-
C
-
189556-96-5
γ-P4S6
-
D
-
189556-95-4
α-P4S6
| Conditions | Yield |
|---|---|
| In carbon disulfide absence of air and moisture; molar ratio P4S5:Ph3AsS=0.2-1:1, stirring for 2 h; product mixt. not sepd., detd by (31)P-NMR spectroscopy; product ratio depending on educt ratio; |
-
-
15578-54-8
tetraphosphorus pentasulphide
-
-
3937-40-4
triphenyl arsine sulfide
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
12037-82-0
phosphorus sulfide
-
C
-
25070-46-6
tetraphosphorus nonasulfide
-
D
-
169833-95-8
β-P4S8
-
E
-
189556-95-4
α-P4S6
| Conditions | Yield |
|---|---|
| In carbon disulfide absence of air and moisture; molar ratio P4S5:Ph3AsS=2:1, stirring for 2h; product mixt. not sepd., detd by (31)P-NMR spectroscopy; |
-
-
7783-06-4
hydrogen sulfide
-
-
2001-45-8
tetraphenyl phosphonium chloride
-
-
7719-12-2, 52843-90-0
phosphorus trichloride
-
A
-
1314-85-8
phosphorus sulfide
| Conditions | Yield |
|---|---|
| With α-picoline In further solvent(s) byproducts: (HNC6H8)Cl; passing dry H2S in a soln. of PCl3 in 2-methylpyridine, exotherm react., cooling of mixture in H2O-bath to 20-30°C, yellow ppt.; condensation of excess 2-methylpyridine, elution of residue with CS2 (twice), isolation of P4S3 by sepn. of solvent from eluate, washing with CH2Cl2, drying in vac.; dissoln. of solid residue in CH3CN and isolation as Ph4P-salt; elem. anal.; |
-
-
7783-06-4
hydrogen sulfide
-
-
7719-12-2, 52843-90-0
phosphorus trichloride
-
A
-
1314-85-8
phosphorus sulfide
-
-
131105-01-6
phosphorus sulfide
-
C
-
12037-82-0
phosphorus sulfide
-
-
15578-54-8
tetraphosphorus pentasulphide
| Conditions | Yield |
|---|---|
| With NaY zeolite vac. line; P-compd. condensation into zeolite, H2S condensation into PCl3/zeolite at liq. N2 temp. (ratio P:S=4:10), mixt. sealing, heating at 164°C; |
-
-
7783-06-4
hydrogen sulfide
-
-
7719-12-2, 52843-90-0
phosphorus trichloride
-
A
-
1314-85-8
phosphorus sulfide
-
-
131105-01-6
phosphorus sulfide
-
-
15578-54-8
tetraphosphorus pentasulphide
| Conditions | Yield |
|---|---|
| With NaY zeolite vac. line; P-compd. condensation into zeolite, H2S condensation into PCl3/zeolite at liq. N2 temp. (ratio P:S=4:3 or 4:5), mixt. sealing, heating at 100°C; |
-
-
7783-06-4
hydrogen sulfide
-
-
7719-12-2, 52843-90-0
phosphorus trichloride
-
A
-
1314-85-8
phosphorus sulfide
-
B
-
12037-82-0
phosphorus sulfide
| Conditions | Yield |
|---|---|
| With NaY zeolite vac. line; P-compd. condensation into zeolite, H2S condensation into PCl3/zeolite at liq. N2 temp. (ratio P:S=4:5), mixt. sealing, heating at 100°C; |
| Conditions | Yield |
|---|---|
| In carbon disulfide; dichloromethane Ag(CH2Cl2)Al(pftb)4 and P4S3 in CS2-CH2Cl2 were stirred overnight at room temp.; suspn. was filtered, filtrate was concd. and stored at 0°C; elem.anal.; | 90% |
| Conditions | Yield |
|---|---|
| In carbon disulfide (N2); P4S3 in CS2 was added to soln. of BBr3 in CS2 at room temp.; cooled to -78°C; filtered; dried in vac. at room temp.; | 88% |
-
-
1314-85-8
phosphorus sulfide
-
-
222402-52-0
[Re(1,1,1-tris(diphenylphosphanylmethyl)ethane)(CO)2]triflate
| Conditions | Yield |
|---|---|
| In dichloromethane CH2Cl2 soln. of Re-complex was brought to reflux, soln. of P4S3 in CH2Cl2 was added for 20 min, refluxed for 30 min under stirring; concd. under vac., hexane was added, filtered under N2, washed with light petroleum ether, dried under N2; | 81% |
-
-
1314-85-8
phosphorus sulfide
-
-
13517-10-7
boron triiodide
