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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Bromo-9H-carbazole CAS number 3652-89-9 Assay ≥99% Appearance White powder Capacity 50mt/year Application OLED/pharmaceutical/pesticide in

4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:100 Gram

FOB Price: $34.0

Type:Lab/Research institutions

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Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co., LTD is a professional research, development and production 2-phenylacetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low carbon environ

4-Bromo-9H-carbazole CAS NO.3652-89-9

Cas:3652-89-9

Min.Order:100 Gram

FOB Price: $2.0

Type:Manufacturers

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Henan Allgreen Chemical Co.,Ltd

high quality Appearance:White or off-white Solid Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:OLED Intermediate Transportation:by air or by sea Port:Shanghai, Qingdao

4-BroMo-9H-carbazole 3652-89-9

Cas:3652-89-9

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 3652-89-9 9H-Carbazole,4-bromo- Manufacturer

Cas:3652-89-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Ality Chemical Corporation

4-BroMo-9H-carbazole Basic information Product Name: 4-BroMo-9H-carbazole Synonyms: 4-BroMo-9H-carbazole;4-broMocarbazole;4-BroMo-9H-carbazole (4BC);9H-Carbazole, 4-broMo-;Carb;1-CYCLOPROPYL-2,6-PIPERAZINEDIONE;Carbazole, 4-bromo-;4-Bromocarbaz

Factory Supply 4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:1 Gram

Negotiable

Type:Other

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

high purity 4-Bromo-9H-carbazole for sale factory

Cas:3652-89-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

4-Bromo-9h-Carbazole CAS 3652-89-9

Cas:3652-89-9

Min.Order:1 Kilogram

FOB Price: $3.0 / 10.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 3652-89-9 with best quality

Cas:3652-89-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name 4-BroMo-9H-carbazole CAS No. 3652-89-9 EINECS N/A MF C12H8BrN MW 246.10 MP 104-105℃ Storage temp.

4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

9H-Carbazole, 4-bromo- 3652-89-9

Cas:3652-89-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

4-BroMo-9H-carbazole CAS: 3652-89-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

4-BroMo-9H-carbazole CAS: 3652-89-9

Cas:3652-89-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

9H-Carbazole, 4-bromo-

Cas:3652-89-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Changchun Artel lmport and Export trade company

best price,best quality and fast delivery assurance available in sample product and customization with years of export experience along with excellent quality, advanced services and competitive prices the quality of products conform u

4-bromo-9H-carbazole CAS NO.3652-89-9

Cas:3652-89-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

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Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi

OLED material intermediate 4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists

4-bromocarbazole 3652-89-9 3652-89-9

Cas:3652-89-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

9H-Carbazole, 4-bromo-

Cas:3652-89-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesis.

Best price High quality 4-BroMo-9H-carbazole 3652-89-9

Cas:3652-89-9

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Triumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Service 1.Own made fine chemical products 2.Out sourcing and qua

4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-Bromo-9H-Carbazole

Cas:3652-89-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:1 Gram

Negotiable

Type:Other

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Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products 4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

Fast Delivery 3652-89-9 reasonable price 4-Bromo-9H-carbazole supplier Molecular Formula C12H8BrN Molar Mass 246.1 Density 1.617±0.06 g/cm3 (20 ºC 760 Torr) Melting Point 104-105℃

Fast Delivery 3652-89-9 reasonable price 4-Bromo-9H-carbazole supplier

Cas:3652-89-9

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

4-BroMo-9H-carbazole/High quality/Best price

Cas:3652-89-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

4-Bromo-9H-carbazole

Cas:3652-89-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Bromo-9H-carbazole Manufacturer/High quality/Best price/In stock

Cas:3652-89-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Trading Company

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4-BroMo-9H-carbazole

Cas:3652-89-9

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Synthetic route

C12H9Br2N

C12H9Br2N

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine at 150℃; for 3h; Temperature; Reagent/catalyst; Inert atmosphere;94.6%
1,3-dibromobenzene
108-36-1

1,3-dibromobenzene

2-bromoaniline
615-36-1

2-bromoaniline

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With palladium diacetate; sodium t-butanolate; XPhos at 130℃; for 24h; Temperature; Suzuki Coupling; Inert atmosphere;92.5%
2-bromo-2′-nitro-1,1′-biphenyl
17613-47-7

