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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM--594-70-7--High purity 2-Methyl-2-nitropropanein stock Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established stable busin

TIANFUCHEM--594-70-7--High purity 2-Methyl-2-nitropropanein stock

Cas:594-70-7

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

GMP factory supply CAS 594-70-7 with high-quality service

Cas:594-70-7

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Propane,2-methyl-2-nitro-

Cas:594-70-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Propane,2-methyl-2-nitro-

Cas:594-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Propane,2-methyl-2-nitro-

Cas:594-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Methyl-2-Nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Antimex Chemical Limied

2-Methyl-2-nitropropaneAppearance:detailed see specifications Storage:Keep away of light, cool place Package:25kg/drum;200kg/drum Application:Used in Synthesis, Pharmaceuticals and other fields Transportation:Sea/air/courier

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:off-white powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as prima

tert-Nitrobutane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

2-Methyl-2-nitropropane cas 594-70-7Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

2-Methyl-2-nitropropane cas 594-70-7

Cas:594-70-7

Min.Order:0

Negotiable

Type:Other

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

2-Methyl-2-nitropropane CAS NO.594-70-7

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Share Chemical Co., Ltd

At Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi

tert-Nitrobutane,

Cas:594-70-7

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 2-Methyl-2-nitropropane, CAS:594-70-7 with the most competitive price and the best qu

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Run-Biotech Co., Ltd.

1.We have rich experience in the development and production 2.Our factory is in Shanghai of China,We have convenient traffic conditions.3.We have advanced testing equipment and shipping line. Package:5g, 10g, 50g, 100g, 1kg Application:Pharmaceutical

2-Nitro-2-methylpropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

Nitro-tert-butane

Cas:594-70-7

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Panslavia Chemicals

2-Methyl-2-nitropropane

Cas:594-70-7

Min.Order:0

Negotiable

Type:

inquiry

Synthetic route

tert-butylamine
75-64-9

tert-butylamine

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With dihydrogen peroxide; Na12[WZn3(H2O)2(ZnW9O34)2] at 75℃; for 7h;100%
With potassium permanganate In water 1.) 11 deg C -> room temperature, 8 h, 2.) 55 deg C, 18 h;78%
With sodium permanganate In hexane at 69℃; for 24h;76%
Trimethylacetic acid
75-98-9

Trimethylacetic acid

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With nitronium tetrafluoborate; silver carbonate In N,N-dimethyl acetamide at 90℃; for 12h; Inert atmosphere; Schlenk technique; regioselective reaction;79%
t-butylnitrite
917-95-3

t-butylnitrite

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With iodosylbenzene; meso-tetraphenylporphyrin iron(III) chloride In dichloromethane at 0℃;75%
tert-butylmercury chloride
38442-51-2

tert-butylmercury chloride

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With potassium nitrite; 18-crown-6 ether In various solvent(s) for 2h; Irradiation;70%
With potassium nitrite; 18-crown-6 ether In dimethyl sulfoxide at 35℃; Irradiation;71 % Spectr.
t-butylnitrite
917-95-3

t-butylnitrite

1-(trimethylsilyl)-2-methyl-1-propenyl triflate
73876-87-6

1-(trimethylsilyl)-2-methyl-1-propenyl triflate

A

2,2,4,4-tetramethyl-1,3-cyclobutanedione
933-52-8

2,2,4,4-tetramethyl-1,3-cyclobutanedione

B

dimethylacetylene
503-17-3

dimethylacetylene

C

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

D

N-tert-butylmethacrylamide
6554-73-0

N-tert-butylmethacrylamide

E

N-tert-butylisobutyramide
7472-49-3

N-tert-butylisobutyramide

F

N-tert-butyl-2-hydroxy-2-methylpropanamide
13947-81-4

N-tert-butyl-2-hydroxy-2-methylpropanamide

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In 1,2-dimethoxyethane at -20℃; for 0.0333333h; Mechanism;A 8.3%
B 70%
C n/a
D 6.4%
E 8.3%
F 5.3%
t-butyl azide
13686-33-4

t-butyl azide

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With HOF* CH3CN In chloroform at -78℃;70%
Isobutane
75-28-5

