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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 2-Acetyl-4-Fluorophenol supplier in China

Cas:394-32-1

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

CHemwill -- 5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

TIANFUCHEM 394-32-1 1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone 394-32-1

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Best qualityCAS 394-32-1 with high-quality service

Cas:394-32-1

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Name: 5'-Fluoro-2'-hydroxyacetophenone Molecular Formula:C8H7FO2 Molecular Weight:154.14 CAS No.:394-32-1 Appearance:Similar White To Whitecrystal Powder Appearance:Similar White To Whitecrystal Powder Storage:Store in cool and dry pl

5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Factory Supply High Quality CAS 394-32-1 ,1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Ethanone,1-(5-fluoro-2-hydroxyphenyl)- 394-32-1

Cas:394-32-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone CAS: 394-32-1 MF: C8H7FO2 MW: 154.14 EINECS: 206-893-5 Mol File: 394-32-1.mol 1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone Structure 1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone Chemical

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Ethanone,1-(5-fluoro-2-hydroxyphenyl)-

Cas:394-32-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:394-32-1

Cas:394-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

2-Acetyl-4-Fluorophenol

Cas:394-32-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Nanjing Fred Technology Co.,Ltd.

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone is one of the most competitive products in our company, we can supply it with good quality and best price. Appearance:light yellow to brown solid Storage:Room temperature, Keep in Dark Place. Package:Grams, Kil

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Saiwante (shanghai) New Material Technology Co., Ltd.

Appearance/Colour:light yellow to beige-brown crystals Melting Point:56-58 °C(lit.) Boiling Point:182.2 °C at 760 mmHg PKA:10.17±0.18(Predicted) Flash Point:97.7 °C PSA:37.30000 Density:1.247 g/cm3 LogP:1.73390 St

394-32-1 5'-Fluoro-2'-hydroxyacetophenone Factory wholesale

Cas:394-32-1

Min.Order:1 Gram

FOB Price: $6.0

Type:Trading Company

inquiry

Hangzhou Lingrui Chemical Co.,Ltd.

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanoneAppearance:white powder Storage:Store in a cool dry place and keep away from strong light Package:according to customers' requirements Application:in research Transportation:By air(EMS or EUB or FedEx or TNT ect

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply 5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:0

Negotiable

Type:Other

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-Methoxy-5-(trifluoromethoxy)benzaldehyde

Cas:394-32-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Newgreat Chemical Co., Ltd

ProName: TIANFUCHEM 394-32-1 1-(5-Fluoro-2-hydr... CasNo: 394-32-1 Molecular Formula: C8H7FO2 Appearance: white powder Application: Organic Chemicals DeliveryTime: prompt PackAge: as clients needs Port: Shanghai,QingdaoTianjin,Guangzhou Pro

Good supplier 5-fluoro-2-hydroxy-acetophenone 394-32-1

Cas:394-32-1

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

SAGECHEM/1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone/SAGECHEM/Manufacturer in China

Cas:394-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

5'-Fluoro-2'-hydroxyacetophenone

Cas:394-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

1-(5-Fluoro-2-hydroxyphenyl)ethanone

Cas:394-32-1

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Luyunjia Chemistry Xiamen Limited

About us HK Luyunjia Chemical Industry Co.,Ltd is a high-tech company specializing in R&D and manufacturing of photoinitiators monomers and oligomers, UV absorbers and pharmaceutical intermediates, and pharmaceutical intermediates of generic dr

394-32-1 1-(5-Fluoro-2-hydroxyphenyl)-1-ethanone

Cas:394-32-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

4-fluorophenyl acetate
405-51-6

4-fluorophenyl acetate

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With aluminum (III) chloride at 140℃; for 3h; Fries Phenol Ester Rearrangement;100%
With trifluorormethanesulfonic acid at 0 - 20℃; for 16h; Fries rearrangement; regiospecific reaction;92%
With hydrogenchloride; aluminum (III) chloride In water at 140 - 145℃; Fries Phenol Ester Rearrangement;92%
4-Fluorophenol
371-41-5