2-bromo-2′-nitro-1,1′-biphenyl

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With triphenylphosphine In 1,2-dichloro-benzene for 12h; Reflux;87%
With triphenylphosphine In 1,2-dichloro-benzene at 170℃; for 12h; Inert atmosphere;87%
With triphenylphosphine In 1,2-dichloro-benzene at 180℃; for 18h; Inert atmosphere;86%
4-Nitro-9H-carbazole
57905-76-7

4-Nitro-9H-carbazole

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Stage #1: 4-Nitro-9H-carbazole With acetic acid; zinc In ethanol; water at 40℃; for 2h; Inert atmosphere;
Stage #2: With hydrogen bromide; sodium nitrite In water for 0.5h; Cooling with ice;
Stage #3: With copper(I) bromide In water for 2h;
72%
Stage #1: 4-Nitro-9H-carbazole With acetic acid; zinc In ethanol; water at 40℃; for 2h; Inert atmosphere;
Stage #2: With hydrogen bromide In ethanol; water for 0.5h; Inert atmosphere; Further stages;
72%
2'-bromo-6'-nitro-1,2-dihydro-1,1'-biphenyl

2'-bromo-6'-nitro-1,2-dihydro-1,1'-biphenyl

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With triphenylphosphine In 1,2-dichloro-benzene for 24h; Reflux;60%
With triphenylphosphine In 1,2-dichloro-benzene for 24h; Reflux;
With triethyl phosphite at 160 - 165℃; for 14h;
C12H8BrN3

C12H8BrN3

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With water; palladium diacetate at 110℃; Microwave irradiation;52%
With tetrabutylammonium tricarbonylnitrosylferrate In 1,2-dichloro-ethane at 100℃; for 1h; Inert atmosphere; Schlenk technique; Microwave irradiation;37%
5-bromo-1,2,3,4-tetrahydrocarbazole
78863-98-6

5-bromo-1,2,3,4-tetrahydrocarbazole

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With chloranil; xylene
cyclohexanone
108-94-1

cyclohexanone

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous sulfuric acid
2: tetrachloro-<1,4>benzoquinone; xylene
View Scheme
3-bromophenylhydrazine
40887-80-7

3-bromophenylhydrazine

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: aqueous sulfuric acid
2: tetrachloro-<1,4>benzoquinone; xylene
View Scheme
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: palladium diacetate; potassium carbonate; triphenylphosphine / ethanol; water; toluene / 18 h / 100 °C / Inert atmosphere
2: triphenylphosphine / N,N-dimethyl acetamide / 14 h / 180 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 80 °C
2: triphenylphosphinepalladium / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / toluene; water / 8 h / 80 °C / Inert atmosphere
2: triphenylphosphine / 1,2-dichloro-benzene / 8 h / 180 °C / Inert atmosphere
View Scheme
(2-bromophenyl)boronic acid
244205-40-1

(2-bromophenyl)boronic acid

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: palladium diacetate; potassium carbonate; triphenylphosphine / ethanol; water; toluene / 18 h / 100 °C / Inert atmosphere
2: triphenylphosphine / N,N-dimethyl acetamide / 14 h / 180 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate / tetrakis(triphenylphosphine) palladium(0) / water; tetrahydrofuran / 80 °C
2: triphenylphosphinepalladium / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 12 h / Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / Reflux
View Scheme
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 12 h / Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / tetrahydrofuran; water / 12 h / 90 °C / Inert atmosphere
2: triphenylphosphine / 1,2-dichloro-benzene / 12 h / 170 °C / Inert atmosphere
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); potassium carbonate / tetrahydrofuran; water / 24 h / 95 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / 180 °C
View Scheme
2-bromoaniline
615-36-1

2-bromoaniline

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; water / 20 h / 95 °C / Inert atmosphere; Schlenk technique
2.1: sodium nitrite / water; acetic acid / 1 h / 0 °C / Inert atmosphere; Schlenk technique
2.2: 1 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
3.1: tetrabutylammonium tricarbonylnitrosylferrate / 1,2-dichloro-ethane / 1 h / 100 °C / Inert atmosphere; Schlenk technique; Microwave irradiation
View Scheme
2’-bromo-[1,1’-biphenyl]-2-amine
54147-91-0

