2-Chloro-3,3,3-trifluoropropene supplier

Name
2-CHLORO-3,3,3-TRIFLUOROPROPENE
EINECS
CAS No. 2730-62-3
Article Data90
CAS DataBase
Density 1.295 g/cm³
Solubility
Melting Point
Formula C₃H₂ClF₃
Boiling Point 27.7 °C at 760 mmHg
Molecular Weight 130.497
Flash Point -16∶C
Transport Information
Appearance
Safety S23; S38
Risk Codes
Molecular Structure
Hazard Symbols Xi
Synonyms Propene,2-chloro-3,3,3-trifluoro- (6CI,8CI);2-Chloro-3,3,3-trifluoro-1-propene;2-Chloro-3,3,3-trifluoropropene;
PSA 0.00000
LogP 2.30120

Synthetic route

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With potassium hydroxide; Aliquat 336 In water at 10 - 20℃; Product distribution / selectivity;	97%
With alkali
With potassium hydroxide In ethanol at -10℃;

: 64240-29-5
1,1,1,2,2-pentachloropropane

: 23153-23-3
1,1,1,3,3-pentachloropropane

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride at 300℃; for 0.001h; Inert atmosphere;	94.9%

: 21700-31-2
1,1,1,2,3-pentachloro-propane

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride In water at 400℃; under 750.075 Torr; for 8h; Inert atmosphere;	94.3%
With hydrogen fluoride; fluorinated Cr2O3 at 255℃;
With hydrogen fluoride; chromium(III) oxide at 255℃; under 915.2 Torr; for 0.00416667h; Industry scale;

: 20411-85-2
2,2-dichloro-3,3,3-trifluoropropyl acetate

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With zinc In ethanol Heating;	73%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 132.1℃; under 6000.6 Torr; Product distribution / selectivity;	72.6%
With hydrogen fluoride; diisopropylamine; chromium(III) oxide at 200 - 300℃; under 760.051 Torr; for 0.000569444 - 0.00277778h; Product distribution / selectivity;
With methoxyhydroquinone; hydrogen fluoride; chromium(III) oxide at 243 - 254℃; under 760.051 Torr; for 66.75h; Product distribution / selectivity;

: 1-Chloro-3,3,3-trifluoro-2-iodopropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 2730-43-0
1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With fluorinated chromia at 200℃; Inert atmosphere;	A 40% B 60%

: 64240-29-5
1,1,1,2,2-pentachloropropane

: 23153-23-3
1,1,1,3,3-pentachloropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 29118-24-9
trans-1,3,3,3-tetrafluoropropene

C: 2730-43-0
1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride at 300℃; for 0.001h; Time; Inert atmosphere;	A 29.6% B 6.6% C 60%

...Expand

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

C: 431-31-2
1,1,1,2,3-pentafluoropropane

D: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

E: 151771-09-4
1-chloro-2,3,3,3-tetrafluoropropane

F: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride at 100 - 125℃; under 33082.7 - 39185.2 Torr; for 12h; Product distribution / selectivity;	A n/a B n/a C 53% D n/a E n/a F n/a

...Expand

: 64240-29-5
1,1,1,2,2-pentachloropropane

: 23153-23-3
1,1,1,3,3-pentachloropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 2730-43-0
1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride at 250℃; for 0.00277778h; Temperature; Time; Inert atmosphere;	A 50% B 49.8%

...Expand

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 374-06-1
2-chloro-2,3,3-trifluoro-butane

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 133.2℃; under 6000.6 Torr; Product distribution / selectivity;	A 25.5% B 6.6%

: 2252-87-1
2,3-dichloro-3,3-difluoroprop-1-ene

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With antimony dichloride trifluoride; antimony(III) fluoride
With antimonypentachloride; antimony(III) fluoride at 170℃; for 4h;

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 661-54-1
3,3,3-trifluoroprop-1-yne

Conditions

Conditions	Yield
With potassium hydroxide

: 16500-91-7
2,3,3,3-tetrachloropropene

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With antimony dichloride trifluoride; antimony(III) fluoride

: 113036-02-5, 113085-26-0, 120575-10-2, 120575-11-3, 164714-23-2
6-chloro-5-trifluoromethyl-1,6-diazabicyclo<3.1.0>hexane

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
In Cyclohexane-d12 at 80℃; for 80h; Product distribution; Mechanism;

: 2252-87-1
2,3-dichloro-3,3-difluoroprop-1-ene

: 7783-56-4
antimony(III) fluoride

antimony dichloride trifluoride: antimony dichloride trifluoride

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
at 30℃;