Isobutane

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 70℃; under 1520.1 Torr; for 14h;61%
With N-hydroxyphthalimide; air; Nitrogen dioxide In various solvent(s) at 70℃; under 760 Torr; for 14h;46%
With nitric acid at 150℃;
[copper(II)(6,6′-(((pyridin-2-ylmethyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol))(acetate)]

[copper(II)(6,6′-(((pyridin-2-ylmethyl)azanediyl)bis(methylene))bis(2,4-di-tert-butylphenol))(acetate)]

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

A

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C34H45CuN3O6

C34H45CuN3O6

Conditions
ConditionsYield
In methanol at 20℃; Solvent;A 0.5%
B 60%
sodium 2-nitropropane
24163-39-1

sodium 2-nitropropane

1N-methyl-2,4,6-triphenylpyridinium tetrafluoroborate
2355-56-8

1N-methyl-2,4,6-triphenylpyridinium tetrafluoroborate

A

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

B

2,4,6-triphenylpyridine
580-35-8

2,4,6-triphenylpyridine

Conditions
ConditionsYield
In dimethyl sulfoxide at 80℃;A 57%
B n/a
In dimethyl sulfoxide at 25℃; for 2h; Rate constant; Kinetics;
N-tert-Butylhydroxylamine
16649-50-6

N-tert-Butylhydroxylamine

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With potassium permanganate In water at 45 - 55℃;52%
[copper(II)(2,4-di-tert-butyl-6-(((3-(tert-butyl)-2-hydroxy-5-methylbenzyl)(pyridin-2-yl-methyl)amino)methyl)phenol)(acetate)]

[copper(II)(2,4-di-tert-butyl-6-(((3-(tert-butyl)-2-hydroxy-5-methylbenzyl)(pyridin-2-yl-methyl)amino)methyl)phenol)(acetate)]

Nitrogen dioxide
10102-44-0

Nitrogen dioxide

A

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C31H38CuN3O6

C31H38CuN3O6

Conditions
ConditionsYield
In methanol at 20℃; Solvent;A n/a
B 0.65%
2,2-dimethylpropane
463-82-1

2,2-dimethylpropane

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With nitric acid
tertiary butyl chloride
507-20-0

tertiary butyl chloride

A

tert.-butylnitrite
540-80-7

tert.-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With silver(I) nitrite; diethyl ether
t-butyl bromide
507-19-7

t-butyl bromide

A

tert.-butylnitrite
540-80-7

tert.-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With silver(I) nitrite unter Kuehlung;
1,1-dibromo-1-nitro-ethane
7119-88-2

1,1-dibromo-1-nitro-ethane

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

A

Nitroethane
79-24-3

Nitroethane

B

2-nitropropane
79-46-9

2-nitropropane

C

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

N-(benzenesulfonyl)-3-phenyloxaziridine
113548-13-3

N-(benzenesulfonyl)-3-phenyloxaziridine

tert-butylamine
75-64-9

tert-butylamine

A

t-butylnitrite
917-95-3

t-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C

N-benzylidene tert-butylamine
6852-58-0

N-benzylidene tert-butylamine

D

N-tert-butyl-α-phenylnitrone
3376-24-7

N-tert-butyl-α-phenylnitrone

Conditions
ConditionsYield
In chloroform-d1 for 1h; Product distribution; other primary amines;A 30 % Spectr.
B n/a
C 65 % Spectr.
D n/a
tert-butylamine
75-64-9

