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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

(R)-(-)-Epichlorohydrin Manufacturer/High quality/Best price/In stock

Cas:51594-55-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality (R)-(-)-Epichlorohydrin supplier in China

Cas:51594-55-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Hangzhou Think Chemical Co. Ltd

(R)-(-)-Epichlorohydrin[CAS:51594-55-9] Name (R)-(-)-Epichlorohydrin Synonyms (R)-(-)-1-Chloro-2,3-epoxypropane; 2-(Chloromethyl)oxirane Molecular Formula

High purity (R)-(-)-Epichlorohydrin factory

Cas:51594-55-9

Min.Order:200 Kilogram

Negotiable

Type:Other

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply (R)-1-chloro-2,3-epoxypropane

Cas:51594-55-9

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 51594-55-9 Oxirane,2-(chloromethyl)-, (2R)-

Cas:51594-55-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality (R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

(R)-(-)-α-Epichlorohydrin

Cas:51594-55-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

We are a professional chemicals, APIs and plant extract leading manufacturer in China. We are specialized in chemical synthesis, process development of pharmaceutical intermediates, active pharmaceutical ingredients (APIs), plant extract and rare

Higher quality lower price (R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

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Henan Tianfu Chemical Co., Ltd.

(R)-(-)-Epichlorohydrin Basic information Product Name: (R)-(-)-Epichlorohydrin Synonyms: (R)-3-Chloro-1,2-epoxypropane;2-(Chlorometyl)oxirane;R(-)-2-(CHLOROMETHYL)OXIRANE;(R)-(-)-1-CHLO

(R)-(-)-Epichlorohydrin 51594-55-9

Cas:51594-55-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 51594-55-9 with high quality products

Cas:51594-55-9

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

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Henan Sinotech Import&Export Corporation

Chemical Name: (R)-(-)-Epichlorohydrin Synonyms: (R)-(-)-1-Chloro-2,3-epoxypropane; (R) 2-Chloromethyl-oxirane CAS No.: 51594-55-9 Molecular Formula: C3H5ClO Hazard Class: 6.1 UN No.: UN2023 Properties: Slightly yellow to transparent li

(R)-(-)-Epichlorohydrin with competitive price

Cas:51594-55-9

Min.Order:2 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

(R)-(-)-EpichlorohydrinCAS51594-55-9

Cas:51594-55-9

Min.Order:1 Kilogram

FOB Price: $10.0 / 20.0

Type:Trading Company

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Shijiazhuang Sdyano Fine Chemical Co., Ltd

1. Best prices with satisfied quality; 2. It's clients' right to choose the package's Courier (EMS, DHL, FedEx, UPS); 3.It's clients' right to choose the packing way for his produccts from many recent effective packing ways;

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

Advantages: Hubei XinRunde Chemical Co., Ltd is a renowned pharmaceutical manufacturer. We can offer high quality products at competitive price in quick delivery with 100% custom pass guaranteed. Never stop striving to offer our best s

99% (R)-(-)-Epichlorohydrin 51594-55-9 Chiral Intermediate

Cas:51594-55-9

Min.Order:10 Gram

Negotiable

Type:Other

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Oxirane,2-(chloromethyl)-, (2R)- 51594-55-9

Cas:51594-55-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Minstar Chemical Co., Ltd

Product Name: (R)-(-)-Epichlorohydrin CAS: 51594-55-9 MF: C3H5ClO MW: 92.52 EINECS: 424-280-2 Mol File: 51594-55-9.mol (R)-(-)-Epichlorohydrin Structure (R)-(-)-Epichlorohydrin Chemical Properties Melting point -48°C alph

R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At prese

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Kilogram

FOB Price: $78.0 / 89.0

Type:Trading Company

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Qingdao Beluga Import and Export Co., LTD

(R)-(-)-Epichlorohydrin CAS:51594-55-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic i

(R)-(-)-Epichlorohydrin CAS:51594-55-9

Cas:51594-55-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Oxirane,2-(chloromethyl)-, (2R)-

Cas:51594-55-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional chemical raw materials and chemical reagents research and development production enterprises. We have several production line,So we can control the lowest price. We also have several