...Expand

: 16500-91-7
2,3,3,3-tetrachloropropene

: 7783-56-4
antimony(III) fluoride

: 107-06-2
1,2-dichloro-ethane

antimony dichloride trifluoride: antimony dichloride trifluoride

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

...Expand

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

potassium hydroxide: potassium hydroxide

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 661-54-1
3,3,3-trifluoroprop-1-yne

...Expand

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 99728-16-2
(Z)-1-chloro-3,3,3-trifluoro-1-propene

C: 754-12-1
2,3,3,3-tetrafluoro-propene

D: 1814-88-6
1,1,1,2,2-pentafluoropropane

E: 460-73-1
1,1,1,3,3-Pentafluoropropane

F: 29118-24-9
trans-1,3,3,3-tetrafluoropropene

G: 29118-25-0
(Z)-1,3,3,3-tetrafluoropropene

H: 102687-65-0
trans-1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; 2percentCo2O3/Cr2O3, fluorided at 325 - 400℃; Product distribution / selectivity;

...Expand

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 754-12-1
2,3,3,3-tetrafluoro-propene

C: 1814-88-6
1,1,1,2,2-pentafluoropropane

D: 460-73-1
1,1,1,3,3-Pentafluoropropane

E: 29118-24-9
trans-1,3,3,3-tetrafluoropropene

F: 29118-25-0
(Z)-1,3,3,3-tetrafluoropropene

G: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride; 2percentCo2O3/Cr2O3, fluorided at 275℃; Product distribution / selectivity;

...Expand

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 677-21-4
1,1,1-trifluoropropylene

C: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride at 140℃; Gas phase;
With hydrogen fluoride at 140℃; Inert atmosphere;

...Expand

: 677-21-4
1,1,1-trifluoropropylene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 99728-16-2
(Z)-1-chloro-3,3,3-trifluoro-1-propene

C: 754-12-1
2,3,3,3-tetrafluoro-propene

D: 25062-10-6
(Z)-1,2-dichloro-3,3,3-trifluoropropene

E: 1814-88-6
1,1,1,2,2-pentafluoropropane

F: 460-73-1
1,1,1,3,3-Pentafluoropropane

G: 29118-24-9
trans-1,3,3,3-tetrafluoropropene

H: 25062-11-7
trans-1,2-dichloro-3,3,3-trifluoropropene

I: 29118-25-0
(Z)-1,3,3,3-tetrafluoropropene

J: CF3CClFCHF2

K: 102687-65-0
trans-1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; chlorine; 2percentCo2O3/Cr2O3, fluorided at 350 - 375℃; Product distribution / selectivity;

...Expand

: 677-21-4
1,1,1-trifluoropropylene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 99728-16-2
(Z)-1-chloro-3,3,3-trifluoro-1-propene

C: 754-12-1
2,3,3,3-tetrafluoro-propene

D: 25062-10-6
(Z)-1,2-dichloro-3,3,3-trifluoropropene

E: 1814-88-6
1,1,1,2,2-pentafluoropropane

F: 460-73-1
1,1,1,3,3-Pentafluoropropane

G: 29118-24-9
trans-1,3,3,3-tetrafluoropropene

H: 25062-11-7
trans-1,2-dichloro-3,3,3-trifluoropropene

I: 29118-25-0
(Z)-1,3,3,3-tetrafluoropropene

J: 102687-65-0
trans-1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; chlorine; 2percentCo2O3/Cr2O3, fluorided at 300℃; Product distribution / selectivity;

...Expand

: 677-21-4
1,1,1-trifluoropropylene

A: 7125-83-9
1,2,2-trichloro-3,3,3-trifluoropropane

B: 2730-62-3
2-chloro-1,1,1-trifluoropropene

C: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

D: 99728-16-2
(Z)-1-chloro-3,3,3-trifluoro-1-propene

E: 754-12-1
2,3,3,3-tetrafluoro-propene

F: 25062-10-6
(Z)-1,2-dichloro-3,3,3-trifluoropropene

G: 25062-11-7
trans-1,2-dichloro-3,3,3-trifluoropropene

H: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

I: 102687-65-0
trans-1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; chlorine at 140℃; Gas phase;

...Expand

: 677-21-4
1,1,1-trifluoropropylene

A: 7125-83-9
1,2,2-trichloro-3,3,3-trifluoropropane

B: 2730-62-3
2-chloro-1,1,1-trifluoropropene

C: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

D: 99728-16-2
(Z)-1-chloro-3,3,3-trifluoro-1-propene

E: 754-12-1
2,3,3,3-tetrafluoro-propene

F: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

G: 102687-65-0
trans-1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; chlorine at 140℃; Gas phase;

