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CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD. founded in 1984, engages in pharmaceutical research, development, production, process design and technical consultation of synthetic and fermentation pharmaceutical products. The organizational s

high quality, lowest price alpha-2-Chloroisodurene 1585-16-6

Cas:1585-16-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product s

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2,4,6-Trimethylbenzyl chloride

Cas:1585-16-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

alpha-2-Chloroisodurene,1585-16-6

Cas:1585-16-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 1585-16-6 with fast shipping

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

alpha-2-Chloroisodurene CAS1585-16-6

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $7.0 / 9.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Product Name: alpha-2-Chloroisodurene Synonyms: 4,6-trimethylbenzyl chloride;Mesitylmethyl chloride;1-(Chloromethyl)-2,4,6-trimethylbenzene;2-(Chloromethyl)mesitylene;alpha-2-Chloroisodurene,98%;2,4,6-Trime

2,4,6-Trimethylbenzylchloride CAS:1585-16-6

Cas:1585-16-6

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzene,2-(chloromethyl)-1,3,5-trimethyl-

Cas:1585-16-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2,4,6 trimethyl benzyl chloride

Cas:1585-16-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,2-(chloromethyl)-1,3,5-trimethyl-

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hefei Zhaobo Technology Co., Ltd.

alpha-2-Chloroisodurene CAS 1585-16-6 Purity: 99% Min Application: Intermediates Appearance: Powder Package: Bag Delivery: 3-5days Our Advantage & Service 1.Top quality: Using high quality material and establishing a strict quality c

alpha-2-Chloroisodurene CAS 1585-16-6

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: alpha-2-Chloroisodurene Synonyms: 4,6-trimethylbenzyl chloride;Mesitylmethyl chloride;1-(Chloromethyl)-2,4,6-trimethylbenzene;2-(Chloromethyl)mesitylene;alpha-2-Chloroisodurene,98%;2,4,6-Trimethylbenzyl chloride;2,4,6-Trimethyl he

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Product Name:alpha-2-Chloroisodurene CAS No:1585-16

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2,4,6-Trimethylbenzyl chloride

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystalline powder Storage:stored in a cool, dry and ventilated place to provent sun and rain Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical

alpha-2-Chloroisodurene

Cas:1585-16-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

alpha-2-Chloroisodurene Cas no.1585-16-6 98%

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

alpha-2-Chloroisodurene CAS NO.1585-16-6

Cas:1585-16-6

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Hebei Mojin Biotechnology Co.,Ltd

1, High quality with competitive price:2, Fast and safe delivery3.Excellent pre-sales and after-sales service4. Well-trained and professional technologist and sales with rich experience in the field for 5-10 yearsAppearance:see detailed specification

Benzene,2-(chloromethyl)-1,3,5-trimethyl-

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2,4,6-Trimethylbenzyl chloride

Cas:1585-16-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2,4,6-trimethylbenzyl alcohol
4170-90-5

2,4,6-trimethylbenzyl alcohol

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With thionyl chloride In dichloromethane at 0 - 20℃; for 1h;100%
With oxalyl dichloride In dichloromethane at 20℃; Appel Halogenation; Reflux;98%
With tetrachloromethane; ring-opening metathesis polymer-supported triphenylphosphine In dichloromethane at 45℃; for 6h;89%
formaldehyd
50-00-0

formaldehyd

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride In water at 65 - 75℃;90%
With hydrogenchloride; acetic acid In water at 37℃; for 1.5h;68%
With hydrogenchloride In water at 60 - 70℃; for 7h;36%
2,4,6-trimethylbenzyl alcohol
4170-90-5

