Stock products, own laboratory Description Product number PC00441 English Name 2-Amino-5-chloro-N,3-dimethylbenzamide CAS Number 890707-28-5
Cas:890707-28-5
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inquiryIdentification: Product Name: Pyrazolic acid Chemical Name: 3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carboxylic acid; Synonyms: K Acid ; 3-bromo-1-(3-chloro-2-pyridinyl)-1H-Pyrazole-5-carboxylic acid CAS No.: 500011-86-9 Molecular F
Cas:890707-28-5
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inquiryHigh purity, content greater than 99% Pharmaceutical level quality control Factory direct Ready delivery from stock Application:Pharmaceutical intermediates
890707-28-5 Basic information Product Name: 890707-28-5 Synonyms: 890707-28-5;2-Amino-5-chloro-N,3-dimethylbenzamide CAS: 890707-28-5
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Cas:890707-28-5
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inquiryDayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:890707-28-5
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inquiryWITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et
Cas:890707-28-5
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inquiry1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized
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inquiryBardoxolone Basic information Product Name: Bardoxolone Synonyms: 2-Amino-5-chloro-N,3-dimethylbenzamide;2-Amino-5-chloro-N,3-dimethylbenzamide 98%;Benzamide, 2-amino-5-chloro-N,3-dimethyl- CAS: 890707-28-5 MF: C9H11ClN2O MW: 198.65 EI
Bardoxolone CAS:890707-28-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediate
Cas:890707-28-5
Min.Order:1 Gram
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inquiryProduct quality: Our company have high quality product , and also the product we have good manufacture . First of all, this product is of fine quality. Every finish should be checked by quality inspection system.And every one should be also tried
Cas:890707-28-5
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiryBest quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia
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inquiryOur Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We
Cas:890707-28-5
Min.Order:10 Kilogram
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inquiryHangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det
Cas:890707-28-5
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inquiryOur Advantages Production: Advanced chemical equipment with years of experience.Staffs for producing various extract products. Quality Control:A complete set of Testing Professional and Analysis Equipment ensures the Quality Requirements and Speci
Cas:890707-28-5
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FOB Price: $150.0 / 180.0
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inquiryZibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:890707-28-5
Min.Order:10 Gram
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inquiry1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd
Cas:890707-28-5
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inquiryfactory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B
Cas:890707-28-5
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inquiryProduct name: 2-Amino-5-Chloro-N,3-Dimethylbenzamide CAS No.: 890707-28-5 Molecule Formula:C9H11ClN2O Molecule Weight:198.65 Purity: 98.5% Package: 25kg/drum Description:White or off-white powder Manufacture Standards:Enterprise Stand
Cas:890707-28-5
Min.Order:1 Kilogram
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inquiryHangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting 2-Amino-5-chloro-N,3-dimethylbenzamide CAS:890707-28-5, Please contact us by email freely. We are leading exporter in China. If you
Cas:890707-28-5
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inquiryCategory Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard Shelf life 2 years Storage should be stored in a well-closed container at low temperature, keep away from mo
Cas:890707-28-5