...Expand

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 431-27-6
1,2-dichloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
Stage #1: 1,1,2,3-Tetrachloropropene With hydrogen fluoride; chromium(III) oxide at 350℃; under 2311.54 Torr; for 0.00177778h; Stage #2: FeCl3/C at 180℃; under 2311.54 Torr; for 0.00244444h; Product distribution / selectivity;
With fluorinated Cr2O3 at 260℃; for 0.005h; Inert atmosphere; Gas phase;
With hydrogen fluoride at 260℃; under 760.051 Torr; for 0.005h; Catalytic behavior;

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

C: 431-27-6
1,2-dichloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
Stage #1: 1,1,2,3-Tetrachloropropene With hydrogen fluoride; 4-methoxy-phenol; chromium(III) oxide at 350℃; under 1794.37 Torr; for 0.00177778h; Stage #2: FeCl3/C at 180℃; under 1794.37 Torr; for 0.00244444h; Product distribution / selectivity;

...Expand

: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 754-12-1
2,3,3,3-tetrafluoro-propene

Conditions

Conditions	Yield
magnesium fluoride at 450 - 530℃; under 760.051 Torr; for 1 - 14h; Product distribution / selectivity;
iron(III) trifluoride at 350 - 385℃; under 760.051 Torr; for 1 - 2h; Product distribution / selectivity;
chromium oxide, fluorinated at 250 - 317℃; under 760.051 Torr; for 1 - 2h; Product distribution / selectivity;

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

C: 754-12-1
2,3,3,3-tetrafluoro-propene

D: 1814-88-6
1,1,1,2,2-pentafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride at 100 - 120℃; under 16274.9 Torr; for 5h; Product distribution / selectivity;

...Expand

: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride; activated by HF Zn/chromia catalyst at 100 - 340℃;	A 70 %Chromat. B 10 %Chromat.

: 677-21-4
1,1,1-trifluoropropylene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 2730-43-0
1-chloro-3,3,3-trifluoropropene

Conditions

Conditions	Yield
With chlorine; activated carbon catalyst at 250℃; under 760.051 Torr; Product distribution / selectivity; Inert atmosphere;
With chlorine; pyrographite at 250℃; under 760.051 Torr; Inert atmosphere;

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 93102-05-7
N-benzyl-N-(methoxymethyl)-N-[(trimethylsilyl)methyl]amine

: 1-benzyl-3-chloro-3-(trifluoromethyl)pyrrolidine

Conditions

Conditions	Yield
With trifluoroacetic acid In tetrahydrofuran at 0℃; for 2h;	98%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 5858-18-4
2,5-dichlorbenzenethiol

: (Z)-(2,5-dichlorophenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

Conditions

Conditions	Yield
Stage #1: 2,5-dichlorbenzenethiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h; Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;	97%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 5720-07-0
4-methoxyphenylboronic acid

: 69843-08-9
1-(1,1,1-trifluoroprop-2-en-2-yl)-4-methoxybenzene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Catalytic behavior; Reagent/catalyst; Solvent; Suzuki-Miyaura Coupling; Autoclave;	95%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 123-08-0
4-hydroxy-benzaldehyde

: (Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzaldehyde

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	93%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 146631-00-7
[4-(benzyloxy)phenyl]boronic acid

: 1-(benzyloxy)-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	91%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 94839-07-3
3,4-(methylenedioxy)-benzeneboronic acid

: 5-(1,1,1-trifluoroprop-2-en-2-yl)benzo[d][1,3]dioxole

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	89%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 873-62-1
m-cyanophenol

: (Z)-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzonitrile

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	89%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 122775-35-3
3,4-Dimethoxyphenylboronic acid

: 1,2-dimethoxy-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	88%

: 150-19-6
O-methylresorcine

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-1-methoxy-3-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	88%

: 371-41-5
4-Fluorophenol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 4-fluorophenyl 3,3,3-trifluoropropen-2-yl ether

Conditions

Conditions	Yield
With potassium carbonate In dimethyl sulfoxide at 70 - 90℃; for 8h;	87%

: 18368-65-5
4-methylpyridine-2-thiol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-4-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)thio)pyridine

Conditions

Conditions	Yield
Stage #1: 4-methylpyridine-2-thiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h; Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;	86%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 10365-98-7
3-methoxyphenylboronic acid