-
-
366837-13-0
tetraphosphorus trisulfide boron triiodide
| Conditions | Yield |
|---|---|
| In carbon disulfide (N2); P4S3 (1 equiv.) in CS2 was added to soln. of BI3 (1 equiv.) in CS2at room temp.; suspn. was stirred for 15 min; filtered; washed (CS2); dried in vac. at room temp.; | 81% |
| Conditions | Yield |
|---|---|
| In toluene; acetonitrile under N2, by Schlenk technique; CuBr soln. in MeCN layered over P4S3 in toluene for 7 d; washed with CH2Cl2/CH3CN; dried in vac.; detd. by XRD and MAS NMR; elem.anal.; | 80% |
-
-
1314-85-8
phosphorus sulfide
-
-
7787-70-4
copper(I) bromide
-
-
554-70-1
triethylphosphine
-
-
1339034-68-2
CuBr(P4S3)(PEt3)2
| Conditions | Yield |
|---|---|
| In toluene; acetonitrile N2; Cu compd. and phosphane in MeCN added to toluene soln. of P4S3 (0.454:1.135:0.454 molar ratio), stirred for 12 h at room temp.; evapd., dissolved (toluene), crystd. (-20°C), elem. anal.; | 80% |
| Conditions | Yield |
|---|---|
| In toluene; acetonitrile N2; Cu compd. and phosphane in MeCN added to toluene soln. of P4S3 (0.454:1.135:0.454 molar ratio), stirred for 12 h at room temp.; evapd., dissolved (toluene), crystd. (-20°C), elem. anal.; | 80% |
-
-
7681-65-4
copper(l) iodide
-
-
1314-85-8
phosphorus sulfide
-
-
554-70-1
triethylphosphine
-
-
1339034-71-7
CuI(P4S3)(PEt3)2
| Conditions | Yield |
|---|---|
| In toluene; acetonitrile N2; Cu compd. and phosphane in MeCN added to toluene soln. of P4S3 (0.454:1.135:0.454 molar ratio), stirred for 12 h at room temp.; evapd., dissolved (toluene), crystd. (-20°C), elem. anal.; | 80% |
-
-
1314-85-8
phosphorus sulfide
-
-
36477-75-5
tungsten pentacarbonyl tetrahydrofuran
-
-
1236232-10-2
W(CO)5(P4S3)
| Conditions | Yield |
|---|---|
| In tetrahydrofuran under N2 by Schlenk technique; P4S3 added to soln. of W(CO)5(THF) (1.36:2.045 mol) in THF; stirred at room temp. for 20 h; evapd.; product washed (toluene, 3 times); elem. anal.; | 78% |
| Conditions | Yield |
|---|---|
| In carbon disulfide AgAl(hfip)4 and P4S3 in CS2 were stirred overnight at room temp.; suspn. was filtered, filtrate was concd. and stored at -30°C; elem. anal.; | 77% |
-
-
1314-85-8
phosphorus sulfide
-
-
143-66-8
sodium tetraphenyl borate
-
-
497846-12-5, 497846-20-5
(η5-pentamethylcyclopentadienyl)ruthenium(II)[(1-diphenylarsanyl-2-diphenylphosphanyl)ethylene](η1-tetraphosphorus trisulfide) tetraphenylborate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: Cl(-); (Ar), Ru complex in THF added to P4S3 in THF, treated with NaBPh4, stirred at room temp. for 2 h; slowly dissolved in ethanol/light petroleum 1:1, crystd., elem. anal.; | 70% |
-
-
1314-85-8
phosphorus sulfide
-
-
154828-19-0
(η5-pentamethylcyclopentadienyl)ruthenium(II)chloro[cis-1,2-bis(diphenylphosphanyl)ethylene]
-
-
143-66-8
sodium tetraphenyl borate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: Cl(-); (Ar), Ru complex in THF added to P4S3 in THF, treated with NaBPh4, stirred at room temp. for 2 h; slowly dissolved in ethanol/light petroleum 1:1, crystd., elem. anal.; | 68% |
-
-
1314-85-8
phosphorus sulfide
-
B
-
36495-37-1
cyclopentadienylchromiumtricarbonyl hydride
| Conditions | Yield |
|---|---|
| In toluene N2 or Ar-atmosphere; stirring (room temp., 13 d); filtering, chromy. (SiO2, n-hexane, n-hexane / toluene = 1 : 2, n-hexane), crystn. on concg. (-28°C), recrystn. (THF / hexane, -30°C, several d); elem. anal.; | A 66% B 19% C 2% D 12.7% |
-
-
1314-85-8
phosphorus sulfide