2,4,6-trimethylbenzyl alcohol

benzoyl chloride
98-88-4

benzoyl chloride

A

(2,4,6-trimethylphenyl)methyl benzoate

(2,4,6-trimethylphenyl)methyl benzoate

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With 1-methylsulfinyl-2-methoxybenzene In acetonitrile at 20℃; for 14h; Sealed tube;A n/a
B 74%
chloromethyl isocyanate
7093-91-6

chloromethyl isocyanate

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

B

2-Isocyanatomethyl-1,3,5-trimethyl-benzene
92277-70-8

2-Isocyanatomethyl-1,3,5-trimethyl-benzene

Conditions
ConditionsYield
With iron(III) chloride 1.) 40 - 60 deg C, 2.) 100 - 150 deg C, 2 h;A 15%
B 32%
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

acetic acid
64-19-7

acetic acid

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
at 65℃; ohne Katalysator; Geschwindigkeit dieser Reaktion und der analogen Reaktionen mit anderen aromatischen Kohlenwasserstoffen bei 65grad und 100grad;
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

acetic acid
64-19-7

acetic acid

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2,4-bis(chloromethyl)mesitylene
1585-17-7

2,4-bis(chloromethyl)mesitylene

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
at 80℃;
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With acetic acid at 65 - 80℃;
chloromethyl methyl ether
107-30-2

chloromethyl methyl ether

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2,4-bis(chloromethyl)mesitylene
1585-17-7

2,4-bis(chloromethyl)mesitylene

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

ethyl chloromethyl ether
3188-13-4

ethyl chloromethyl ether

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With carbon disulfide; tin(IV) chloride
With tetrachloromethane; tin(IV) chloride at -5℃;
With acetic acid
formaldehyd
50-00-0

formaldehyd

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2,4-bis(chloromethyl)mesitylene
1585-17-7

2,4-bis(chloromethyl)mesitylene

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride at 65℃; Einleiten von HCl;
hydrogenchloride
7647-01-0

hydrogenchloride

formaldehyd
50-00-0

formaldehyd

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2,4-bis(chloromethyl)mesitylene
1585-17-7

2,4-bis(chloromethyl)mesitylene

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
at 65℃; Einleiten von HCl;
hydrogenchloride
7647-01-0

hydrogenchloride

2,4,6-trimethylbenzyl acetate
63548-92-5

2,4,6-trimethylbenzyl acetate

A

methyl-(2,4,6-trimethyl-benzyl)-ether
5336-55-0

methyl-(2,4,6-trimethyl-benzyl)-ether

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

hydrogenchloride
7647-01-0

hydrogenchloride

formaldehyd
50-00-0

formaldehyd

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

dimesitylmethane
733-07-3

dimesitylmethane

B

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

C

1,3-dichloromethyl-2,4,6-trimethyl-benzene

1,3-dichloromethyl-2,4,6-trimethyl-benzene

formaldehyd
50-00-0

formaldehyd

1,3,5-trimethyl-benzene
108-67-8

1,3,5-trimethyl-benzene

A

2,4,6-tris(chloromethyl)-mesitylene
3849-01-2

2,4,6-tris(chloromethyl)-mesitylene

B

2,4-bis(chloromethyl)mesitylene
1585-17-7

2,4-bis(chloromethyl)mesitylene

C

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride for 2h; Heating; Title compound not separated from byproducts.;
1,2,3,5-Tetramethylbenzene
527-53-7

1,2,3,5-Tetramethylbenzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With hydrogenchloride; formaldehyd for 2h; Heating;
bis-(2,4,6-trimethyl-benzyl)-ether
4709-84-6

bis-(2,4,6-trimethyl-benzyl)-ether

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With tetrachlorosilane; NbCl3(N,N′-bis-(2,6-diisopropylphenyl)-1,4-diaza-2,3-dimethyl-1,3-butadiene) In chloroform-d1 at 80℃; for 24h;95 %Spectr.
sodium cyanide
143-33-9

sodium cyanide

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

mesitylacetonitrile
34688-71-6

mesitylacetonitrile

Conditions
ConditionsYield
In dimethyl sulfoxide at 80℃; for 0.5h; Substitution;100%
Stage #1: sodium cyanide In ethanol; water Heating / reflux;
Stage #2: 2-chloromethyl-1,3,5-trimethylbenzene In ethanol; water for 3h; Heating / reflux;
72%
In ethanol
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

