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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Methyl 2,2-dimethylphenylacetate Manufacturer/High quality/Best price/In stock

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Methyl 2,2-Dimethylphenylacetate supplier in China

Cas:57625-74-8

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply methyl 2-methyl-2-phenylpropanoate

Cas:57625-74-8

Min.Order:1

Negotiable

Type:Other

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Anhui Dexinjia Biopharm Co., Ltd

As a leading and professional manufacturer of APIs and API intermediates in China,Anhui Dexinjia Biopharm Co., Ltd founded in 2006, Except for the R&D center, our company has built a close cooperation relation with Chinese Academy of Sciences, T

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

α,α-Dimethylbenzeneacetic acid methyl ester

Cas:57625-74-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Now we would like to update our product list for you, kindly check the below information: 1. Catalyst series ( such as Noble Metal Catalyst, Phosphorous ligand, etc ) 2. Pharmaceutical Intermediate ( such as diabtes series, Anti

57625-74-8

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 57625-74-8 with competitive price

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzeneacetic acid, a,a-dimethyl-, methyl ester 57625-74-8

Cas:57625-74-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

Methyl 2,2-dimethylphenylacetate CAS:57625-74-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality

Methyl 2,2-dimethylphenylacetate CAS:57625-74-8

Cas:57625-74-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzeneacetic acid, a,a-dimethyl-, methyl ester

Cas:57625-74-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzeneacetic acid, a,a-dimethyl-, methyl ester

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Methyl2,2-Dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Manufacturers

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Triumph International Development Limilted

Appearance:detailed see specifications Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Aripiprazole Intermediate functional... Transportation:Common products:Sea/

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Methyl 2-methyl-2-phenylpropanoate

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Nanjing Fred Technology Co.,Ltd.

Methyl 2,2-dimethylphenylacetate is one of the most competitive products in our company, we can supply it with good quality and best price. Appearance:colorless oil Storage:Room temperature, Keep in Dark Place. Package:According to the demand of cust

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzeneacetic acid, a,a-dimethyl-, methyl ester

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

cas:57625-74-8

Cas:57625-74-8

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Kunsui Technology Co., Ltd.

1. A strong scientific research team . 2. Stable quality (with a complete scientific research center and testing center to ensure the quality stability of each batch of products). 3. Rich export experience (with practical experience in exporting to m

Organic Intermediate Methyl 2-methyl-2-phenylpropanoate Powder CAS 57625-74-8

Cas:57625-74-8

Min.Order:1 Kilogram

FOB Price: $8.2 / 8.8

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

57625-74-8 CAS NO.57625-74-8

Cas:57625-74-8

Min.Order:1 Metric Ton

FOB Price: $7.0 / 8.0

Type:Trading Company

inquiry

Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best qualit

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

Methyl 2-methyl-2-phenylpropanoate cas no. 57625-74-8 98%

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Methyl dimethylbenzeneacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

Methyl 2,2-Dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Shanghai Finebiotech Co.,Ltd.

Shanghai Finebiotech Co.,Ltd.was established in 2020, which providing professional chemical services. As a customer-oriented company, we have distinguished ourself from others in providing worldwide customers with cost-effective and efficient service

Methyl 2,2-dimethylphenylacetate

Cas:57625-74-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

methanol
67-56-1

methanol

2-methyl-2-phenylpropionic acid
826-55-1

2-methyl-2-phenylpropionic acid

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With sulfuric acid at 20 - 70℃; for 21.5h; Inert atmosphere;99.5%
With sulfuric acid at 70℃; for 12h;94%
With sulfuric acid Heating;
benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

methyl iodide
74-88-4

methyl iodide

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 24h;95%
Stage #1: benzeneacetic acid methyl ester; methyl iodide With sodium hydride In tetrahydrofuran at 0 - 25℃; for 18h;
Stage #2: With acetic acid In tetrahydrofuran at 0℃;
85%
Stage #1: benzeneacetic acid methyl ester; methyl iodide With sodium hydride In tetrahydrofuran at 0 - 25℃; for 18h;
Stage #2: With acetic acid In tetrahydrofuran
85%
Methyl isobutyrate
547-63-7