Min.Order:1 Kilogram
FOB Price: $30.0 / 65.0
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inquiryShandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W
Cas:890707-28-5
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inquiry1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer
Cas:890707-28-5
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inquiryTriumph has the complete production of G- KG - MT service chain,we can make the new technology into productivity quickly in the research and development of new products. Main Business Custom Synthesis:
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inquiryHigh quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use
Cas:890707-28-5
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inquirySuperior quality, moderate price & quick delivery. Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:as per your request Application:Used as Pharmaceutical Intermediates,ect. Transportation:as per your request
Cas:890707-28-5
Min.Order:10 Gram
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inquiryWe are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp
Cas:890707-28-5
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
Cas:890707-28-5
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inquiryJinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands
Cas:890707-28-5
Min.Order:100 Gram
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inquiry2-amino-3-methyl-5-chlorobenzoic acid methyl ester
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
In methanol at 65 - 68℃; for 5h; Temperature; | 98% |
In methanol at 45℃; for 6h; | 97.2% |
In ethylene glycol; acetonitrile at 0 - 70℃; for 17.5 - 23h; Product distribution / selectivity; | 84.8% |
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
In isopropyl alcohol at 60℃; for 7h; | 96.8% |
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
In methanol at 50℃; for 6h; | 95.4% |
6-chloro-8-methyl-1H-benzo[d][1,3]oxazine-2,4-dione
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With acetic acid In ethyl acetate at 35 - 45℃; for 0.333333h; | 95% |
With acetic acid In ethyl acetate at 22 - 52℃; for 0.333333 - 2.75h; Product distribution / selectivity; | 93% |
With acetic acid In water; acetonitrile at 25 - 30℃; for 2.5h; Product distribution / selectivity; | 87% |
6-chloro-8-methyl-1H-benzo[d][1,3]oxazine-2,4-dione
methylamine hydrochloride
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With potassium hydrogencarbonate In acetonitrile at 25 - 30℃; for 3h; Solvent; Reagent/catalyst; Temperature; | 93.6% |
Stage #1: methylamine hydrochloride With triethylamine In dichloromethane at 20℃; for 2h; Stage #2: 6-chloro-8-methyl-1H-benzo[d][1,3]oxazine-2,4-dione With acetic acid In dichloromethane; ethyl acetate Reflux; | |
With potassium carbonate In ethanol at 25 - 80℃; for 5.5h; Reagent/catalyst; Temperature; |
2-amino-5-chloro-3-methylbenzoic acid
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Stage #1: 2-amino-5-chloro-3-methylbenzoic acid With benzotriazol-1-ol; diisopropyl-carbodiimide In dichloromethane at 20℃; for 2h; Stage #2: methylamine In dichloromethane at 0℃; for 2h; Temperature; | 92.6% |
Stage #1: 2-amino-5-chloro-3-methylbenzoic acid With thionyl chloride for 3h; Reflux; Stage #2: methylamine In tetrahydrofuran; water at 20℃; Cooling with ice; | 59.3% |
Stage #1: 2-amino-5-chloro-3-methylbenzoic acid With thionyl chloride for 3h; Reflux; Stage #2: methylamine In tetrahydrofuran; water at 20℃; for 12h; Cooling with ice; | 59.3% |
6-chloro-8-methyl-1H-benzo[d][1,3]oxazine-2,4-dione
methylamine
A
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
C
2-amino-5-chloro-3-methylbenzoic acid
Conditions | Yield |
---|---|
With water; acetic acid In ethyl acetate at 48 - 52℃; for 1h; Product distribution / selectivity; | A 87.3% B 3.4% C 1.7% |
N-methyl-3-methyl-2-aminobenzamide
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With hydrogenchloride; dihydrogen peroxide; acetic acid at 5 - 20℃; | 85% |
