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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem’s R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis

2-Methylthiophenol

Cas:137-06-4

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Thiocresol

Cas:137-06-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

high quality 2-Methylbenzenethiol

Cas:137-06-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality Appearance:CLEAR COLOURLESS TO SLIGHTY YELLOW-BROWN LIQUID Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical

o-Toluenethiol

Cas:137-06-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Methyl benzenethiol

Cas:137-06-4

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

2-Methylthiophenol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

high quality 2-Methylbenzenethiol

Cas:137-06-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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Hangzhou Lingrui Chemical Co.,Ltd.

2-Methylthiophenol)Appearance:Pls see the Details Storage:Keep away of light, hot, water, Store in dry, dark and ventilated place Package:according to customers' requirements Application:Steroids, Cosmetics Ingredients, APIs, Intermediates, OLED&Batt

2-Methylthiophenol)

Cas:137-06-4

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

2-MethylbenzenethiolCAS NO.: 137-06-4

Cas:137-06-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

2-Chloroaniline hydrochloride

Cas:137-06-4

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

O-Toluenethiol

Cas:137-06-4

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

o-Toluenethiol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-(Methyl)Thiophenol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 137-06-4 with competitive price

Cas:137-06-4

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Methylthiophenol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen AmoyChem Co.,Ltd

Amoychem is committed to providing the top-quality chemical products and services Internationally. We offer our customers with friendly, professional service and reliable, high performance products that have been manufactured according to the accredi

2-Thiocresol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Other

inquiry

Hubei Langyou International Trading Co., Ltd

high quality 2-Methylbenzenethiol Application:high quality 2-Methylbenzenethiol

high quality 2-Methylbenzenethiol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan ZeShanCheng Biomedical Technology Co., Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highl

2-Methylthiophenol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers. Prompt reaction, good quality and best service make us reliable and outstanding in this industry.Appearance:Clear colorless to pale yel

2-Thiocresol manufacture

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

137-06-4 Application:intermediate

2-Thiocresol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

high quality 2-MethylbenzenethiolAppearance:CLEAR COLOURLESS TO SLIGHTY YELLOW-BROWN LIQUID Storage:Room temperature Package:as you requested Application:Pharmaceutical intermediates Transportation:By express (Door to door) such as FEDEX, DHL, EMS fo

high quality 2-Methylbenzenethiol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

2-Thiocresol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao little fox Biological &Technology Co.,Ltd

o-thiocresol CAS 137-06-4 Storage:dry and cool place Application:API

o-thiocresol CAS 137-06-4

Cas:137-06-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#137-06-4;CAT#A807179

Cas:137-06-4

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

2-Methylbenzenethiol Basic information Product Name: 2-Methylbenzenethiol Synonyms: 2-mercapto-toluen;2-Methybenzenethiol;2-methyl-benzenethio;2-methylmercaptobenze

137-06-4 C7H8S 2-Methylbenzenethiol

Cas:137-06-4

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Shaanxi Mingqi Chemical Co., Ltd

Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer a

Factory Direct Sales Low Price o-thiocresol

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

Zhengzhou Kingorgchem Chemical Technology Co., Ltd. was founded on the basis of Organophosphorus Chemistry Lab of Institute of Chemistry Henan Academy of Sciences in 2015. The laboratory covers 600 m2 and the pilot plant covers 2000 m2. Kingorgchem i

National Research Platform ISO 9001 137-06-4

Cas:137-06-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

2-THIOCRESOL

Cas:137-06-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei MuHai biological technology co., LTD

Deliver Day : within 24 hours after get the payment Payment Terms : T/T, Western Union, MoneyGram, bank transfer Packaging: Safe and discreet packaging Shipment : UPS / DHL / FEDEX / EMS and Client's request Origin China Quality : High

2-MethylthiophenolCAS NO.: 137-06-4

Cas:137-06-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Trading Company

inquiry

Changzhou Pesan Chemical Co.,Ltd

Strong R&D strength and team We have a R&D team with around 30 R&D personnel.All of our employees have chemical backgrounds and have worked in the chemical industry for many years.Our laboratory can synthesize target products with wei

