1,3-Dimethyladamantane supplier

Name
1,3-Dimethyladamantane
EINECS 211-870-8
CAS No. 702-79-4
Article Data60
CAS DataBase
Density 0.972 g/cm³
Solubility Soluble in organic solvents,insoluble in water.
Melting Point -30 °C
Formula C₁₂H₂0
Boiling Point 199.9 °C at 760 mmHg
Molecular Weight 164.291
Flash Point 52.8 °C
Transport Information
Appearance clear colourless liquid
Safety 16
Risk Codes 10
Molecular Structure
Hazard Symbols F
Synonyms Adamantane,1,3-dimethyl- (6CI,8CI);1,3-Dimethyltricyclo[3.3.1.13,7]decane;1,3-dimethyl-adamantane;Tricyclo[3.3.1.13,7]decane,1,3-dimethyl-;
PSA 0.00000
LogP 3.61280

Synthetic route

: 941-37-7
3,5-dimethyl-1-bromoadamantane

: 702-79-4
1,3-dimethyladamantane

Conditions

Conditions	Yield
With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride at 90℃; for 1h; Solvent; Barton-McCombie Deoxygenation; Inert atmosphere;	100%
With decane; 2,2’-azobis(4-methoxy-2,4-dimethyl)valeronitrile; tri-n-butyl-tin hydride In toluene at 80℃; for 0.0166667h;	99 % Chromat.
Multi-step reaction with 2 steps 1: 98 percent / aq. HCl / dimethylformamide / 1.5 h 2: H2SO4 (91.5percent) / 72 h / Ambient temperature; var. of conc.of H2SO4, and var. of reaction time View Scheme

: 702-77-2
1-bromo-3-methyladamantane

: 75-16-1
methylmagnesium bromide

A: 702-79-4
1,3-dimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
In dibutyl ether at 85℃;	A 99% B 1%

...Expand

: 941-37-7
3,5-dimethyl-1-bromoadamantane

: 75-16-1
methylmagnesium bromide

A: 702-79-4
1,3-dimethyladamantane

B: 707-35-7
1,3,5-trimethyladamantane

Conditions

Conditions	Yield
In dibutyl ether at 95℃;	A 2% B 98%

...Expand

: 2146-36-3
decahydroacenaphthene

: 702-79-4
1,3-dimethyladamantane

Conditions

Conditions	Yield
With aluminium trichloride at 69.85℃; for 50h;	90%
With hydrogen fluoride; boron trifluoride Temperature; Autoclave;	75%
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Concentration; Temperature; Time; Autoclave; Sealed tube;	65%

: 281-23-2
adamantane

: 74-88-4
methyl iodide

A: 702-79-4
1,3-dimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With Rh(PPh3)3Cl In dichloromethane at 150℃; for 3h;	A 79% B 21%

...Expand

: 2146-36-3
decahydroacenaphthene

A: 702-79-4
1,3-dimethyladamantane

B: 770-69-4
1-ethyladamantane

Conditions

Conditions	Yield
With hydrogen fluoride; boron trifluoride at 100℃; for 4h; Temperature; Autoclave;	A 77% B 15%

: 26919-42-6
(3,5-dimethyl-adamantan-1-yl)-methanol

: 702-79-4
1,3-dimethyladamantane

Conditions

Conditions	Yield
With cerium(III) chloride; 9,10-diphenylanthracene; 1,2-bis(2,4,6-triisopropylphenyl)disulfane; tetrabutyl-ammonium chloride In acetonitrile for 24h; Irradiation; Inert atmosphere;	69%

: 58865-53-5
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A: 702-79-4
1,3-dimethyladamantane

B: 770-69-4
1-ethyladamantane

C: 16267-35-9
1,4-dimethyladamantane

Conditions

Conditions	Yield
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 10h; Autoclave; Sealed tube;	A 67% B 6% C 22%

...Expand

: 876-53-9
1,3-dibromoadamantane

: 75-16-1
methylmagnesium bromide

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
In dibutyl ether at 140℃;	A 52% B 4% C 44%

...Expand

: 876-53-9
1,3-dibromoadamantane

: 75-16-1
methylmagnesium bromide

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

C: 702-77-2
1-bromo-3-methyladamantane

Conditions

Conditions	Yield
In dibutyl ether at 140℃;	A 52% B 4% C 44%

...Expand

: 876-53-9
1,3-dibromoadamantane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With methylmagnesium bromide In dibutyl ether at 140℃;	A 52% B 4% C 44%

