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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

High purity Diphenylacetonitrile 98% TOP1 supplier in China

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Ality Chemical Corporation

Diphenylacetonitrile Basic information Product Name: Diphenylacetonitrile Synonyms: dibenzylcyanide;Difenylacetonitril;diphenyl-acetonitril;Diphenyl-alpha-cyanomethane;USAF kf-13;usafkf-13;Benzeneacetonitrile, alpha-phenyl-;DIPHENYLACETONITRILE

Factory Supply Diphenylacetonitrile 86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Other

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Qingdao Beluga Import and Export Co., LTD

Beluga chemical professional supply 2,2-Diphenylacetonitrile CAS 86-29-3 1. Beluga Chemical has a professional RESEARCH and development team and strong technical force to ensure technical support and research capabilities. 2. Made in China and ex

2,2-Diphenylacetonitrile CAS 86-29-3

Cas:86-29-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualified

Factory Supply Diphenylacetonitrile Supplier Manufacturer With Competitive Price

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Jinan Finer Chemical Co., Ltd

Product description: Product name Diphenylacetonitrile CAS number 86-29-3 Assay ≥98% Appearance White crystalline powder Capacity 500mt/year Application Pharmaceutical/pestic

Diphenylacetonitrile

Cas:86-29-3

Min.Order:10 Gram

FOB Price: $12.0

Type:Lab/Research institutions

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White crystalline powder Complies Assay 99%min

high purity Diphenylacetonitrile 99%min,main manufacture products

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $100.0

Type:Manufacturers

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

Diphenylacetonitrile

Cas:86-29-3

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

ISO system Fast delivery Competitive price Appearance:white powder Storage:Normal condition Package:25kg/bag or 25kg/drum Application:herbicide Transportation:by sea Port:shanghai

Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience 2. Free samples will be provided,ensure specifications and quality are right for customer 3. Customers will receive the most professional techn

Large Stock 99.0% Diphenylacetonitrile 86-29-3 Producer

Cas:86-29-3

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

High purity Diphenylacetonitrile 98% TOP1 supplier in China CAS NO.86-29-3

Cas:86-29-3

Min.Order:1 Metric Ton

FOB Price: $1.0 / 3.0

Type:Trading Company

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Chemwill Asia Co., Ltd.

Diphenylacetonitrile -- CHemwill

Cas:86-29-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

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Henan Tianfu Chemical Co., Ltd.

Diphenylacetonitrile Basic information Product Name: Diphenylacetonitrile Synonyms: DIPHENYLMETHYL CYANIDE;DIPHENYLACETONITRILE;DIPHENYL-A-CYANOMETHANE;DIPHENATRILE

Diphenylacetonitrile 86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Nengqian Chemical Import and Export Co., LTD

Our advantages: 1, High quality with competitive price: 1) Standard:BP/USP/EP/Enterprise standard 2) All Purity≥99% 3) We are manufacturer and can provide high quality products with factory price. 2, Fast and safe delivery 1) Parcel can be

2021 best selling goods Diphenyl acetonitrile 86-29-3

Cas:86-29-3

Min.Order:1 Gram

FOB Price: $8.0 / 18.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 86-29-3 with fast shipping

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Hot Sell Factory Supply Raw Material CAS 86-29-3 Diphenylacetonitrile

Cas:86-29-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $2.5 / 5.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

Diphenylacetonitrile/ LIDE PHARMA- Factory supply / Best price

Cas:86-29-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Henan Sinotech Import&Export Corporation

Product name: Diphenylacetonitrile CAS : 86-29-3 Appearance: White crystals Content: 99% Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application:Syntheses Material Intermediates Transportation:B

Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED intermediat

Diphenylacetonitrile 86-29-3CAS NO.: 86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $4.0 / 5.0

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzeneacetonitrile, alpha-phenyl- 86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Diphenylacetonitrile with CAS:86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $13.0 / 30.0

Type:Trading Company

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzeneacetonitrile, alpha-phenyl-

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shanghai Terui OP New Material Technology Co., Ltd.

