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Wuhan Kemi-Works Chemical Co., Ltd

Superiority : 1.ISO certificate 2..Powerful R & D team 3.The ability of quantized production,from grams to tons; 4.Various kinds of advanced equipment in the laboratory and plant; 5.Strict QC standard to meet the demand of customers,a

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

Zhengzhou Yuanli Biological Technology Co., Ltd.

Most professional and biggest manufacturer of Good quality 4-Methyldiphenylamine 620-84-8 1. Product name: 4-Methyldiphenylamine 2. CAS: 620-87-8 3. Molecular formula: C13H13N 4. Molecular weight: 183.25 5. Appearance: white to almost white sol

Good quality 4-Methyldiphenylamine 620-84-8

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

4-Methyldiphenylamine Manufacturer/High quality/Best price/In stock

Cas:620-84-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Jinan Finer Chemical Co., Ltd

Product description: Product name 4-Methyldiphenylamine CAS number 620-84-8 Assay ≥99% Appearance White Crystalline Powder Capacity 200mt/year Application OLED/pharmaceutical

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

inquiry

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

We can provide GMP validation service that complies with SFDA, FDA, WHO and EU EMPA.Excellent registration team could help us easlily to register our products in different countries.If you and your customer are interested in some products or need CMO

4-Methyldiphenylamine manufacturer/supplier

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

The company has a professional R & D team, mature technology, very competitive prices and stable high quality products for customers to order high quality and low price product efforts! Appearance:White or off-white Solid Storage:Sealed, dry, m

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 620-84-8 4-Methyldiphenylamine Manufacturer

Cas:620-84-8

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

N-Phenyl-p-toluidine

Cas:620-84-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Ality Chemical Corporation

4-Methyldiphenylamine Basic information Product Name: 4-Methyldiphenylamine Synonyms: PHENYL-P-TOLYL-AMINE;N-PHENYL-P-TOLUIDINE;4-METHYDIPHENYLAMINE;4-METHYLDIPHENYLAMINE;4-Methyl-N-phenylbenzenamine;4-Methyl-N-phenylaniline;2/ 4-Methyldiphenyl

Factory Supply 4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Triphenylamine And Its Derivatives Organic Light Emitting Display(OLED) 4-Methyldiphenylamine Name 4-Methyld

4-Methyldiphenylamine -

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1. All inquiries will be replied within 12 hours. 2. Dedication to quality, supply & service. 3. Strictly on selecting raw materials. 4. Reasonable & competitive price, fast lead time. 5. Sample is available for your eva

4-Methyldiphenylamine CAS 620-84-8

Cas:620-84-8

Min.Order:1 Kilogram

FOB Price: $9.0 / 99.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 620-84-8 with competitive price

Cas:620-84-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Chemical Name 4-Methyldiphenylamine Synonyms N-Phenyl-p-toluidine; 4-Methyl-N-phenylbenzenamine CAS No. 620-84-8 EINECS No. 210-655-6

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Minstar Chemical Co., Ltd

Product Name: 4-Methyldiphenylamine CAS: 620-84-8 MF: C13H13N MW: 183.25 EINECS: 210-655-6 Mol File: 620-84-8.mol 4-Methyldiphenylamine Structure 4-Methyldiphenylamine Chemical Properties Melting point 90°C Boiling point

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzenamine,4-methyl-N-phenyl-

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

4-Methyldiphenylamine CAS: 620-84-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic int

4-Methyldiphenylamine CAS: 620-84-8

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzenamine,4-methyl-N-phenyl-

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

best price,best quality and fast delivery assurance available in sample product and customization with years of export experience along with excellent quality, advanced services and competitive prices the quality of products conform u

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzenamine,4-methyl-N-phenyl-

Cas:620-84-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

superior quality moderate price & quick delivery Appearance:powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Organic synthesis interm

Benzenamine,4-methyl-N-phenyl-

Cas:620-84-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

4-methyldiphenylamine

Cas:620-84-8

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality 4-Methyldiphenylamine

Cas:620-84-8

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Wuhu Nuowei Chemistry Technologies Co., Ltd.