...Expand

: 58865-53-5
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A: 702-79-4
1,3-dimethyladamantane

B: 16207-81-1
1,2-dimethyladamantane

C: 770-69-4
1-ethyladamantane

D: 16267-35-9
1,4-dimethyladamantane

Conditions

Conditions	Yield
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 30h; Concentration; Time;	A 49% B 9% C 11% D 24%
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time;	A 18% B 8% C 10% D 21%

...Expand

: 75-76-3
tetramethylsilane

: 768-95-6
1-adamanthanol

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

C: 1687-36-1
1,3,5,7-tetramethyladamantane

D: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 5h; Product distribution; other time;;	A 33% B n/a C 10% D 29% E 13%

...Expand

: 75-76-3
tetramethylsilane

: 768-95-6
1-adamanthanol

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 5h;	A 33% B 10% C 29% D 13%
With aluminum tri-bromide

...Expand

: 1678-91-7
ethyl-cyclohexane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 493-02-7
trans-Decalin

D: 770-69-4
1-ethyladamantane

E: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;	A 18.76% B 6.3% C 1.25% D 3.46% E 15.01% F 2.76%

...Expand

: 82166-21-0
methyl cyclohexane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 493-02-7
trans-Decalin

D: 770-69-4
1-ethyladamantane

E: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;	A 10.78% B 7.79% C 4.7% D 4.25% E 17.49% F 1.5%

...Expand

: 58865-53-5
(1α,4α,4aβ,5α,8α,8aβ)-decahydro-1,4:5,8-dimethanonaphthalene

A: 702-79-4
1,3-dimethyladamantane

B: 16267-35-9
1,4-dimethyladamantane

Conditions

Conditions	Yield
With Y-zeolite(Na/H 0.4) In hexane at 300℃; for 10h; Concentration; Time;	A 17% B 15%
With Y-zeolite(Na/H 0.97) In hexane at 300℃; for 30h; Concentration; Time;	A 6% B 9%

: 696-29-7
(1-methylethyl)-cyclohexane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 493-02-7
trans-Decalin

D: 770-69-4
1-ethyladamantane

E: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;	A 8.98% B 7.37% C 7.47% D 2.04% E 13.24% F 1.59%

...Expand

: 1678-98-4
isobutylcyclohexane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 493-02-7
trans-Decalin

D: 770-69-4
1-ethyladamantane

E: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride; tertiary butyl chloride at 160℃; for 15h; Product distribution;	A 8.23% B 8.26% C 9.82% D 0.59% E 10.13% F 1.33%

...Expand

: 768-90-1
1-Adamantyl bromide

: 75-76-3
tetramethylsilane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Further byproducts given;	A 32 % Chromat. B 21 % Chromat. C 39 % Chromat.
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given;	A 35 % Chromat. B 13 % Chromat. C 37 % Chromat.

...Expand

: 768-90-1
1-Adamantyl bromide

: 75-76-3
tetramethylsilane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

C: 1687-36-1
1,3,5,7-tetramethyladamantane

D: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3; AlCl3 instead AlBr3;

...Expand

: 768-90-1
1-Adamantyl bromide

: 75-76-3
tetramethylsilane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

C: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminium trichloride In dichloromethane at 20℃; for 0.166667h; Yield given. Yields of byproduct given;

...Expand

: 768-90-1
1-Adamantyl bromide

: 75-76-3
tetramethylsilane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given;
With aluminum tri-bromide In dichloromethane at 40℃; for 1.5h; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 74-83-9
methyl bromide

: 702-77-2
1-bromo-3-methyladamantane

: 702-79-4
1,3-dimethyladamantane

Conditions

Conditions	Yield
With magnesium 1.) n-butyl ether, 2.) n-butyl ether, 70 deg C; Yield given. Multistep reaction;

: 75-76-3
tetramethylsilane

: 935-56-8
1-chloroadamantane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Further byproducts given;	A 37 % Chromat. B 12 % Chromat. C 38 % Chromat.
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Further byproducts given;	A 35 % Chromat. B 12 % Chromat. C 34 % Chromat.