We have overseas warehouses in California, New Laredo Mexico, Vancouver Canada, Amsterdam Netherlands, and Melbourne Australia. Overseas warehouses can provide some of the best-selling products. We look forward to the cooperation of local powerful

Hebei Mojin Biotechnology Co.,Ltd

Hebei Mojin Biotechnology Co., Ltd, Our company is a professional in lead acetate, diphenyl ethylamine and other chemical raw materials and chemical reagents research and development production enterprises. Our business covers more than 30 countrie

White Crystalline Powder Factory Price Diphenylacetonitrile CAS 86-29-3

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Trading Company

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Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 86-29-3 Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

2,2-Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

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Lonwin Chemical Group Limited

Diphenylacetonitrile CAS: 86-29-3 Specification Product name Diphenylacetonitrile CAS number 86-29-3 Assay ≥98% Appearance White crystalline powder Capacity 500mt/year Applicat

Factory supply Diphenylacetonitrile

Cas:86-29-3

Min.Order:1 Kilogram

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Type:Other

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Synthetic route

1,1-diphenyl-2,2-dinitroethylene
15795-74-1

1,1-diphenyl-2,2-dinitroethylene

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With samarium diiodide In tetrahydrofuran for 2h; Ambient temperature;100%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

diphenylmethyl p-tolyl sulfone
5433-78-3

diphenylmethyl p-tolyl sulfone

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 25℃; for 1h; Inert atmosphere;100%
2,2-diphenylacetamide
4695-13-0

2,2-diphenylacetamide

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With copper diacetate; 1,2-bis-(dicyclohexylphosphino)ethane In tetrahydrofuran at 20℃; for 12h; Catalytic behavior; Mechanism; Reagent/catalyst; Solvent; Temperature; Inert atmosphere;99%
With bis(trichloromethyl) carbonate; triethylamine In chloroform at 50℃; for 2h;87%
With palladium diacetate; Selectfluor; acetonitrile at 20℃; for 18h;84%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

diphenylchloromethane
90-99-3

diphenylchloromethane

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With iodine; lithium carbonate In dichloromethane at 35℃; for 5h;99%
With titanium tetrachloride In dichloromethane at 0℃; for 2h;93%
diphenyl-acetaldehyde-oxime
41401-03-0

diphenyl-acetaldehyde-oxime

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With trifluoromethylsulfonic anhydride; Triphenylphosphine oxide In dichloromethane; 1,2-dichloro-ethane for 0.0833333h; Ambient temperature;98%
With 4-nitro-1-((trifluoromethyl)sulfonyl)-1H-imidazole; triethylamine In acetonitrile at 20℃; for 0.166667h; Inert atmosphere; Sealed tube;78%
2,2-diphenyl-pentanedinitrile
2997-21-9

2,2-diphenyl-pentanedinitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
IrH5(P-(i-Pr)3)2 In toluene at 150℃; for 12h;98%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With iodine; lithium carbonate In dichloromethane at 35℃; for 5h;98%
With tris(pentafluorophenyl)borate In acetonitrile at 20℃; for 1h;93%
With zinc trifluoromethanesulfonate In nitromethane at 100℃; for 5.5h;90%
With 3-dodecyl-2-iodo-1-methyl-1H-imidazol-3-ium hexafluoroantimonate; iodine In nitromethane at 20℃; for 2h; Inert atmosphere;46%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

benzhydryl methyl ether
1016-09-7

benzhydryl methyl ether

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With gold(III) chloride In dichloromethane at 20℃; for 0.0833333h; Reagent/catalyst; Time; Inert atmosphere;96%
bromobenzene
108-86-1

bromobenzene

phenylacetonitrile
140-29-4

phenylacetonitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With P(i-BuNCH2CH2)3N; sodium hexamethyldisilazane; palladium diacetate In toluene at 100℃; for 6h;93%
With potassium phosphate; dicyclohexyl-({2-[2-(dicyclohexylphosphanyl)phenyl]-phenyl})-phosphane; palladium diacetate In 1,4-dioxane at 80℃; for 24h; Inert atmosphere; Sealed tube;89%
With potassium hydroxide In water at 45℃; for 17h;84%
With caesium carbonate; triphenylphosphine; palladium dichloride In N,N-dimethyl-formamide at 130℃; for 2h; Phenylation;44%
3,3-Diphenylpropionic acid
606-83-7

