CAS No.3982-91-0,Thiophosphoryl chloride Suppliers,MSDS download

: 7704-34-9
sulfur

: 7719-12-2, 52843-90-0
phosphorus trichloride

: 3982-91-0
trichlorothiophosphine

Conditions

Conditions	Yield
With disulfur dichloride; iron(III) chloride In neat (no solvent) addn. of a mixt. of 140 g PCl3 and 1.7 g S2Cl2 drop by drop to a hot mixt. of 160 g PSCl3, 2 g anhydrous FeCl3 and 38 g S on stirring and refluxing (4.5 h); refluxing for 1 h, distg. off PSCl3;;	100%
In neat (no solvent) react. molten S with PCl3 at 124-126 °C at ambient pressure; use of a catalyst formed on melting S with active carbon and boiling in PSCl3 at 200 °C;;
disulfur dichloride In not given react. with S2Cl2 as catalyst;;

: barium sulfide

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: phosphorous (V) sulfide

C: barium(II) chloride

Conditions

Conditions	Yield
In neat (no solvent) react. on heating under blazing up;;

...Expand

: calcium(II) sulfide

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: phosphorous (V) sulfide

C: calcium chloride

Conditions

Conditions	Yield
In neat (no solvent) react. on heating under blazing up;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: mercury sulfide

A: 3982-91-0
trichlorothiophosphine

B: phosphorous (V) sulfide

C: mercury dichloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: thiosulfate; react. on heating;;

...Expand

: 7719-09-7
thionyl chloride

: phosphorus

A: 10025-67-9
disulfur dichloride

B: 3982-91-0
trichlorothiophosphine

C: 10026-13-8, 874483-75-7
phosphorus pentachloride

D: 7446-09-5
sulfur dioxide

E: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
In neat (no solvent) excess of SOCl2; 180°C;;
In neat (no solvent) excess of SOCl2; 180°C;;

...Expand

: 7446-09-5
sulfur dioxide

: 7719-12-2, 52843-90-0
phosphorus trichloride

A: 3982-91-0
trichlorothiophosphine

B: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent) byproducts: POCl3; decompn. of SO2- and PCl3-vapours in a calcinating tube;; formation of POCl3, PSCl3 and a small amount of S;;
In neat (no solvent) byproducts: POCl3; decompn. of SO2- and PCl3-vapours in a calcinating tube;; formation of POCl3, PSCl3 and a small amount of S;;

...Expand

: 7446-09-5
sulfur dioxide

: 7719-12-2, 52843-90-0
phosphorus trichloride

A: 3982-91-0
trichlorothiophosphine

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
tetramethyl ammonium-pyrosulfite 50°C;
phosphorus tribromide 50°C;
phosphorus(V) oxybromide 50°C;

...Expand

: 10025-67-9
disulfur dichloride

: tricalcium diphosphate

A: 3982-91-0
trichlorothiophosphine

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

C: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
With silica gel In neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 % phosphate are caused to react.;;
In neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 % phosphate are caused to react.;;
In neat (no solvent) react. of Ca3(PO4)2 with S2Cl2 at 1000 °C;; after 1 h 19.5 % phosphate are caused to react.;;
With SiO2 In neat (no solvent) byproducts: SiCl4; react. of Ca3(PO4)2 with S2Cl2 at 1000 °C in presence of SiO2;; after 1 h 9.5 % phosphate are caused to react.;;

...Expand

: 10025-67-9
disulfur dichloride

: phosphorus

A: 3982-91-0
trichlorothiophosphine

B: 7704-34-9
sulfur

C: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
In neat (no solvent) addn. of P (excess) to boiling S2Cl2;;

...Expand

: 10025-67-9
disulfur dichloride

: phosphorus

A: 3982-91-0
trichlorothiophosphine

B: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent) addn. of P to boiling S2Cl2;;
In neat (no solvent) react. at boiling temp.;;
With Fe or Al In neat (no solvent) heating P with S2Cl2 in presence of Fe or Al;;
In neat (no solvent) heating P with S2Cl2;;