2’-bromo-[1,1’-biphenyl]-2-amine

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: sodium nitrite / water; acetic acid / 1 h / 0 °C / Inert atmosphere; Schlenk technique
1.2: 1 h / 0 - 20 °C / Inert atmosphere; Schlenk technique
2.1: tetrabutylammonium tricarbonylnitrosylferrate / 1,2-dichloro-ethane / 1 h / 100 °C / Inert atmosphere; Schlenk technique; Microwave irradiation
View Scheme
Multi-step reaction with 2 steps
1.1: acetic acid; sodium nitrite / water / 2 h / 0 °C
1.2: 25 °C
2.1: water; palladium diacetate / 110 °C / Microwave irradiation
View Scheme
phenylboronic acid
98-80-6

phenylboronic acid

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 - 90 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 24 h / 80 °C
2: triethyl phosphite / 14 h / 160 - 165 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 - 90 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
1-bromo-2-iodo- 3-nitrobenzene
32337-96-5

1-bromo-2-iodo- 3-nitrobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 - 90 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 24 h / 80 °C
2: triethyl phosphite / 14 h / 160 - 165 °C
View Scheme
Multi-step reaction with 2 steps
1: tetrakis(triphenylphosphine) palladium(0); sodium hydroxide / tetrahydrofuran; water / 80 - 90 °C
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
2-iodophenylamine
615-43-0

2-iodophenylamine

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: sodium carbonate; palladium diacetate / ethylene glycol; water / 48 h / 90 °C
2.1: acetic acid; sodium nitrite / water / 2 h / 0 °C
2.2: 25 °C
3.1: water; palladium diacetate / 110 °C / Microwave irradiation
View Scheme
4-bromo-1,2,3,9-tetrahydrocarbazole

4-bromo-1,2,3,9-tetrahydrocarbazole

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
With chloranil at 110℃; for 4h; Concentration;40.2 g
aniline
62-53-3

aniline

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: magnesium oxide / toluene / 4 h / 110 °C / Inert atmosphere
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / N,N-dimethyl acetamide / 8 h / 80 °C
3: sodium tetrahydroborate / tetrahydrofuran / 2 h / 20 °C
4: hydrogen bromide; ferric(III) bromide / 4 h / 20 °C
5: chloranil / 4 h / 110 °C
View Scheme
Multi-step reaction with 3 steps
1.1: triethylamine / 8 h / Reflux
2.1: iron(III) chloride; pyrographite; hydrazine hydrate / ethanol / 6 h / 70 - 80 °C
3.1: sulfuric acid; acetic acid / 15 °C
3.2: 1 h / 15 - 20 °C
3.3: 2 h / Reflux
View Scheme
1,3-cylohexanedione
504-02-9

1,3-cylohexanedione

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: magnesium oxide / toluene / 4 h / 110 °C / Inert atmosphere
2: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / N,N-dimethyl acetamide / 8 h / 80 °C
3: sodium tetrahydroborate / tetrahydrofuran / 2 h / 20 °C
4: hydrogen bromide; ferric(III) bromide / 4 h / 20 °C
5: chloranil / 4 h / 110 °C
View Scheme
3-phenylaminocyclohex-2-enone
24706-50-1

3-phenylaminocyclohex-2-enone

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate / N,N-dimethyl acetamide / 8 h / 80 °C
2: sodium tetrahydroborate / tetrahydrofuran / 2 h / 20 °C
3: hydrogen bromide; ferric(III) bromide / 4 h / 20 °C
4: chloranil / 4 h / 110 °C
View Scheme
1,2,3,9-tetrahydro-4H-carbazol-4-one
15128-52-6

1,2,3,9-tetrahydro-4H-carbazol-4-one

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium tetrahydroborate / tetrahydrofuran / 2 h / 20 °C
2: hydrogen bromide; ferric(III) bromide / 4 h / 20 °C
3: chloranil / 4 h / 110 °C
View Scheme
1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene
190788-59-1

2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)nitrobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / water; toluene; 1,4-dioxane / 12 h / Reflux
2: triphenylphosphine / 1,2-dichloro-benzene / 24 h / Reflux
View Scheme
2-Chloronitrobenzene
88-73-3

