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Enke Pharma-tech Co.,Ltd. (Cangzhou, China )

Cangzhou Enke Pharma Tech Co.,ltd. is located in Cangzhou City, Hebei province ,where is a famous petroleum chemical industry city in China. Enke Pharma a high-tech enterprise ,and we are dedicated to developing and manufacturing new ap

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Lab/Research institutions

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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

1,3-Dimethyladamantane Manufacturer/High quality/Best price/In stock

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality 1,3-Dimethyl-Adamantane supplier in China

Cas:702-79-4

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1091.html Product Name 1,3-Dimethyladamantane CAS No. 702-79-4 Appearance Colorless transparent liquid Assay

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Gram

FOB Price: $11.0

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Product Name: 1,3-Dimethyladamantane CAS RN.: 702-79-4 EINECS: 211-870-8

1,3-Dimethyladamantane 702-79-4

Cas:702-79-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply 1,3-dimethyltricyclo[3.3.1.13,7]decane

Cas:702-79-4

Min.Order:1

Negotiable

Type:Other

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality 99% 702-79-4 1,3-Dimethyladamantane Manufacturer

Cas:702-79-4

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

Hebei Yanxi Chemical Co., Ltd. is a professional research, development and production of lead acetate benzene acetamide enterprise backbone members by local well-known entrepreneurs and professional senior engineers in the party's "low car

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

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Leader Biochemical Group

About Product Details Item Specification Test Results Appearance White crystalline powder Conform

China Largest Factory Supply High Quality 1,3-Dimethyladamantane CAS 702-79-4

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 5.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1,3-Dimethyladamantane-

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Factory direct supply CAS 702-79-4 with best quality

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Top sale 702-79-4 1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in t

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product name: 1,3-Dimethyladamantane English name: 1,3-Dimethyladamantane Alias: 1,3-Dimethyltricyclo(3.3.1.13,7)decane; 1,3-Dimethylasamantane; 1,3-dimethyltricyclo[3.3.1.1~3,7~]decane Molecular formula: C12H20 Molecular weight: 164.29 CAS No

1,3-Dimethyladamantane CAS: 702-79-4

Cas:702-79-4

Min.Order:5 Metric Ton

FOB Price: $1.0 / 2.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

1,3-Dimethyladamantane 702-79-4

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the

1,3-Dimethyladamantane/ LIDE PHARMA- Factory supply / Best price

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

★.Best quality according to requirement ★.Competitive price in China market ★.Mature Technical support ★.Professional logistic support ★.Shortest delivery time . Appearance:Refer to COA Storage:Store in dry, cool and ventilated place Package:Acc

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

1,3-Dimethyladamantane CAS:702-79-4 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

1,3-Dimethyladamantane CAS:702-79-4

Cas:702-79-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Terui OP New Material Technology Co., Ltd.

We have overseas warehouses in California, New Laredo Mexico, Vancouver Canada, Amsterdam Netherlands, and Melbourne Australia. Overseas warehouses can provide some of the best-selling products. We look forward to the cooperation of local powerful

Wuhan Wonda Pharm Limited

1.high quality: quality is life. quality is the most important element for all goods. we have a lab doing research in wuhan china. hplc and nmr is available if needed. 2.reasonable price: we provide high quality products wi

Organic Intermediate 1,3-Dimethyladamantane 702-79-4

Cas:702-79-4

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Mojin Biotechnology Co.,Ltd

Company information: Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countries, most of the big cust

Factory Price 1, 3-Dimethyladamantane CAS 702-79-4

Cas:702-79-4

Min.Order:1 Kilogram

FOB Price: $7.0 / 10.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Purestar Chem Enterprise Co.,Ltd

【Chemical Name】1,3-Dimethyladamantane 【CAS No】702-79-4 【Molecular Formula】C12H22 【Molecular Weight】164.29 【Structural Formula】 【Properties】Transparent clear liquid; Density: 0.8860g/cm3(20/20 deg C); Freezing/Melting Point: -30 deg C; Boiling Poi

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Metric Ton

FOB Price: $6.0

Type:Trading Company

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

1 ,3-dimethyl adamantane

Cas:702-79-4

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

1. Well-equipped, stable and high-quality raw material supply chain, to provide customers with the best quality products. 2.Strict quality inspection process and professional certificate testing to ensure the quality level of the final product. 3.E

hot sale 1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou JINLAN Pharm-Drugs Technology Co., Ltd

Specification:USP/EP Month production ablity:50kg/Month Low price& High quality Manufacturer Appearance:white powder Storage:Room Temperature Application:702-79-4

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hubei Lidu New Material Technology Co., Ltd