Stage #1: N-methyl-3-methyl-2-aminobenzamide With hydrogenchloride In N,N-dimethyl-formamide at 10 - 30℃; Stage #2: With sodium sulfite In water; N,N-dimethyl-formamide at 30 - 35℃; for 3.25h; Stage #3: With sodium hydroxide; sodium sulfite In water; N,N-dimethyl-formamide at 10℃; for 0.25h; pH=2.2; Product distribution / selectivity; | 72.7% |
With N-chloro-succinimide In acetonitrile for 1h; Reflux; | |
With sulfuryl dichloride In dichloromethane at 0 - 30℃; | |
With thionyl chloride In acetonitrile at 40 - 50℃; |
carbon monoxide
2-bromo-4-chloro-6-methylphenylamine
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
palladium diacetate; 1,4-di(diphenylphosphino)-butane In ethylene glycol at 25 - 110℃; under 2842.59 Torr; Inert atmosphere; Sealed tube; | 70% |
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
In dichloromethane | |
In dichloromethane |
2-amino-5-chloro-3-methylbenzoic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: thionyl chloride / Reflux 2: dichloromethane View Scheme | |
Multi-step reaction with 2 steps 1: thionyl chloride / 3 h / Reflux 2: dichloromethane View Scheme | |
Multi-step reaction with 2 steps 1.1: 1,4-dioxane / 2 h / 50 °C 2.1: triethylamine / dichloromethane / 2 h / 20 °C 2.2: Reflux View Scheme |
2-hydroxyethyl 2-amino-5-chloro-3-methylbenzoate
2-(dimethylamino)ethyl 2-amino-5-chloro-3-methylbenzoate
methylamine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
at 110℃; under 3876.26 Torr; for 6.06667h; Product distribution / selectivity; Sealed tube; Inert atmosphere; |
3-methylantranilic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 2.1: thionyl chloride / 3 h / Reflux 2.2: 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 2 steps 1.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 2.1: thionyl chloride / 3 h / Reflux 2.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 2 steps 1: benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0.5 h / Cooling with ice 2: N-chloro-succinimide / acetonitrile / 1 h / Reflux View Scheme |
o-toluidine
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: sodium sulfate / water / 40 °C 1.2: Reflux 2.1: sulfuric acid / 0.33 h / 80 °C 3.1: dihydrogen peroxide; sodium hydroxide / water / 0 - 50 °C 4.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 5.1: thionyl chloride / 3 h / Reflux 5.2: 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 5 steps 1.1: sodium sulfate / water / 40 °C 1.2: 0.17 h / Reflux 2.1: sulfuric acid / 60 - 80 °C 3.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 3.2: pH 4 4.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 5.1: thionyl chloride / 3 h / Reflux 5.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 5 steps 1.1: sodium sulfate; hydrogenchloride; hydroxylamine hydrochloride / water / 0.17 h / Reflux 2.1: sulfuric acid / 0.83 h / 70 - 80 °C 3.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 4.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 5.1: thionyl chloride / 3 h / Reflux 5.2: 12 h / 20 °C / Cooling with ice View Scheme |
2-(hydroxyimino)-N-(2-methylphenyl)acetamide
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: sulfuric acid / 0.33 h / 80 °C 2.1: dihydrogen peroxide; sodium hydroxide / water / 0 - 50 °C 3.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 4.1: thionyl chloride / 3 h / Reflux 4.2: 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 4 steps 1.1: sulfuric acid / 60 - 80 °C 2.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 2.2: pH 4 3.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 4.1: thionyl chloride / 3 h / Reflux 4.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 4 steps 1.1: sulfuric acid / 0.83 h / 70 - 80 °C 2.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 3.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 4.1: thionyl chloride / 3 h / Reflux 4.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 3 steps 1.1: sulfuric acid / 1,2-dichloro-ethane / 12 h / 0 - 30 °C 2.1: acetic acid; dihydrogen peroxide / 0.25 h / 5 °C 2.2: 28.17 h / 5 - 20 °C 2.3: 3.75 h / 10 - 40 °C 3.1: acetic acid / ethyl acetate / 3.25 h / 0 - 25 °C / pH 9 - 10 View Scheme | |