...Expand

: 7719-09-7
thionyl chloride

: 7719-12-2, 52843-90-0
phosphorus trichloride

A: 3982-91-0
trichlorothiophosphine

B: 10026-13-8, 874483-75-7
phosphorus pentachloride

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent) slowly at 80-160°C;; POCl3 only supposed;;

...Expand

: 7719-09-7
thionyl chloride

: 7803-51-2
phosphan

A: 7647-01-0
hydrogenchloride

B: 3982-91-0
trichlorothiophosphine

C: phosphorus

D: 1314-85-8
phosphorus sulfide

E: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent) room temp.;; further unidentified liquid products;;

...Expand

: 7719-09-7
thionyl chloride

: phosphorous (V) sulfide

A: 10025-67-9
disulfur dichloride

B: 3982-91-0
trichlorothiophosphine

C: 7446-09-5
sulfur dioxide

D: phosphorus pentoxide

E: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent) 100-150°C;;	A 0% B n/a C n/a D 0% E n/a
In neat (no solvent) 100-150°C;;	A 0% B n/a C n/a D 0% E n/a

...Expand

: 7719-09-7
thionyl chloride

: phosphorous (V) sulfide

A: 10025-67-9
disulfur dichloride

B: 3982-91-0
trichlorothiophosphine

C: 7446-09-5
sulfur dioxide

D: 7704-34-9
sulfur

Conditions

Conditions	Yield
In neat (no solvent) 100-150°C;;	A 0% B n/a C n/a D n/a

...Expand

: 7719-09-7
thionyl chloride

: phosphorous

A: 10025-67-9
disulfur dichloride

B: 3982-91-0
trichlorothiophosphine

C: 10026-13-8, 874483-75-7
phosphorus pentachloride

D: 7446-09-5
sulfur dioxide

E: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
In neat (no solvent) excess of SOCl2; 180°C;;
In neat (no solvent) excess of SOCl2; 180°C;;

...Expand

: 7719-12-2, 52843-90-0
phosphorus trichloride

: 3982-91-0
trichlorothiophosphine

Conditions

Conditions	Yield
With sulfur at 76°C, in common pressure;	0%
With sulfur; barium sulfide in autoclave at 150°C for 4-5 h;	>99
With sulfur; calcium(II) sulfide in autoclave at 150°C for 4-5 h;	>99

: 10025-67-9
disulfur dichloride

: 7719-12-2, 52843-90-0
phosphorus trichloride

A: 3982-91-0
trichlorothiophosphine

B: 10026-13-8, 874483-75-7
phosphorus pentachloride

Conditions

Conditions	Yield
In neat (no solvent) 6h, 160°C;;	A >99 B >99
In neat (no solvent) 6h, 160°C;;	A >99 B >99

...Expand

: 7791-25-5
sulfuryl dichloride

: 7719-12-2, 52843-90-0
phosphorus trichloride

A: 3982-91-0
trichlorothiophosphine

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent) simultaneous formation of POCl3 and PSCl3 via reaction of PCl3 with SO2Cl2;; isolation via fractionation;;
In not given react. with SO2Cl2;; fractional distn.;;
In not given react. with SO2Cl2;; fractional distn.;;

...Expand

: 10025-67-9
disulfur dichloride

: calcium metaphosphate

A: 3982-91-0
trichlorothiophosphine

B: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

C: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
With silica gel In neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;
With SiO2 In neat (no solvent) byproducts: SiCl4; react. of Ca(PO3)2 with S2Cl2 at 1000 °C in presence of SiO2;;

...Expand

: 10025-67-9
disulfur dichloride

: 12440-00-5
phosphorus(III) oxide

A: 3982-91-0
trichlorothiophosphine

B: 7446-09-5
sulfur dioxide

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: S; vigorous reaction;;