dimethyl amine
124-40-3

dimethyl amine

2,4,6-trimethyl-<(dimethylamino)methyl>benzene
34274-10-7

2,4,6-trimethyl-<(dimethylamino)methyl>benzene

Conditions
ConditionsYield
In tetrahydrofuran; water at 0 - 20℃; for 3.5h; Substitution;100%
In tetrahydrofuran at 20℃; for 48h; Inert atmosphere;94%
In tetrahydrofuran Ambient temperature;92%
2'-O-acetyl-3-O-descladinosyl-3-O-allyl-6-O-methylerythromycin A 9-(E)-O-acetyloxime 11,12-cyclic carbonate
1360059-83-1

2'-O-acetyl-3-O-descladinosyl-3-O-allyl-6-O-methylerythromycin A 9-(E)-O-acetyloxime 11,12-cyclic carbonate

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

C46H72N2O12
1360059-88-6

C46H72N2O12

Conditions
ConditionsYield
Stage #1: 2'-O-acetyl-3-O-descladinosyl-3-O-allyl-6-O-methylerythromycin A 9-(E)-O-acetyloxime 11,12-cyclic carbonate With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 0.25h;
Stage #2: 2-chloromethyl-1,3,5-trimethylbenzene With potassium tert-butylate In N,N-dimethyl-formamide at 20℃; for 1h;
100%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

(2S,3S)-1,4-bis(allyloxy)-2,3-dihydroxybutane
713132-48-0

(2S,3S)-1,4-bis(allyloxy)-2,3-dihydroxybutane

(2S,3S)-2,3-bis(2,4,6-trimethyl-phenylmethoxy)-1,4-bis(allyloxy)butane
713132-54-8

(2S,3S)-2,3-bis(2,4,6-trimethyl-phenylmethoxy)-1,4-bis(allyloxy)butane

Conditions
ConditionsYield
Stage #1: (2S,3S)-1,4-bis(allyloxy)-2,3-dihydroxybutane With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.333333h;
Stage #2: 2-chloromethyl-1,3,5-trimethylbenzene In N,N-dimethyl-formamide at 50℃; for 7h;
99%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

9b-(3-butyl-phenyl)-1-(4,6-dimethyl-pyrimidin-2-yloxy)-5,9b-dihydro-1H-2a,5-diaza-benzo[a]cyclobuta[c]cycloheptene-2,4-dione

9b-(3-butyl-phenyl)-1-(4,6-dimethyl-pyrimidin-2-yloxy)-5,9b-dihydro-1H-2a,5-diaza-benzo[a]cyclobuta[c]cycloheptene-2,4-dione

9b-(3-butyl-phenyl)-1-(4,6-dimethyl-pyrimidin-2-yloxy)-5-(2,4,6-trimethyl-benzyl)-5,9b-dihydro-1H-2a,5-diaza-benzo[a]cyclobuta[c]cycloheptene-2,4-dione

9b-(3-butyl-phenyl)-1-(4,6-dimethyl-pyrimidin-2-yloxy)-5-(2,4,6-trimethyl-benzyl)-5,9b-dihydro-1H-2a,5-diaza-benzo[a]cyclobuta[c]cycloheptene-2,4-dione

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 50 - 60℃;99%
{Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)}(1-)*{Na(C4H8O)2}(1+)={Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)}{Na(C4H8O)2}

{Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)}(1-)*{Na(C4H8O)2}(1+)={Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)}{Na(C4H8O)2}

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

{Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)CH2C6H2(CH3)3}

{Re(NC6H3(CH(CH3)2)2)2(C2(CH2C(CH3)3)2)CH2C6H2(CH3)3}

Conditions
ConditionsYield
In tetrahydrofuran addn. of 111 μmol of the benzylchloride to a soln. of 111 μmol of the bis(imido) compound in 7 ml THF at -40°C and evaporation;; extraction with pentane, filtration and concentration; coupling product present as an impurity; detn. by (1)H-NMR- and (13)C-NMR spectroscopy;;99%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

benzoic acid
65-85-0

benzoic acid

(2,4,6-trimethylphenyl)methyl benzoate

(2,4,6-trimethylphenyl)methyl benzoate

Conditions
ConditionsYield
With triethylamine for 1h; Heating; Inert atmosphere; Ionic liquid;99%
sodium cyanide
773837-37-9

sodium cyanide

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

mesitylacetonitrile
34688-71-6

mesitylacetonitrile

Conditions
ConditionsYield
With trimethyldodecylammonium chloride In toluene at 68 - 72℃; for 6h; Reagent/catalyst; Temperature;98.8%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