3,3-Diphenylpropionic acid

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With trifluoroacetic acid; trifluoroacetic anhydride; sodium nitrite at 20℃; nitrosative cleavage;93%
Diphenylacetaldehyde
947-91-1

Diphenylacetaldehyde

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With ammonia; oxygen In tert-Amyl alcohol at 40℃; under 750.075 Torr; for 24h; Green chemistry;93%
With HCl·DMPU; hydroxylamine hydrochloride In acetonitrile at 60℃;92%
Multi-step reaction with 3 steps
1: ammonia / water / 20 °C / Green chemistry
2: iodine / water / 20 °C / Green chemistry
3: ammonia / water / 20 °C / Green chemistry
View Scheme
phenylacetonitrile
140-29-4

phenylacetonitrile

chlorobenzene
108-90-7

chlorobenzene

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
Stage #1: phenylacetonitrile With tris-(dibenzylideneacetone)dipalladium(0); bis(proazaphosphatrane); potassium tert-butylate In toluene at 20℃; for 0.333333h; Schlenk technique; Inert atmosphere;
Stage #2: chlorobenzene In toluene at 80℃; for 4h; Inert atmosphere; Schlenk technique;
92%
With sodium hexamethyldisilazane; 2,8,9-tris(2-methylpropyl)-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane; palladium diacetate In toluene at 90℃; for 6h;91%
2-hydroxy-2-methylpropanenitrile
75-86-5

2-hydroxy-2-methylpropanenitrile

diphenylchloromethane
90-99-3

diphenylchloromethane

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With potassium carbonate; 18-crown-6 ether In acetonitrile for 6h; Heating;91%
tetra-n-butylammonium cyanide
10442-39-4

tetra-n-butylammonium cyanide

2-(diphenylmethyloxy)tetrahydro-2H-pyran
79373-25-4

2-(diphenylmethyloxy)tetrahydro-2H-pyran

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone In acetonitrile for 6.5h; Heating;90%
2,2-diphenylacetic acid
117-34-0

2,2-diphenylacetic acid

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With sodium azide; TEA; triethylphosphine; (bis-(2-methoxyethyl)amino)sulfur trufluoride In dichloromethane; dimethyl sulfoxide at 0℃; for 30h;90%
With sodium azide; triethylamine; triphenylphosphine; (bis-(2-methoxyethyl)amino)sulfur trufluoride In dichloromethane; dimethyl sulfoxide at 0 - 20℃; for 0.833333h;88%
Multi-step reaction with 2 steps
1: diethyl ether; NH3 / 230 °C / im geschlossenen Rohr
2: PCl5; POCl3
View Scheme
Multi-step reaction with 3 steps
1: thionyl chloride
2: ammonia
3: thionyl chloride / 90 - 105 °C
View Scheme
Multi-step reaction with 2 steps
1.1: thionyl chloride / tetrahydrofuran / 1 h / 50 °C
1.2: 0.08 h / 0 °C
2.1: palladium diacetate; Selectfluor; acetonitrile / 18 h / 20 °C
View Scheme
phenylacetonitrile
140-29-4

phenylacetonitrile

benzyl alcohol
100-51-6

benzyl alcohol

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
Stage #1: benzyl alcohol With sodium methylate In ethyl acetate; acetonitrile at 70℃; for 2h; Industrial scale;
Stage #2: phenylacetonitrile at 110℃; for 10h; Concentration; Industrial scale;
90%
Diphenyl-acetonitrile N-oxide
85823-49-0