...Expand

: 10025-67-9
disulfur dichloride

: phosphorous

A: 3982-91-0
trichlorothiophosphine

B: 7704-34-9
sulfur

C: 7719-12-2, 52843-90-0
phosphorus trichloride

Conditions

Conditions	Yield
In neat (no solvent) in coldness under inflammation;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 333-20-0
potassium thioacyanate

A: 10025-67-9
disulfur dichloride

B: 3982-91-0
trichlorothiophosphine

C: potassium chloride

D: 506-77-4
cyanogen chloride

Conditions

Conditions	Yield
In neat (no solvent) haeting at lower temp.; formation of CNCl, PSCl3, KCl and a small amount of S2Cl2;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 333-20-0
potassium thioacyanate

A: 3982-91-0
trichlorothiophosphine

B: potassium chloride

C: 506-77-4
cyanogen chloride

Conditions

Conditions	Yield
heating;
heating;

...Expand

: lead(II) thiosulfate

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: 7719-09-7
thionyl chloride

C: lead(II) chloride

D: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In neat (no solvent) heating PbS2O3 (dryed at 400 °C) with a reflux condenser; react. starting without heating, react. accelerated on heating; formation of POCl3, SOCl2, PSCl3 and PbCl2 as residue;;

...Expand

: phosphorous (V) sulfide

: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

A: 3982-91-0
trichlorothiophosphine

B: 86119-84-8, 7664-38-2
phosphoric acid

Conditions

Conditions	Yield
In neat (no solvent) react. with P2S5 in a sealing tube at 150 °C;;
In neat (no solvent) heating in a sealing tube at 150 °C;;
In neat (no solvent) react. with P2S5 in a sealing tube at 150 °C;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 3982-91-0
trichlorothiophosphine

Conditions

Conditions	Yield
With metal sulfide In not given byproducts: metal chloride; react. with metal sulfides forming PSCl3 and corresponding metal chlorides;;
With hydrogen sulfide In neat (no solvent) byproducts: HCl; react. of dry H2S with PCl5 under heating;;
With hydrogen sulfide In neat (no solvent) byproducts: HCl;
With metal chloride In not given byproducts: metal sulfide; react. of PCl5 with metal chloride;;
With metal chloride In not given byproducts: metal sulfide; react. of PCl5 with metal chloride;;

: 3931-89-3
thiophosphoryl(V) bromide

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: 29679-77-4
phosphorus pentabromide

Conditions

Conditions	Yield
In not given react. with PSBr3;;
In not given react. with PSBr3;;

...Expand

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 7783-06-4
hydrogen sulfide

: 3982-91-0
trichlorothiophosphine

Conditions

Conditions	Yield
In neat (no solvent) react. with liquid H2S;;
In carbon disulfide passing H2S through a liquid mixt. of PCl5 and CS2;; distn. in a stream of CO2;;
In not given react. of liquid H2S with PCl5;;

: potassium sulfide

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: potassium chloride

C: phosphorous (V) sulfide

Conditions

Conditions	Yield
In neat (no solvent) react. on heating under blazing up;;

...Expand

: tin disulfide

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 3982-91-0
trichlorothiophosphine

B: phosphorous (V) sulfide

C: tin(ll) chloride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: thiosulfate; react. on haeting;;

...Expand

: 3982-91-0
trichlorothiophosphine

: 7732-18-5
water

A: 52826-97-8
PSCl2(1+)

B: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 100% B n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 7732-18-5
water

: HPSCl3(1+)

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. H2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	100%

: 3982-91-0
trichlorothiophosphine

: TamBP phenol

: C42H72N3O21P7S

Conditions

Conditions	Yield
With caesium carbonate In acetonitrile at 0 - 20℃; for 12h;	98%

: 3982-91-0
trichlorothiophosphine

: sodium 3,5-bis(borane-diphenylphosphino)phenolate*2(tetrahydrofurane)

: 436805-36-6
chloro bis(3,5-bis(borane-diphenylphosphino)-phenoxy)thiophosphate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: NaCl; in the absence of air using Schlenk techniques; mixed between -95 and -100°C under stirring; mixt. stirred overnight at room temp.; partially concd. (vac.); ppt. centrifuged; filtered under Ar; filtrate evapd; as oil;	97.5%