tert-butylamine

A

tert-butylnitroso dimer
31107-20-7, 117894-51-6

tert-butylnitroso dimer

B

t-butylnitrite
917-95-3

t-butylnitrite

C

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With oxaziridinium tetrafluoroborate derived from N-methyl-1,2,3,4-tetrahydroisoquinoline In dichloromethane at 0℃; for 48h;A 50 % Spectr.
B 30 % Spectr.
C 20 % Spectr.
With oxaziridinium tetrafluoroborate derived from N-methyl-1,2,3,4-tetrahydroisoquinoline In dichloromethane for 2h;A 5 % Spectr.
B 65 % Spectr.
C 25 % Spectr.
tert-butylamine
75-64-9

tert-butylamine

aqueous potassium permanganate

aqueous potassium permanganate

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

tert-Butyl iodide
558-17-8

tert-Butyl iodide

silver nitrite

silver nitrite

A

tert.-butylnitrite
540-80-7

tert.-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

tert-butylamine
75-64-9

tert-butylamine

sulfomonoperoxoic acid

sulfomonoperoxoic acid

A

t-butylnitrite
917-95-3

t-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C

tertbutyl-hydroxylamine

tertbutyl-hydroxylamine

dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

CCl3NO2

CCl3NO2

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Isobutane
75-28-5

Isobutane

diluted HNO3

diluted HNO3

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
at 150℃;
Zn(CH3)2

Zn(CH3)2

bromonitropropane

bromonitropropane

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

Conditions
ConditionsYield
With diethyl ether
diethyl ether
60-29-7

diethyl ether

tertiary butyl chloride
507-20-0

tertiary butyl chloride

silver nitrite

silver nitrite

A

tert.-butylnitrite
540-80-7

tert.-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

t-butyl bromide
507-19-7

t-butyl bromide

silver nitrite

silver nitrite

A

tert.-butylnitrite
540-80-7

tert.-butylnitrite

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

2,2-dimethylpropane
463-82-1

2,2-dimethylpropane

nitric acid
7697-37-2

nitric acid

A

nitromethane
75-52-5

nitromethane

B

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C

2,2-dimethyl-1-nitro-propane
34715-98-5

2,2-dimethyl-1-nitro-propane

Conditions
ConditionsYield
at 410℃;
Isobutane
75-28-5

Isobutane

nitric acid
7697-37-2

nitric acid

A

2-nitropropane
79-46-9

2-nitropropane

B

1-nitroisobutane
625-74-1

1-nitroisobutane

C

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

D

acetone
67-64-1

acetone

Conditions
ConditionsYield
at 420℃; Produkt 5:Nitromethan;
2,2-dimethylpropyl nitrate
926-42-1

2,2-dimethylpropyl nitrate

A

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

B

NO2

NO2

Conditions
ConditionsYield
In tetralin at 154℃; Mechanism; Kinetics; Ea, log A, other solvent, other temperatures;
2,2-dimethylpropyl nitrate
926-42-1

2,2-dimethylpropyl nitrate

A

formaldehyd
50-00-0

formaldehyd

B

tert.-butylnitrite
540-80-7

tert.-butylnitrite

C

tetramethyl-2,2,3,3 butane
594-82-1

tetramethyl-2,2,3,3 butane

D

2-methyl-2-butanol nitrate
21823-36-9

2-methyl-2-butanol nitrate

E

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

F

pivalaldehyde
630-19-3

pivalaldehyde

G

NO2

NO2

Conditions
ConditionsYield
In cyclohexane at 175℃; Mechanism; gas phase;
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

N-tert-Butylhydroxylamine
16649-50-6

N-tert-Butylhydroxylamine

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 10 - 20℃; for 3h;100%
With ammonia borane; gold on titanium oxide In ethanol at 20℃; for 0.666667h; Inert atmosphere;85%
Reduction;82%
tetrakis(triphenylphosphine)nickel(0)
15133-82-1

tetrakis(triphenylphosphine)nickel(0)

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C4H9NONi(P(C6H5)3)2
71928-64-8

