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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Chloro-3,3,3-trifluoropropene Manufacturer/High quality/Best price/In stock

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Chloro-3,3,3-trifluoro-1-propene

Cas:2730-62-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4'-DIMETHYLAMINOACETOPHENONE CAS:2730-62-3

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $10.0 / 25.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 2730-62-3 with best quality

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

CAS Number 2730-62-3 Product Name 2-chloro-3,3,3-trifluoroprop-1-ene Synonyms 2-chloro-3,3,3-trifluoro-1-propene; 2-chloro-3,3,3-trifluoroprop-1-ene; 1-propene, 2-chloro-3,3,3-trifluor

2-Chloro-3,3,3-trifluoroprop-1-ene

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

1-Propene,2-chloro-3,3,3-trifluoro-

Cas:2730-62-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1-Propene,2-chloro-3,3,3-trifluoro-

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 2730-62-3 ,2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-Chloro-3,3,3-trifluoropropene

Cas:2730-62-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

1-Propene,2-chloro-3,3,3-trifluoro-

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 2-CHLORO-3,3,3-TRIFLUOROPROPENE Synonyms: HCFO-1233xf;2-CHLORO-3,3,3-TRIFLUOROPROP-1-ENE;2-CHLORO-3,3,3-TRIFLUOROPROPENE;2-Chloro-3,3,3-trifluoroprop-1-ene 98%;2-Chloro-3,3,3-trifluoroprop-1-ene98%;2-Chloro-3,3,3-trifluoro-1-propene

2-CHLORO-3,3,3-TRIFLUOROPROPENE 2730-62-3

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $230.0

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

2-CHLORO-3,3,3-TRIFLUOROPROPENE Basic information Product Name: 2-CHLORO-3,3,3-TRIFLUOROPROPENE Synonyms: 2-CHLORO-3,3,3-TRIFLUOROPROP-1-ENE;2-CHLORO-3,3,3-TRIFLUOROPROPENE;R-1233XF;2-Chloro-3,3,3-trifluoroprop-1-ene 98%;2-Chloro-3,3,3-trifluo

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home

2-Chloro-3,3,3-trifluoropropene china manufacture

Cas:2730-62-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Chloro-3,3,3-trifluoropropene

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-Chloro-3,3,3-trifluoroprop-1-ene cas no. 2730-62-3 98%

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,Pharmaceutical intermediates Transportation:air,sea,courier

2-Chloro-3,3,3-trifluoropropene

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hubei Taiho Chemical Co.,LTD

TAIHO Unique Advantages:1.We're factory2.Free samples available3.Commodity inspection can be done4.ISO9001,Kosher certifications5.10 years experiences Storage:Store in cool &dry place Package:aluminium foil bag/fiber can/plastic drum Application:comp

1-Propene,2-chloro-3,3,3-trifluoro-

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

2-Chloro-3,3,3-trifluoropropene

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

2-chloro-3,3,3-trifluoroprop-1-ene CAS No.2730-62-3

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-Chloro-3,3,3-trifluoropropene cas 2730-62-3Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Chloro-3,3,3-trifluoropropene cas 2730-62-3

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Newgreat Chemical Co., Ltd

Wuhan Xinweiye Chemical Co., Ltd. is mainly engaged in the process development and production of customized synthesis and pharmaceutical intermediates. We have professional researchers in organic synthesis, analytical chemistry and production process

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Cas:2730-62-3

Min.Order:0

Negotiable

Type:Other

inquiry

Synthetic route

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With potassium hydroxide; Aliquat 336 In water at 10 - 20℃; Product distribution / selectivity;97%
With alkali
With potassium hydroxide In ethanol at -10℃;
1,1,1,2,2-pentachloropropane
64240-29-5

1,1,1,2,2-pentachloropropane

1,1,1,3,3-pentachloropropane
23153-23-3

1,1,1,3,3-pentachloropropane

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride at 300℃; for 0.001h; Inert atmosphere;94.9%
1,1,1,2,3-pentachloro-propane
21700-31-2