Methyl isobutyrate

chlorobenzene
108-90-7

chlorobenzene

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
Stage #1: Methyl isobutyrate With sodium hexamethyldisilazane In toluene at 20℃; for 0.166667h; Inert atmosphere;
Stage #2: chlorobenzene With di-μ-bromobis(tri-tert-butylphosphino)dipalladium(I) In toluene at 100℃; for 4h; Inert atmosphere;
92%
d(4)-methanol
811-98-3

d(4)-methanol

2-(2-bromophenyl)-2-methylpropionaldehyde
212626-89-6

2-(2-bromophenyl)-2-methylpropionaldehyde

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 2BF4(1+)*C27H50P2*2H(1+); palladium diacetate; caesium carbonate In toluene at 60℃; for 14h; Inert atmosphere;92%
bromobenzene
108-86-1

bromobenzene

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene
31469-15-5

1-methoxy-2-methyl-1-trimethylsiloxy-1-propene

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With zinc(II) fluoride; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 12h;91%
With zinc(II) fluoride; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In N,N-dimethyl-formamide at 80℃; for 12h; Product distribution; Further Variations:; Solvents; Reagents;93 % Chromat.
methanol
67-56-1

methanol

2-(2-bromophenyl)-2-methylpropionaldehyde
212626-89-6

2-(2-bromophenyl)-2-methylpropionaldehyde

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 2BF4(1+)*C27H50P2*2H(1+); palladium diacetate; caesium carbonate In toluene at 60℃; for 14h; Inert atmosphere;91%
2-methyl-2-phenylpropionic acid
826-55-1

2-methyl-2-phenylpropionic acid

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With potassium carbonate In dimethyl sulfoxide at 90℃; for 16h; Inert atmosphere; Green chemistry;91%
methanol
67-56-1

methanol

2-bromo-2-methyl-1-phenyl-propan-1-one
10409-54-8

2-bromo-2-methyl-1-phenyl-propan-1-one

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With silver hexafluoroantimonate for 2h; Ambient temperature; further reagent: Ag2CO3;90%
With silver nitrate
With zinc dibromide at 115℃; for 5h; Addition; Rearrangement;
methyl 6-methoxy-2-naphthylacetate
23981-48-8

methyl 6-methoxy-2-naphthylacetate

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

B

methyl 2-(6-methoxy-2-naphthyl)propionate
30012-51-2

methyl 2-(6-methoxy-2-naphthyl)propionate

Conditions
ConditionsYield
With potassium carbonate at 220℃; for 6h;A n/a
B 90%
bromobenzene
108-86-1

bromobenzene

Methyl isobutyrate
547-63-7

Methyl isobutyrate

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With tri-tert-butyl phosphine; lithium dicyclohexylamide; bis(dibenzylideneacetone)-palladium(0) In toluene at 20℃; for 18h;87%
carbon dioxide
124-38-9

carbon dioxide

diazomethyl-trimethyl-silane
18107-18-1

diazomethyl-trimethyl-silane

isopropenylbenzene
98-83-9

isopropenylbenzene

A

3-phenyl-butyric acid methyl ester
3461-39-0

3-phenyl-butyric acid methyl ester

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
Stage #1: carbon dioxide; isopropenylbenzene With triethanolamine; tetraethylammonium iodide In N,N-dimethyl-formamide at 20℃; under 760.051 Torr; for 3.5h; Electrochemical reaction;
Stage #2: diazomethyl-trimethyl-silane In methanol; toluene for 0.666667h; regioselective reaction;
A 85%
B n/a
N-methoxy-2-methyl-2-phenylpropionamide
1072809-89-2