(R)-(-)-Epichlorohydrin cas:51594-55-9

Cas:51594-55-9

Min.Order:25 Gram

FOB Price: $90.0 / 100.0

Type:Trading Company

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Kilogram

FOB Price: $50.0 / 100.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Oxirane,2-(chloromethyl)-, (2R)-

Cas:51594-55-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: (R)-(-)-Epichlorohydrin Synonyms: (R)-(+)-2-(Chloromethyl)oxirane / R-Epichlorohydrin;(2R)-(-)-3-Chloro-1,2-propenoxide 99%;(R)-(-)-1-CHLORO-2,3-EPOXYPROPANE;(R)-1-CHLORO-2,3-EPOXYPROPANE;(R)-(-)-CHLOROMETHYLOXIRANE;(R)-CHLOROMETHYL

(R)-(-)-Epichlorohydrin 99% Manufactuer hot sale best quality

Cas:51594-55-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

R(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Tianjin Kind Pharma Co., Ltd.

Factory direct sales, accept customization. Kind Pharma has its own laboratory, we can do analytical testing for API (Active Pharmaceutical Ingredient), pharmaceutical intermediate, pesticide intermediate, additive and other chemical products, so it

(R)-(-)-Epichlorohydrin

Cas:51594-55-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

(R )-epichlorohydrin

Cas:51594-55-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Afine Chemicals Limited

Our Services 1. New Molecules R&D 2. Own test center HPLC NMR GC LC-MS 3. API and Intermediates from China reputed manufacturers 4. Documents support COA MOA MSDS DMF open part Our advantages 1. Government awarded company. Top 100 enter

R-EPICHLOROHYDRIN

Cas:51594-55-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

(2R)-2-(chloromethyl)oxirane

Cas:51594-55-9

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

(S)-1-Acetoxy-2-bromo-3-chloropropane

(S)-1-Acetoxy-2-bromo-3-chloropropane

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With dmap; potassium carbonate In ethylene glycol at 30℃; for 0.333333h; Epoxidation;95%
(R)-3-chloro-2-hydroxypropyl 4-methylbenzenesulfonate
83398-53-2

(R)-3-chloro-2-hydroxypropyl 4-methylbenzenesulfonate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With sodium ethane-1,2-diolate In ethylene glycol for 0.25h; Ambient temperature;85%
3-chloro-2-hydroxypropyl methanesulfonate

3-chloro-2-hydroxypropyl methanesulfonate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With sodium In ethylene glycol Ambient temperature;85%
epichlorohydrin
106-89-8

epichlorohydrin

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water at 0 - 20℃;82%
With water; [(1-SS)-(Dibenzoyl-DTA)] at 5 - 20℃; for 3h; Product distribution / selectivity; Resolution of racemate;80%
Stage #1: epichlorohydrin With water; (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate at 5℃; for 4.5h;
Stage #2: With ascorbic acid at 20℃; for 0.5h;
38.5%
(R)-glycidyl tosylate
113826-06-5

(R)-glycidyl tosylate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With hydrogenchloride for 24h; Ambient temperature;54%
epichlorohydrin
106-89-8

epichlorohydrin

A

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

B

(S)-3-chloropropan-1,2-diol
60827-45-4

(S)-3-chloropropan-1,2-diol

Conditions
ConditionsYield
With (S,S)-salen-Co(III)-OAc complex; H2O (dist.) at 0℃; for 14h;A 46%
B 45%
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water In tetrahydrofuran at 0 - 4℃; for 16h;A 43%
B n/a
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water at 5℃; for 5h;
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water enantioselective reaction;
epichlorohydrin
106-89-8

epichlorohydrin

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

C

1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

Conditions
ConditionsYield
With hydrogenchloride; tert-butyl methyl ether; dimeric chiral (salen)Co complex linked with Al In diethyl ether at 0 - 5℃; for 2h; Product distribution; Further Variations:; Catalysts;A n/a
B n/a
C 45%
epichlorohydrin
106-89-8

epichlorohydrin

A

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

B

(2R)-3-chloro-1,2-propanediol
57090-45-6

(2R)-3-chloro-1,2-propanediol

Conditions
ConditionsYield
With water at 20℃; for 8h; optical yield given as %ee;A 45%
B n/a
(R)-2,3-dichloroprop-1-yl butyrate