| Conditions | Yield |
|---|---|
| In toluene 13 d at room temp.; chromy. (silica gel, toluene/hexane 7:3); | A 8% B 66% |
-
-
1314-85-8
phosphorus sulfide
-
-
143-66-8
sodium tetraphenyl borate
-
-
497846-08-9, 497846-16-9
(η5-pentamethylcyclopentadienyl)ruthenium(II)[bis(diphenylphosphanyl)methane](η1-tetraphosphorus trisulfide) tetraphenylborate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: Cl(-); (Ar), Ru complex in THF added to P4S3 in THF, treated with NaBPh4, stirred at room temp. for 2 h; slowly dissolved in ethanol/light petroleum 1:1, crystd., elem. anal.; | 65% |
-
-
1314-85-8
phosphorus sulfide
-
-
143-66-8
sodium tetraphenyl borate
-
-
497846-06-7, 497846-14-7
(η5-pentamethylcyclopentadienyl)ruthenium(II)[bis(diphenylphosphanyl)ethane](η1-tetraphosphorus trisulfide) tetraphenylborate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran byproducts: Cl(-); (Ar), Ru complex in THF added to P4S3 in THF, treated with NaBPh4, stirred at room temp. for 2 h; slowly dissolved in ethanol/light petroleum 1:1, crystd., elem. anal.; | 65% |
-
-
1314-85-8
phosphorus sulfide
-
-
32843-51-9
[CpFeCl(dppe)]
-
-
2923-28-6
silver trifluoromethanesulfonate
-
-
1221971-68-1
[(η5-C5H5)Fe(1,2-(diphenylphosphino)ethane)(η1-P(basal)-tetraphosphorus trisulfide)] triflate
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; dichloromethane (N2); slurry of Fe compd., AgOTf and P4S3 in CH2Cl2/THF stirred for 4 h; mixt. filtered, filtrate evapd. under vac., residue washed with toluene and n-hexane, dried; elem. anal.; | 60% |
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; dichloromethane (N2); slurry of Fe compd., AgOTf, and P4S3 in CH2Cl2/THF stirred for 4 h; mixt. filtered, filtrate evapd. under vac., residue washed with toluene and n-hexane, dried; elem. anal.; | 60% |
-
-
1314-85-8
phosphorus sulfide
| Conditions | Yield |
|---|---|
| With isoprene In toluene N2 or Ar-atmosphere; stirring (room temp., 9 d); filtering, concg., chromy. (SiO2, n-hexane, n-hexane / toluene = 9 : 1, 8 : 2, 7 : 3, 1 : 1, toluene, ether), evapn.; | A 58.9% B 2.5% C 5.3% D 4.4% |
-
-
1314-85-8
phosphorus sulfide
-
-
91043-03-7
(Cr(η5-C5H5)(CO)2)2Se
-
B
-
36495-37-1
cyclopentadienylchromiumtricarbonyl hydride
| Conditions | Yield |
|---|---|
| In toluene N2-atmosphere; stirring (room temp., 6 d), filtering; chromy. (SiO2, n-hexane / toluene); | A 6.4% B 5% C 51.5% D 1% E 15.5% |
-
-
1314-85-8
phosphorus sulfide
-
-
428441-32-1
silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate
| Conditions | Yield |
|---|---|
| Stage #1: phosphorus sulfide; silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate In dichloromethane at 20℃; Inert atmosphere; Stage #2: dicarbonylcyclopentadienylbromoiron(II) In dichloromethane for 32h; Inert atmosphere; | 50% |
-
-
1314-85-8
phosphorus sulfide
-
-
22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]
| Conditions | Yield |
|---|---|
| With ethanol In tetrahydrofuran; ethanol; benzene under N2, solm. of P4S3 in benzene added to soln. obtained by mixing Nisalt in ethanol and triphos in THF, refluxed for 2 h; concd. under N2, crystals filtered off, dried in vac., recrystd. from acetone and ethanol; elem. anal.; | 45% |
-
-
10544-50-0
sulfur
-
-
1314-85-8
phosphorus sulfide
| Conditions | Yield |
|---|---|