Diphenyl-acetonitrile N-oxide

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With acetic acid; zinc In methanol for 3h; Ambient temperature;89.3%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

benzhydryl acetate
954-67-6

benzhydryl acetate

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With iron(III) trifluoromethanesulfonate In 1,2-dichloro-ethane at 50℃; for 1h;88%
toluene-4-sulfonic acid phenyl ester
640-60-8

toluene-4-sulfonic acid phenyl ester

phenylacetonitrile
140-29-4

phenylacetonitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With potassium phosphate; palladium diacetate; XPhos In dichloromethane; tert-butyl alcohol at 110℃; for 4h; Inert atmosphere; Schlenk technique; Sealed tube;87%
phenyl methanesulfonate
16156-59-5

phenyl methanesulfonate

phenylacetonitrile
140-29-4

phenylacetonitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate; XPhos In dichloromethane; tert-butyl alcohol at 110℃; for 4h; Inert atmosphere; Schlenk technique; Sealed tube;86%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

nitromethane
75-52-5

nitromethane

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With trimethylsilyl cyanide; zinc trifluoromethanesulfonate at 100℃; for 6.5h; Time; Inert atmosphere; Schlenk technique;85%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

Bromodiphenylmethane
776-74-9

Bromodiphenylmethane

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With iodine; lithium carbonate In dichloromethane at 35℃; for 5h;85%
bromobenzene
108-86-1

bromobenzene

phenylacetonitrile
140-29-4

phenylacetonitrile

A

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

B

2,2,2-triphenylacetonitrile
6639-43-6

2,2,2-triphenylacetonitrile

Conditions
ConditionsYield
With ethoxyethoxyethanol; sodium amide In 1,2-dimethoxyethane 1.) 45 deg C, 2 h, 2.) 0 deg C, 0.5 h, 3.) 0 deg C, 2 h;A 84%
B 15%
With potassium phosphate; tri-tert-butylphosphonium tetrafluoroborate; palladium diacetate In 1,4-dioxane; water at 100℃; for 12h; Inert atmosphere; Sealed tube;A 33%
B 45%
bromobenzene
108-86-1

bromobenzene

acetonitrile
75-05-8

acetonitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With P(i-BuNCH2CH2)3N; sodium hexamethyldisilazane; palladium diacetate In toluene at 100℃; for 16h;81%
Stage #1: acetonitrile With sodium hexamethyldisilazane In toluene at 25℃; for 0.166667h;
Stage #2: bromobenzene With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; palladium diacetate In toluene at 100℃; for 16h; Further stages.;
68.4%
(η6-fluorobenzene)tricarbonylchromium
12082-05-2

(η6-fluorobenzene)tricarbonylchromium

phenylacetonitrile
140-29-4

phenylacetonitrile

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With potassium hydroxide; iodine In diethyl ether; dimethyl sulfoxide addn. of C6H5CH2CN to mixt. of Cr(CO)3-complex/powd. KOH in DMSO (stirring; 20°C, 1 h), diln. with aq. HCl, extn. with Et2O, treating with excess I2 (room temp., 3 h); distn. (reduced pressure); identification by GC and NMR;80%
bromobenzene
108-86-1

bromobenzene

acetonitrile
75-05-8

acetonitrile

A

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

B

phenylacetonitrile
140-29-4

phenylacetonitrile

Conditions
ConditionsYield
With ethoxyethoxyethanol; sodium amide In 1,2-dimethoxyethane 1.) 45 deg C, 2 h, 2.) -10 deg C, 2 h, 3.) -30 deg C, 14 h;A 17%
B 79%
(RS)-mandelonitrile
532-28-5, 613-88-7

(RS)-mandelonitrile

benzene
71-43-2

benzene

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With sulfuric acid at 40 - 45℃; for 1h;78%
With aluminium trichloride anschliessendes Erwaermen;
With phosphorus pentoxide
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

copper(l) cyanide

copper(l) cyanide

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
In tetrahydrofuran at 80℃; for 12h;75%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

potassium cyanide
151-50-8

potassium cyanide

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Conditions
ConditionsYield
With sulfuric acid In trifluoroacetic acid for 6h; Ambient temperature;71%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