Hubei Lidu New Materials Technology Co. , Ltd. is located in No. 12,3C Industrial Park, Zhongxiang Economic Development Zone, Hubei Province. The company is committed to fine chemical raw materials, pharmaceutical intermediates and other production,

1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

cas 702-79-4 1,3-Dimethyladamantane

Cas:702-79-4

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

3,5-dimethyl-1-bromoadamantane
941-37-7

3,5-dimethyl-1-bromoadamantane

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride at 90℃; for 1h; Solvent; Barton-McCombie Deoxygenation; Inert atmosphere;100%
With decane; 2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile; tri-n-butyl-tin hydride In toluene at 80℃; for 0.0166667h;99 % Chromat.
Multi-step reaction with 2 steps
1: 98 percent / aq. HCl / dimethylformamide / 1.5 h
2: H2SO4 (91.5percent) / 72 h / Ambient temperature; var. of conc.of H2SO4, and var. of reaction time
View Scheme
1-bromo-3-methyladamantane
702-77-2

1-bromo-3-methyladamantane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
In dibutyl ether at 85℃;A 99%
B 1%
3,5-dimethyl-1-bromoadamantane
941-37-7

3,5-dimethyl-1-bromoadamantane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

Conditions
ConditionsYield
In dibutyl ether at 95℃;A 2%
B 98%
decahydroacenaphthene
2146-36-3

decahydroacenaphthene

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

Conditions
ConditionsYield
With aluminium trichloride at 69.85℃; for 50h;90%
With hydrogen fluoride; boron trifluoride Temperature; Autoclave;75%
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Concentration; Temperature; Time; Autoclave; Sealed tube;65%
adamantane
281-23-2

adamantane

methyl iodide
74-88-4

methyl iodide

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With Rh(PPh3)3Cl In dichloromethane at 150℃; for 3h;A 79%
B 21%
decahydroacenaphthene
2146-36-3

decahydroacenaphthene

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1-ethyladamantane
770-69-4

1-ethyladamantane

Conditions
ConditionsYield
With hydrogen fluoride; boron trifluoride at 100℃; for 4h; Temperature; Autoclave;A 77%
B 15%
(3,5-dimethyl-adamantan-1-yl)-methanol
26919-42-6

(3,5-dimethyl-adamantan-1-yl)-methanol

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

Conditions
ConditionsYield
With cerium(III) chloride; 9,10-diphenylanthracene; 1,2-bis(2,4,6-triisopropylphenyl)disulfane; tetrabutyl-ammonium chloride In acetonitrile for 24h; Irradiation; Inert atmosphere;69%
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
58865-53-5

(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1-ethyladamantane
770-69-4

1-ethyladamantane

C

1,4-dimethyladamantane
16267-35-9

1,4-dimethyladamantane

Conditions
ConditionsYield
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Autoclave; Sealed tube;A 67%
B 6%
C 22%
1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
In dibutyl ether at 140℃;A 52%
B 4%
C 44%
1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

methylmagnesium bromide
75-16-1

methylmagnesium bromide

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

C

1-bromo-3-methyladamantane
702-77-2

1-bromo-3-methyladamantane

Conditions
ConditionsYield
In dibutyl ether at 140℃;A 52%
B 4%
C 44%
1,3-dibromoadamantane
876-53-9

1,3-dibromoadamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With methylmagnesium bromide In dibutyl ether at 140℃;A 52%
B 4%
C 44%
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
58865-53-5

(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,2-dimethyladamantane
16207-81-1

1,2-dimethyladamantane

C

1-ethyladamantane
770-69-4

1-ethyladamantane

D

1,4-dimethyladamantane
16267-35-9

1,4-dimethyladamantane

Conditions
ConditionsYield
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 30h; Concentration; Time;A 49%
B 9%
C 11%
D 24%
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time;A 18%
B 8%
C 10%
D 21%
tetramethylsilane
75-76-3

tetramethylsilane

1-adamanthanol
768-95-6

1-adamanthanol

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

C

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

D

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 5h; Product distribution; other time;;A 33%
B n/a
C 10%
D 29%
E 13%
tetramethylsilane
75-76-3

tetramethylsilane

1-adamanthanol
768-95-6

1-adamanthanol

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 5h;A 33%
B 10%
C 29%
D 13%
With aluminum tri-bromide
ethyl-cyclohexane
1678-91-7

ethyl-cyclohexane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

trans-Decalin
493-02-7

trans-Decalin

D

1-ethyladamantane
770-69-4

1-ethyladamantane

E

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;A 18.76%
B 6.3%
C 1.25%
D 3.46%
E 15.01%
F 2.76%
methyl cyclohexane
82166-21-0

methyl cyclohexane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

trans-Decalin
493-02-7

trans-Decalin

D

1-ethyladamantane
770-69-4

1-ethyladamantane

E

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;A 10.78%
B 7.79%
C 4.7%
D 4.25%
E 17.49%
F 1.5%
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene
58865-53-5