2,4,6-trimethylbenzyl alcohol
4170-90-5

2,4,6-trimethylbenzyl alcohol

Conditions
ConditionsYield
With iron(III) sulfate; water In toluene at 110℃; for 0.7h; Ionic liquid;98%
With potassium carbonate; acetone
Multi-step reaction with 2 steps
1: silver acetate; glacial acetic acid
2: aqueous KOH
View Scheme
1,4-dichloro-5-hydroxy-9,10-anthracenedione
6770-15-6

1,4-dichloro-5-hydroxy-9,10-anthracenedione

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione
123839-74-7

1,4-dichloro-5-<(2,4,6-trimethylphenyl)methoxy>-9,10-anthracenedione

Conditions
ConditionsYield
With caesium carbonate98%
With caesium carbonate In N,N-dimethyl-formamide; acetone for 23h; Heating;78%
With caesium carbonate In N,N-dimethyl-formamide; acetone
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

triphenylphosphine
603-35-0

triphenylphosphine

Triphenyl<(2,4,6-trimethylphenyl)methyl>phosphoniumchlorid
54757-04-9

Triphenyl<(2,4,6-trimethylphenyl)methyl>phosphoniumchlorid

Conditions
ConditionsYield
In benzene for 120h; Ambient temperature;98%
In toluene for 12h; Heating;95%
In benzene at 70℃; for 48h;80%
C36H51N3Re(1-)

C36H51N3Re(1-)

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

Re{NC6H3(CH(CH3)2)2}3(CH2C6H2(CH3)3)
135228-48-7

Re{NC6H3(CH(CH3)2)2}3(CH2C6H2(CH3)3)

Conditions
ConditionsYield
In tetrahydrofuran addn. of 0.06 mmol of the benzyl compound (in 2 ml THF) to a soln. of 0.06 mmol of the tris(imido) compound in 8 ml THF and evaporation after 20 minutes;; extraction with pentane and cooling to -40°C; small amounts of the dibenzyl coupling product; detn. by (1)H-NMR- and (13)C-NMR spectroscopy;;98%
{Re(NC6H3(CH(CH3)2)2)(C2(CH2C(CH3)3)2)2}{Na(C4H8O)2}

{Re(NC6H3(CH(CH3)2)2)(C2(CH2C(CH3)3)2)2}{Na(C4H8O)2}

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

{Re(NC6H3(CH(CH3)2)2)(C2(CH2C(CH3)3)2)2CH2C6H2(CH3)3}

{Re(NC6H3(CH(CH3)2)2)(C2(CH2C(CH3)3)2)2CH2C6H2(CH3)3}

Conditions
ConditionsYield
In tetrahydrofuran addn. of 116 μmol of 2,4,6-trimethylbenzylchloride to a soln. of 116 μmol of the Na(THF)2 salt in 10 ml THF at -40°C and evaporation;; extraction with pentane, filtration, evaporation, solvation in pentane and concentration; contamination with the dibenzyl coupling product; detn. by (1)H-NMR- and (13)C-NMR spectroscopy;;98%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

mesytaldehyde
487-68-3

mesytaldehyde

Conditions
ConditionsYield
With 1-dodecyl-3-methylimidazolium iron chloride; periodic acid at 30℃; for 1.5h;98%
With 4Na(1+)*6H(1+)*NiMo6O24(10-)=Na4H6NiMo6O24; oxygen In water; acetonitrile at 20℃; under 760.051 Torr; for 12h; Irradiation;91%
With sodium nitrate; acetic acid In water for 8h; Reflux;83%
With potassium hydroxide; cetyltrimethylammonim bromide; potassium nitrate In water for 7.5h; pH=10 - 11; Reflux;82%
With (NH4)4[ZnMo6O18(OH)6]; oxygen In water; acetonitrile at 60℃; under 760.051 Torr; for 12h;81%
(S)-4-benzyl-1-(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazole
1353761-69-9