...Expand

: 75-76-3
tetramethylsilane

: 935-56-8
1-chloroadamantane

A: 702-79-4
1,3-dimethyladamantane

B: 281-23-2
adamantane

C: 1687-36-1
1,3,5,7-tetramethyladamantane

D: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Product distribution; other time; various ratios of the educts and AlBr3;

...Expand

: 75-76-3
tetramethylsilane

: 935-56-8
1-chloroadamantane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 0.166667h; Yield given. Further byproducts given. Yields of byproduct given;
With aluminum tri-bromide In dichloromethane at 20℃; for 1h; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 75-76-3
tetramethylsilane

: 281-23-2
adamantane

A: 702-79-4
1,3-dimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 3h; Yield given. Yields of byproduct given;

...Expand

: 75-76-3
tetramethylsilane

: 281-23-2
adamantane

A: 702-79-4
1,3-dimethyladamantane

B: 1687-36-1
1,3,5,7-tetramethyladamantane

C: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

E: 2109-06-0
1,3,5-Trimethyl-7-ethyladamantane

F: 30904-21-3
1,2,3,5,7-pentamethyladamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Product distribution; other time; other temperature; AlCl3 instead AlBr3;

...Expand

: 75-76-3
tetramethylsilane

: 281-23-2
adamantane

A: 702-79-4
1,3-dimethyladamantane

B: 707-35-7
1,3,5-trimethyladamantane

: 768-91-2
1-methyl-adamantane

Conditions

Conditions	Yield
With aluminum tri-bromide In dichloromethane at 20℃; for 6h; Yield given. Yields of byproduct given;

...Expand

: 702-79-4
1,3-dimethyladamantane

: di-1-(3,5-dimethyladamantyl)phosphinic chloride

Conditions

Conditions	Yield
With aluminum (III) chloride; phosphorus trichloride for 5h; Inert atmosphere; Reflux;	99%

: 702-79-4
1,3-dimethyladamantane

: 77287-34-4, 77287-35-5, 60100-09-6
formamide

: 351329-88-9
1-formamido-3,5-dimethyltricyclo[3.3.1.13,7]decane

Conditions

Conditions	Yield
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 20 - 25℃; for 6.5h; Stage #2: formamide at 30 - 35℃; for 3h;	96.96%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0 - 5℃; Stage #2: formamide at 55 - 60℃; for 2h; Stage #3: With ammonia In dichloromethane; water at 0 - 25℃;	95%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h; Stage #2: formamide at 0 - 20℃; for 2.5h; Ritter-type reaction; Further stages.;	89%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; Stage #2: formamide at 0 - 20℃;	89.3%
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; Stage #2: formamide at 0 - 20℃; for 2h;

: 702-79-4
1,3-dimethyladamantane

: 76-05-1
trifluoroacetic acid

: 707-37-9
1,3-dimethyl-5-adamantanol

Conditions

Conditions	Yield
Stage #1: 1,3-dimethyladamantane; trifluoroacetic acid With oxygen; sodium nitrite at 20℃; for 3h; Stage #2: With hydrogenchloride Further stages.;	96%

: 702-79-4
1,3-dimethyladamantane

: 19807-41-1
chlorophenylcarbene

: C19H25Cl

Conditions

Conditions	Yield
In benzene at 23℃; Kinetics;	96%

: 702-79-4
1,3-dimethyladamantane

: 707-37-9
1,3-dimethyl-5-adamantanol

Conditions

Conditions	Yield
With water; bromine at 25℃; Reflux;	95%
With oxygen; cobalt acetylacetonate In acetic acid at 80℃; under 760.051 Torr; for 15h;	90%
With water; bromine for 2h; Ambient temperature;	87%

: 702-79-4
1,3-dimethyladamantane

: 131211-29-5
bis(3,5-dimethyl-1-adamantyl)phosphinic chloride

Conditions

Conditions	Yield
With aluminium trichloride; phosphorus trichloride at 75 - 85℃; for 5h;	94.7%

: 816444-61-8
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide

: 702-79-4
1,3-dimethyladamantane

: 1396022-02-8
(S)-N-[[(3,5-dimethyl-1-adamantyl)amino](4-tolyl)oxido-λ4-sulfanylidene]tosylamide

Conditions

Conditions	Yield
With dirhodium tetrakis{(2S)-2-(1,3-dioxo-1H-benzo[de]isoquinolin-2(3H)-yl)propanoic acid}; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,2-dichloro-ethane at -35℃; for 72h; Molecular sieve; diastereoselective reaction;	94%