1,1,1,2,3-pentachloro-propane

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride In water at 400℃; under 750.075 Torr; for 8h; Inert atmosphere;94.3%
With hydrogen fluoride; fluorinated Cr2O3 at 255℃;
With hydrogen fluoride; chromium(III) oxide at 255℃; under 915.2 Torr; for 0.00416667h; Industry scale;
2,2-dichloro-3,3,3-trifluoropropyl acetate
20411-85-2

2,2-dichloro-3,3,3-trifluoropropyl acetate

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With zinc In ethanol Heating;73%
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 132.1℃; under 6000.6 Torr; Product distribution / selectivity;72.6%
With hydrogen fluoride; diisopropylamine; chromium(III) oxide at 200 - 300℃; under 760.051 Torr; for 0.000569444 - 0.00277778h; Product distribution / selectivity;
With methoxyhydroquinone; hydrogen fluoride; chromium(III) oxide at 243 - 254℃; under 760.051 Torr; for 66.75h; Product distribution / selectivity;
1-Chloro-3,3,3-trifluoro-2-iodopropane

1-Chloro-3,3,3-trifluoro-2-iodopropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

1-chloro-3,3,3-trifluoropropene
2730-43-0

1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With fluorinated chromia at 200℃; Inert atmosphere;A 40%
B 60%
1,1,1,2,2-pentachloropropane
64240-29-5

1,1,1,2,2-pentachloropropane

1,1,1,3,3-pentachloropropane
23153-23-3

1,1,1,3,3-pentachloropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

trans-1,3,3,3-tetrafluoropropene
29118-24-9

trans-1,3,3,3-tetrafluoropropene

C

1-chloro-3,3,3-trifluoropropene
2730-43-0

1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride at 300℃; for 0.001h; Time; Inert atmosphere;A 29.6%
B 6.6%
C 60%
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2-chloro-1,1,1,2-tetrafluoropropane
421-73-8

2-chloro-1,1,1,2-tetrafluoropropane

C

1,1,1,2,3-pentafluoropropane
431-31-2

1,1,1,2,3-pentafluoropropane

D

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

E

1-chloro-2,3,3,3-tetrafluoropropane
151771-09-4

1-chloro-2,3,3,3-tetrafluoropropane

F

2-chloro-1,1,1,3-tetrafluoropropane
117970-90-8

2-chloro-1,1,1,3-tetrafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride; antimonypentachloride at 100 - 125℃; under 33082.7 - 39185.2 Torr; for 12h; Product distribution / selectivity;A n/a
B n/a
C 53%
D n/a
E n/a
F n/a
1,1,1,2,2-pentachloropropane
64240-29-5

1,1,1,2,2-pentachloropropane

1,1,1,3,3-pentachloropropane
23153-23-3

1,1,1,3,3-pentachloropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

1-chloro-3,3,3-trifluoropropene
2730-43-0

1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride at 250℃; for 0.00277778h; Temperature; Time; Inert atmosphere;A 50%
B 49.8%
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2-chloro-2,3,3-trifluoro-butane
374-06-1

2-chloro-2,3,3-trifluoro-butane

Conditions
ConditionsYield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 133.2℃; under 6000.6 Torr; Product distribution / selectivity;A 25.5%
B 6.6%
2,3-dichloro-3,3-difluoroprop-1-ene
2252-87-1

2,3-dichloro-3,3-difluoroprop-1-ene

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With antimony dichloride trifluoride; antimony(III) fluoride
With antimonypentachloride; antimony(III) fluoride at 170℃; for 4h;
2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

3,3,3-trifluoroprop-1-yne
661-54-1

3,3,3-trifluoroprop-1-yne

Conditions
ConditionsYield
With potassium hydroxide
2,3,3,3-tetrachloropropene
16500-91-7