C4H9NONi(P(C6H5)3)2

Conditions
ConditionsYield
In benzene Kinetics; byproducts: P(C6H5)3, OP(C6H5)3; the soln. of Ni(PPh3)4/benzene was added to the soln. of t-BuNO2/benzene with stirring at under Ar, stirred for 1 h; evapd. in vac., washed with hot hexane, dried in vac.;100%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

tetrakis(triethylphosphine)nickel(0)
51320-65-1

tetrakis(triethylphosphine)nickel(0)

C4H9NONi(P(C2H5)3)2
71928-82-0

C4H9NONi(P(C2H5)3)2

Conditions
ConditionsYield
In pentane Kinetics; byproducts: P(C2H5)3, OP(C2H5)3; to the soln. of Ni(PEt3)4/butane the soln. of t-BuNO2/pentane was addedwith stirring at -6°C under Ar, stirred for 1 h, warmed to 25°C; butane was added, cooled to -20°C, the liquid was remuved, partially evapd., this procedure repeated five times, crystd. at -78°C;100%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

tert-butylamine hydrochloride
10017-37-5

tert-butylamine hydrochloride

Conditions
ConditionsYield
Stage #1: 2-Methyl-2-nitropropane With iron(III)-acetylacetonate; hydrazine hydrate In methanol at 150℃; for 0.0333333h; Microwave irradiation;
Stage #2: With hydrogenchloride In water; ethyl acetate chemoselective reaction;
99%
Stage #1: 2-Methyl-2-nitropropane With C36H56Cl3CrN2O; magnesium; 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane In tetrahydrofuran at 60℃; for 24h; Inert atmosphere; Schlenk technique;
Stage #2: With hydrogenchloride In tetrahydrofuran; water; ethyl acetate at 20℃;
99%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

(1R,3aR,4S,7aR)-octahydro-1-[(1’R,2’E)-4’-acetoxy-1’-methyl-but-2’-en-1’-yl]-7a-methyl-4-triethylsilyloxy-1H-indene
1435482-51-1

(1R,3aR,4S,7aR)-octahydro-1-[(1’R,2’E)-4’-acetoxy-1’-methyl-but-2’-en-1’-yl]-7a-methyl-4-triethylsilyloxy-1H-indene

(1R,3aR,4S,7aR)-octahydro-1-[(1’R,2’E)-1’,5’-dimethyl-5’-nitro-hex-2’-en-1’-yl]-7a-methyl-4-triethylsilyloxy-1H-indene
1435482-53-3

(1R,3aR,4S,7aR)-octahydro-1-[(1’R,2’E)-1’,5’-dimethyl-5’-nitro-hex-2’-en-1’-yl]-7a-methyl-4-triethylsilyloxy-1H-indene

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); caesium carbonate In dimethyl sulfoxide at 20℃; for 16h;99%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

C-(2-methoxyphenyl)-N-tert-butylnitrone
130995-65-2

C-(2-methoxyphenyl)-N-tert-butylnitrone

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;97%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

tert-butylamine
75-64-9

tert-butylamine

Conditions
ConditionsYield
With [Zn(BH4)2(py)] In tetrahydrofuran for 0.67h; Heating;96%
Stage #1: 2-Methyl-2-nitropropane In water; acetonitrile at 20℃; for 0.0833333h;
Stage #2: With sodium tetrahydroborate In water; acetonitrile at 20℃; for 0.5h;
90%
With palladium on activated charcoal; tetrabutylammomium bromide; water; sodium hydroxide; silicon at 100℃; for 6h;86%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

2-((2-bromobenzyl)oxy)benzaldehyde
137266-01-4

2-((2-bromobenzyl)oxy)benzaldehyde

C18H20BrNO2

C18H20BrNO2

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 20℃; for 66h;96%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

isovaleraldehyde
590-86-3

isovaleraldehyde

C9H19NO

C9H19NO

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 20℃; for 20h;95%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