(R)-2,3-dichloroprop-1-yl butyrate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With potassium hydroxide In methanol for 1h; Ambient temperature;43%
epichlorohydrin
106-89-8

epichlorohydrin

A

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

B

(2R)-3-chloro-1,2-propanediol
57090-45-6

(2R)-3-chloro-1,2-propanediol

C

(S)-3-chloropropan-1,2-diol
60827-45-4

(S)-3-chloropropan-1,2-diol

Conditions
ConditionsYield
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water In tetrahydrofuran at 0 - 20℃;A 43%
B n/a
C n/a
With (S,S)-(salen)Co(III)-OTs; water at 0 - 4℃; for 16h;A 42.3%
B n/a
C n/a
With poly-salen-Co(III); water In tetrahydrofuran at 10℃; for 12h;
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; water In tetrahydrofuran at 0 - 20℃; Title compound not separated from byproducts;
epichlorohydrin
106-89-8

epichlorohydrin

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

C

(2R)-3-chloro-1,2-propanediol
57090-45-6

(2R)-3-chloro-1,2-propanediol

Conditions
ConditionsYield
With (S,S)-[N,N-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino]cobalt(III) acetate; (salen)Co(III)-AlCl3; water In tetrahydrofuran at 19.84℃; for 3h; Kinetics; Reagent/catalyst; Solvent; optical yield given as %ee; enantioselective reaction;A n/a
B n/a
C 41%
With C8F17COOH; water; (R,R)-Co(III)(salen) In toluene at 20℃; for 15h;A n/a
B n/a
C 40%
With chiral oligo-(salen)Co(OTs) complexes; lutidinium p-toluene sulfonate; water In dichloromethane; acetonitrile at 0 - 20℃; for 1.5h;A n/a
B n/a
C 40%
epichlorohydrin
106-89-8

epichlorohydrin

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With Agromyces mediolanus ZJB120203 epoxide hydrolase Resolution of racemate; enantioselective reaction;A 21.5%
B n/a
enantiomeric resolution by complexation gas chromatography on nickel(II)bis<(1R)-3-(heptafluorobutyryl)camphorate>;
With water; C6H15N*C44H61CoN2O10 at 5 - 20℃; for 3 - 9h; Product distribution / selectivity; Resolution of racemate;
2,3-Dichloro-1-propanol
616-23-9

2,3-Dichloro-1-propanol

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With potassium carbonate In dichloromethane at 25℃; for 144h; Product distribution; Mechanism; study of asymmetric cyclization using optically active Co(II)(Sal)2(R-CHXDA) type catalyst;
1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With potassium carbonate; Co(II)(3,5-Cl,Cl-sal)2(S-CHXDA) (e.e. 1.) 130-150 deg C, 3 hr in vacuo; 2.) CH2Cl2, 25 deg C, 6 days; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
With potassium carbonate In dichloromethane at 25℃; Product distribution; Mechanism; study of asymmetric cyclization using different optically active cobalt (salen) or nickel (salen) type complexes;
With potassium phosphate; [(R,R)-(salen)Co(II)]2*Al(NO3)3 In tetrahydrofuran at 20℃; for 3h;
(S)-3-chloro-2-hydroxypropyl-1-(toluene-4-sulfonate)
67800-61-7

(S)-3-chloro-2-hydroxypropyl-1-(toluene-4-sulfonate)

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With sodium 2-hydroxyethoxide In ethylene glycol for 0.0833333h; Title compound not separated from byproducts;
(S)-1-bromo-3-chloro-2-propyl acetate
95548-93-9

(S)-1-bromo-3-chloro-2-propyl acetate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With disodium 1,2-ethanedithiolate In ethylene glycol for 0.25h; Yield given;
(1S,2R,4R,4'R)-4'-Chloromethyl-4,7,7-trimethylbicyclo<2.2.1>heptane-2-spiro-2'-(1',3'-dioxolan)-3-one
95589-30-3

(1S,2R,4R,4'R)-4'-Chloromethyl-4,7,7-trimethylbicyclo<2.2.1>heptane-2-spiro-2'-(1',3'-dioxolan)-3-one