: 946614-13-7
1-methoxy-3-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	85%

: 106-41-2
4-bromo-phenol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-1-bromo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	85%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 99769-19-4
[3-(methoxycarbonyl)phenyl]boronic acid

: methyl 3-(1,1,1-trifluoroprop-2-en-2-yl)benzoate

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	84%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 90-05-1
2-methoxy-phenol

: (Z)-1-methoxy-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	84%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 540-38-5
4-Iodophenol

: (Z)-1-iodo-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	84%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 5122-94-1
4-biphenylboronic acid

: 1601477-35-3
4-(3,3,3-trifluoroprop-1-en-2-yl)-1,1’-biphenyl

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	83%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 135-19-3
β-naphthol

: (Z)-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)naphthalene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	83%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 95-48-7
ortho-cresol

: (Z)-1-methyl-2-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	83%

: 99-89-8
4-Isopropylphenol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-1-isopropyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	83%

: 696-63-9
4-Methoxybenzenethiol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

A: (4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

B: (4-methoxyphenyl)(3,3,3-trifluoroprop-1-en-1-yl)sulfane

Conditions

Conditions	Yield
Stage #1: 4-Methoxybenzenethiol With potassium hydroxide In isopropyl alcohol at 20℃; for 0.166667h; Stage #2: 2-chloro-1,1,1-trifluoropropene With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone In isopropyl alcohol at 50℃; for 4h; stereoselective reaction;	A 83% B 13%

...Expand

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 87199-17-5
4-formylphenylboronic acid,

: 4-(1,1,1-trifluoroprop-2-en-2-yl)benzaldehyde

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	82%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 123-30-8
4-amino-phenol

: (Z)-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)aniline

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	82%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 16152-51-5
(4-isopropylphenyl)boronic acid

: 1-isopropyl-4-(1,1,1-trifluoroprop-2-en-2-yl)benzene

Conditions

Conditions	Yield
With bis-triphenylphosphine-palladium(II) chloride; sodium hydrogencarbonate; 2-(dicyclohexylphosphino)-1-(2-methoxyphenyl)-1H-pyrrole In 1,4-dioxane; water at -100 - 100℃; for 5h; Suzuki-Miyaura Coupling; Autoclave;	81%

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: 108-95-2
phenol

: 117971-12-7
(Z)-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	81%

: 106-44-5
p-cresol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-1-methyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	81%

: 123-07-9
4-Ethylphenol

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

: (Z)-1-ethyl-4-((3,3,3-trifluoroprop-1-en-1-yl)oxy)benzene

Conditions

Conditions	Yield
With potassium phosphate tribasic heptahydrate In N,N-dimethyl-formamide at -100 - 100℃; for 5h; Autoclave; Sealed tube;	80%

2-Chloro-3,3,3-trifluoropropene Chemical Properties

Molecular Structure of 1-Propene,2-chloro-3,3,3-trifluoro- (CAS NO.2730-62-3):

Empirical Formula: C₃H₂ClF₃
Molecular Weight: 130.4962
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å²
Index of Refraction: 1.334
Molar Refractivity: 20.82 cm³
Molar Volume: 100.7 cm³Surface Tension: 15.1 dyne/cm
Density: 1.295 g/cm³
Enthalpy of Vaporization: 26.23 kJ/mol
Boiling Point: 27.7 °C at 760 mmHg
Vapour Pressure: 690 mmHg at 25°C
SMILES: Cl/C(=C)C(F)(F)F
InChI: InChI=1/C3H2ClF3/c1-2(4)3(5,6)7/h1H2

2-Chloro-3,3,3-trifluoropropene Safety Profile

Hazard Codes: Xi
Safety Statements: 23-38
S23:Do not breathe vapour.
S38:In case of insufficient ventilation, wear suitable respiratory equipment.
RIDADR: 3163
Hazard Note: Irritant
HazardClass: GAS

2-Chloro-3,3,3-trifluoropropene Specification

1-Propene,2-chloro-3,3,3-trifluoro- , with CAS number of 2730-62-3, can be called 1-propene, 2-chloro-3,3,3-trifluoro- ; 2-Chloro-3,3,3-trifluoro-1-propene ; 2-Chloro-3,3,3-trifluoroprop-1-ene .

Product Name

2-CHLORO-3,3,3-TRIFLUOROPROPENE

Synthetic route

2-Chloro-3,3,3-trifluoropropene Chemical Properties

2-Chloro-3,3,3-trifluoropropene Safety Profile

2-Chloro-3,3,3-trifluoropropene Specification

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