| In water P4S3 was added to an aq. soln. of Na2S*9H2O and S8 under stirring (temp. increase to about 50°C); the soln. was heated at 80 °C for 45 min and H2O added; after cooling to room temp. pptn. by addn. of ethanol;; isolation of S2O6(4-): recrystn. of the ppt. from a small amt. of hot H2O; isolation of S3P7O(5-) from filtrate: addn. of EtOH, stirring for 15-20 min, decantation, repeated pptn. from aq. Ca(Ac)2/NH4NO3 soln. with EtOH; elem. anal.;; | A 40% B n/a |
-
-
12092-47-6
di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium
-
-
1314-85-8
phosphorus sulfide
-
-
22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]
-
-
87890-72-0
{(triphos)Rh(P3S3)}*C6H6
| Conditions | Yield |
|---|---|
| In tetrahydrofuran; butan-1-ol; benzene N2-atmosphere; refluxing (5 h); concn. of hot soln. (crystn.); | 35% |
| In not given | |
| In tetrahydrofuran; benzene P4S3 (2 mmol) in benzene (50 ml) was added to a mixture of triphos (2 mmol) in THF (20 ml) and {RhCl(cod)}2 (1 mmol) in THF (50 ml) under nitrogen, reflux for 1 h, addition of 40 ml warm 1-butanol; filtration, refluxing filtrate overnight;; crystals washed with ethanol and light petroleum (bp 40-70 ° C), recrystn. from benzene and CH2Cl2, elem. anal.;; | 35-40 |
-
-
1314-85-8
phosphorus sulfide
-
-
12037-82-0
phosphorus sulfide
| Conditions | Yield |
|---|---|
| With I2 In carbon disulfide byproducts: PI3; react. of iodine in CS2 with P4S3;; | 34% |
| With iodine In not given byproducts: PI3; react. of P4S3 with iodine;; | |
| With I2 In not given byproducts: PI3; react. of P4S3 with iodine;; | |
| With S In not given |
-
-
1314-85-8
phosphorus sulfide
-
A
-
36495-37-1
cyclopentadienylchromiumtricarbonyl hydride
| Conditions | Yield |
|---|---|
| In toluene N2 or Ar-atmosphere; stirring (room temp., 24 h, 60°C, 18 h); filtering, concg., chromy. (SiO2, n-hexane / toluene = 4 : 1, 3 : 1, 1 :1, toluene / ether = 1 : 1), evapn.; | A 34% B 14% C 10% D 30% |
-
-
1314-85-8
phosphorus sulfide
-
-
428441-32-1
silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate
| Conditions | Yield |
|---|---|
| Stage #1: phosphorus sulfide; silver tetrakis([2,2,2-trifluoro-1,1-bis(trifluoromethyl)ethyl]oxy)aluminate In dichloromethane at 20℃; Inert atmosphere; Stage #2: (η5-C5H5)Fe(CO)PPh3Br In dichloromethane for 28h; Inert atmosphere; | 34% |
-
-
15684-35-2
cobalt(II) tetrafluoroborate hexahydrate
-
-
1314-85-8
phosphorus sulfide
-
-
22031-12-5
[2-((diphenylphospino)methyl)-2-methyl-1,3-propanediyl]bis[diphenylphosphine]
| Conditions | Yield |
|---|---|
| With benzene In tetrahydrofuran; ethanol; benzene P4S3 dissolved in benzene was added to soln. of Co(BF4)2*6H2O in EtOH and ligand in THF, soln. was refluxed under N2 for 1 h; concd. under N2; | 30% |
| With benzene In ethanol; benzene under N2 atm. warm soln. P4S3 in benzene added to soln. Co(BF4)2*6H2O in ethanol and toome in benzene, soln. refluxed overnight; ethanol added, soln. concd., complex collected, washed with ethanol-benzene (1:1) and light petroleum (b.p. 40-70°C) and dried, recrystd. from CH2Cl2 and benzene; elem. anal.; |
| Conditions | Yield |
|---|---|
| In toluene Inert atmosphere; Schlenk technique; Glovebox; Reflux; | 30% |
-
-
1314-85-8
phosphorus sulfide
-
B
-
36495-37-1
cyclopentadienylchromiumtricarbonyl hydride
| Conditions | Yield |
|---|---|
| In toluene N2 or Ar-atmosphere; stirring (60°C, 3 d); filtering, concg., chromy. (SiO2, n-hexane, n-hexane / toluene = 9 : 1, 8 : 2, 7 : 3, 1 : 1, toluene, ether), evapn.; | A 22.2% B 3% C 1% D 0.4% E 6.8% |
Related products
Hot Products
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View