2,3,3,3-tetrachloropropene

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
With antimony dichloride trifluoride; antimony(III) fluoride
6-chloro-5-trifluoromethyl-1,6-diazabicyclo<3.1.0>hexane
113036-02-5, 113085-26-0, 120575-10-2, 120575-11-3, 164714-23-2

6-chloro-5-trifluoromethyl-1,6-diazabicyclo<3.1.0>hexane

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
In Cyclohexane-d12 at 80℃; for 80h; Product distribution; Mechanism;
2,3-dichloro-3,3-difluoroprop-1-ene
2252-87-1

2,3-dichloro-3,3-difluoroprop-1-ene

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

antimony dichloride trifluoride

antimony dichloride trifluoride

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

Conditions
ConditionsYield
at 30℃;
2,3,3,3-tetrachloropropene
16500-91-7

2,3,3,3-tetrachloropropene

antimony(III) fluoride
7783-56-4

antimony(III) fluoride

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

antimony dichloride trifluoride

antimony dichloride trifluoride

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

potassium hydroxide

potassium hydroxide

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

3,3,3-trifluoroprop-1-yne
661-54-1

3,3,3-trifluoroprop-1-yne

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

(Z)-1-chloro-3,3,3-trifluoro-1-propene
99728-16-2

(Z)-1-chloro-3,3,3-trifluoro-1-propene

C

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

D

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

E

1,1,1,3,3-Pentafluoropropane
460-73-1

1,1,1,3,3-Pentafluoropropane

F

trans-1,3,3,3-tetrafluoropropene
29118-24-9

trans-1,3,3,3-tetrafluoropropene

G

(Z)-1,3,3,3-tetrafluoropropene
29118-25-0

(Z)-1,3,3,3-tetrafluoropropene

H

trans-1-chloro-3,3,3-trifluoropropene
102687-65-0

trans-1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; 2percentCo2O3/Cr2O3, fluorided at 325 - 400℃; Product distribution / selectivity;
2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

C

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

D

1,1,1,3,3-Pentafluoropropane
460-73-1

1,1,1,3,3-Pentafluoropropane

E

trans-1,3,3,3-tetrafluoropropene
29118-24-9

trans-1,3,3,3-tetrafluoropropene

F

(Z)-1,3,3,3-tetrafluoropropene
29118-25-0

(Z)-1,3,3,3-tetrafluoropropene

G

2-chloro-1,1,1,3-tetrafluoropropane
117970-90-8

2-chloro-1,1,1,3-tetrafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride; 2percentCo2O3/Cr2O3, fluorided at 275℃; Product distribution / selectivity;
2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

C

2-chloro-1,1,1,3-tetrafluoropropane
117970-90-8

2-chloro-1,1,1,3-tetrafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride at 140℃; Gas phase;
With hydrogen fluoride at 140℃; Inert atmosphere;
1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

(Z)-1-chloro-3,3,3-trifluoro-1-propene
99728-16-2

(Z)-1-chloro-3,3,3-trifluoro-1-propene

C

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

D

(Z)-1,2-dichloro-3,3,3-trifluoropropene
25062-10-6

(Z)-1,2-dichloro-3,3,3-trifluoropropene

E

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

F

1,1,1,3,3-Pentafluoropropane
460-73-1

1,1,1,3,3-Pentafluoropropane

G

trans-1,3,3,3-tetrafluoropropene
29118-24-9

trans-1,3,3,3-tetrafluoropropene

H

trans-1,2-dichloro-3,3,3-trifluoropropene
25062-11-7

trans-1,2-dichloro-3,3,3-trifluoropropene

I

(Z)-1,3,3,3-tetrafluoropropene
29118-25-0

(Z)-1,3,3,3-tetrafluoropropene

J

CF3CClFCHF2

CF3CClFCHF2

K

trans-1-chloro-3,3,3-trifluoropropene
102687-65-0

trans-1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; chlorine; 2percentCo2O3/Cr2O3, fluorided at 350 - 375℃; Product distribution / selectivity;
1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