: 702-79-4
1,3-dimethyladamantane

: 941-37-7
3,5-dimethyl-1-bromoadamantane

Conditions

Conditions	Yield
With aluminum (III) chloride; bromine In 1,2-dichloro-ethane at 15℃; Reagent/catalyst; Temperature; Solvent;	92%
With bromine for 12h; Reflux;	91.5%
With iron(III)-acetylacetonate; carbon tetrabromide at 150℃; for 3h; Sealed tube; Inert atmosphere;	85%

: 24517-64-4
2-amino-3-pyridinecarbonitrile

: 702-79-4
1,3-dimethyladamantane

: 1514005-20-9
2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)nicotinonitrile

Conditions

Conditions	Yield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;	92%

: 702-79-4
1,3-dimethyladamantane

: 75-05-8
acetonitrile

: 14931-70-5
1,3‑diacetamido‑5,7‑dimethyladamantane

Conditions

Conditions	Yield
Stage #1: 1,3-dimethyladamantane With nitric acid at 25℃; for 1h; Stage #2: acetonitrile for 0.5h; Stage #3: acetonitrile With sulfuric acid at 20℃; for 4h; Ritter Amidation;	92%

: 421-85-2
Trifluoromethanesulfonamide

: 702-79-4
1,3-dimethyladamantane

: 1309688-17-2
N-((1,3,5,7)-3,5-dimethyladamantan-1-yl)-1,1,1-trifluoromethanesulfonamide

Conditions

Conditions	Yield
With bis(4-bromobenzoyloxy)iodobenzene; iodine In dichloromethane at 20℃; for 14h; Schlenk technique; Inert atmosphere; Irradiation;	92%

: 67-56-1
methanol

: 702-79-4
1,3-dimethyladamantane

: 201230-82-2
carbon monoxide

: 24556-26-1
dimethyl 5,7-dimethyladamantane-1,3-dicarboxylate

Conditions

Conditions	Yield
Stage #1: 1,3-dimethyladamantane; carbon monoxide With Al2Br7(1-)*CBr3(1+) In 1,2-dibromomethane at 0℃; under 760.051 Torr; for 3h; Stage #2: methanol In 1,2-dibromomethane at 0 - 20℃; chemoselective reaction;	91%

...Expand

: 702-79-4
1,3-dimethyladamantane

: 101821-77-6
3,5-dimethyladamantan-1-yl nitrate

Conditions

Conditions	Yield
With nitric acid at 10℃;	90.3%
With nitric acid In acetic acid at 20℃; for 1h;
With nitric acid for 3h; Cooling;
With nitric acid In acetic acid at 15 - 20℃; for 1h;

: 702-79-4
1,3-dimethyladamantane

: 75-05-8
acetonitrile

: 19982-07-1
1-acetamido-3,5-dimethyladamantane

Conditions

Conditions	Yield
Stage #1: 1,3-dimethyladamantane With sulfuric acid; nitric acid at 0℃; for 6h; Stage #2: acetonitrile at 0 - 20℃; for 3.5h; Ritter-type reaction; Further stages.;	90.3%
With sulfuric acid In tert-butyl alcohol at 60 - 65℃; for 18h; Ritter Amidation; Large scale;	90%
With sulfuric acid at 60 - 80℃; for 10h; Ritter Amidation;	73.5%

: 702-79-4
1,3-dimethyladamantane

: 21912-23-2
1,3‑dibromo‑5,7‑dimethyladamantane

Conditions

Conditions	Yield
With bromine; iron In 1,2-dichloro-ethane at 25℃; Temperature; Reagent/catalyst; Solvent;	90%
With bromine; iron at 20℃; for 1.5h; Bromination;	83%

: 64-18-6
formic acid

: 702-79-4
1,3-dimethyladamantane

: 13928-68-2
5,7-dimethyl-1,3-adamantanedicarboxylic acid

Conditions

Conditions	Yield
With sulfuric acid at 20 - 28℃; for 5h;	90%

: 95-14-7
1,2,3-Benzotriazole

: 702-79-4
1,3-dimethyladamantane

: 1528767-79-4
1-((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)-1H-benzo[d][1,2,3]triazole

Conditions

Conditions	Yield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;	89%

: 702-79-4
1,3-dimethyladamantane

: 1885-29-6
anthranilic acid nitrile

: 1521610-22-9
2-(((1r,3R,5S,7r)-3,5-dimethyladamantan-1-yl)amino)benzonitrile

Conditions

Conditions	Yield
With aluminum tri-bromide; carbon tetrabromide In neat (no solvent) at 15 - 20℃; for 0.0833333h; Green chemistry; chemoselective reaction;	87%