: 3982-91-0
trichlorothiophosphine

: 10102-44-0
Nitrogen dioxide

A: OPSCl3(1+)

B: NO*PSCl3(1+)

C: 10102-43-9
nitrogen(II) oxide

D: oxygen

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. NO2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 97% B 3% C n/a D n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 201230-82-2
carbon monoxide

A: 14989-32-3
sulphur monochloride

B: 52826-97-8
PSCl2(1+)

C: PSCl3(1+)

D: 75601-84-2
PCl2(1+)

E: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CO; the reagent ions were selected using a quadrupole massfilter before being injected into a drift region contg. helium carrier gas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A n/a B 93% C 1% D 6% E n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 10024-97-2
dinitrogen monoxide

A: 14989-32-3
sulphur monochloride

B: 52826-97-8
PSCl2(1+)

C: PSCl3(1+)

D: 75601-84-2
PCl2(1+)

E: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A n/a B 93% C 1% D 6% E n/a
In gas Kinetics; byproducts: O; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; O was also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A n/a B 69% C 18% D 13% E n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 7664-41-7
ammonia

: 55145-67-0, 13455-05-5
phosphorothioic triamide

Conditions

Conditions	Yield
In chloroform dissolving NH3-gas at -10°C in dry CHCl3; dropwisre addn. of PSCl3 in CHCl3 during 1.5 h; passing NH3 through the soln. at -10°C; sucking off; drying in vac. and dissolving in CHCl3; boiling for 3-4 h in presence of diethylamine;; recrystn. from hot methanol;;	90%
In chloroform dissolving NH3-gas at -10°C in dry CHCl3; dropwisre addn. of PSCl3 in CHCl3 during 1.5 h; passing NH3 through the soln. at -10°C; sucking off; drying in vac. and dissolving in CHCl3; boiling for 3-4 h in presence of diethylamine;; recrystn. from hot methanol;;	90%
In not given formation from PSCl3 and NH3;;

: 3982-91-0
trichlorothiophosphine

: 28240-68-8
methylenebis(dichlorophosphine)

: 1499-32-7
methylene-bis-(phosphonic dichloride)

Conditions

Conditions	Yield
With aluminum (III) chloride at 110 - 140℃; for 6h; Inert atmosphere;	89%

: 3982-91-0
trichlorothiophosphine

: 67-63-0
isopropyl alcohol

: 19021-61-5
O-isopropyl phosphorodichloridothioate

Conditions

Conditions	Yield
With pyridine at 20℃; for 2h;	84%

: 3982-91-0
trichlorothiophosphine

: 98-54-4
para-tert-butylphenol

: 68591-35-5
C10H13Cl2OPS

Conditions

Conditions	Yield
Stage #1: para-tert-butylphenol With sodium hydroxide In water at 0℃; Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;	81%

: 3982-91-0
trichlorothiophosphine

: 7727-37-9
nitrogen

A: 52826-97-8
PSCl2(1+)

B: PSCl(1+)

C: PSCl3(1+)

D: 75601-84-2
PCl2(1+)

E: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

Conditions

Conditions	Yield
In gas Kinetics; byproducts: SCl, Cl2; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2; the reagent ions were selected using a quadrupole massfilter before being injected into a drift region contg. He; 298 K; SCl, Cl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 80% B 4% C 2% D 14% E n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 124-38-9
carbon dioxide

A: 14989-32-3
sulphur monochloride

B: 52826-97-8
PSCl2(1+)

C: PSCl3(1+)

D: O2*PSCl2(1+)

E: 75601-84-2
PCl2(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: Cl, CCl; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CO2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. He; at 298 K; Cl, CCl were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A n/a B 80% C 11% D 3% E 6%