(Z)-1-chloro-3,3,3-trifluoro-1-propene
99728-16-2

(Z)-1-chloro-3,3,3-trifluoro-1-propene

C

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

D

(Z)-1,2-dichloro-3,3,3-trifluoropropene
25062-10-6

(Z)-1,2-dichloro-3,3,3-trifluoropropene

E

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

F

1,1,1,3,3-Pentafluoropropane
460-73-1

1,1,1,3,3-Pentafluoropropane

G

trans-1,3,3,3-tetrafluoropropene
29118-24-9

trans-1,3,3,3-tetrafluoropropene

H

trans-1,2-dichloro-3,3,3-trifluoropropene
25062-11-7

trans-1,2-dichloro-3,3,3-trifluoropropene

I

(Z)-1,3,3,3-tetrafluoropropene
29118-25-0

(Z)-1,3,3,3-tetrafluoropropene

J

trans-1-chloro-3,3,3-trifluoropropene
102687-65-0

trans-1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; chlorine; 2percentCo2O3/Cr2O3, fluorided at 300℃; Product distribution / selectivity;
1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

A

1,2,2-trichloro-3,3,3-trifluoropropane
7125-83-9

1,2,2-trichloro-3,3,3-trifluoropropane

B

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

C

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

D

(Z)-1-chloro-3,3,3-trifluoro-1-propene
99728-16-2

(Z)-1-chloro-3,3,3-trifluoro-1-propene

E

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

F

(Z)-1,2-dichloro-3,3,3-trifluoropropene
25062-10-6

(Z)-1,2-dichloro-3,3,3-trifluoropropene

G

trans-1,2-dichloro-3,3,3-trifluoropropene
25062-11-7

trans-1,2-dichloro-3,3,3-trifluoropropene

H

2-chloro-1,1,1,3-tetrafluoropropane
117970-90-8

2-chloro-1,1,1,3-tetrafluoropropane

I

trans-1-chloro-3,3,3-trifluoropropene
102687-65-0

trans-1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; chlorine at 140℃; Gas phase;
1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

A

1,2,2-trichloro-3,3,3-trifluoropropane
7125-83-9

1,2,2-trichloro-3,3,3-trifluoropropane

B

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

C

2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

D

(Z)-1-chloro-3,3,3-trifluoro-1-propene
99728-16-2

(Z)-1-chloro-3,3,3-trifluoro-1-propene

E

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

F

2-chloro-1,1,1,3-tetrafluoropropane
117970-90-8

2-chloro-1,1,1,3-tetrafluoropropane

G

trans-1-chloro-3,3,3-trifluoropropene
102687-65-0

trans-1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With hydrogen fluoride; chlorine at 140℃; Gas phase;
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

1,2-dichloro-3,3,3-trifluoropropene
431-27-6

1,2-dichloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
Stage #1: 1,1,2,3-Tetrachloropropene With hydrogen fluoride; chromium(III) oxide at 350℃; under 2311.54 Torr; for 0.00177778h;
Stage #2: FeCl3/C at 180℃; under 2311.54 Torr; for 0.00244444h; Product distribution / selectivity;
With fluorinated Cr2O3 at 260℃; for 0.005h; Inert atmosphere; Gas phase;
With hydrogen fluoride at 260℃; under 760.051 Torr; for 0.005h; Catalytic behavior;
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2-chloro-1,1,1,2-tetrafluoropropane
421-73-8