4-Fluorophenol

acetyl chloride
75-36-5

acetyl chloride

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With aluminum (III) chloride at 130℃; for 2h;98.4%
With aluminium trichloride at 130℃; for 2h;89%
With aluminium trichloride at 180℃; for 0.5h;65%
Stage #1: 4-Fluorophenol; acetyl chloride In toluene at 40℃;
Stage #2: With aluminium trichloride In toluene at 80℃; Further stages.;
Stage #1: 4-Fluorophenol; acetyl chloride In neat (no solvent) at 0 - 20℃; for 2h;
Stage #2: With aluminum (III) chloride In neat (no solvent) at 130℃; for 2h;
1-(5-fluoro-2-methoxyphenyl)ethanone
445-82-9

1-(5-fluoro-2-methoxyphenyl)ethanone

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at -5 - 25℃;90%
With pyridine hydrochloride
With boron tribromide In dichloromethane at -78 - 23℃; for 1h;
1-(2-benzyloxy-5-fluorophenyl)-ethanone
1799-18-4

1-(2-benzyloxy-5-fluorophenyl)-ethanone

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With palladium diacetate; sodium hydride In N,N-dimethyl acetamide at 25℃; for 4h; Inert atmosphere;82%
4-Fluorophenol
371-41-5

4-Fluorophenol

acetic acid
64-19-7

acetic acid

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With aluminum oxide; methanesulfonic acid at 120℃; for 2h;60%
With boron trifluoride at 150℃; unter Druck;
1-fluoro-4-methoxybenzene
459-60-9

1-fluoro-4-methoxybenzene

acetyl chloride
75-36-5

acetyl chloride

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With aluminium trichloride In tetrachloromethane44.1%
1-fluoro-4-methoxybenzene
459-60-9

1-fluoro-4-methoxybenzene

acetyl chloride
75-36-5

acetyl chloride

A

1-(5-fluoro-2-methoxyphenyl)ethanone
445-82-9

1-(5-fluoro-2-methoxyphenyl)ethanone

B

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
With carbon disulfide; aluminium trichloride
Stage #1: 1-fluoro-4-methoxybenzene; acetyl chloride With aluminum (III) chloride In dichloromethane Friedel-Crafts Acylation; Inert atmosphere;
Stage #2: With water; acetic acid; sodium hydroxide at 0 - 8℃; Cooling with ice; Overall yield = 97%; Overall yield = 13.0g;
aluminium trichloride
7446-70-0

aluminium trichloride

4-fluorophenyl acetate
405-51-6

4-fluorophenyl acetate

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
at 150℃;
4-Fluorophenol
371-41-5

4-Fluorophenol

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: AlCl3 / 130 °C
View Scheme
Multi-step reaction with 2 steps
1: H2SO4 / 120 °C
2: AlCl3 / 160 °C
View Scheme
Multi-step reaction with 2 steps
1: 84.55 percent / pyridine / CH2Cl2 / 5 °C
2: 44 percent / aluminium chloride / 2 h / 140 °C
View Scheme
4-Fluorophenol
371-41-5

4-Fluorophenol

p-difluoro-benzene

p-difluoro-benzene

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 80 percent / conc. H2SO4
2: 85 percent / AlCl3 / 2 h / 160 °C
View Scheme
1-fluoro-4-methoxybenzene
459-60-9

1-fluoro-4-methoxybenzene

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: AlCl3; benzene
2: 100 °C
3: AlCl3 / 150 °C
View Scheme
Multi-step reaction with 2 steps
1: AlCl3; CS2
2: pyridine hydrochloride
View Scheme
4-ethoxy-1-fluorobenzene
459-26-7

4-ethoxy-1-fluorobenzene

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: AlCl3; benzene
2: 100 °C
3: AlCl3 / 150 °C
View Scheme
AlCl3 (for Friedel-Crafts reactions)

AlCl3 (for Friedel-Crafts reactions)