2-Chloronitrobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: copper / 10 h / 200 °C
2.1: triethyl phosphite / 2 h / 150 °C
3.1: zinc; acetic acid / ethanol; water / 2 h / 40 °C / Inert atmosphere
3.2: 0.5 h / Cooling with ice
3.3: 2 h
View Scheme
Multi-step reaction with 3 steps
1.1: copper / 12 h / 200 °C
2.1: triethyl phosphite / 2 h / 160 °C / Inert atmosphere
3.1: zinc; acetic acid / ethanol; water / 2 h / 40 °C / Inert atmosphere
3.2: 0.5 h / Inert atmosphere
View Scheme
1‐bromo‐3‐fluoro‐2‐nitrobenzene
886762-70-5

1‐bromo‐3‐fluoro‐2‐nitrobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1.1: triethylamine / 8 h / Reflux
2.1: iron(III) chloride; pyrographite; hydrazine hydrate / ethanol / 6 h / 70 - 80 °C
3.1: sulfuric acid; acetic acid / 15 °C
3.2: 1 h / 15 - 20 °C
3.3: 2 h / Reflux
View Scheme
3-bromo-N1-phenylbenzene-1,2-diamine

3-bromo-N1-phenylbenzene-1,2-diamine

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Stage #1: 3-bromo-N1-phenylbenzene-1,2-diamine With sulfuric acid; acetic acid at 15℃;
Stage #2: With sodium nitrite In water at 15 - 20℃; for 1h;
Stage #3: With copper In water for 2h; Reflux;
46.4 g
2-nitrophenyl bromide
577-19-5

2-nitrophenyl bromide

(2-bromophenyl)boronic acid
244205-40-1

(2-bromophenyl)boronic acid

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; tetrakis(triphenylphosphine) palladium(0) / toluene; ethanol; water / 110 °C / Inert atmosphere
2: triphenylphosphine / 1,2-dichloro-benzene / 180 °C / Inert atmosphere
View Scheme
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

2,4,6-trichlorobenzoyl chloride
4136-95-2

2,4,6-trichlorobenzoyl chloride

9-(2,4,6-trichlorobenzoyl)-4-bromo-9H-carbazole

9-(2,4,6-trichlorobenzoyl)-4-bromo-9H-carbazole

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide at 0 - 23℃; for 2h; Inert atmosphere;100%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

diphenylamine
122-39-4

diphenylamine

N,N-diphenyl-9H-carbazol-4-amine

N,N-diphenyl-9H-carbazol-4-amine

Conditions
ConditionsYield
With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; lithium hexamethyldisilazane; tri tert-butylphosphoniumtetrafluoroborate In tetrahydrofuran at 65℃; for 12h; Inert atmosphere;99%
With tributylphosphine; palladium diacetate; sodium t-butanolate In toluene at 110℃; for 16h; Inert atmosphere;58.4%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

di-tert-butyl dicarbonate
24424-99-5

di-tert-butyl dicarbonate

tert-butyl 4-bromo-9H-carbazole-9-carboxylate

tert-butyl 4-bromo-9H-carbazole-9-carboxylate

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide at 0℃; for 2h; Inert atmosphere;
Stage #2: di-tert-butyl dicarbonate In N,N-dimethyl-formamide for 1h;
98%
With dmap In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;84%
With N-ethyl-N,N-diisopropylamine In acetonitrile at 25℃; for 2h; Inert atmosphere;77%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

iodobenzene
591-50-4

iodobenzene

4-bromo-9-diphenyl-9H-carbazole
1097884-37-1

4-bromo-9-diphenyl-9H-carbazole

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole; iodobenzene With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide for 0.5h; Inert atmosphere;
Stage #2: With copper(l) iodide; 1-(2-pyridyl)-3-(2-pyridyl)-1,3-propanedione In N,N-dimethyl-formamide at 110℃; Inert atmosphere;
97%
With dibenzo-18-crown-6; copper; potassium carbonate at 150℃; for 24h;95%
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 140℃; for 16h; Sealed tube;92%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

methyl iodide
74-88-4

methyl iodide

4-bromo-9-methyl-9H-carbazole

4-bromo-9-methyl-9H-carbazole

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran; mineral oil at 0 - 20℃; for 18h; Inert atmosphere;
96%
Stage #1: 4-bromo-9H-carbazole With sodium hydride In tetrahydrofuran at 0 - 20℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; for 18h;
92.7%
Stage #1: 4-bromo-9H-carbazole With sodium hydride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; for 18h;
92.7%
Stage #1: 4-bromo-9H-carbazole With sodium hydride In tetrahydrofuran at 20℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; for 18h;
92.7%
Stage #1: 4-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide at 0℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: methyl iodide In N,N-dimethyl-formamide at 0 - 20℃; for 12h; Inert atmosphere; Schlenk technique;
85%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