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With hydrogen bromide; sodium 2-hydroxyethoxide 1.) AcOH, 60 deg C, 5 h,; Yield given. Multistep reaction;
epichlorohydrin
106-89-8

epichlorohydrin

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

C

(2R)-3-chloro-1,2-propanediol
57090-45-6

(2R)-3-chloro-1,2-propanediol

D

(S)-3-chloropropan-1,2-diol
60827-45-4

(S)-3-chloropropan-1,2-diol

Conditions
ConditionsYield
With water; poly(Co(III)(OTs)-salen-norbornene) In chlorobenzene at 20℃; for 0.5h; Product distribution; Further Variations:; Catalysts; reaction times;
Co(Salen)/SBA-16-C8 In tetrahydrofuran; water at 24.84℃; for 20h;
With C118H146Co2N4O14S2; water In acetonitrile at 20℃; optical yield given as %ee; enantioselective reaction;
epichlorohydrin
106-89-8

epichlorohydrin

A

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

B

1,3-Dichloro-2-propanol
96-23-1

1,3-Dichloro-2-propanol

C

(2S)-1-azido-3-chloropropan-2-ol
681225-50-3

(2S)-1-azido-3-chloropropan-2-ol

D

(2R)-1-azido-3-chloropropan-2-ol
180587-77-3

(2R)-1-azido-3-chloropropan-2-ol

Conditions
ConditionsYield
With sodium azide; sodium acetate buffer; Agrobacterium radiobacter AD1 haloalcohol dehalogenase at 22℃; pH=4.5; Product distribution; Further Variations:; pH-values;
3-chloroprop-1-ene
107-05-1

3-chloroprop-1-ene

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Conditions
ConditionsYield
With tert.-butylhydroperoxide; Caldariomyces fumago chloroperoxidase at 20℃; for 1h; pH=5.5; aq. phosphate buffer; Ionic liquid; Enzymatic reaction; optical yield given as %ee; enantioselective reaction;88.8 %Chromat.
carbon dioxide
124-38-9

carbon dioxide

epichlorohydrin
106-89-8

epichlorohydrin

A

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

B

(S)-4-(chloromethyl)-1,3-dioxolan-2-one
99968-48-6

(S)-4-(chloromethyl)-1,3-dioxolan-2-one

C

(R)-4-(chloromethyl)-1,3-dioxolan-2-one
99968-49-7

(R)-4-(chloromethyl)-1,3-dioxolan-2-one

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride at 25℃; under 6000.6 Torr; for 8h; Autoclave; enantioselective reaction;A n/a
B n/a
C n/a
aniline
62-53-3

aniline

epichlorohydrin
106-89-8

epichlorohydrin

A

(S)-epichlorohydrin
67843-74-7

(S)-epichlorohydrin

B

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

C

(S)-(+)-1-chloro-3-(phenylamino)-propan-2-ol
195455-97-1

(S)-(+)-1-chloro-3-(phenylamino)-propan-2-ol

D

(R)-(+)-N-(3-chloro-2-hydroxypropyl)aniline
195455-98-2

(R)-(+)-N-(3-chloro-2-hydroxypropyl)aniline

Conditions
ConditionsYield
Stage #1: epichlorohydrin With C65H56CoN3O8 In dichloromethane at 27 - 28℃; for 0.166667h;
Stage #2: aniline In dichloromethane at 27 - 28℃; enantioselective reaction;
A n/a
B n/a
C n/a
D n/a
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

n-heptylmagnesium bromide
13125-66-1

n-heptylmagnesium bromide

(R)-1-chloro-2-decanol
261160-96-7

(R)-1-chloro-2-decanol

Conditions
ConditionsYield
With CuCN In tetrahydrofuran at 0℃; for 2h; Grignard reaction;100%
With copper(I) bromide dimethylsulfide complex In tetrahydrofuran at -20℃;
With CuCN
potassium cyanate
590-28-3

potassium cyanate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(5R)-5-(chloromethyl)-1,3-oxazolidin-2-one
169048-79-7