2-Methylbenzenethiol 137-06-4

Cas:137-06-4

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With copper(ll) sulfate pentahydrate; ethane-1,2-dithiol; potassium hydroxide In water; dimethyl sulfoxide at 90℃; for 20h; Inert atmosphere;96%
Stage #1: ortho-methylphenyl iodide With copper(l) iodide; potassium carbonate; sulfur In N,N-dimethyl-formamide at 90℃; for 12h; Inert atmosphere;
Stage #2: With sodium tetrahydroborate In N,N-dimethyl-formamide at 40℃; Inert atmosphere; Cooling with ice;
90%
With sodiumsulfide nonahydrate; copper; ethane-1,2-dithiol In dimethyl sulfoxide at 100℃; for 20h; Inert atmosphere; Green chemistry;88%
With copper(l) iodide; thiourea; L-proline; sodium t-butanolate In dimethyl sulfoxide at 90℃; for 24h; Inert atmosphere;86%
2-methylphenyl bromide
95-46-5

2-methylphenyl bromide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With hydrogen sulfide at 360℃; Reagent/catalyst;98.5%
Stage #1: 2-methylphenyl bromide With water; caesium carbonate; sodium thiosulfate; bis(dibenzylideneacetone)-palladium(0); XPhos In toluene; tert-butyl alcohol at 80℃; for 24h; Inert atmosphere;
Stage #2: With hydrogenchloride; zinc In water for 1h; Cooling with ice;
75%
With sulfur; magnesium 1.) ether; Multistep reaction;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

phenol
108-95-2

phenol

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With hydrogenchloride; aluminium chloride In diethyl ether; toluene; Petroleum ether
bis(2-methylphenyl)disulfide
4032-80-8

bis(2-methylphenyl)disulfide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With sodium tetrahydroborate; lithium chloride In tetrahydrofuran at 0 - 35℃;96%
With sodium tetrahydroborate; zirconium(IV) chloride In tetrahydrofuran at 35℃; for 0.166667h; Reduction;95%
Dimethyldisulphide
624-92-0

Dimethyldisulphide

phenol
108-95-2

phenol

A

para-thiocresol
106-45-6

para-thiocresol

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With iron(III) chloride In Petroleum ether
methyl o-tolyl sulfide
14092-00-3

methyl o-tolyl sulfide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; sodium hydride; diethylamine In xylene for 6h; Heating;85%
toluene
108-88-3

toluene

A

para-thiocresol
106-45-6

para-thiocresol

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
Stage #1: toluene With trifluoromethylsulfonic anhydride; (MeO2CH2CH2)2SO In dichloromethane at -35 - 20℃;
Stage #2: With triethylamine In tetrahydrofuran at 20℃; for 12h;
Stage #3: With potassium tert-butylate In tetrahydrofuran at -78℃; for 0.166667h; Title compound not separated from byproducts;
S-o-tolyl dimethylcarbamothioate
7305-14-8

S-o-tolyl dimethylcarbamothioate

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With potassium hydroxide In tetrahydrofuran; methanol for 3h; Ambient temperature;
O‐(o‐tolyl) dimethylcarbamothioate
10345-39-8

O‐(o‐tolyl) dimethylcarbamothioate

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2 h / 210 °C
2: KOH / tetrahydrofuran; methanol / 3 h / Ambient temperature
View Scheme
ortho-cresol
95-48-7

ortho-cresol

colloid/al platinum

colloid/al platinum

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 1,4-diazabicyclo<2.2.2>octane (dabco) / dimethylformamide / 1.5 h / 60 - 70 °C
2: 2 h / 210 °C
3: KOH / tetrahydrofuran; methanol / 3 h / Ambient temperature
View Scheme
2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With sodium hydroxide; n-butanethiol 1) N-methyl-2-pyrrolidone, removal of water by toluene reflux, 2) reflux (ca. 186 deg C), 20 h; Yield given. Multistep reaction;
With pumice stone; hydrogen sulfide at 700℃;
With pumice stone; hydrogen sulfide; thorium dioxide at 700℃;
Benzo[b]thiophene
95-15-8