(S)-4-benzyl-1-(2,6-diisopropylphenyl)-4,5-dihydro-1H-imidazole

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

(S)-4-benzyl-1-(2,6-diisopropylphenyl)-3-(2,4,6-trimethylbenzyl)-4,5-dihydro-1H-imidazol-3-ium chloride
1450713-42-4

(S)-4-benzyl-1-(2,6-diisopropylphenyl)-3-(2,4,6-trimethylbenzyl)-4,5-dihydro-1H-imidazol-3-ium chloride

Conditions
ConditionsYield
In toluene at 100℃; for 1h;98%
In acetonitrile at 110℃; for 5h;85%
(1R,5S)-1,8,8-trimethyl-4-(o-tolyl)-2,4-diazabicyclo[3.2.1]oct-2-ene

(1R,5S)-1,8,8-trimethyl-4-(o-tolyl)-2,4-diazabicyclo[3.2.1]oct-2-ene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

(1R,5S)-1,8,8-trimethyl-4-(o-tolyl)-2-(2,4,6-trimethylbenzyl)-2,4-diazabicyclo[3.2.1]oct-2-en-2-ium chloride

(1R,5S)-1,8,8-trimethyl-4-(o-tolyl)-2-(2,4,6-trimethylbenzyl)-2,4-diazabicyclo[3.2.1]oct-2-en-2-ium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃; for 16h; Schlenk technique;98%
4-chloromethoxybenzene
623-12-1

4-chloromethoxybenzene

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

(4-methoxyphenyl)-(2,4,6-trimethylphenyl)methane

(4-methoxyphenyl)-(2,4,6-trimethylphenyl)methane

Conditions
ConditionsYield
With Ni(1,3-bis(2,6-bis(diphenylmethyl)-4-methylphenyl)imidazol-2-ylidene)(PPh3)Br2; magnesium In tetrahydrofuran at 0 - 60℃; for 24.5h; Glovebox; Inert atmosphere; Schlenk technique;98%
Dichloromethyl methyl ether
4885-02-3

Dichloromethyl methyl ether

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

2,4,6-trimethyl-3-(chloromethyl)benzaldehyde
105041-52-9

2,4,6-trimethyl-3-(chloromethyl)benzaldehyde

Conditions
ConditionsYield
Stage #1: Dichloromethyl methyl ether; 2-chloromethyl-1,3,5-trimethylbenzene With titanium tetrachloride In dichloromethane at 17 - 20℃; for 0.333333h; Inert atmosphere;
Stage #2: With water In dichloromethane for 0.25h; Inert atmosphere;
97%
With titanium tetrachloride In dichloromethane at 20℃; for 0.5h;84%
With titanium tetrachloride In dichloromethane at 20℃; for 0.25h;64%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

thiophenol
108-98-5

thiophenol

2,4,6-trimethylbenzyl phenyl sulfide
65597-70-8

2,4,6-trimethylbenzyl phenyl sulfide

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydroxide In chloroform; water for 16h; Ambient temperature;97%
1-Methylbenzimidazole
1632-83-3

1-Methylbenzimidazole

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

1-methyl-3-(2,4,6-trimethylbenzyl)benzimidazolium chloride
1258272-04-6

1-methyl-3-(2,4,6-trimethylbenzyl)benzimidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 95℃; for 4h; Inert atmosphere; Schlenk technique;97%
In N,N-dimethyl-formamide at 80℃; Inert atmosphere; Schlenk technique;
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