(5R)-5-(chloromethyl)-1,3-oxazolidin-2-one

Conditions
ConditionsYield
In water for 15h; Heating;100%
With magnesium sulfate In water at 100℃; Inert atmosphere;75%
With water for 15h; Reflux;59%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

2-chloro-ethanol
107-07-3

2-chloro-ethanol

(R)-1-(2-chloroethoxy)-3-chloropropan-2-ol
934346-53-9

(R)-1-(2-chloroethoxy)-3-chloropropan-2-ol

Conditions
ConditionsYield
With boron trifluoride diethyl etherate at 45℃; for 1.5h;100%
With boron trifluoride diethyl etherate at 45℃; for 3h;100%
With boron trifluoride diethyl etherate In tetrahydrofuran at 0 - 45℃; for 1.5h;86.6%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[(4-hydroxyphenyl)methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[(4-hydroxyphenyl)methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2 [4-chloro-3-[[4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2 [4-chloro-3-[[4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

Conditions
ConditionsYield
With potassium carbonate In ethanol at 73℃; for 5h;100%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[(3-fluoro-4-hydroxyphenyl)methyl]phenyl]-6-(methylthio)tetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[(3-fluoro-4-hydroxyphenyl)methyl]phenyl]-6-(methylthio)tetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[[3-fluoro-4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6R)-2-[4-chloro-3-[[3-fluoro-4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

Conditions
ConditionsYield
With potassium carbonate In ethanol at 75℃; for 5h;100%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(2S,3R,4R,5S,6S)-2-[4-chloro-3-[(4-hydroxyphenyl)methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6S)-2-[4-chloro-3-[(4-hydroxyphenyl)methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6S)-2-[4-chloro-3-[[4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

(2S,3R,4R,5S,6S)-2-[4-chloro-3-[[4-[[(2S)-oxiran-2-yl]methoxy]phenyl]methyl]phenyl]-6-methylthiotetrahydropyran-3,4,5-triol

Conditions
ConditionsYield
With potassium carbonate In ethanol at 75℃; Inert atmosphere;100%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

4-bromoethoxybenzene
588-96-5

4-bromoethoxybenzene

(R)-1-chloro-3-(4-ethoxyphenyl)propane-2-ol

(R)-1-chloro-3-(4-ethoxyphenyl)propane-2-ol

Conditions
ConditionsYield
Stage #1: 4-bromoethoxybenzene With magnesium In tetrahydrofuran at 60℃; for 2h; Grignard Reaction; Inert atmosphere;
Stage #2: (R)-(-)-epichlorohydrin With copper(l) iodide In tetrahydrofuran at 20℃; for 1h; Grignard Reaction; Inert atmosphere;
100%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

N-(4-((3-hydroxyphenyl)diazenyl)phenyl)acetamide

N-(4-((3-hydroxyphenyl)diazenyl)phenyl)acetamide

(S)-N-(4-((3-(oxiran-2-ylmethoxy)phenyl)diazenyl)phenyl)acetamide

(S)-N-(4-((3-(oxiran-2-ylmethoxy)phenyl)diazenyl)phenyl)acetamide

Conditions
ConditionsYield
Stage #1: N-(4-((3-hydroxyphenyl)diazenyl)phenyl)acetamide With potassium carbonate In butanone for 0.166667h;
Stage #2: (R)-(-)-epichlorohydrin In butanone for 48h; Reflux;
100%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

ethyl trimethylsilyl methylphosphonite
208451-05-2

ethyl trimethylsilyl methylphosphonite

((R)-3-Chloro-2-trimethylsilanyloxy-propyl)-methyl-phosphinic acid ethyl ester

((R)-3-Chloro-2-trimethylsilanyloxy-propyl)-methyl-phosphinic acid ethyl ester

Conditions
ConditionsYield
With zinc(II) chloride at 70℃; for 4h;99%
3-fluoro-4-(morpholin-4-yl)-phenyl isocyanate
224323-51-7

3-fluoro-4-(morpholin-4-yl)-phenyl isocyanate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(5R)-5-(chloromethyl)-3-[3-fluoro-4-(4-morpholinyl)phenyl]-2-oxazolidinone