Wuhu Nuovo Chemical Technology Co., Ltd. was established in August 2014, mainly engaged in the development, production and sales of ionic liquids, ribose, nucleosides, nucleotides and related chemicals; Products are mainly used in new energy, new ma

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:100 Gram

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

4-Methyldiphenylamine

Cas:620-84-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

p-toluidine
106-49-0

p-toluidine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
Stage #1: p-toluidine With n-butyllithium; dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc In tetrahydrofuran; hexane at 0 - 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane In tetrahydrofuran; hexane at 0 - 20℃; for 3h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;
100%
bromobenzene
108-86-1

bromobenzene

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With chloro[2-(dicyclohexylphosphino)-3 ,6-dimethoxy-2’,4’, 6’-triisopropyl- 1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II); sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 24h; Inert atmosphere;99%
With sodium t-butanolate; catacxium A In toluene at 110℃; for 12h; Buchwald-Hartwig reaction;99%
With (1,3-bis(2,6-diisopropylphenyl)-3,4,5,6-tetrahydropyrimidin-2-ylidene)Pd(cinnamyl, 3-phenylallyl)Cl; sodium t-butanolate In neat (no solvent) at 110℃; for 12h; Buchwald-Hartwig Coupling; Inert atmosphere; Green chemistry;99%
para-bromotoluene
106-38-7

para-bromotoluene

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0) In toluene at 20℃; for 18h;99%
With [Pd(N,N'-bis(2,6-bis(di-p-tolylmethyl)-4-methylphenyl)-imidazol-2-ylidene)(acetylacetonate)Cl]; lithium hexamethyldisilazane In 1,4-dioxane at 110℃; for 3h; Buchwald-Hartwig Coupling; Inert atmosphere; Sealed tube;99%
With nickel(II) bromide trihydrate; N,N-dimethyl-cyclohexanamine; C70H75BN2 In 1,2-dimethoxyethane; N,N-dimethyl-formamide at 50℃; for 12h; Inert atmosphere;98%
para-chlorotoluene
106-43-4

para-chlorotoluene

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 110℃; for 16h; Mechanism; Product distribution; other amines; other aryl halides and tosylates; var. chelating alkylphosphines, var. time, var. temp., further solvent;99%
With (R)-1-[(SP)-2-(diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 110℃; for 16h;99%
With potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride; tris(dibenzylideneacetone)dipalladium (0) In 1,4-dioxane at 100℃; for 5h;99%
iodobenzene
591-50-4

iodobenzene

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With nickel(II) iodide; potassium phosphate; 2-Phenyl-1,3,2-dioxaborinane In 1,4-dioxane at 115℃; for 24h; Buchwald-Hartwig Coupling; Inert atmosphere; chemoselective reaction;99%
With C29H25CuIN3OPPd; sodium t-butanolate In toluene at 40℃; for 24h;94%
With nickel(II) chloride hexahydrate; triethylamine at 125℃; for 0.333333h; Microwave irradiation; Neat (no solvent);92%
p-toluidine
106-49-0

p-toluidine

chlorobenzene
108-90-7

chlorobenzene

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine In 1,2-dimethoxyethane at 100℃; for 24h;99%
With bis(η3-allyl-μ-chloropalladium(II)); potassium tert-butylate; 1,3-bis[(2,6-diisopropyl)phenyl]imidazolinium chloride In 1,4-dioxane at 100℃; for 1.5h; Inert atmosphere;99%
With chloro[2-(dicyclohexylphosphino)-3 ,6-dimethoxy-2’,4’, 6’-triisopropyl- 1,1’-biphenyl] [2-(2-aminoethyl)phenyl]palladium(II); sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 24h; Inert atmosphere;99%
p-tolyl triflate
29540-83-8

p-tolyl triflate

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With C59H74F4OPPd(1+)*CF3O3S(1-); 1,8-diazabicyclo[5.4.0]undec-7-ene In tert-butyl methyl ether at 20℃; for 0.333333h; Catalytic behavior; Reagent/catalyst;99%
With caesium carbonate; palladium diacetate In toluene at 100℃; for 8h;
With palladium diacetate; caesium carbonate; XPhos In toluene at 100℃; for 1.5h;
diphenyl sulfide
139-66-2

diphenyl sulfide

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With SingaCycle-A3; potassium hexamethylsilazane In 1,4-dioxane; toluene at 100℃; for 12h; Schlenk technique; Inert atmosphere;99%
tris(4-methylphenyl)bismuth diacetate
107536-32-3

tris(4-methylphenyl)bismuth diacetate

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 11h; Ambient temperature;98%
p-toluidine
106-49-0

p-toluidine

triphenylbismuth(V) diacetate
28899-97-0

triphenylbismuth(V) diacetate

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
copper In dichloromethane for 0.75h; Ambient temperature;97%
1,1'-sulfinylbisbenzene
945-51-7