3-Trifluoromethylbenzaldehyde
454-89-7

3-Trifluoromethylbenzaldehyde

C-<3-(α,α,α-trifluoromethyl)phenyl>-N-tert-butylnitrone
139607-33-3

C-<3-(α,α,α-trifluoromethyl)phenyl>-N-tert-butylnitrone

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;93%
With acetic acid; zinc In ethanol at 0 - 20℃; for 16h;39%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

ortho-anisaldehyde
135-02-4

ortho-anisaldehyde

N-tert-butyl-α-(2-methoxy)phenylnitrone
130995-65-2

N-tert-butyl-α-(2-methoxy)phenylnitrone

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 0 - 60℃; for 22.5h; Inert atmosphere; Darkness; Molecular sieve;92%
With zinc diacetate; acetic acid In ethanol877.2 mg(93%)
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

isobutylamine
78-81-9

isobutylamine

Conditions
ConditionsYield
With sodium tetrahydroborate; nickel(II) chloride hexahydrate In water at 20℃; for 3h; Inert atmosphere; Green chemistry;92%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

3,4 difluorobenzaldehyde
34036-07-2

3,4 difluorobenzaldehyde

3,4-difluorophenyl t-butyl nitrone
204707-23-3

3,4-difluorophenyl t-butyl nitrone

Conditions
ConditionsYield
With acetic acid In ethanol91%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

2,5-difluorobenzaldehyde
2646-90-4

2,5-difluorobenzaldehyde

N-tert-butyl-α-(2,5-difluorophenyl)nitrone
204707-24-4

N-tert-butyl-α-(2,5-difluorophenyl)nitrone

Conditions
ConditionsYield
With acetic acid In ethanol90%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C16H15NO2

C16H15NO2

C20H24N2O2

C20H24N2O2

Conditions
ConditionsYield
Stage #1: 2-Methyl-2-nitropropane With acetic acid; zinc In ethanol at 20℃; for 3h; Cooling with ice;
Stage #2: C16H15NO2 In ethanol at 20℃; for 10h;
90%
Stage #1: 2-Methyl-2-nitropropane With acetic acid; zinc In ethanol at 20℃; for 3h; Cooling with ice;
Stage #2: C16H15NO2 In ethanol at 20℃; for 10h;
90%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C12H13NO2

C12H13NO2

C16H22N2O2

C16H22N2O2

Conditions
ConditionsYield
Stage #1: 2-Methyl-2-nitropropane With acetic acid; zinc In ethanol at 20℃; for 3h; Cooling with ice;
Stage #2: C12H13NO2 In ethanol at 20℃; for 16h;
89%
Stage #1: 2-Methyl-2-nitropropane With acetic acid; zinc In ethanol at 20℃; for 3h; Cooling with ice;
Stage #2: C12H13NO2 In ethanol at 20℃; for 16h;
89%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

propionaldehyde
123-38-6

propionaldehyde

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 20℃; for 29h;88%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

N-ethyl-N,N-diisopropylamine
7087-68-5

N-ethyl-N,N-diisopropylamine

N-ethylidene-1,1-dimethylethanamine N-oxide
55830-07-4

N-ethylidene-1,1-dimethylethanamine N-oxide

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate In acetonitrile at 50℃; for 9h; Irradiation;88%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

butyraldehyde
123-72-8

butyraldehyde

N-butylidene-1,1-dimethylethanamine N-Oxide
72552-75-1

N-butylidene-1,1-dimethylethanamine N-Oxide

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate; N,N-bis(1-methylethyl)-2-methyl-1-propanamine In acetonitrile at 50℃; for 9h; Irradiation;88%
4-Trifluoromethylbenzaldehyde
455-19-6

4-Trifluoromethylbenzaldehyde

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C-<4-(α,α,α-trifluoromethyl)phenyl>-N-tert-butylnitrone
122778-03-4, 137957-46-1

C-<4-(α,α,α-trifluoromethyl)phenyl>-N-tert-butylnitrone

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;86%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