2,2,3,3-tetraphenylsuccinonitrile
3122-21-2

2,2,3,3-tetraphenylsuccinonitrile

Conditions
ConditionsYield
With methanol; sodium bromide In tetrahydrofuran at 20℃; for 0.7h; Electrolysis;100%
With 2-chloro-2-methyl-3-(p-nitrophenyl)-3-propanone; potassium tert-butylate In dimethyl sulfoxide at 20℃; for 1.5h;86%
With 2,6-diphenyl-4-methoxyphenoxyl radical In chlorobenzene at 110℃; for 0.75h;65%
formaldehyd
50-00-0

formaldehyd

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

α-hydroxymethyl-α-phenylbenzenacetonitrile
92552-36-8

α-hydroxymethyl-α-phenylbenzenacetonitrile

Conditions
ConditionsYield
With pyridine; N-benzyl-trimethylammonium hydroxide In water at 0 - 23℃;100%
With N-benzyl-trimethylammonium hydroxide In methanol; toluene at 20℃; for 2h;98%
With water; calcium oxide In tetrahydrofuran at 30℃;
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

allyl bromide
106-95-6

allyl bromide

2,2-diphenyl-pent-4-enenitrile
5558-71-4

2,2-diphenyl-pent-4-enenitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With lithium hexamethyldisilazane In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere;
Stage #2: allyl bromide In tetrahydrofuran at -78 - 20℃; Inert atmosphere;
100%
Stage #1: Diphenylacetonitrile With n-butyllithium; diisopropylamine In tetrahydrofuran; hexane at 0℃; for 1h;
Stage #2: allyl bromide In tetrahydrofuran; hexane at 20℃; for 3h;
98%
Stage #1: Diphenylacetonitrile With sodium hydride In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: allyl bromide In N,N-dimethyl-formamide at 0 - 20℃;
93%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

3(S)-(4-methylphenylsulfonyloxy)-1-phenylmethyl pyrrolidine
26055-95-8

3(S)-(4-methylphenylsulfonyloxy)-1-phenylmethyl pyrrolidine

2,2-diphenyl-2-[(3S)-N-benzyl-pyrrolidin-3-yl]acetonitrile
197964-14-0

2,2-diphenyl-2-[(3S)-N-benzyl-pyrrolidin-3-yl]acetonitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With sodium hydride In toluene for 2h; Reflux;
Stage #2: 3(S)-(4-methylphenylsulfonyloxy)-1-phenylmethyl pyrrolidine In toluene for 3h; Reflux;
100%
2-acetoxy-3-butene
6737-11-7

2-acetoxy-3-butene

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

3-methyl-2,2-diphenylpent-4-enenitrile
60171-90-6

3-methyl-2,2-diphenylpent-4-enenitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 1h; Inert atmosphere; Schlenk technique;
Stage #2: 2-acetoxy-3-butene With bis[(1,2,3-η)-2-butenyl]di(μ-chloro)palladium(II); tri-tert-butyl phosphine In tetrahydrofuran; mineral oil at 0 - 20℃; for 16h; Tsuji-Trost Allylation; Inert atmosphere; Schlenk technique; regioselective reaction;
100%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

benzophenone
119-61-9

benzophenone

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In toluene for 3h;99%
With tetrabutylammomium bromide; oxygen In N,N-dimethyl-formamide Hg cathode, Pt anode, -1.0 V vs SCE;95%
With oxygen; potassium carbonate In water; dimethyl sulfoxide Ambient temperature;95%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

methyl iodide
74-88-4

methyl iodide

2,2-diphenylpropionitrile
5558-67-8

2,2-diphenylpropionitrile

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 85℃; for 2h; Inert atmosphere; Sealed tube;99%
With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 2h; Inert atmosphere;92%
With sodium amide 1.) benzene, reflux, 2 h, 2.) benzene, reflux, 2 h; Yield given. Multistep reaction;
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran at 0 - 20℃; for 1h; Inert atmosphere;
Stage #2: methyl iodide In tetrahydrofuran at 0 - 20℃; for 13h; Inert atmosphere;
Stage #1: Diphenylacetonitrile With sodium hexamethyldisilazane In tetrahydrofuran at -78℃; for 0.5h;
Stage #2: methyl iodide In tetrahydrofuran at -78 - 20℃;
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