Benzo[b]thiophene

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With potassium hydroxide at 300 - 310℃; im Autoklaven;
ortho-methylphenyl iodide
615-37-2

ortho-methylphenyl iodide

thiourea
17356-08-0

thiourea

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With sodium hydroxide; bis(triethylphosphine)nickel(II) chloride; sodium cyanoborohydride 1.) DMF, 60 deg C, 10 h, 2.) water, room temperature; Yield given. Multistep reaction;
2,2,4,4-tetrachloro-2,4-dihydro-1,3-benzodithiin
87641-74-5

2,2,4,4-tetrachloro-2,4-dihydro-1,3-benzodithiin

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran for 7h; Heating; Title compound not separated from byproducts;
dithiocarbonic acid O-ethyl ester-S-o-tolyl ester
24022-34-2

dithiocarbonic acid O-ethyl ester-S-o-tolyl ester

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
(3S,3aR,4S,6aR,9S,9aR,9bR)-4-Hydroxy-9-methyl-6-methylene-3-o-tolylsulfanylmethyl-octahydro-azuleno[4,5-b]furan-2,8-dione
248584-39-6

(3S,3aR,4S,6aR,9S,9aR,9bR)-4-Hydroxy-9-methyl-6-methylene-3-o-tolylsulfanylmethyl-octahydro-azuleno[4,5-b]furan-2,8-dione

A

grosheimin
22489-66-3

grosheimin

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With phosphate buffer In methanol at 37℃; pH=7.4; Kinetics; Hydrolysis;
Toluene-2-sulfonyl chloride
133-59-5

Toluene-2-sulfonyl chloride

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With sulfuric acid elektrochemische Reduktion;
With hydrogenchloride; iron
[(2-Methylphenyl)sulfanyl]acetic acid
18619-15-3

[(2-Methylphenyl)sulfanyl]acetic acid

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With perchloric acid; pyridinium chlorochromate In water; acetic acid at 24.85 - 44.85℃; Kinetics; Oxidation;
ortho-tolylmagnesium bromide
932-31-0

ortho-tolylmagnesium bromide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With diethyl ether; sulfur Zersetzung des Reaktionsproduktes mit angesaeuertem Wasser;
2-methylbenzene diazonium
17333-74-3

2-methylbenzene diazonium

A

di-o-tolyl sulfide
4537-05-7

di-o-tolyl sulfide

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With sodium sulfide
With sodium sulfide
4-bromo-toluene-2-sulfonic acid
56919-17-6

4-bromo-toluene-2-sulfonic acid

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With hydrogenchloride; tin Behandeln des Reaktionsprodukts in Alkohol mit Natriumamalgam;
o-toluidine
95-53-4

o-toluidine

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With hydrogenchloride; sodium nitrite Eintragen des Reaktionsgemisches in wss. Natriumpolysulfid und Erhitzen des danach erhaltenen Reaktionsprodukts mit wss. NaOH;
2-Methyl-benzenethiol

2-Methyl-benzenethiol

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With triethylamine In various solvent(s) Kinetics; Reduction;
potassium ethyl xanthogenate
140-89-6

potassium ethyl xanthogenate

o-toluene-diazonium chloride
2028-34-4

o-toluene-diazonium chloride

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
Erwaermen auf ca. 70grad und Verseifung mit alkoh. Kalilauge;
[(2-Methylphenyl)sulfanyl]acetic acid
18619-15-3

[(2-Methylphenyl)sulfanyl]acetic acid

A

Glyoxilic acid
298-12-4

Glyoxilic acid

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With perchloric acid; sodium perborate; acetic acid at 24.9℃; Rate constant; Thermodynamic data; Mechanism; var. temp., ΔH(excit.), ΔS(excit.);
1-chloro-2-(chloromethyl)benzene
611-19-8