N-methoxy-2-methyl-2-phenylpropionamide

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide In N,N-dimethyl-formamide at 85℃; for 1.5h; Electrolysis;83%
phenyl isopropyl ketone
611-70-1

phenyl isopropyl ketone

trimethyl orthoformate
149-73-5

trimethyl orthoformate

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With poly[4-(diacetoxyiodo)styrene]; sulfuric acid In acetonitrile at 60℃; for 0.5h;81%
methyl 3-bromo-2-methyl-2-phenylpropanoate
84782-16-1

methyl 3-bromo-2-methyl-2-phenylpropanoate

A

3-phenyl-butyric acid methyl ester
3461-39-0

3-phenyl-butyric acid methyl ester

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With titanium(IV) tetraethanolate; tetraethylammonium tosylate In N,N-dimethyl-formamide electroreduction (lead cathode, carbon rod anode, 4-5 F/mol);A 80%
B 5%
carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

benzeneacetic acid methyl ester
101-41-7

benzeneacetic acid methyl ester

A

2-phenylpropionic acid methyl ester
31508-44-8

2-phenylpropionic acid methyl ester

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With potassium carbonate at 220℃; for 8h;A 80%
B n/a
methanol
67-56-1

methanol

carbon monoxide
201230-82-2

carbon monoxide

isopropenylbenzene
98-83-9

isopropenylbenzene

A

3-phenyl-butyric acid methyl ester
3461-39-0

3-phenyl-butyric acid methyl ester

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 5-chloro-2-hydroxybenzoic acid; boric acid; Tri(p-tolyl)phosphine; palladium diacetate under 31028.9 Torr; for 48h; Heating;A 74%
B n/a
With trifluromethanesulfonate[bis(1-naphthyl)diphenylphosphine]palladium(II); toluene-4-sulfonic acid In 1,2-dichloro-ethane at 75℃; for 24h; Reagent/catalyst; Inert atmosphere; High pressure; chemoselective reaction;
methacrylic acid methyl ester
80-62-6

methacrylic acid methyl ester

benzene
71-43-2

benzene

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 1,1,1,3',3',3'-hexafluoro-propanol at 20℃;70%
With aluminium trichloride
2-(2-bromophenyl)-2-methylpropionaldehyde
212626-89-6

2-(2-bromophenyl)-2-methylpropionaldehyde

butan-1-ol
71-36-3

butan-1-ol

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 2BF4(1+)*C27H50P2*2H(1+); palladium diacetate; caesium carbonate In toluene at 60℃; for 14h; Inert atmosphere;70%
N-[1-Methoxy-2-methyl-2-phenyl-prop-(Z)-ylidene]-4-methyl-benzenesulfonamide

N-[1-Methoxy-2-methyl-2-phenyl-prop-(Z)-ylidene]-4-methyl-benzenesulfonamide

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With sulfuric acid In methanol for 9h; Heating;68%
dihydroxy-methyl-borane
13061-96-6

dihydroxy-methyl-borane

2-methyl-2-phenylpropionic acid
826-55-1

2-methyl-2-phenylpropionic acid

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With pyridine; copper (II) carbonate hydroxide at 90℃; for 24h; Chan-Lam Coupling;65%
methyl 2-dimethylbismuthanyl-2-methylpropanoate
934733-52-5

methyl 2-dimethylbismuthanyl-2-methylpropanoate

iodobenzene
591-50-4

iodobenzene

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
Stage #1: methyl 2-dimethylbismuthanyl-2-methylpropanoate In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: iodobenzene With tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃; for 24h;
48%
methanol
67-56-1

methanol

phenyl isopropyl ketone
611-70-1

phenyl isopropyl ketone

trimethyl orthoformate
149-73-5

trimethyl orthoformate

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With iodine; silver nitrate for 5h; Heating;17%
2-methyl-2-phenylpropionic acid
826-55-1