4-fluorophenyl acetate
405-51-6

4-fluorophenyl acetate

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

3-fluoro-6-methoxybenzonitrile
189628-38-4

3-fluoro-6-methoxybenzonitrile

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: tetrahydrofuran / 6 h / Reflux
1.2: 20 h / 75 °C
2.1: boron tribromide / dichloromethane / 1 h / -78 - 23 °C
View Scheme
trifluoromethylsulfonic anhydride
358-23-6

trifluoromethylsulfonic anhydride

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

2-acetyl-4-fluorophenyl triflate
874388-48-4

2-acetyl-4-fluorophenyl triflate

Conditions
ConditionsYield
With pyridine at 0 - 20℃;100%
With pyridine at 0 - 20℃; for 12h;92%
With pyridine at 0 - 20℃;68%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

chloroacetic acid ethyl ester
105-39-5

chloroacetic acid ethyl ester

(2-acetyl-4-fluorophenoxy)acetic acid ethyl ester
34849-57-5

(2-acetyl-4-fluorophenoxy)acetic acid ethyl ester

Conditions
ConditionsYield
With potassium carbonate In acetone for 16h; Reflux; Inert atmosphere;100%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

ethyl iodoacetae
623-48-3

ethyl iodoacetae

(2-acetyl-4-fluorophenoxy)acetic acid ethyl ester
34849-57-5

(2-acetyl-4-fluorophenoxy)acetic acid ethyl ester

Conditions
ConditionsYield
With potassium carbonate In water; acetone99%
With potassium carbonate In N,N-dimethyl-formamide at 90℃;
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

1-(5-fluoro-2-iodophenyl)ethan-1-ol

1-(5-fluoro-2-iodophenyl)ethan-1-ol

Conditions
ConditionsYield
With sodium tetrahydroborate In methanol at 20℃; for 1h; Cooling with ice;99%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

5'-fluoro-2'-hydroxy-3'-nitroacetophenone
70978-39-1

5'-fluoro-2'-hydroxy-3'-nitroacetophenone

Conditions
ConditionsYield
With nitric acid; acetic acid In acetic acid at 0 - 20℃; for 3h;98.48%
With nitric acid In tetrachloromethane at 20℃; Reflux;97%
With nitric acid; acetic acid at 0 - 20℃; for 16h;89%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

dimethyl sulfate
77-78-1

dimethyl sulfate

1-(5-fluoro-2-methoxyphenyl)ethanone
445-82-9

1-(5-fluoro-2-methoxyphenyl)ethanone

Conditions
ConditionsYield
With potassium carbonate In acetone at 20℃; for 18h; Reflux;98%
propargyl p-toluenesulfonate
6165-76-0

propargyl p-toluenesulfonate

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

1-(5-fluoro-2-(prop-2-yn-1-yloxy)phenyl)ethan-1-one
879216-16-7

1-(5-fluoro-2-(prop-2-yn-1-yloxy)phenyl)ethan-1-one

Conditions
ConditionsYield
With 2,3,5,6,8,9,11,12,14,15-decahydro-1,4,7,10,13,16-benzohexaoxacyclooctadecin; potassium carbonate In acetonitrile Heating;98%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one oxime

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one oxime

Conditions
ConditionsYield
With hydroxylamine hydrochloride In pyridine; methanol at 20℃; for 14h;98%
With hydroxylamine hydrochloride; sodium acetate In methanol at 78℃; for 4h;88%
With hydroxylamine hydrochloride; sodium acetate In methanol at 70℃; for 4h;
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

oxalic acid diethyl ester
95-92-1

oxalic acid diethyl ester

ethyl 4-(5-fluoro-2-hydroxyphenyl)-2,4-dioxobutanoate

ethyl 4-(5-fluoro-2-hydroxyphenyl)-2,4-dioxobutanoate

Conditions
ConditionsYield
With sodium methylate In methanol at 65 - 70℃; Claisen Condensation;97%
With sodium ethanolate In ethanol at 80℃; for 1.33333h; Cooling with ice;
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