C24H16BrN

C24H16BrN

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole; 4-bromo-1,1'-biphenyl With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide for 0.5h; Inert atmosphere;
Stage #2: With copper(l) iodide; 1-(2-pyridyl)-3-(2-pyridyl)-1,3-propanedione In N,N-dimethyl-formamide at 110℃; Inert atmosphere;
96%
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

4-(trimethylsilyl)-9H-carbazole

4-(trimethylsilyl)-9H-carbazole

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 1h; Inert atmosphere;
Stage #2: chloro-trimethyl-silane In tetrahydrofuran; hexane at -78 - 20℃; for 2h; Inert atmosphere;
95%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

2-iodonaphthalene
612-55-5

2-iodonaphthalene

C22H14BrN

C22H14BrN

Conditions
ConditionsYield
With dibenzo-18-crown-6; copper; potassium carbonate at 150℃; for 24h;95%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

phenylhydrazine
100-63-0

phenylhydrazine

4-bromo-9-diphenyl-9H-carbazole
1097884-37-1

4-bromo-9-diphenyl-9H-carbazole

Conditions
ConditionsYield
With copper(l) iodide; caesium carbonate In acetonitrile at 0℃; for 4h; Schlenk technique;95%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

2-(dibenzo[b,d]thiophen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

2-(dibenzo[b,d]thiophen-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

4-(1-dibenzo[b,d]thienyl)carbazole

4-(1-dibenzo[b,d]thienyl)carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene at 70℃; for 19.5h; Inert atmosphere;93%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

phenylboronic acid
98-80-6

phenylboronic acid

4-phenyl-9H-carbazole
1201561-34-3

4-phenyl-9H-carbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 3h; Reflux;91%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; toluene for 3h; Reflux;91%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In ethanol; water; toluene for 3h; Reflux;91%
With palladium diacetate; potassium carbonate; tris-(o-tolyl)phosphine In ethanol; water; toluene for 8h; Inert atmosphere; Reflux;63%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid
333432-28-3

9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid

C27H21N

C27H21N

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 12h; Inert atmosphere; Reflux;90%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

bis(pinacol)diborane
73183-34-3

bis(pinacol)diborane

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-carbazole

Conditions
ConditionsYield
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate In 1,4-dioxane at 120℃; for 6h;89%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; tricyclohexylphosphine In N,N-dimethyl-formamide at 130℃; for 12h;83%
With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; tricyclohexylphosphine In N,N-dimethyl-formamide at 130℃; for 12h;83%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

p-methoxybenzyl chloride
824-94-2

p-methoxybenzyl chloride

C20H16BrNO

C20H16BrNO

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With sodium hydride In tetrahydrofuran; mineral oil
Stage #2: p-methoxybenzyl chloride In tetrahydrofuran; mineral oil
88%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

4-iodo-biphenyl
1591-31-7

4-iodo-biphenyl

C24H16BrN

C24H16BrN

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tert-butylphosphine; sodium t-butanolate In toluene at 60℃; for 12h;87%
With copper(l) iodide; copper; potassium carbonate In 1,2-dichloro-benzene for 12h; Inert atmosphere; Reflux;71%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate
3709-20-4

dimethyl 2-phenyl-1,1-cyclopropanedicarboxylate

dimethyl 2-(2-(4-bromo-9H-carbazol-9-yl)-2-phenylethyl)malonate

dimethyl 2-(2-(4-bromo-9H-carbazol-9-yl)-2-phenylethyl)malonate

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In dichloromethane at 0 - 20℃; for 12h; Sealed tube; regioselective reaction;86%
3-bromo-9-phenyl-9H-carbazole
1153-85-1

3-bromo-9-phenyl-9H-carbazole

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

C30H19BrN2

C30H19BrN2

Conditions
ConditionsYield
Stage #1: 3-bromo-9-phenyl-9H-carbazole; 4-bromo-9H-carbazole With copper(l) iodide; potassium carbonate In N,N-dimethyl-formamide for 0.5h; Inert atmosphere;
Stage #2: With copper(l) iodide; 1-(2-pyridyl)-3-(2-pyridyl)-1,3-propanedione In N,N-dimethyl-formamide at 110℃; Inert atmosphere;
84%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