2-methyl-2-phenylpropionic acid

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

2-phenylpropionic acid methyl ester
31508-44-8

2-phenylpropionic acid methyl ester

methyl iodide
74-88-4

methyl iodide

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
(i) NaNH2, liq. NH3, (ii) /BRN= 969135/; Multistep reaction;
With n-butyllithium; ammonium chloride; diisopropylamine In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; water
Stage #1: 2-phenylpropionic acid methyl ester With n-butyllithium; diisopropylamine In tetrahydrofuran at -78℃; for 1h; Schlenk technique; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran at -78 - 20℃; Schlenk technique; Inert atmosphere;
methanol
67-56-1

methanol

2-bromo-2-methyl-1-phenyl-propan-1-one
10409-54-8

2-bromo-2-methyl-1-phenyl-propan-1-one

A

2-methoxy-2-methyl-1-phenyl-1-propanone
59671-36-2

2-methoxy-2-methyl-1-phenyl-1-propanone

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With zinc dibromide at 115℃; for 4h;
methanol
67-56-1

methanol

2-methyl-2-phenylpropanoyl chloride
36293-05-7

2-methyl-2-phenylpropanoyl chloride

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
for 1h; Heating; Yield given;
α,α,α',α'-teteramethyldibenzyl ketone
71254-82-5

α,α,α',α'-teteramethyldibenzyl ketone

A

3-phenyl-butyric acid methyl ester
3461-39-0

3-phenyl-butyric acid methyl ester

B

2-isopropylbenzoic acid
2438-04-2

2-isopropylbenzoic acid

C

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

D

2-methyl-2,5-diphenyl-3-hexanone
71302-96-0

2-methyl-2,5-diphenyl-3-hexanone

E

2,6-diphenyl-4-heptanone
66164-33-8

2,6-diphenyl-4-heptanone

F

1-o-cumyl-3-phenyl-1-butanone
129976-23-4

1-o-cumyl-3-phenyl-1-butanone

Conditions
ConditionsYield
With t-butoxide In tert-butyl alcohol at 185℃; Product distribution;
phenylacetonitrile
140-29-4

phenylacetonitrile

carbonic acid dimethyl ester
616-38-6

carbonic acid dimethyl ester

A

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

B

1-phenylethyl cyanide
1823-91-2

1-phenylethyl cyanide

Conditions
ConditionsYield
With polyethylene glycol (PEG 6000); potassium carbonate at 180℃; Product distribution; Mechanism; further bases, solvents;
methyl 3-bromo-2-methyl-2-phenylpropanoate
84782-16-1

methyl 3-bromo-2-methyl-2-phenylpropanoate

A

methyl 2-methyl-3-phenylpropionate
29393-16-6, 38574-62-8, 78964-60-0, 29417-83-2

methyl 2-methyl-3-phenylpropionate

B

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride In benzene for 4h; Heating; Yield given. Yields of byproduct given;
With ammonium iodide; copper; zinc In methanol Product distribution; Ambient temperature;A 30 % Spectr.
B 60 % Spectr.
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) In benzene at 61℃; Product distribution; Kinetics;
2-methyl-2,4-diphenyl-3-pentanone
71254-83-6

2-methyl-2,4-diphenyl-3-pentanone

A

3-phenyl-butyric acid methyl ester
3461-39-0

3-phenyl-butyric acid methyl ester

B

2-isopropylbenzoic acid
2438-04-2

2-isopropylbenzoic acid

C

2-phenylpropionic acid methyl ester
31508-44-8

2-phenylpropionic acid methyl ester

D

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

E

1-(2-Isopropyl-phenyl)-2-phenyl-propan-1-one
71254-87-0

1-(2-Isopropyl-phenyl)-2-phenyl-propan-1-one

F

2,5-diphenyl-3-hexanone
71254-85-8, 71254-86-9

2,5-diphenyl-3-hexanone

Conditions
ConditionsYield
With t-butoxide In tert-butyl alcohol at 185℃; Product distribution;
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