1-(5-fluoro-2-hydroxyphenyl)-3-(4-methoxyphenyl)propane-1,3-dione
850799-88-1

1-(5-fluoro-2-hydroxyphenyl)-3-(4-methoxyphenyl)propane-1,3-dione

Conditions
ConditionsYield
Stage #1: 1-(5-fluoro-2-hydroxyphenyl)ethan-1-one With lithium hexamethyldisilazane In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
Stage #2: 4-methoxy-benzoyl chloride In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
96.31%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

allyl bromide
106-95-6

allyl bromide

1-[2-(allyloxy)-5-fluorophenyl]ethanone
1092306-36-9

1-[2-(allyloxy)-5-fluorophenyl]ethanone

Conditions
ConditionsYield
With potassium carbonate In 4-methyl-2-pentanone for 8h; Reflux;96%
With potassium carbonate In acetone Reflux;
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

4-Fluoro-2-((R)-1-hydroxy-ethyl)-phenol

4-Fluoro-2-((R)-1-hydroxy-ethyl)-phenol

Conditions
ConditionsYield
Stage #1: 1-(5-fluoro-2-hydroxyphenyl)ethan-1-one With (3aR)-1-methyl-3,3-diphenyl-tetrahydro-pyrrolo[1,2-c][1,3,2]oxazaborole In tetrahydrofuran at 0℃; for 0.333333h; Inert atmosphere;
Stage #2: With borane-THF In tetrahydrofuran for 0.5h; Inert atmosphere; Heating;
95%
With (-)-diisopinocamphenylborane chloride In tetrahydrofuran for 12h; Ambient temperature;
Methyl 4-(bromomethyl)benzoate
2417-72-3

Methyl 4-(bromomethyl)benzoate

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

methyl 4-((2-acetyl-4-fluorophenoxy)methyl)benzoate

methyl 4-((2-acetyl-4-fluorophenoxy)methyl)benzoate

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 16h;95%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

4-fluorobenzoyl chloride
403-43-0

4-fluorobenzoyl chloride

1-(5-fluoro-2-hydroxyphenyl)-3-(4-fluorophenyl)propane-1,3-dione
1225785-23-8

1-(5-fluoro-2-hydroxyphenyl)-3-(4-fluorophenyl)propane-1,3-dione

Conditions
ConditionsYield
Stage #1: 1-(5-fluoro-2-hydroxyphenyl)ethan-1-one With lithium hexamethyldisilazane In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
Stage #2: 4-fluorobenzoyl chloride In tetrahydrofuran; hexane at -78 - 20℃; Inert atmosphere;
94.5%
ethyl bromide
74-96-4

ethyl bromide

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

2'-ethoxy-5'-fluoroacetophenone
1466-79-1

2'-ethoxy-5'-fluoroacetophenone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;94%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

5-chloro-1-methyl-1H-imidazole-2-carbaldehyde
37050-18-3

5-chloro-1-methyl-1H-imidazole-2-carbaldehyde

(E)-3-(5-Chloro-1-methyl-1H-imidazol-2-yl)-1-(5-fluoro-2-hydroxy-phenyl)-propenone

(E)-3-(5-Chloro-1-methyl-1H-imidazol-2-yl)-1-(5-fluoro-2-hydroxy-phenyl)-propenone

Conditions
ConditionsYield
With sodium hydroxide In ethanol Ambient temperature;93%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

3-(2-fluorophenyl)-1-(5-fluoro-2-hydroxyphenyl)-2-propen-1-one
224294-29-5

3-(2-fluorophenyl)-1-(5-fluoro-2-hydroxyphenyl)-2-propen-1-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol93%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

methyl iodide
74-88-4

methyl iodide

1-(5-fluoro-2-methoxyphenyl)ethanone
445-82-9

1-(5-fluoro-2-methoxyphenyl)ethanone

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 20℃;93%
With potassium carbonate In acetone at 20℃;
2,6-difluorobenzaldehyde
437-81-0