(3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine
116183-79-0

(3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine

2,2-diphenyl-2-[(3S)-N-benzyl-pyrrolidin-3-yl]acetonitrile
197964-14-0

2,2-diphenyl-2-[(3S)-N-benzyl-pyrrolidin-3-yl]acetonitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With potassium tert-butylate In tetrahydrofuran at 0℃; for 1.08333h;
Stage #2: (3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine In tetrahydrofuran at 0 - 40℃;
99%
With potassium tert-butylate In tetrahydrofuran at 0 - 40℃; for 16 - 26h;99%
Stage #1: Diphenylacetonitrile With potassium tert-butylate In tetrahydrofuran at 0℃; for 1.08333h;
Stage #2: (3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine In tetrahydrofuran at 0 - 40℃; for 15.0833 - 25.1667h;
99%
Stage #1: Diphenylacetonitrile With potassium tert-butylate In tetrahydrofuran at 0℃; for 1.08333h;
Stage #2: (3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine In tetrahydrofuran at 0 - 40℃; for 15.0833 - 25.1667h;
99%
Stage #1: Diphenylacetonitrile With potassium tert-butylate In tetrahydrofuran at 0℃; for 1.08333h;
Stage #2: (3S)-3-<(4-tolylsulfonyl)oxy>-1-(phenylmethyl)pyrrolidine In tetrahydrofuran at 0 - 40℃; for 15 - 25h;
99%
[((CH3)2CHCH2)4Al2H(C3HN2(C6H5)2)]

[((CH3)2CHCH2)4Al2H(C3HN2(C6H5)2)]

Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

[((CH3)2CHCH2)4Al2(C3HN2(C6H5)2)NCHCH(C6H5)2]

[((CH3)2CHCH2)4Al2(C3HN2(C6H5)2)NCHCH(C6H5)2]

Conditions
ConditionsYield
In hexane at ambient temp.; XRD;99%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

bromopentene
1119-51-3

bromopentene

2,2-diphenyl-6-heptenenitrile
342819-91-4

2,2-diphenyl-6-heptenenitrile

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 85℃; for 2h; Inert atmosphere; Sealed tube;99%
Stage #1: Diphenylacetonitrile With lithium dimethylamide In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere;
Stage #2: bromopentene In tetrahydrofuran at 20℃; Inert atmosphere;
Stage #1: Diphenylacetonitrile With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; Inert atmosphere;
Stage #2: bromopentene In N,N-dimethyl-formamide; mineral oil at 0 - 20℃; for 12h; Inert atmosphere;
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

allyl alcohol
107-18-6

allyl alcohol

2,2-diphenyl-pent-4-enenitrile
5558-71-4

2,2-diphenyl-pent-4-enenitrile

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); carbon dioxide In dimethyl sulfoxide at 80℃; under 760.051 Torr; for 14h; Reagent/catalyst; Sealed tube;99%
With potassium carbonate In toluene at 80℃; for 18h; Catalytic behavior; Green chemistry;94%
With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)nickel (0) In methanol at 80℃; Sealed tube; Schlenk technique; Inert atmosphere;94%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

1-Bromo-2-butyne
3355-28-0

1-Bromo-2-butyne

2,2-diphenylhex-4-ynenitrile

2,2-diphenylhex-4-ynenitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h;
Stage #2: 1-Bromo-2-butyne In tetrahydrofuran; toluene; mineral oil at 20℃;
99%
Stage #1: Diphenylacetonitrile With lithium diisopropyl amide In tetrahydrofuran at -78℃; for 2h;
Stage #2: 1-Bromo-2-butyne In tetrahydrofuran at -78 - 0℃;
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

3-ethylethynyl-metyl carbonate
196882-96-9

3-ethylethynyl-metyl carbonate

C19H17N

C19H17N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2'-methylbiphenyl In N,N-dimethyl-formamide at 80℃; for 1h; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;99%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