: 108-31-6
maleic anhydride

: 702-79-4
1,3-dimethyladamantane

: 119347-82-9
3-(3,5-Dimethyl-adamantan-1-yl)-dihydro-furan-2,5-dione

Conditions

Conditions	Yield
With di-tert-butyl peroxide In chlorobenzene at 150℃; for 5h;	86%

: 702-79-4
1,3-dimethyladamantane

: 60389-56-2
1,3-difluoro-5,7-dimethyladamantane

Conditions

Conditions	Yield
With iodine pentafluoride In 1,2-dichloro-ethane at 80℃; for 12h; regioselective reaction;	86%

: 702-79-4
1,3-dimethyladamantane

: 51-79-6
urethane

: 118648-19-4
1-ethoxycarbonylamino-3,5-dimethyladamantane

Conditions

Conditions	Yield
With nitric acid at 30℃; for 1h;	85%
With nitric acid 1.) 25 deg C, 15 min, 2.) RT, 1 h; Yield given. Multistep reaction;

: 702-79-4
1,3-dimethyladamantane

: 30934-81-7
1-fluoro-3,5-dimethyladamantane

Conditions

Conditions	Yield
With iodine pentafluoride In dichloromethane at 10℃; for 12h; regioselective reaction;	85%

: 702-79-4
1,3-dimethyladamantane

: 4-(tert-butyl)phenyl sulfamate

: C22H33NO3S

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2h;	85%

: 816444-61-8
N-[(1S)-amino(4-tolyl)oxido-λ4-sulfanylidene]tosylamide

: 702-79-4
1,3-dimethyladamantane

: (1r,3R,5S,7r)-N-[N-(S)-(p-toluenesulfonyl)-p-toluenesulfonimidoyl]-3,5-dimethyladamantan-1-amine

Conditions

Conditions	Yield
With Rh2(S-N-(1,8-naphthoyl)alanine)4; bis(tertbutylcarbonyloxy)iodobenzene In methanol; 1,1,2,2-tetrachloroethane at -78 - -35℃; for 72h; Molecular sieve; Inert atmosphere;	83%

: 702-79-4
1,3-dimethyladamantane

: 92720-79-1
2,2,2-trifluoroethylsulfamate ester

: C14H22F3NO3S

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h;	81%

: 702-79-4
1,3-dimethyladamantane

: 19792-91-7
phenyl sulfamate

: C18H25NO3S

Conditions

Conditions	Yield
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene; sodium hydrogencarbonate for 2.5h;	80%

1,3-Dimethyladamantane Chemical Properties

Molecular Structure:
Molecular Formula: C₁₂H₂0
Molecular Weight: 164.29
CAS NO: 702-79-4
EINECS: 211-870-8
H bond acceptors: 0
H bond donors: 0
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å²
Index of Refraction: 1.52
Molar Refractivity: 51.44 cm³
Molar Volume: 168.9 cm³
Surface Tension: 39.1 dyne/cm
Density: 0.972 g/cm³
Flash Point: 52.8 °C
Enthalpy of Vaporization: 41.83 kJ/mol
Boiling Point: 199.9 °C at 760 mmHg
Vapour Pressure: 0.472 mmHg at 25°C
Melting Point: -30 °C
Stability: Stable. Incompatible with strong oxidizing agents. Flammable
Appearance: clear colourless liquid
IUPAC Name: 1,3-Dimethyladamantane
The chemical synonyms of 1,3-Dimethyladamantane (CAS NO.702-79-4): 1,3-Dimethyltricyclo(3.3.1.13,7)decane
Product Categories: Chemical intermediate for Memantine HCl;Adamantane derivatives;Adamantanes;Alkanes;Cyclic;Organic Building Blocks

1,3-Dimethyladamantane Safety Profile

1,3-Dimethyladamantane (CAS NO.702-79-4):
Hazard Codes: F
Risk Statements: 10
R10:Flammable.
Safety Statements: 16
S16:Keep away from sources of ignition.
RIDADR UN: 1993 3/PG 3
WGK Germany: 3
HazardClass: 3
PackingGroup: III

Product Name

1,3-Dimethyladamantane

Synthetic route

1,3-Dimethyladamantane Chemical Properties

1,3-Dimethyladamantane Safety Profile

Related Products

Hot Products