2-chloro-1,1,1,2-tetrafluoropropane

C

1,2-dichloro-3,3,3-trifluoropropene
431-27-6

1,2-dichloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
Stage #1: 1,1,2,3-Tetrachloropropene With hydrogen fluoride; 4-methoxy-phenol; chromium(III) oxide at 350℃; under 1794.37 Torr; for 0.00177778h;
Stage #2: FeCl3/C at 180℃; under 1794.37 Torr; for 0.00244444h; Product distribution / selectivity;
2-chloro-1,1,1,2-tetrafluoropropane
421-73-8

2-chloro-1,1,1,2-tetrafluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

Conditions
ConditionsYield
magnesium fluoride at 450 - 530℃; under 760.051 Torr; for 1 - 14h; Product distribution / selectivity;
iron(III) trifluoride at 350 - 385℃; under 760.051 Torr; for 1 - 2h; Product distribution / selectivity;
chromium oxide, fluorinated at 250 - 317℃; under 760.051 Torr; for 1 - 2h; Product distribution / selectivity;
1,1,2,3-Tetrachloropropene
10436-39-2

1,1,2,3-Tetrachloropropene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2-chloro-1,1,1,2-tetrafluoropropane
421-73-8

2-chloro-1,1,1,2-tetrafluoropropane

C

2,3,3,3-tetrafluoro-propene
754-12-1

2,3,3,3-tetrafluoro-propene

D

1,1,1,2,2-pentafluoropropane
1814-88-6

1,1,1,2,2-pentafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride at 100 - 120℃; under 16274.9 Torr; for 5h; Product distribution / selectivity;
2,3-dichloro-1,1,1-trifluoropropane
338-75-0

2,3-dichloro-1,1,1-trifluoropropane

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

2-chloro-1,1,1,2-tetrafluoropropane
421-73-8

2-chloro-1,1,1,2-tetrafluoropropane

Conditions
ConditionsYield
With hydrogen fluoride; activated by HF Zn/chromia catalyst at 100 - 340℃;A 70 %Chromat.
B 10 %Chromat.
1,1,1-trifluoropropylene
677-21-4

1,1,1-trifluoropropylene

A

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

B

1-chloro-3,3,3-trifluoropropene
2730-43-0

1-chloro-3,3,3-trifluoropropene

Conditions
ConditionsYield
With chlorine; activated carbon catalyst at 250℃; under 760.051 Torr; Product distribution / selectivity; Inert atmosphere;
With chlorine; pyrographite at 250℃; under 760.051 Torr; Inert atmosphere;
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine
93102-05-7

N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

1-benzyl-3-chloro-3-(trifluoromethyl)pyrrolidine

1-benzyl-3-chloro-3-(trifluoromethyl)pyrrolidine

Conditions
ConditionsYield
With trifluoroacetic acid In tetrahydrofuran at 0℃; for 2h;98%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

2,5-dichlorbenzenethiol
5858-18-4

2,5-dichlorbenzenethiol

(Z)-(2,5-dichlorophenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

(Z)-(2,5-dichlorophenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

Conditions
ConditionsYield
Stage #1: 2,5-dichlorbenzenethiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h;
Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;
97%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-methoxyphenylboronic acid
5720-07-0

4-methoxyphenylboronic acid

1-(1,1,1-trifluoroprop-2-en-2-yl)-4-methoxybenzene
69843-08-9

1-(1,1,1-trifluoroprop-2-en-2-yl)-4-methoxybenzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Catalytic behavior; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Autoclave;95%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-hydroxy-benzaldehyde
123-08-0

4-hydroxy-benzaldehyde

(Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzaldehyde

(Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzaldehyde

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;93%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

[4-(benzyloxy)phenyl]boronic acid
146631-00-7

[4-(benzyloxy)phenyl]boronic acid

1-(benzyloxy)-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

1-(benzyloxy)-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;91%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

3,4-(methylenedioxy)-benzeneboronic acid
94839-07-3

3,4-(methylenedioxy)-benzeneboronic acid

5-(1,1,1-trifluoroprop-2-en-2-yl)benzo[d][1,3]dioxole

5-(1,1,1-trifluoroprop-2-en-2-yl)benzo[d][1,3]dioxole

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;89%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

m-cyanophenol
873-62-1

m-cyanophenol

(Z)-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzonitrile

(Z)-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzonitrile

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;89%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