...Expand

: 3982-91-0
trichlorothiophosphine

: 95-48-7
ortho-cresol

: 91674-47-4
2-methylpheylphosphorodichloridate

Conditions

Conditions	Yield
Stage #1: ortho-cresol With sodium hydroxide In water at 0℃; Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;	80%

: 3982-91-0
trichlorothiophosphine

: 106-44-5
p-cresol

: 18961-95-0
p-tolyl phosphorodichloridothionate

Conditions

Conditions	Yield
Stage #1: p-cresol With sodium hydroxide In water at 0℃; Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 5h;	76%

: 3982-91-0
trichlorothiophosphine

: 367-12-4
2-fluorophenol

: 1428326-54-8
C6H4Cl2FOPS

Conditions

Conditions	Yield
Stage #1: 2-fluorophenol With sodium hydroxide In water at 0℃; Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 8h;	75%

: 3982-91-0
trichlorothiophosphine

: 80937-33-3
oxygen

A: 52826-97-8
PSCl2(1+)

B: PSCl3(1+)

C: O2*PSCl2(1+)

D: 14700-96-0, 14835-24-6, 15723-23-6, 16547-50-5, 16885-04-4, 16887-00-6, 16904-11-3, 16904-12-4, 16999-02-3, 20337-89-7, 20499-73-4, 22537-15-1, 22537-27-5, 22541-73-7, 22541-74-8, 24203-47-2, 33944-49-9, 34937-26-3, 37352-90-2
clorine

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. O2/N2; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carrier gas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 21% B 73% C 6% D n/a

...Expand

: 3982-91-0
trichlorothiophosphine

: 95-57-8
2-monochlorophenol

: 68591-34-4
phosphorodichloridothioic acid O-ortho-chlorophenyl ester

Conditions

Conditions	Yield
Stage #1: 2-monochlorophenol With sodium hydroxide In water at 0℃; Stage #2: trichlorothiophosphine With tetrabutylammomium bromide In dichloromethane; water at 0 - 20℃; for 8h;	72%

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: 52826-97-8
PSCl2(1+)

B: CF2Cl3(1+)

C: PSCl3(1+)

D: 64710-27-6
Cl3FP(1+)

E: PCl3(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: CF2, CF2S, CClF2; High Pressure; ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a region contg. He; at 298 K; CF2, CF2S, CClF2, CFS, PS were obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 4% B 2% C 69% D n/a E 25%

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: 3982-91-0
trichlorothiophosphine

: 2551-62-4
sulfur(VI) hexafluoride

A: 80799-96-8
ClS2(1+)

B: 52826-97-8
PSCl2(1+)

C: PSCl3(1+)

D: 64710-27-6
Cl3FP(1+)

E: PCl3(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: S2(1+), PFCl3, F; High Pressure; ions generated in an electron impact high-pressure ion source contg. SF6were selected using a quadrupole mass filter before being injected into a region contg. He; 298 K; S*PSCl3(1+), SF, SFCl, S2, ClF, ClP, FS2, S2 (1+), PFCl3, F were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 4% B 14% C 69% D 6% E 3%

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: 3982-91-0
trichlorothiophosphine

: 2551-62-4
sulfur(VI) hexafluoride

A: 43431-44-3
FS2(1+)

B: PSCl3(1+)

C: S*PSCl3(1+)

D: 64710-27-6
Cl3FP(1+)

E: PCl3(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: SF2, F2, PFCl3; High Pressure; the ions were generated in an electron impact high-pressure ion source contg. SF6; the ions were selected using a quadrupole mass filter before being injected into a drift region contg. He carrier gas; 298 K; SF2, F2, PFCl3, FS2, SSF2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;;	A 8% B 66% C 13% D 8% E 5%

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: 3982-91-0
trichlorothiophosphine

: 1310-73-2
sodium hydroxide

: trisodium thiophosphate

Conditions

Conditions	Yield
In water at 3 - 95℃; for 2.66667h; Product distribution / selectivity; Heating / reflux;	65%

: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: PFCl2(1+)

B: 38264-02-7
SCF(1+)

C: 75601-84-2
PCl2(1+)