(5R)-5-(chloromethyl)-3-[3-fluoro-4-(4-morpholinyl)phenyl]-2-oxazolidinone

Conditions
ConditionsYield
With magnesium halide at 80℃; for 4h;99%
With MgI2 etherate In neat (no solvent) at 20 - 65℃; stereoselective reaction;97%
With MgI2*etherate In tetrahydrofuran at 20 - 65℃; Inert atmosphere;96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

1-bromo-1-(trimethylsilyl)ethene
13683-41-5

1-bromo-1-(trimethylsilyl)ethene

(R)-1-chloro-4-(trimethylsilyl)pent-4-en-2-ol

(R)-1-chloro-4-(trimethylsilyl)pent-4-en-2-ol

Conditions
ConditionsYield
Stage #1: 1-bromo-1-(trimethylsilyl)ethene With magnesium; ethylene dibromide In tetrahydrofuran at 20℃; for 1.25h; Reflux; Inert atmosphere;
Stage #2: (R)-(-)-epichlorohydrin With copper(l) cyanide In tetrahydrofuran at -50 - -20℃; for 2h; Inert atmosphere; Schlenk technique;
99%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

i-pentyl bromide
107-82-4

i-pentyl bromide

(R)-1-chloro-6-methylheptan-2-ol
929211-91-6

(R)-1-chloro-6-methylheptan-2-ol

Conditions
ConditionsYield
Stage #1: i-pentyl bromide With magnesium In diethyl ether
Stage #2: (R)-(-)-epichlorohydrin With copper(l) iodide In diethyl ether at -78 - -20℃; for 12h;
98%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

4-(5-(2-(diethylamino)-6-methylpyridin-4-yl)-1,2,4-oxadiazol-3-yl)-2-ethyl-6-methylphenol
1062669-89-9

4-(5-(2-(diethylamino)-6-methylpyridin-4-yl)-1,2,4-oxadiazol-3-yl)-2-ethyl-6-methylphenol

(S)-N,N-diethyl-4-(3-(3-ethyl-5-methyl-4-(oxiran-2-ylmethoxy)phenyl)-1,2,4-oxadiazol-5-yl)-6-methylpyridin-2-amine
1062670-10-3

(S)-N,N-diethyl-4-(3-(3-ethyl-5-methyl-4-(oxiran-2-ylmethoxy)phenyl)-1,2,4-oxadiazol-5-yl)-6-methylpyridin-2-amine

Conditions
ConditionsYield
Stage #1: (R)-(-)-epichlorohydrin; 4-(5-(2-(diethylamino)-6-methylpyridin-4-yl)-1,2,4-oxadiazol-3-yl)-2-ethyl-6-methylphenol With tetramethlyammonium chloride at 25℃; for 48h;
Stage #2: With sodium hydroxide In methanol at 0 - 20℃; for 1h;
98%
With sodium hydroxide In water; isopropyl alcohol at 20℃; for 48h;67%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

phenylmethyl 1-piperazinecarboxylate
31166-44-6

phenylmethyl 1-piperazinecarboxylate

(R)-benzyl 4-(3-chloro-2-hydroxypropyl)piperazine-1-carboxylate

(R)-benzyl 4-(3-chloro-2-hydroxypropyl)piperazine-1-carboxylate

Conditions
ConditionsYield
In ethanol at 20 - 50℃;98%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

7-fluoro-1-(piperazine-1-yl)isoquinoline trifluoroacetate

7-fluoro-1-(piperazine-1-yl)isoquinoline trifluoroacetate

7-fluoro-1-(4-{[(2S)-oxiran-2-yl]methyl}piperazin-1-yl)isoquinoline

7-fluoro-1-(4-{[(2S)-oxiran-2-yl]methyl}piperazin-1-yl)isoquinoline

Conditions
ConditionsYield
With sodium hydroxide In methanol at -10 - 4℃;98%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

Me2 AlCl

Me2 AlCl

trimethyl(propargyl)silane
13361-64-3

trimethyl(propargyl)silane

(R)-1-chloro-6-trimethylsilanyl-hex-4-yn-2-ol

(R)-1-chloro-6-trimethylsilanyl-hex-4-yn-2-ol

Conditions
ConditionsYield
With n-butyllithium In toluene97%
With n-butyllithium In toluene97%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