2-diazo-2-phenylacetic acid isopropyl ester
264882-04-4

2-diazo-2-phenylacetic acid isopropyl ester

isopropyl (R)-2-(4-bromo-9H-carbazol-9-yl)-2-phenylacetate

isopropyl (R)-2-(4-bromo-9H-carbazol-9-yl)-2-phenylacetate

Conditions
ConditionsYield
With copper(l) iodide; C36H24N4; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In tert-butyl methyl ether; toluene at 30℃; Molecular sieve; Inert atmosphere; Schlenk technique; enantioselective reaction;83%
bromobenzene
108-86-1

bromobenzene

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

4-bromo-9-diphenyl-9H-carbazole
1097884-37-1

4-bromo-9-diphenyl-9H-carbazole

Conditions
ConditionsYield
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium t-butanolate In toluene at 110℃;82%
With 18-crown-6 ether; copper; potassium carbonate In water for 10h; Reflux;79%
With dibenzo-18-crown-6; potassium acetate; copper In N,N-dimethyl-formamide at 120℃; for 4h;77%
With dibenzo-18-crown-6; potassium acetate; copper In N,N-dimethyl-formamide at 120℃; for 4h;77%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

C14H5(2)H4ClN2

C14H5(2)H4ClN2

C26H12(2)H4BrN3

C26H12(2)H4BrN3

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide Inert atmosphere;
Stage #2: C14H5(2)H4ClN2 In N,N-dimethyl-formamide Inert atmosphere;
79.1%
Stage #1: 4-bromo-9H-carbazole With sodium hydride In N,N-dimethyl-formamide for 1h; Inert atmosphere;
Stage #2: C14H5(2)H4ClN2
79.1%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

9-phenanthrenylboronic acid
68572-87-2

9-phenanthrenylboronic acid

C26H17N

C26H17N

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water; toluene Reflux;78%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In 1,4-dioxane; water; toluene Reflux;78%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

2-bromobenzoic acid chloride
7154-66-7

2-bromobenzoic acid chloride

(2-bromophenyl)(9H-carbazol-4-yl)methanone
1346645-51-9

(2-bromophenyl)(9H-carbazol-4-yl)methanone

Conditions
ConditionsYield
Stage #1: 4-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-bromobenzoic acid chloride In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
77%
Stage #1: 4-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-bromobenzoic acid chloride In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
77%
Stage #1: 4-bromo-9H-carbazole With n-butyllithium In tetrahydrofuran; hexane at -78 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-bromobenzoic acid chloride In tetrahydrofuran; hexane at -78 - 20℃; for 2h;
77%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

N-[1,1"-biphenyl]-4-yl-N-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-[1,1-biphenyl]-4-amine
952431-30-0

N-[1,1"-biphenyl]-4-yl-N-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]-[1,1-biphenyl]-4-amine

C42H30N2

C42H30N2

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;75%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

C31H20BrN

C31H20BrN

C43H27BrN2

C43H27BrN2

Conditions
ConditionsYield
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 95℃; for 24h;75%
N-phenyl-9H-carbazol-3-boronic acid
854952-58-2

N-phenyl-9H-carbazol-3-boronic acid

4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

9-phenyl-9H,9'H-3,4'-bicarbazole
1407183-66-7

9-phenyl-9H,9'H-3,4'-bicarbazole

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water; toluene at 80℃; for 8h; Inert atmosphere;74%
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In 1,2-dimethoxyethane; water; toluene at 80℃; for 8h; Inert atmosphere;74%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 4h; Inert atmosphere; Reflux;63%
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In tetrahydrofuran; water for 4h; Reflux; Inert atmosphere;59%
4-bromo-9H-carbazole
3652-89-9

4-bromo-9H-carbazole

N-biphenylyl-N-(Naphthylphenyl)aminophenyl boronic acid pinacol ester

N-biphenylyl-N-(Naphthylphenyl)aminophenyl boronic acid pinacol ester

C46H32N2

C46H32N2

Conditions
ConditionsYield
With potassium phosphate; tetrakis(triphenylphosphine) palladium(0) In ethanol; water; toluene for 12h; Inert atmosphere; Reflux;72%

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