(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,4-dimethyladamantane
16267-35-9

1,4-dimethyladamantane

Conditions
ConditionsYield
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time;A 17%
B 15%
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 30h; Concentration; Time;A 6%
B 9%
(1-methylethyl)-cyclohexane
696-29-7

(1-methylethyl)-cyclohexane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

trans-Decalin
493-02-7

trans-Decalin

D

1-ethyladamantane
770-69-4

1-ethyladamantane

E

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;A 8.98%
B 7.37%
C 7.47%
D 2.04%
E 13.24%
F 1.59%
isobutylcyclohexane
1678-98-4

isobutylcyclohexane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

trans-Decalin
493-02-7

trans-Decalin

D

1-ethyladamantane
770-69-4

1-ethyladamantane

E

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;A 8.23%
B 8.26%
C 9.82%
D 0.59%
E 10.13%
F 1.33%
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

tetramethylsilane
75-76-3

tetramethylsilane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Further byproducts given;A 32 % Chromat.
B 21 % Chromat.
C 39 % Chromat.
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given;A 35 % Chromat.
B 13 % Chromat.
C 37 % Chromat.
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

tetramethylsilane
75-76-3

tetramethylsilane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

C

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

D

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3; AlCl3 instead AlBr3;
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

tetramethylsilane
75-76-3

tetramethylsilane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

C

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Yield given. Yields of byproduct given;
1-Adamantyl bromide
768-90-1

1-Adamantyl bromide

tetramethylsilane
75-76-3

tetramethylsilane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given;
With aluminum tri-bromide In dichloromethane at 40℃; for 1.5h; Yield given. Further byproducts given. Yields of byproduct given;
methyl bromide
74-83-9

methyl bromide

1-bromo-3-methyladamantane
702-77-2

1-bromo-3-methyladamantane

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

Conditions
ConditionsYield
With magnesium 1.) n-butyl ether, 2.) n-butyl ether, 70 deg C; Yield given. Multistep reaction;
tetramethylsilane
75-76-3

tetramethylsilane

1-chloroadamantane
935-56-8

1-chloroadamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Further byproducts given;A 37 % Chromat.
B 12 % Chromat.
C 38 % Chromat.
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given;A 35 % Chromat.
B 12 % Chromat.
C 34 % Chromat.
tetramethylsilane
75-76-3

tetramethylsilane

1-chloroadamantane
935-56-8

1-chloroadamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

adamantane
281-23-2

adamantane

C

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

D

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3;
tetramethylsilane
75-76-3

tetramethylsilane

1-chloroadamantane
935-56-8

1-chloroadamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Yield given. Further byproducts given. Yields of byproduct given;
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given;
tetramethylsilane
75-76-3

tetramethylsilane

adamantane
281-23-2

adamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 3h; Yield given. Yields of byproduct given;
tetramethylsilane
75-76-3

tetramethylsilane

adamantane
281-23-2

adamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5,7-tetramethyladamantane
1687-36-1

1,3,5,7-tetramethyladamantane

C

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

E

1,3,5-Trimethyl-7-ethyladamantane
2109-06-0

1,3,5-Trimethyl-7-ethyladamantane

F

1,2,3,5,7-pentamethyladamantane
30904-21-3

1,2,3,5,7-pentamethyladamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Product distribution; other time; other temperature; AlCl3 instead AlBr3;
tetramethylsilane
75-76-3

tetramethylsilane

adamantane
281-23-2

adamantane

A

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

B

1,3,5-trimethyladamantane
707-35-7

1,3,5-trimethyladamantane

1-methyl-adamantane
768-91-2

1-methyl-adamantane

Conditions
ConditionsYield
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Yield given. Yields of byproduct given;
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

di-1-(3,5-dimethyladamantyl)phosphinic chloride

di-1-(3,5-dimethyladamantyl)phosphinic chloride

Conditions
ConditionsYield
With aluminum (III) chloride; phosphorus trichloride for 5h; Inert atmosphere; Reflux;99%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-formamido-3,5-dimethyltricyclo[3.3.1.13,7]decane
351329-88-9