1-chloro-2-(chloromethyl)benzene

A

2-methylchlorobenzene
95-49-8

2-methylchlorobenzene

B

(E)-2,2'-dichlorostilbene
25144-38-1

(E)-2,2'-dichlorostilbene

C

1,2-bis(2-chlorophenyl)ethane
6639-40-3

1,2-bis(2-chlorophenyl)ethane

D

1,1-di(2-chlorophenyl)ethylene
97063-37-1

1,1-di(2-chlorophenyl)ethylene

E

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
With hydrogen sulfide at 560℃; Product distribution; thermolysis in stream of hydrogen sulfide;
2-ethoxy-S-allylthiophenol
102968-96-7

2-ethoxy-S-allylthiophenol

A

styrene
292638-84-7

styrene

B

1-benzofurane
271-89-6

1-benzofurane

C

acetophenone
98-86-2

acetophenone

D

2-thiocresol
137-06-4

2-thiocresol

E

phenol
108-95-2

phenol

Conditions
ConditionsYield
at 750℃; under 0.001 - 0.005 Torr; for 0.333333h; Mechanism; pyrolysis of o-substituted N-, O-, and S-allyl compounds;
(Dimethylamino-o-tolylsulfanyl-methylene)-dimethyl-ammonium; iodide

(Dimethylamino-o-tolylsulfanyl-methylene)-dimethyl-ammonium; iodide

A

tetramethylurea
632-22-4

tetramethylurea

B

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
at 20℃; Rate constant; pH=11;
Benzo[b]thiophene
95-15-8

Benzo[b]thiophene

potassium hydroxide

potassium hydroxide

2-thiocresol
137-06-4

2-thiocresol

Conditions
ConditionsYield
at 300 - 310℃; im Autoklaven;
2-thiocresol
137-06-4

2-thiocresol

bis(2-methylphenyl)disulfide
4032-80-8

bis(2-methylphenyl)disulfide

Conditions
ConditionsYield
1,3-dibromo-5,5-dimethylimidazolidine-2,4-dione In chloroform at 20℃; for 0.0166667h;100%
With aluminum oxide; sodium iodate In hexane at 20℃; for 0.5h;99%
With N,N,N,N,-tetramethylethylenediamine; eosin y In ethanol for 2h; Irradiation;99%
2-thiocresol
137-06-4

2-thiocresol

methyl iodide
74-88-4

methyl iodide

methyl o-tolyl sulfide
14092-00-3

methyl o-tolyl sulfide

Conditions
ConditionsYield
With potassium carbonate In acetone at 25℃; for 17h;100%
With sodium hydride In N,N-dimethyl-formamide 1.) 0 deg C, 15 min, 2.) room temperature, 45 min;97%
With potassium carbonate In acetone at 20℃; for 18h;95%
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

2-thiocresol
137-06-4

2-thiocresol

4-[(2-methylphenyl)thio]benzamide

4-[(2-methylphenyl)thio]benzamide

Conditions
ConditionsYield
Stage #1: 4-iodobenzoic acid With SPPSLRAM SynPhase Lanterns(R); N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In dichloromethane; N,N-dimethyl-formamide at 45℃; for 15h;
Stage #2: 2-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h;
Stage #3: With trifluoroacetic acid In dichloromethane
100%
4-iodobenzoic acid
619-58-9

4-iodobenzoic acid

2-thiocresol
137-06-4

2-thiocresol

4-[(2-methylphenyl)thio]benzoic acid

4-[(2-methylphenyl)thio]benzoic acid

Conditions
ConditionsYield
Stage #1: 4-iodobenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h;
Stage #2: 2-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h;
Stage #3: With trifluoroacetic acid In dichloromethane
100%
3-iodo-4-toluic acid
82998-57-0

3-iodo-4-toluic acid

2-thiocresol
137-06-4

2-thiocresol

4-methyl-3-[(2-methylphenyl)thio]benzoic acid

4-methyl-3-[(2-methylphenyl)thio]benzoic acid

Conditions
ConditionsYield
Stage #1: 3-iodo-4-toluic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h;
Stage #2: 2-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h;
Stage #3: With trifluoroacetic acid In dichloromethane
100%
4-iodo-3-methylbenzoic acid
52107-87-6