2,6-difluorobenzaldehyde

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

3-(2,6-difluorophenyl)-1-(5-fluoro-2-hydroxyphenyl)-2-propen-1-one
224294-27-3

3-(2,6-difluorophenyl)-1-(5-fluoro-2-hydroxyphenyl)-2-propen-1-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol92%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

cyclopentanone
120-92-3

cyclopentanone

6-fluorospiro[chroman-2,1'-cyclopentan]-4-one
111478-02-5

6-fluorospiro[chroman-2,1'-cyclopentan]-4-one

Conditions
ConditionsYield
With pyrrole In toluene for 20h; Reflux;92%
pyrrolidine In acetonitrile
[Pd(CH2-C6H4-P(o-tolyl)2-κC,P)(μ-OOCCH3)]2

[Pd(CH2-C6H4-P(o-tolyl)2-κC,P)(μ-OOCCH3)]2

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

2-acetyl-4-fluorophenolato-[o-(di-o-tolylphosphino)benzyl]palladium(II)
209810-53-7, 209743-84-0

2-acetyl-4-fluorophenolato-[o-(di-o-tolylphosphino)benzyl]palladium(II)

Conditions
ConditionsYield
With potassium tert-butoxide In toluene Ar-atmosphere; stirring (12 h); filtering, evapn. (vac.), crystn. (toluene / pentane); elem. anal.;92%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

cyanoacetic acid
372-09-8

cyanoacetic acid

C11H6FNO2
288399-90-6

C11H6FNO2

Conditions
ConditionsYield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide; triethylamine In acetic acid butyl ester; ethyl acetate at 120℃; Perkin condensation;92%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

Diethyl carbonate
105-58-8

Diethyl carbonate

6-fluoro-4-hydroxycoumarin
1994-13-4

6-fluoro-4-hydroxycoumarin

Conditions
ConditionsYield
With sodium hydride In mineral oil at 0 - 100℃;91%
With potassium tert-butylate In tetrahydrofuran at 20℃; for 10h; Inert atmosphere;78%
With sodium hydride In dimethyl sulfoxide at 0 - 100℃; for 2h;29%
1,1,1-trifluoroacetophenone
434-45-7

1,1,1-trifluoroacetophenone

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

(S)-4,4,4-trifluoro-1-(5-fluoro-2-hydroxyphenyl)-3-hydroxy-3-phenylbutan-1-one

(S)-4,4,4-trifluoro-1-(5-fluoro-2-hydroxyphenyl)-3-hydroxy-3-phenylbutan-1-one

Conditions
ConditionsYield
With C19H25F6N3S In toluene at 0℃; for 96h; Aldol Addition; Inert atmosphere; enantioselective reaction;91%
6-chloro-8-formyl-1,3-benzodioxane
63944-31-0

6-chloro-8-formyl-1,3-benzodioxane

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

(E)-3-(6-Chloro-4H-benzo[1,3]dioxin-8-yl)-1-(5-fluoro-2-hydroxy-phenyl)-propenone
147722-92-7

(E)-3-(6-Chloro-4H-benzo[1,3]dioxin-8-yl)-1-(5-fluoro-2-hydroxy-phenyl)-propenone

Conditions
ConditionsYield
With sodium hydroxide In ethanol Ambient temperature;90%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

4-fluorobenzaldehyde
459-57-4

4-fluorobenzaldehyde

(E)-1-(2-hydroxy-5-fluorophenyl)-3-(4-fluorophenyl)prop-2-en-1-one
224294-26-2

(E)-1-(2-hydroxy-5-fluorophenyl)-3-(4-fluorophenyl)prop-2-en-1-one

Conditions
ConditionsYield
With sodium hydroxide In ethanol90%
With potassium hydroxide In ethanol; water at 20℃; Claisen-Schmidt Condensation;80%
With sodium hydroxide In ethanol; water at 30℃; for 24h;19%
1-(5-fluoro-2-hydroxyphenyl)ethan-1-one
394-32-1

1-(5-fluoro-2-hydroxyphenyl)ethan-1-one

N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

3-(dimethylamino)-1-(5-fluoro-2-hydroxyphenyl)prop-2-en-1-one

3-(dimethylamino)-1-(5-fluoro-2-hydroxyphenyl)prop-2-en-1-one

Conditions
ConditionsYield
In toluene at 80℃; Sealed tube; Inert atmosphere;90%
at 95℃; for 4h;69%
at 100℃; for 2h;
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