N-(2,6-dimethylphenyl)-2-(piperazin-1-yl)acetamide
5294-61-1

N-(2,6-dimethylphenyl)-2-(piperazin-1-yl)acetamide

(R)-2-(4-(3-chloro-2-hydroxypropyl)piperazin-1-yl)-N-(2,6-dimethylphenyl)acetamide
1427177-24-9

(R)-2-(4-(3-chloro-2-hydroxypropyl)piperazin-1-yl)-N-(2,6-dimethylphenyl)acetamide

Conditions
ConditionsYield
In water at 15℃; for 1h;97%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

dibenzylamine
103-49-1

dibenzylamine

(R)-N,N-dibenzyl-1-(oxiran-2-yl)methanamine
316157-42-3

(R)-N,N-dibenzyl-1-(oxiran-2-yl)methanamine

Conditions
ConditionsYield
With sodium hydroxide In water; isopropyl alcohol at 10 - 25℃; Large scale;97%
In tetrahydrofuran Solvent; Reflux;91%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(3aR,6R,7aR)-8,8-dimethyl-3-(pentan-3-ylideneamino)-1,3,4,5,6,7-hexahydro-2H-3a,6-methanobenzo[d]oxazol-2-one
1051911-44-4

(3aR,6R,7aR)-8,8-dimethyl-3-(pentan-3-ylideneamino)-1,3,4,5,6,7-hexahydro-2H-3a,6-methanobenzo[d]oxazol-2-one

C18H28N2O3

C18H28N2O3

Conditions
ConditionsYield
Stage #1: (3aR,6R,7aR)-8,8-dimethyl-3-(pentan-3-ylideneamino)-1,3,4,5,6,7-hexahydro-2H-3a,6-methanobenzo[d]oxazol-2-one With n-butyllithium; diisopropylamine; lithium diisopropyl amide In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: (R)-(-)-epichlorohydrin In tetrahydrofuran; hexane at -78℃; for 0.0833333h;
97%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

(2R)-1-chloro-5-(trimethylsilyl)pent-4-yn-2-ol
143724-90-7

(2R)-1-chloro-5-(trimethylsilyl)pent-4-yn-2-ol

Conditions
ConditionsYield
Stage #1: trimethylsilylacetylene With n-butyllithium; boron trifluoride diethyl etherate In tetrahydrofuran at -78℃;
Stage #2: (R)-(-)-epichlorohydrin In tetrahydrofuran at -60℃; regioselective reaction;
96%
With n-butyllithium; boron trifluoride diethyl etherate In tetrahydrofuran at 30℃; for 22h;90%
With n-butyllithium; boron trifluoride diethyl etherate Yield given. Multistep reaction;
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

N-(3,4-dichlorobenzyl)ethanoloamine
40172-06-3

N-(3,4-dichlorobenzyl)ethanoloamine

C12H16Cl3NO2
914927-61-0

C12H16Cl3NO2

Conditions
ConditionsYield
at 20℃; for 18h;96%
methanol
67-56-1

methanol

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

6-ethyl-o-toluidine
24549-06-2

6-ethyl-o-toluidine

(R)-1-((2-ethyl-6-methylphenyl)amino)-3-methoxypropan-2-ol
1578258-67-9

(R)-1-((2-ethyl-6-methylphenyl)amino)-3-methoxypropan-2-ol

Conditions
ConditionsYield
Stage #1: methanol; (R)-(-)-epichlorohydrin; 6-ethyl-o-toluidine at 70℃; for 6h; Reflux;
Stage #2: With potassium hydroxide at 10 - 30℃; for 8h;
96%
methyl (3-fluoro-4-morpholinophenyl)carbamate
212325-40-1

methyl (3-fluoro-4-morpholinophenyl)carbamate

(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(5R)-5-(chloromethyl)-3-[3-fluoro-4-(4-morpholinyl)phenyl]-2-oxazolidinone