C8H10O3

C8H10O3

C20H17N

C20H17N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2'-methylbiphenyl In N,N-dimethyl-formamide at 80℃; for 1h; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;99%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

C10H14O3

C10H14O3

C22H21N

C22H21N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2'-methylbiphenyl In N,N-dimethyl-formamide at 80℃; for 1h; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;99%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

C11H16O3

C11H16O3

C23H23N

C23H23N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2'-methylbiphenyl In N,N-dimethyl-formamide at 80℃; for 1h; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;99%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

2,2-Diphenylethylamine
3963-62-0

2,2-Diphenylethylamine

Conditions
ConditionsYield
With triethylamine alane In tetrahydrofuran for 1h; Ambient temperature;98.5%
With ammonia; hydrogen In toluene at 120℃; under 22502.3 Torr; for 16h; Autoclave;90%
With lithium aluminium tetrahydride; diethyl ether
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Diphenylmethane
101-81-5

Diphenylmethane

Conditions
ConditionsYield
With PEG-400; sodium hydroxide for 0.0333333h; microwave irradiation;98%
With potassium hydroxide at 150℃; for 2h;80%
With sodium azide; acetic acid In 1-methyl-pyrrolidin-2-one; water at 220℃; for 0.266667h;73%
Multi-step reaction with 2 steps
1: sodium azide; acetic acid / 1-methyl-pyrrolidin-2-one; water / 0.27 h / 220 °C / Microwave irradiation
2: acetic acid / 1-methyl-pyrrolidin-2-one; water / 240 °C
View Scheme
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Methyl 2-butynoate
23326-27-4

Methyl 2-butynoate

(E)-methyl 4-cyano-3-methyl-4,4-diphenylbut-2-enoate
946617-85-2

(E)-methyl 4-cyano-3-methyl-4,4-diphenylbut-2-enoate

Conditions
ConditionsYield
With N-benzyl-trimethylammonium hydroxide In 1,4-dioxane; methanol for 2h; Heating;98%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

propargyl bromide
106-96-7

propargyl bromide

2,2-diphenyl-4-pentynenitrile
21599-40-6

2,2-diphenyl-4-pentynenitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran at 20℃; for 1h;
Stage #2: propargyl bromide In tetrahydrofuran at 20℃; for 12h;
97%
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h;
Stage #2: propargyl bromide In tetrahydrofuran; toluene; mineral oil at 20℃;
94%
Stage #1: Diphenylacetonitrile With sodium hydride In tetrahydrofuran; mineral oil at 0 - 20℃; for 1h;
Stage #2: propargyl bromide In tetrahydrofuran; toluene; mineral oil
94%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

2-Bromoethyl methyl ether
6482-24-2

2-Bromoethyl methyl ether

4-methoxy-2,2-diphenylbutanenitrile

4-methoxy-2,2-diphenylbutanenitrile

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran; mineral oil at 85℃; for 2h; Inert atmosphere; Sealed tube;97%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

Carbonic acid dec-2-ynyl ester methyl ester
104846-77-7

Carbonic acid dec-2-ynyl ester methyl ester

C24H27N

C24H27N

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2'-methylbiphenyl In N,N-dimethyl-formamide at 80℃; for 1h; Inert atmosphere; Glovebox; Sealed tube; regioselective reaction;97%
Diphenylacetonitrile
86-29-3

Diphenylacetonitrile

2-Iodobenzyl bromide
40400-13-3

2-Iodobenzyl bromide

3-(2-iodophenyl)-2,2-diphenylpropanenitrile

3-(2-iodophenyl)-2,2-diphenylpropanenitrile

Conditions
ConditionsYield
Stage #1: Diphenylacetonitrile With sodium hydride In N,N-dimethyl-formamide; benzene at 0℃; for 0.5h;
Stage #2: 2-Iodobenzyl bromide In N,N-dimethyl-formamide; benzene at 0 - 20℃; Further stages.;
96%
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