1-formamido-3,5-dimethyltricyclo[3.3.1.13,7]decane

Conditions
ConditionsYield
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 20 - 25℃; for 6.5h;
Stage #2: formamide at 30 - 35℃; for 3h;
96.96%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0 - 5℃;
Stage #2: formamide at 55 - 60℃; for 2h;
Stage #3: With ammonia In dichloromethane; water at 0 - 25℃;
95%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h;
Stage #2: formamide at 0 - 20℃; for 2.5h; Ritter-type reaction; Further stages.;
89%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃;
Stage #2: formamide at 0 - 20℃;
89.3%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃;
Stage #2: formamide at 0 - 20℃; for 2h;
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

trifluoroacetic acid
76-05-1

trifluoroacetic acid

1,3-dimethyl-5-adamantanol
707-37-9

1,3-dimethyl-5-adamantanol

Conditions
ConditionsYield
Stage #1: 1,3-dimethyladamantane; trifluoroacetic acid With oxygen; sodium nitrite at 20℃; for 3h;
Stage #2: With hydrogenchloride Further stages.;
96%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

chlorophenylcarbene
19807-41-1

chlorophenylcarbene

C19H25Cl

C19H25Cl

Conditions
ConditionsYield
In benzene at 23℃; Kinetics;96%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1,3-dimethyl-5-adamantanol
707-37-9

1,3-dimethyl-5-adamantanol

Conditions
ConditionsYield
With water; bromine at 25℃; Reflux;95%
With oxygen; cobalt acetylacetonate In acetic acid at 80℃; under 760.051 Torr; for 15h;90%
With water; bromine for 2h; Ambient temperature;87%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

bis(3,5-dimethyl-1-adamantyl)phosphinic chloride
131211-29-5

bis(3,5-dimethyl-1-adamantyl)phosphinic chloride

Conditions
ConditionsYield
With aluminium trichloride; phosphorus trichloride at 75 - 85℃; for 5h;94.7%
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide
816444-61-8

N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

(S)-N-[[(3,5-dimethyl-1-adamantyl)amino](4-tolyl)oxido-λ4-sulfanylidene]tosylamide
1396022-02-8

(S)-N-[[(3,5-dimethyl-1-adamantyl)amino](4-tolyl)oxido-λ4-sulfanylidene]tosylamide

Conditions
ConditionsYield
With dirhodium tetrakis{(2S)-2-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)propanoic acid}; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,2-dichloro-ethane at -35℃; for 72h; Molecular sieve; diastereoselective reaction;94%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

3,5-dimethyl-1-bromoadamantane
941-37-7

3,5-dimethyl-1-bromoadamantane

Conditions
ConditionsYield
With aluminum (III) chloride; bromine In 1,2-dichloro-ethane at 15℃; Reagent/catalyst; Temperature; Solvent;92%
With bromine for 12h; Reflux;91.5%
With iron(III)-acetylacetonate; carbon tetrabromide at 150℃; for 3h; Sealed tube; Inert atmosphere;85%
2-amino-3-pyridinecarbonitrile
24517-64-4

2-amino-3-pyridinecarbonitrile

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)nicotinonitrile
1514005-20-9

2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)nicotinonitrile

Conditions
ConditionsYield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;92%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

acetonitrile
75-05-8

acetonitrile

1,3‑diacetamido‑5,7‑dimethyladamantane
14931-70-5

1,3‑diacetamido‑5,7‑dimethyladamantane

Conditions
ConditionsYield
Stage #1: 1,3-dimethyladamantane With nitric acid at 25℃; for 1h;
Stage #2: acetonitrile for 0.5h;
Stage #3: acetonitrile With sulfuric acid at 20℃; for 4h; Ritter Amidation;
92%
Trifluoromethanesulfonamide
421-85-2

Trifluoromethanesulfonamide

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

N-((1,3,5,7)-3,5-dimethyladamantan-1-yl)-1,1,1-trifluoromethanesulfonamide
1309688-17-2

N-((1,3,5,7)-3,5-dimethyladamantan-1-yl)-1,1,1-trifluoromethanesulfonamide

Conditions
ConditionsYield
With bis(4-bromobenzoyloxy)iodobenzene; iodine In dichloromethane at 20℃; for 14h; Schlenk technique; Inert atmosphere; Irradiation;92%
methanol
67-56-1

methanol

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

carbon monoxide
201230-82-2

carbon monoxide

dimethyl 5,7-dimethyladamantane-1,3-dicarboxylate
24556-26-1

dimethyl 5,7-dimethyladamantane-1,3-dicarboxylate

Conditions
ConditionsYield
Stage #1: 1,3-dimethyladamantane; carbon monoxide With Al2Br7(1-)*CBr3(1+) In 1,2-dibromomethane at 0℃; under 760.051 Torr; for 3h;
Stage #2: methanol In 1,2-dibromomethane at 0 - 20℃; chemoselective reaction;
91%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