3-diazo-5-phenyl-3H-1,2,4-triazole
80670-36-6

3-diazo-5-phenyl-3H-1,2,4-triazole

A

t-butylnitrite
917-95-3

t-butylnitrite

B

benzonitrile
100-47-0

benzonitrile

Conditions
ConditionsYield
at 80℃; Yields of byproduct given;A 86%
B n/a
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

benzaldehyde
100-52-7

benzaldehyde

(Z)-N-benzylidene-2-methylpropan-2-amine oxide
3376-24-7, 52392-70-8, 85225-53-2

(Z)-N-benzylidene-2-methylpropan-2-amine oxide

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 20℃; for 21h;85%
With tin(II) chloride dihdyrate; sodium carbonate In tetrahydrofuran for 32h; Reflux;82%
With acetic acid; zinc In ethanol 1.) 10 deg C, 2 h, 2.) 6 deg C, 48 h;78%
5-hydroxypentanal
4221-03-8

5-hydroxypentanal

2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

C9H19NO2

C9H19NO2

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 20℃; for 19h;85%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

N,N-bis(1-methylethyl)-2-methyl-1-propanamine
44976-81-0

N,N-bis(1-methylethyl)-2-methyl-1-propanamine

(Z)-2-methyl-N-(2-methylpropylidene)propan-2-amine N-oxide
85664-55-7

(Z)-2-methyl-N-(2-methylpropylidene)propan-2-amine N-oxide

Conditions
ConditionsYield
With tris(2,2'-bipyridyl)ruthenium(II)chloride hexahydrate In acetonitrile at 50℃; for 9h; Irradiation;84%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

3-Fluorobenzaldehyde
456-48-4

3-Fluorobenzaldehyde

(Z)-N-3-fluorobenzylidene-t-butanamine oxide
139607-30-0

(Z)-N-3-fluorobenzylidene-t-butanamine oxide

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;83%
With acetic acid; zinc In ethanol at 0 - 20℃;
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

3-methoxy-benzaldehyde
591-31-1

3-methoxy-benzaldehyde

N-tert-butyl-α-(3-methoxy)phenylnitrone
115995-22-7

N-tert-butyl-α-(3-methoxy)phenylnitrone

Conditions
ConditionsYield
With acetic acid; zinc In ethanol at 0 - 60℃; for 24h; Inert atmosphere; Darkness; Molecular sieve;83%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

β-naphthaldehyde
66-99-9

β-naphthaldehyde

(Z)‑N‑(tert‑butyl)‑1‑(naphthalen‑2‑yl)methanimine oxide
120350-90-5, 1251855-74-9, 1590374-51-8

(Z)‑N‑(tert‑butyl)‑1‑(naphthalen‑2‑yl)methanimine oxide

Conditions
ConditionsYield
With tin(II) chloride dihdyrate; sodium carbonate In tetrahydrofuran for 32h; Reflux;81%
With acetic acid; zinc In ethanol at 0 - 20℃;
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

4-chlorobenzaldehyde
104-88-1

4-chlorobenzaldehyde

(Z)‑N‑(tert‑butyl)‑1‑(4‑chlorophenyl)methanimine oxide
40117-30-4, 137957-45-0

(Z)‑N‑(tert‑butyl)‑1‑(4‑chlorophenyl)methanimine oxide

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;80%
With tin(II) chloride dihdyrate; sodium carbonate In tetrahydrofuran for 32h; Reflux;80%
2-Methyl-2-nitropropane
594-70-7

2-Methyl-2-nitropropane

4-bromo-benzaldehyde
1122-91-4

4-bromo-benzaldehyde

N-<(4-Bromophenyl)methylene>-2-methyl-2-propanamine N-oxide
76790-28-8, 127896-05-3

N-<(4-Bromophenyl)methylene>-2-methyl-2-propanamine N-oxide

Conditions
ConditionsYield
With acetic acid; zinc In ethanol for 2h; Ambient temperature;80%
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