(5R)-5-(chloromethyl)-3-[3-fluoro-4-(4-morpholinyl)phenyl]-2-oxazolidinone

Conditions
ConditionsYield
Stage #1: methyl-(3-fluoro-4-morpholinophenyl)carbamate With n-butyllithium In tetrahydrofuran; hexane at -10℃; for 1.16667h;
Stage #2: (R)-(-)-epichlorohydrin In tetrahydrofuran; hexane at -10 - 55℃; for 4.66667h;
96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

1-Phenyl-1H-tetrazole-5-thiol
86-93-1

1-Phenyl-1H-tetrazole-5-thiol

(2R)-1-chloro-3-[(1-phenyl-1,2,3,4-tetrazol-5-yl)mercapto]-2-propanol

(2R)-1-chloro-3-[(1-phenyl-1,2,3,4-tetrazol-5-yl)mercapto]-2-propanol

Conditions
ConditionsYield
With triethylamine In methanol at 20℃;96%
With triethylamine In methanol at 20℃;96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

2-(benzylamino)-N-(3,4-difluorophenyl)acetamide

2-(benzylamino)-N-(3,4-difluorophenyl)acetamide

2-{benzyl[(2R)-3-chloro-2-hydroxypropyl]amino}-N-(3,4-difluorophenyl)acetamide

2-{benzyl[(2R)-3-chloro-2-hydroxypropyl]amino}-N-(3,4-difluorophenyl)acetamide

Conditions
ConditionsYield
With magnesium sulfate In methanol; dichloromethane at 20 - 35℃;96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

4-sulfanylphenol
637-89-8

4-sulfanylphenol

(R)-4-((3-chloro-2-hydroxypropyl)thio)phenol

(R)-4-((3-chloro-2-hydroxypropyl)thio)phenol

Conditions
ConditionsYield
With potassium carbonate In ethanol at 20℃; for 8.25h; Cooling with ice;96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

isopropylmagnesium bromide
920-39-8

isopropylmagnesium bromide

C6H13ClO

C6H13ClO

Conditions
ConditionsYield
With copper(l) iodide In tetrahydrofuran at -10 - 25℃; for 12h; Inert atmosphere;96%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

(2R)-3-chloro-1,2-propanediol
57090-45-6

(2R)-3-chloro-1,2-propanediol

Conditions
ConditionsYield
With (R)-2-chloropropionic acid In water at 80 - 90℃; for 15h; Reagent/catalyst; Temperature;95.57%
With (R,R)-Jacobsen catalyst; water In tetrahydrofuran at 4℃; for 24h;41%
Stage #1: With N,N'-bis(3,5-di-tert-butylsalicylidene)ethylenediaminocobalt(II); camphor-10-sulfonic acid; oxygen In tetrahydrofuran for 1h;
Stage #2: (R)-(-)-epichlorohydrin With water In tetrahydrofuran at 20℃; for 20h;
93.7 %Chromat.
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

N-[4-(3-morpholinon-4-yl)phenyl]-5-chloro-2-thiophenecarboxamide

N-[4-(3-morpholinon-4-yl)phenyl]-5-chloro-2-thiophenecarboxamide

(R)-N-(2,3-epoxy-1-propyl)-N-[4-(3-morpholinon-4-yl)phenyl]-5-chloro-2-thiophenecarboxamide

(R)-N-(2,3-epoxy-1-propyl)-N-[4-(3-morpholinon-4-yl)phenyl]-5-chloro-2-thiophenecarboxamide

Conditions
ConditionsYield
Stage #1: N-[4-(3-morpholinon-4-yl)phenyl]-5-chloro-2-thiophenecarboxamide With sodium hydride In N,N-dimethyl-formamide at 20℃; for 0.333333h;
Stage #2: (R)-(-)-epichlorohydrin at 50 - 60℃; for 3h;
95.5%
(R)-(-)-epichlorohydrin
51594-55-9

(R)-(-)-epichlorohydrin

hydrogen cyanide
74-90-8

hydrogen cyanide

(R)-γ-chloro-β-hydroxybutyronitrile
84367-31-7

(R)-γ-chloro-β-hydroxybutyronitrile

Conditions
ConditionsYield
With triethylamine In water at 25℃; for 8h; Temperature;95.05%
With trimethylamine In toluene at 60℃; for 5h; Temperature; Autoclave;
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