D: 81128-92-9
PS(1+)

E: 40640-70-8
fluorodichloromethyl(1+)

Conditions

Yield

In gas Kinetics; byproducts: CFSCl3(1+), PFCl3(1+), CClS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. CF4 were selected using a mass filter before being injected into a region contg. He; 298 K; CFSCl3(1+), PFCl3(1+), CClS(1+), CCl3F, PCl3, CClS, CClFS, PSCl, P, CS, PFCl2 were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;

A 15%
B 64%
C n/a
D n/a
E 9%

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: 3982-91-0
trichlorothiophosphine

: 7727-37-9
nitrogen

A: 52826-97-8
PSCl2(1+)

B: PSCl(1+)

C: PSCl3(1+)

D: 75601-84-2
PCl2(1+)

E: NS(1+)

Conditions

Conditions	Yield
In gas Kinetics; byproducts: Cl, N, PS(1+); High Pressure; ions generated in an electron impact high-pressure source contg. N2 wereselected using a quadrupole mass filter before being injected into a dr ift region contg. He; at 298 K; PS(1+), Cl, N, SCl, PCl3, Cl2, NCl3 werealso obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 62% B 1% C 16% D 15% E 5%

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: 3982-91-0
trichlorothiophosphine

: 12125-02-9
ammonium chloride

: 14475-36-6, 34859-01-3
dichlorothiophosphoric acid amide

Conditions

Conditions	Yield
for 20h; Reflux;	58.5%

: 3982-91-0
trichlorothiophosphine

: 1310-73-2
sodium hydroxide

: trisodium thiophosphate

Conditions

Conditions	Yield
In water for 0.5h; Product distribution / selectivity; Reflux;	56.5%
In water according to S.K. Yasuda, J.L. Lambert, Inorg. Synth. 1957, 5, 102; PSCl3 added to aq. NaOH; suspended in anhydr. methanol;	42%
In neat (no solvent)
In neat (no solvent)
In water react. of aq. NaOH and PSCl3;

: 3982-91-0
trichlorothiophosphine

: hydroxyferrocene

A: 206068-79-3
diferrocenyl chlorothiophosphonate

B: triferrocenyl thiophosphate

Conditions

Conditions	Yield
With NEt3 In tetrahydrofuran byproducts: NEt3HCl; Ar-atmosphere; mixing equimolar amt. of ferrocene derivative and NEt3, cooling to -78°C, slow addn. of 0.5 equiv. of PSCl3, stirring (room temp., overnight); filtration, evapn. (vac.), chromy. (SiO2, CH2Cl2);	A 49% B n/a

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: 3982-91-0
trichlorothiophosphine

: 75-73-0
carbon tetrafluoride

A: 52826-97-8
PSCl2(1+)

B: CF3(1+)*PSCl3=CF3*PSCl3(1+)

C: 64710-27-6
Cl3FP(1+)

D: 420-32-6
thiocarbonyl fluoride

E: 75-72-9
chlorotrifluoromethane

Conditions

Conditions	Yield
In gas Kinetics; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. CF4; the reagent ions were selected using a quadrupole mass filter before being injected into a drift region contg. helium carriergas; at 298 K; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 48% B 44% C 8% D n/a E n/a

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: 3982-91-0
trichlorothiophosphine

: 10024-97-2
dinitrogen monoxide

A: 52826-97-8
PSCl2(1+)

B: PSCl3(1+)

C: NO*PSCl3(1+)

D: 75601-84-2
PCl2(1+)

E: 10102-43-9
nitrogen(II) oxide

Conditions

Conditions	Yield
In gas Kinetics; byproducts: ClNOS, ClNO; High Pressure; the reagent ions were generated in an electron impact high-pressure ion source contg. N2O; the reagent ions were selected using a quadrupole mass filter before being injected into a region contg. He; at 298 K; ClNO, ClNOS were also obtained; monitoring by quadrupole mass spectrometer at the end of the flow tube;	A 7% B 47% C 33% D 13% E n/a

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