2-methyl-2-phenyl-propan-1-ol
2173-69-5

2-methyl-2-phenyl-propan-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 3h;99%
With sodium tetrahydroborate In tetrahydrofuran at 20℃;92%
With lithium aluminium tetrahydride In diethyl ether at 0℃;
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

2-methyl-2-phenyl propanoyl hydrazide
5809-15-4

2-methyl-2-phenyl propanoyl hydrazide

Conditions
ConditionsYield
With hydrazine hydrate for 6.5h; Heating;99%
With hydrazine hydrate In methanol for 6h; Reflux;73%
With hydrazine In ethanol for 6h; Reflux;73%
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

2-methyl-2-phenylpropionic acid
826-55-1

2-methyl-2-phenylpropionic acid

Conditions
ConditionsYield
With water; sodium hydroxide In 1,4-dioxane for 24h;98%
With sodium hydroxide In methanol; water for 4h; Ambient temperature; Yield given;
With sodium hydroxide; water In methanol at 80℃; for 12h; Hydrolysis;
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

diisopropylamine
108-18-9

diisopropylamine

α,α-dimethylphenylacetyldiisopropylamine

α,α-dimethylphenylacetyldiisopropylamine

Conditions
ConditionsYield
at 20℃;92%
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

acetyl chloride
75-36-5

acetyl chloride

methyl 2-(4-acetylphenyl)isobutyrate

methyl 2-(4-acetylphenyl)isobutyrate

Conditions
ConditionsYield
Stage #1: methyl 2-methyl-2-phenylpropionate With aluminum (III) chloride In carbon disulfide at 0 - 10℃; for 0.5h; Inert atmosphere;
Stage #2: acetyl chloride In carbon disulfide at 0 - 40℃; for 21.3333h; Temperature;
91.8%
1,5-dibromo-pentane
111-24-0

1,5-dibromo-pentane

methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

C15H22O

C15H22O

Conditions
ConditionsYield
With magnesium In tetrahydrofuran at 0 - 20℃; for 5h;89%
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

methyl iodide
74-88-4

methyl iodide

2,3-dimethyl-3-phenylbutan-2-ol
2371-91-7

2,3-dimethyl-3-phenylbutan-2-ol

Conditions
ConditionsYield
magnesium In diethyl ether for 3h; Heating;81%
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

A

dimethyl 3-methyl-2-oxo-3-phenylbuthylphosphonate

dimethyl 3-methyl-2-oxo-3-phenylbuthylphosphonate

B

dimethyl 3-methyl-2-oxo-3-phenylbutylphosphonate
87929-30-4

dimethyl 3-methyl-2-oxo-3-phenylbutylphosphonate

Conditions
ConditionsYield
With n-butyllithium In tetrahydrofuran; hexane; water; ethyl acetateA 75.7%
B n/a
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

dimethyl methane phosphonate
756-79-6

dimethyl methane phosphonate

dimethyl 3-methyl-2-oxo-3-phenylbutylphosphonate
87929-30-4

dimethyl 3-methyl-2-oxo-3-phenylbutylphosphonate

Conditions
ConditionsYield
Stage #1: dimethyl methane phosphonate With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 0.5h;
Stage #2: methyl 2-methyl-2-phenylpropionate In tetrahydrofuran; hexane at -78℃; for 2.16667h;
65%
methyl 2-methyl-2-phenylpropionate
57625-74-8

methyl 2-methyl-2-phenylpropionate

acrylic acid methyl ester
292638-85-8

acrylic acid methyl ester

(E)-methyl 3-(2-(1-methoxy-2-methyl-1-oxopropan-2-yl)phenyl)acrylate

(E)-methyl 3-(2-(1-methoxy-2-methyl-1-oxopropan-2-yl)phenyl)acrylate

Conditions
ConditionsYield
With (S)-acetamidoalanine; palladium diacetate; silver nitrate at 80℃; for 24h; chemoselective reaction;65%

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