1,1'-sulfinylbisbenzene

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With SingaCycle-A1; sodium t-butanolate In tetrahydrofuran at 60℃; for 1h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; regioselective reaction;97%
p-toluidine
106-49-0

p-toluidine

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With potassium fluoride In dimethyl sulfoxide at 130℃; for 2h; Ullmann-Goldberg Substitution; Inert atmosphere;97%
4-tolyl iodide
624-31-7

4-tolyl iodide

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With copper acetylacetonate; potassium hydroxide In glycerol at 100℃; for 15h; Inert atmosphere; Green chemistry;96%
With triethylamine In N,N-dimethyl-formamide at 80℃; for 2h; Ullmann Condensation;96%
With triethylamine In N,N-dimethyl-formamide at 80℃; for 2h; Ullmann Condensation;96%
4-methylphenylboronic acid
5720-05-8

4-methylphenylboronic acid

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With Fe3O4 magnetic nanoparticles-supported EDTA-copper(II) complex In water at 50℃; for 1h; Green chemistry;96%
With polystyrene-supported Cu(I) catalyst In methanol at 40℃; for 15h; Ullmann coupling; Inert atmosphere;94%
With (1,3-bis(2,6-diisopropyl-4-((E)-3-methoxy-3-oxoprop-1-en-1-yl)phenyl)-2,3-dihydro-1H-imidazole-2-yl)copper(I) chloride In dichloromethane at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Chan-Lam Coupling;94%
p-toluidine
106-49-0

p-toluidine

phenylboronic acid
98-80-6

phenylboronic acid

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With potassium carbonate In ethanol; water at 20℃; for 8h;96%
With C21H16CuN2O2; potassium carbonate In water at 28℃; for 12h; Chan-Lam Coupling;95%
With Fe3O4 magnetic nanoparticles-supported EDTA-copper(II) complex In water at 50℃; for 2h; Green chemistry;95%
iodobenzene
591-50-4

iodobenzene

o-toluidine
95-53-4

o-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With potassium hydroxide; copper(II) oxide In dimethyl sulfoxide at 110℃; for 1.6h;96%
para-bromotoluene
106-38-7

para-bromotoluene

N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 5.5h; Inert atmosphere;96%
With cesium fluoride; bis(dibenzylideneacetone)-palladium(0); XPhos at 100℃; for 5.5h; Inert atmosphere;96%
4-tolyl iodide
624-31-7

4-tolyl iodide

nitrobenzene
98-95-3

nitrobenzene

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With sodium tetrahydroborate at 120℃; for 4.8h;96%
aniline
62-53-3

aniline

methyl p-toluene sulfonate
80-48-8

methyl p-toluene sulfonate

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With [(2,6-bis(2,4,6-triisopropylphenyl)phenyl)dicyclohexylphosphine](allyl-η3)palladium(II) chloride; potassium hydrogencarbonate In tert-butyl alcohol at 100℃; for 12h; Inert atmosphere; Sealed tube;96%
phenyl N,N-dimethylsulfamate
66950-63-8

phenyl N,N-dimethylsulfamate

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel(0); sodium t-butanolate In toluene at 20 - 105℃; Inert atmosphere;95%
cyclohexanone
108-94-1

cyclohexanone

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With styrene; 10 wt% Pd(OH)2 on carbon In toluene at 140℃; under 3750.38 Torr; for 11.5h; Flow reactor;95%
With 1,10-Phenanthroline; oxygen; palladium diacetate In toluene at 135℃; for 37h; Sealed tube;82%
With styrene; Au-Pd/Al2O3 In 1,3,5-trimethyl-benzene at 130℃; under 760.051 Torr; for 24h; Schlenk technique; Inert atmosphere;73%
With gold-palladium bimetallic nanoparticles supported on TiO2 In 1,3,5-trimethyl-benzene at 160℃; under 760.051 Torr; for 24h; Inert atmosphere; Schlenk technique;85 %Chromat.
4-methylphenyl tosylate
3899-96-5

4-methylphenyl tosylate

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; potassium phosphate; palladium diacetate; phenylboronic acid In butan-1-ol at 110℃; for 15h; Inert atmosphere;94%
With potassium phosphate; C36H50Cl3N5Pd In tert-Amyl alcohol at 120℃; for 18h; Buchwald-Hartwig Coupling; Inert atmosphere; Schlenk technique; chemoselective reaction;87%
With (1,3-bis(2,6-diisopropylphenyl)imidazolidene)Ni(styrene)2; lithium tert-butoxide In 1,4-dioxane for 3h; Inert atmosphere; Heating; Schlenk technique;80%
diphenylzinc
1078-58-6