4-iodo-3-methylbenzoic acid

2-thiocresol
137-06-4

2-thiocresol

3-methyl-4-[(2-methylphenyl)thio]benzoic acid

3-methyl-4-[(2-methylphenyl)thio]benzoic acid

Conditions
ConditionsYield
Stage #1: 4-iodo-3-methylbenzoic acid With dmap; SPPSLHMP SynPhase Lanterns(R); dacarbazine In dichloromethane; N,N-dimethyl-formamide at 50℃; for 15h;
Stage #2: 2-thiocresol With borohydride polymer supported Amberlite(R) IRA400; bis(bipyridine)nickel(II) bromide In tetrahydrofuran; ethanol at 70℃; for 15h;
Stage #3: With trifluoroacetic acid In dichloromethane
100%
2-Iodobenzoic acid
88-67-5

2-Iodobenzoic acid

2-thiocresol
137-06-4

2-thiocresol

2-(2'-Methylphenylthio)benzoic acid
87548-96-7

2-(2'-Methylphenylthio)benzoic acid

Conditions
ConditionsYield
With potassium hydroxide; copper In water for 7h; Heating;99%
methanol
67-56-1

methanol

2-thiocresol
137-06-4

2-thiocresol

2-methylbenzenesulfinic acid methyl ester
94626-19-4

2-methylbenzenesulfinic acid methyl ester

Conditions
ConditionsYield
With N-Bromosuccinimide In dichloromethane at 0℃; for 1h;99%
With oxygen; potassium carbonate at 60℃; for 24h; Schlenk technique; chemoselective reaction;75%
With eosin at 20℃; for 1h; Irradiation;75%
(i) Pb(OAc)4, (ii) /BRN= 1098229/, Pb(OAc)4; Multistep reaction;
2-thiocresol
137-06-4

2-thiocresol

5-Isopropyl-6-methanesulfonyl-1-propoxy-1H-pyrimidine-2,4-dione
191472-62-5

5-Isopropyl-6-methanesulfonyl-1-propoxy-1H-pyrimidine-2,4-dione

5-Isopropyl-1-propoxy-6-o-tolylsulfanyl-1H-pyrimidine-2,4-dione

5-Isopropyl-1-propoxy-6-o-tolylsulfanyl-1H-pyrimidine-2,4-dione

Conditions
ConditionsYield
With sodium hydroxide for 0.333333h; Ambient temperature;99%
2-thiocresol
137-06-4

2-thiocresol

6-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate
345948-96-1

6-methyl-2-oxo-2H-chromen-4-yl 4-methylbenzenesulfonate

C17H14O2S
627100-56-5

C17H14O2S

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20 - 25℃;99%
N-tosyldiphenylmethylamine
853-83-8

N-tosyldiphenylmethylamine

2-thiocresol
137-06-4

2-thiocresol

benzhydryl-o-tolyl sulfide

benzhydryl-o-tolyl sulfide

Conditions
ConditionsYield
With chloro-trimethyl-silane; zinc(II) chloride In dichloromethane at 20℃; for 1h;99%
cyclohexenone
930-68-7

cyclohexenone

2-thiocresol
137-06-4

2-thiocresol

(S)-3-(o-tolylthio)cyclohexanone
177473-06-2

(S)-3-(o-tolylthio)cyclohexanone

Conditions
ConditionsYield
With 1-(3,5-bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((2S,4S,8R)-8-vinylquinuclidin-2-yl)methyl)urea In toluene at 20℃; for 7h; Michael addition; optical yield given as %ee; enantioselective reaction;99%
2-bromoanisole
578-57-4