3,5-dimethyladamantan-1-yl nitrate
101821-77-6

3,5-dimethyladamantan-1-yl nitrate

Conditions
ConditionsYield
With nitric acid at 10℃;90.3%
With nitric acid In acetic acid at 20℃; for 1h;
With nitric acid for 3h; Cooling;
With nitric acid In acetic acid at 15 - 20℃; for 1h;
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

acetonitrile
75-05-8

acetonitrile

1-acetamido-3,5-dimethyladamantane
19982-07-1

1-acetamido-3,5-dimethyladamantane

Conditions
ConditionsYield
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h;
Stage #2: acetonitrile at 0 - 20℃; for 3.5h; Ritter-type reaction; Further stages.;
90.3%
With sulfuric acid In tert-butyl alcohol at 60 - 65℃; for 18h; Ritter Amidation; Large scale;90%
With sulfuric acid at 60 - 80℃; for 10h; Ritter Amidation;73.5%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1,3‑dibromo‑5,7‑dimethyladamantane
21912-23-2

1,3‑dibromo‑5,7‑dimethyladamantane

Conditions
ConditionsYield
With bromine; iron In 1,2-dichloro-ethane at 25℃; Temperature; Reagent/catalyst; Solvent;90%
With bromine; iron at 20℃; for 1.5h; Bromination;83%
formic acid
64-18-6

formic acid

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

5,7-dimethyl-1,3-adamantanedicarboxylic acid
13928-68-2

5,7-dimethyl-1,3-adamantanedicarboxylic acid

Conditions
ConditionsYield
With sulfuric acid at 20 - 28℃; for 5h;90%
1,2,3-Benzotriazole
95-14-7

1,2,3-Benzotriazole

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)-1H-benzo[d][1,2,3]triazole
1528767-79-4

1-((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)-1H-benzo[d][1,2,3]triazole

Conditions
ConditionsYield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;89%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

anthranilic acid nitrile
1885-29-6

anthranilic acid nitrile

2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)benzonitrile
1521610-22-9

2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)benzonitrile

Conditions
ConditionsYield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;87%
maleic anhydride
108-31-6

maleic anhydride

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

3-(3,5-Dimethyl-adamantan-1-yl)-dihydro-furan-2,5-dione
119347-82-9

3-(3,5-Dimethyl-adamantan-1-yl)-dihydro-furan-2,5-dione

Conditions
ConditionsYield
With di-tert-butyl peroxide In chlorobenzene at 150℃; for 5h;86%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1,3-difluoro-5,7-dimethyladamantane
60389-56-2

1,3-difluoro-5,7-dimethyladamantane

Conditions
ConditionsYield
With iodine pentafluoride In 1,2-dichloro-ethane at 80℃; for 12h; regioselective reaction;86%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

urethane
51-79-6

urethane

1-ethoxycarbonylamino-3,5-dimethyladamantane
118648-19-4

1-ethoxycarbonylamino-3,5-dimethyladamantane

Conditions
ConditionsYield
With nitric acid at 30℃; for 1h;85%
With nitric acid 1.) 25 deg C, 15 min, 2.) RT, 1 h; Yield given. Multistep reaction;
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

1-fluoro-3,5-dimethyladamantane
30934-81-7

1-fluoro-3,5-dimethyladamantane

Conditions
ConditionsYield
With iodine pentafluoride In dichloromethane at 10℃; for 12h; regioselective reaction;85%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

4-(tert-butyl)phenyl sulfamate

4-(tert-butyl)phenyl sulfamate

C22H33NO3S

C22H33NO3S

Conditions
ConditionsYield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2h;85%
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide
816444-61-8

N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide

1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

(1r,3R,5S,7r)-N-[N-(S)-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-3,5-dimethyladamantan-1-amine

(1r,3R,5S,7r)-N-[N-(S)-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-3,5-dimethyladamantan-1-amine

Conditions
ConditionsYield
With Rh2(S-N-(1,8-naphthoyl)alanine)4; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,1,2,2-tetrachloroethane at -78 - -35℃; for 72h; Molecular sieve; Inert atmosphere;83%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

2,2,2-trifluoroethylsulfamate ester
92720-79-1

2,2,2-trifluoroethylsulfamate ester

C14H22F3NO3S

C14H22F3NO3S

Conditions
ConditionsYield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h;81%
1,3-dimethyladamantane
702-79-4

1,3-dimethyladamantane

phenyl sulfamate
19792-91-7

phenyl sulfamate

C18H25NO3S

C18H25NO3S

Conditions
ConditionsYield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h;80%
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