diphenylzinc

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
Stage #1: p-toluidine With n-butyllithium In hexane; chlorobenzene at 0 - 20℃; for 0.5h;
Stage #2: With zinc dichloro(N,N,N′,N′-tetramethylethylenediamine) In hexane; chlorobenzene for 1h;
Stage #3: diphenylzinc With iron(III)-acetylacetonate; 1,2-dichloro-2-methylpropane In hexane; chlorobenzene at 80℃; for 15h;
94%
p-toluidine
106-49-0

p-toluidine

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

A

biphenyl
92-52-4

biphenyl

B

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
Stage #1: p-toluidine With n-butyllithium; dichloro(N,N,N’,N‘-tetramethylethylenediamine)zinc In tetrahydrofuran; hexane at 0 - 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
Stage #2: phenylmagnesium bromide With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; bis(acetylacetonate)nickel(II); 1,2-dichloro-2-methylpropane In tetrahydrofuran; hexane at 0 - 20℃; for 3h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;
A 17 %Chromat.
B 94%
p-toluidine
106-49-0

p-toluidine

butyl diphenyl sulfonium triflate

butyl diphenyl sulfonium triflate

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With potassium phosphate; bis[tris( 1,1-dimethylethyl)phosphine]-palladium; copper(I) bromide In acetonitrile at 60℃; for 16h; Ullmann Condensation; Inert atmosphere; Glovebox; Sealed tube;94%
di(p-tolyl)borinic acid
66117-64-4

di(p-tolyl)borinic acid

aniline
62-53-3

aniline

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With pyridine; copper diacetate trihydrate In dichloromethane at 20℃; for 24h; Catalytic behavior; Reagent/catalyst; Solvent; Chan-Lam Coupling;93%
1,1'-sulfinylbisbenzene
945-51-7

1,1'-sulfinylbisbenzene

p-toluidine
106-49-0

p-toluidine

methyl iodide
74-88-4

methyl iodide

A

racemic methyl phenyl sulfoxide
1193-82-4

racemic methyl phenyl sulfoxide

B

N,4-dimethyl-N-phenylaniline
38158-65-5

N,4-dimethyl-N-phenylaniline

C

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
Stage #1: 1,1'-sulfinylbisbenzene; p-toluidine With potassium tert-butylate In 1,4-dioxane at 60℃; Inert atmosphere;
Stage #2: methyl iodide In 1,4-dioxane at 25℃; for 1.5h; Inert atmosphere; regioselective reaction;
A 93%
B n/a
C n/a
p-toluidine
106-49-0

p-toluidine

triphenyltin chloride
639-58-7

triphenyltin chloride

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With copper diacetate; triethylamine at 20℃; for 24h;92%
With triethylamine at 20℃; for 15h;90%
With triethylamine at 90℃; for 17h; Stille Cross Coupling;81%
With triethylamine at 95℃;76%
toluene-4-sulfonic acid phenyl ester
640-60-8

toluene-4-sulfonic acid phenyl ester

p-toluidine
106-49-0

p-toluidine

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

Conditions
ConditionsYield
With di-tert-butyl{2′-isopropoxy-[1,1′-binaphthalen]-2-yl}phosphane; potassium phosphate; palladium diacetate; phenylboronic acid In butan-1-ol at 110℃; for 15h; Inert atmosphere;91%
With (R)-(-)-1-[(S)-2-(dicyclohexylphosphino)ferrocenyl]ethyl di-t-butylphosphine; bis(tri-ortho-tolylphosphine)palladium(0); sodium t-butanolate In toluene at 25℃; for 24h; Inert atmosphere;87%
With 1,1'-bis-(diphenylphosphino)ferrocene; [1,1′-bis(diphenylphosphino)ferrocene]bis(triphenylphosphite)nickel(0); sodium t-butanolate In toluene at 100℃; for 18h; Schlenk technique; Inert atmosphere;47%
With sodium t-butanolate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride; chlorobis(triphenylphosphine)(1-naphthyl)nickel(II) In 1,4-dioxane at 110℃; for 0.5h;46%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

3-methyl-10H-phenothiazine
3939-47-7

3-methyl-10H-phenothiazine

Conditions
ConditionsYield
With iodine; sulfur In 1,2-dichloro-benzene at 160℃; for 0.75h; Inert atmosphere;14%
With iodine; sulfur
With iodine; sulfur at 195℃;
With iodine; sulfur at 280℃;
With iodine; sulfur In water at 190℃; for 0.333333h; microwave irradiation;
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

2-methylphenothiazine
5828-51-3

2-methylphenothiazine

Conditions
ConditionsYield
With sulfur; iodine In 1,2-dichloro-benzene at 160℃; for 2h; Heating / reflux;28%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