2-bromoanisole

2-thiocresol
137-06-4

2-thiocresol

2-methoxyphenyl 2-methylphenyl sulfide
105510-24-5

2-methoxyphenyl 2-methylphenyl sulfide

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; tris-(dibenzylideneacetone)dipalladium(0); N-ethyl-N,N-diisopropylamine In toluene for 3h; Inert atmosphere; Reflux;99%
With 1-(pyridin-2-yl)-1H-benzo[d][1,2,3]triazole; potassium tert-butylate; palladium diacetate In dimethyl sulfoxide at 100℃; for 12h; Inert atmosphere; Schlenk technique;87%
With copper(l) iodide; 1-Hydroxymethyl-1H-benzotriazole; potassium tert-butylate In dimethyl sulfoxide at 100℃;78%
2-Bromo-m-xylene
576-22-7

2-Bromo-m-xylene

2-thiocresol
137-06-4

2-thiocresol

(2,6-dimethylphenyl)(o-tolyl)sulfane
38630-01-2

(2,6-dimethylphenyl)(o-tolyl)sulfane

Conditions
ConditionsYield
Stage #1: 2-Bromo-m-xylene With dichloro[1,3-bis(2,6-di-3-pentylphenyl)imidazol-2-ylidene](3-chloropyridyl)palladium(II); lithium isopropoxide In toluene at 80℃; for 0.5h; Inert atmosphere;
Stage #2: 2-thiocresol With potassium tert-butylate In toluene at 40℃; for 24h; Inert atmosphere;
99%
2-thiocresol
137-06-4

2-thiocresol

rac-2-(2-bromophenyl)-1-tosylaziridine
200803-17-4

rac-2-(2-bromophenyl)-1-tosylaziridine

3-(o-tolylthio)-1-tosylindoline
1429656-46-1

3-(o-tolylthio)-1-tosylindoline

Conditions
ConditionsYield
Stage #1: 2-thiocresol; 2-(2-bromophenyl)-N-tosylaziridine With potassium carbonate In toluene at 20℃; for 0.416667h; Inert atmosphere;
Stage #2: With palladium diacetate; potassium carbonate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In toluene at 110 - 115℃; for 3h; Inert atmosphere;
99%
Benzoylformic acid
611-73-4

Benzoylformic acid

2-thiocresol
137-06-4

2-thiocresol

S-(o-tolyl) benzothioate

S-(o-tolyl) benzothioate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;99%
With ammonium peroxydisulfate; copper(II) oxide In water; dimethyl sulfoxide at 80℃; for 12h;73%
(4-methylphenyl)(oxo)acetic acid
7163-50-0

(4-methylphenyl)(oxo)acetic acid

2-thiocresol
137-06-4

2-thiocresol

S-o-tolyl 4-methylbenzothioate

S-o-tolyl 4-methylbenzothioate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;99%
2-oxo-2-o-tolylacetic acid

2-oxo-2-o-tolylacetic acid

2-thiocresol
137-06-4

2-thiocresol

S-o-tolyl 2-methylbenzothioate
101093-42-9

S-o-tolyl 2-methylbenzothioate

Conditions
ConditionsYield
With dipotassium peroxodisulfate In water; acetonitrile at 70℃; for 24h; Inert atmosphere; Schlenk technique; Sealed tube;99%
phenylhydrazine
100-63-0

phenylhydrazine

2-thiocresol
137-06-4

2-thiocresol

2-(phenylthio)toluene
13963-35-4

2-(phenylthio)toluene

Conditions
ConditionsYield
With manganese(II)carbonate; C26H36N2O6; oxygen; potassium carbonate at 60℃; under 750.075 Torr; for 19h;99%
With copper(II) nitrate trihydrate; 4,7-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-1,10-phenanthroline; oxygen; caesium carbonate In water at 100℃; under 760.051 Torr; for 36h; Schlenk technique; Green chemistry; chemoselective reaction;95%
p-Methoxybenzoic anhydride
794-94-5

p-Methoxybenzoic anhydride

2-thiocresol
137-06-4

2-thiocresol

1-[(4-methoxyphenyl)thio]-2-methylbenzene
22894-90-2

1-[(4-methoxyphenyl)thio]-2-methylbenzene

Conditions
ConditionsYield
With manganese; 1,3-bis-(diphenylphosphino)propane; sodium carbonate; nickel dichloride In toluene at 150℃; for 24h; Sealed tube; Inert atmosphere;99%

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