3,4-Dimethoxyphenylboronic acid
122775-35-3

3,4-Dimethoxyphenylboronic acid

1,2-dimethoxy-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

1,2-dimethoxy-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;88%
O-methylresorcine
150-19-6

O-methylresorcine

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-1-methoxy-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-methoxy-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;88%
4-Fluorophenol
371-41-5

4-Fluorophenol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-fluorophenyl 3,3,3-trifluoropropen-2-yl ether

4-fluorophenyl 3,3,3-trifluoropropen-2-yl ether

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 70 - 90℃; for 8h;87%
4-methylpyridine-2-thiol
18368-65-5

4-methylpyridine-2-thiol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-4-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)thio)pyridine

(Z)-4-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)thio)pyridine

Conditions
ConditionsYield
Stage #1: 4-methylpyridine-2-thiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h;
Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;
86%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

3-methoxyphenylboronic acid
10365-98-7

3-methoxyphenylboronic acid

1-methoxy-3-(1,1,1-trifluoroprop-2-en-2-yl)benzene
946614-13-7

1-methoxy-3-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;85%
4-bromo-phenol
106-41-2

4-bromo-phenol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-1-bromo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-bromo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;85%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

[3-(methoxycarbonyl)phenyl]boronic acid
99769-19-4

[3-(methoxycarbonyl)phenyl]boronic acid

methyl 3-(1,1,1-trifluoroprop-2-en-2-yl)benzoate

methyl 3-(1,1,1-trifluoroprop-2-en-2-yl)benzoate

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;84%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

2-methoxy-phenol
90-05-1

2-methoxy-phenol

(Z)-1-methoxy-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-methoxy-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;84%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-Iodophenol
540-38-5

4-Iodophenol

(Z)-1-iodo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-iodo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;84%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-biphenylboronic acid
5122-94-1

4-biphenylboronic acid

4-(3,3,3-trifluoroprop-1-en-2-yl)-1,1’-biphenyl
1601477-35-3

4-(3,3,3-trifluoroprop-1-en-2-yl)-1,1’-biphenyl

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;83%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

β-naphthol
135-19-3

β-naphthol

(Z)-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)naphthalene

(Z)-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)naphthalene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;83%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

ortho-cresol
95-48-7

ortho-cresol

(Z)-1-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;83%
4-Isopropylphenol
99-89-8

4-Isopropylphenol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-1-isopropyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-isopropyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;83%
4-Methoxybenzenethiol
696-63-9

4-Methoxybenzenethiol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

A

(4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

(4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

B

(4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

(4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

Conditions
ConditionsYield
Stage #1: 4-Methoxybenzenethiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h;
Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;
A 83%
B 13%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-formylphenylboronic acid,
87199-17-5

4-formylphenylboronic acid,

4-(1,1,1-trifluoroprop-2-en-2-yl)benzaldehyde

4-(1,1,1-trifluoroprop-2-en-2-yl)benzaldehyde

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;82%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

4-amino-phenol
123-30-8

4-amino-phenol

(Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)aniline

(Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)aniline

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;82%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(4-isopropylphenyl)boronic acid
16152-51-5

(4-isopropylphenyl)boronic acid

1-isopropyl-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

1-isopropyl-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;81%
2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

phenol
108-95-2

phenol

(Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene
117971-12-7

(Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;81%
p-cresol
106-44-5

p-cresol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-1-methyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-methyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;81%
4-Ethylphenol
123-07-9

4-Ethylphenol

2-chloro-1,1,1-trifluoropropene
2730-62-3

2-chloro-1,1,1-trifluoropropene

(Z)-1-ethyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

(Z)-1-ethyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions
ConditionsYield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;80%

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