1-(2,4,6-trimethylbenzyl)-4,5-dihydroimidazole
587887-00-1

1-(2,4,6-trimethylbenzyl)-4,5-dihydroimidazole

1,3-bis(2,4,6-trimethylbenzyl)-4,5-dihydroimidazolium chloride

1,3-bis(2,4,6-trimethylbenzyl)-4,5-dihydroimidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 25℃; for 6h;96%
1-(3,5-dimethylbenzyl)-5,6-dimethyl-1H-benzo[d]imidazole

1-(3,5-dimethylbenzyl)-5,6-dimethyl-1H-benzo[d]imidazole

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

5,6-dimethyl-1,3-bis(2,4,6-trimethylbenzyl)-1H-benzo[d]imidazole-3-ium chloride

5,6-dimethyl-1,3-bis(2,4,6-trimethylbenzyl)-1H-benzo[d]imidazole-3-ium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 70℃; Schlenk technique;96%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

2-(fluoromethyl)-1,3,5-trimethylbenzene
75142-57-3

2-(fluoromethyl)-1,3,5-trimethylbenzene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In acetonitrile for 2h; Reflux;95%
With potassium fluoride; 18-crown-6 ether In acetonitrile at 80℃; for 90h;
4-Benzyloxyphenol
103-16-2

4-Benzyloxyphenol

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

1-benzyloxy-4-(2,4,6-trimethylbenzyloxy)benzene
187328-97-8

1-benzyloxy-4-(2,4,6-trimethylbenzyloxy)benzene

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 20℃;95%
4-cyclohexyl-2-mercapto-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile
290313-19-8

4-cyclohexyl-2-mercapto-6-oxo-1,6-dihydro-pyrimidine-5-carbonitrile

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

4-cyclohexyl-6-oxo-2-(2,4,6-trimethyl-benzylsulfanyl)-1,6-dihydro-pyrimidine-5-carbonitrile
1383539-70-5

4-cyclohexyl-6-oxo-2-(2,4,6-trimethyl-benzylsulfanyl)-1,6-dihydro-pyrimidine-5-carbonitrile

Conditions
ConditionsYield
With potassium carbonate In acetone at 0 - 20℃; for 36h;95%
piperazine
110-85-0

piperazine

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

1-(2,4,6-trimethylbenzyl)-piperazine
41717-26-4

1-(2,4,6-trimethylbenzyl)-piperazine

Conditions
ConditionsYield
In tetrahydrofuran for 4h; Reflux;94.3%
In tetrahydrofuran for 4h; Reflux; Inert atmosphere;49%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

benzonitrile
100-47-0

benzonitrile

N-(2,4,6-trimethylbenzyl)benzamide
20781-30-0

N-(2,4,6-trimethylbenzyl)benzamide

Conditions
ConditionsYield
With iron(III) chloride for 8h; Ritter reaction; Heating;94%
2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

N-(isobutyl)benzimidazole
305346-88-7

N-(isobutyl)benzimidazole

1-(isobutyl)-3-(2,4,6-trimethylbenzyl)benzimidazolium chloride

1-(isobutyl)-3-(2,4,6-trimethylbenzyl)benzimidazolium chloride

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere; Schlenk technique;94%
In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere; Schlenk technique;94%
In N,N-dimethyl-formamide at 80℃; for 24h; Inert atmosphere; Schlenk technique;94%
In N,N-dimethyl-formamide at 80℃; for 24h;94%
5,6-dimethyl-1H-benzo[d]imida-zole
582-60-5

5,6-dimethyl-1H-benzo[d]imida-zole

2-chloromethyl-1,3,5-trimethylbenzene
1585-16-6

2-chloromethyl-1,3,5-trimethylbenzene

5,6-dimethyl-1-(2,4,6-trimethylbenzyl)-1H-benzo[d]imidazole

5,6-dimethyl-1-(2,4,6-trimethylbenzyl)-1H-benzo[d]imidazole

Conditions
ConditionsYield
Stage #1: 5,6-dimethyl-1H-benzo[d]imida-zole With potassium hydroxide In ethanol at 20℃; for 0.25h;
Stage #2: 2-chloromethyl-1,3,5-trimethylbenzene In ethanol at 20℃; for 17h; Reflux;
94%

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