3-Methyl-9H-carbazole
4630-20-0

3-Methyl-9H-carbazole

Conditions
ConditionsYield
With dibenzoyl peroxide In chloroform for 6h; Heating; Irradiation;40%
With oxygen In acetic acid; toluene at 80℃; under 760.051 Torr;
With oxygen; palladium diacetate; acetic acid In toluene at 100℃; for 6.5h;
With oxygen; acetic acid In toluene Inert atmosphere;
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

4-halogenbiphenyl

4-halogenbiphenyl

biphenyl-4-yl-phenyl-p-tolyl-amine

biphenyl-4-yl-phenyl-p-tolyl-amine

Conditions
ConditionsYield
With copper; potassium carbonate In nitrobenzene Substitution; Ullmann reaction; Heating;40.9%
2,6-di-tert-butyl-4-benzylidene-cyclohexa-2,5-dienone
7078-98-0

2,6-di-tert-butyl-4-benzylidene-cyclohexa-2,5-dienone

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

2,6-di-tert-butyl-4-(phenyl(4-(p-tolylamino)phenyl)methyl)phenol

2,6-di-tert-butyl-4-(phenyl(4-(p-tolylamino)phenyl)methyl)phenol

Conditions
ConditionsYield
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 0.0833333h; Inert atmosphere;41%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

1-phenylbutan-1,3-dione
93-91-4

1-phenylbutan-1,3-dione

(2-methyl-5-(phenyl(p-tolyl)amino)-1-(p-tolyl)-1H-indol-3-yl)(phenyl)methanone

(2-methyl-5-(phenyl(p-tolyl)amino)-1-(p-tolyl)-1H-indol-3-yl)(phenyl)methanone

Conditions
ConditionsYield
With pyridine; oxygen; copper dichloride In 2-methyl-propan-1-ol at 100℃; for 16h; Schlenk technique; Green chemistry; regioselective reaction;45%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

3-methoxypropylamine
5332-73-0

3-methoxypropylamine

C30H29N3O

C30H29N3O

Conditions
ConditionsYield
With oxygen; copper(l) chloride In 2-methyl-propan-1-ol at 100℃; for 12h; chemoselective reaction;46%
1-methylindole
603-76-9

1-methylindole

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

6-methyl-N-phenyl-N,5-di-p-tolyl-5,6-dihydroindolo[2,3-b]indol-2-amine

6-methyl-N-phenyl-N,5-di-p-tolyl-5,6-dihydroindolo[2,3-b]indol-2-amine

Conditions
ConditionsYield
With oxygen; copper dichloride In 1,4-dioxane at 80℃; for 16h; Molecular sieve; chemoselective reaction;46%
4-tolyl iodide
624-31-7

4-tolyl iodide

4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

N-phenyl-di-p-tolylamine
20440-95-3

N-phenyl-di-p-tolylamine

Conditions
ConditionsYield
With potassium carbonate; copper; copper(l) chloride In pyridine at 210 - 220℃; for 10h;47%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

C22H30S2

C22H30S2

C24H25NS

C24H25NS

Conditions
ConditionsYield
With iodine In N,N-dimethyl-formamide at 90℃; for 16h;48%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

4-halogen-4'-methylbiphenyl

4-halogen-4'-methylbiphenyl

(4'-methyl-biphenyl-4-yl)-phenyl-p-tolyl-amine

(4'-methyl-biphenyl-4-yl)-phenyl-p-tolyl-amine

Conditions
ConditionsYield
With copper; potassium carbonate In nitrobenzene Substitution; Ullmann reaction; Heating;49.7%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

4-bromo-4'-iodobiphenyl
105946-82-5

4-bromo-4'-iodobiphenyl

N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine
20441-06-9

N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine

Conditions
ConditionsYield
With 18-crown-6 ether; potassium carbonate In 1,2-dichloro-benzene at 200℃; for 70h; Inert atmosphere;50%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

C8H6BrI

C8H6BrI

C21H18BrN

C21H18BrN

Conditions
ConditionsYield
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 95℃; for 4h;51%
4-methyldiphenylamine
620-84-8

4-methyldiphenylamine

N‐(pyrimidin‐2‐yl)indoline

N‐(pyrimidin‐2‐yl)indoline

N-phenyl-1-(pyrimidin-2-yl)-N-(p-tolyl)indolin-7-amine

N-phenyl-1-(pyrimidin-2-yl)-N-(p-tolyl)indolin-7-amine

Conditions
ConditionsYield
With oxygen; copper diacetate In 1,2-dichloro-ethane at 130℃; for 24h; Sealed tube;53%

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