Multi-step reaction with 3 steps 1.1: sulfuric acid / 1,2-dichloro-ethane / 12 h / 0 - 30 °C 2.1: acetic acid; dihydrogen peroxide / 0.25 h / 5 °C 2.2: 28.17 h / 5 - 20 °C 2.3: 3.75 h / 10 - 40 °C 3.1: potassium carbonate / ethanol / 5.5 h / 25 - 80 °C View Scheme |
7-methyl-1H-indole-2,3-dione
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: dihydrogen peroxide; sodium hydroxide / water / 0 - 50 °C 2.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 3.1: thionyl chloride / 3 h / Reflux 3.2: 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 3 steps 1.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 1.2: pH 4 2.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 3.1: thionyl chloride / 3 h / Reflux 3.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 3 steps 1.1: dihydrogen peroxide; sodium hydroxide / water / 0.5 h / 0 - 50 °C 2.1: N-chloro-succinimide / N,N-dimethyl-formamide / 0.67 h / 100 °C 3.1: thionyl chloride / 3 h / Reflux 3.2: 12 h / 20 °C / Cooling with ice View Scheme | |
Multi-step reaction with 2 steps 1.1: acetic acid; dihydrogen peroxide / 0.25 h / 5 °C 1.2: 28.17 h / 5 - 20 °C 1.3: 3.75 h / 10 - 40 °C 2.1: acetic acid / ethyl acetate / 3.25 h / 0 - 25 °C / pH 9 - 10 View Scheme | |
Multi-step reaction with 3 steps 1: sulfuryl dichloride; acetic acid / 120 - 125 °C 2: sulfuric acid; acetic acid; dihydrogen peroxide / 60 - 65 °C 3: ethyl acetate / 20 °C View Scheme |
benzoic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: acetic acid; chlorine / 3 h / 30 - 40 °C / Inert atmosphere 2.1: 0.08 h 2.2: Grignard reagent / 1 h 3.1: sulfuric acid; nitric acid / 1 h / 0 - 40 °C 4.1: zinc; sodium hydroxide / 2 h / 70 °C 5.1: diisopropyl-carbodiimide; benzotriazol-1-ol / dichloromethane / 2 h / 20 °C 5.2: 2 h / 0 °C View Scheme |
3,5-dichlorobenzoic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: 0.08 h 1.2: Grignard reagent / 1 h 2.1: sulfuric acid; nitric acid / 1 h / 0 - 40 °C 3.1: zinc; sodium hydroxide / 2 h / 70 °C 4.1: diisopropyl-carbodiimide; benzotriazol-1-ol / dichloromethane / 2 h / 20 °C 4.2: 2 h / 0 °C View Scheme |
3-Chloro-5-Methylbenzoic Acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1.1: sulfuric acid; nitric acid / 1 h / 0 - 40 °C 2.1: zinc; sodium hydroxide / 2 h / 70 °C 3.1: diisopropyl-carbodiimide; benzotriazol-1-ol / dichloromethane / 2 h / 20 °C 3.2: 2 h / 0 °C View Scheme |
toluene
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1.1: oxygen; cobalt(II) aceylacetonate; N-hydroxyphthalimide / dichloromethane / 1 h / 30 °C / 22502.3 Torr / Sealed tube 2.1: acetic acid; chlorine / 3 h / 30 - 40 °C / Inert atmosphere 3.1: 0.08 h 3.2: Grignard reagent / 1 h 4.1: sulfuric acid; nitric acid / 1 h / 0 - 40 °C 5.1: zinc; sodium hydroxide / 2 h / 70 °C 6.1: diisopropyl-carbodiimide; benzotriazol-1-ol / dichloromethane / 2 h / 20 °C 6.2: 2 h / 0 °C View Scheme |
2-methyl-4,6-dichloroaniline
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: copper bromide / N,N-dimethyl-formamide / 18 h / 90 - 95 °C 2: sodium hydroxide / 10 h / 70 - 75 °C 3: sulfuric acid / 16 h / Reflux 4: methanol / 5 h / 65 - 68 °C View Scheme |
2-amino-5-chloro-3-methylbenzonitrile
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sodium hydroxide / 10 h / 70 - 75 °C 2: sulfuric acid / 16 h / Reflux 3: methanol / 5 h / 65 - 68 °C View Scheme |
3-methyl-2-nitrobenzoic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: hydrogen / ethanol / 4 h / 50 °C / 1500.15 Torr 2: chlorine / 1,2-dichloro-ethane / 3 h / 50 °C 3: sulfuric acid / 6 h / 5 °C / Reflux 4: isopropyl alcohol / 7 h / 60 °C View Scheme | |
Multi-step reaction with 4 steps 1: hydrogen / ethanol / 4 h / 50 °C / 1500.15 Torr 2: chlorine / 1,2-dichloro-ethane / 3 h / 50 °C 3: sulfuric acid / 6 h / 5 °C / Reflux 4: methanol / 6 h / 50 °C View Scheme | |
Multi-step reaction with 4 steps 1: hydrogen / ethanol / 4 h / 50 °C / 1500.15 Torr 2: chlorine / 1,2-dichloro-ethane / 3 h / 50 °C 3: sulfuric acid / 8 h / 5 °C / Reflux 4: methanol / 6 h / 45 °C View Scheme | |
Multi-step reaction with 3 steps 1.1: thionyl chloride / toluene / 90 - 100 °C 1.2: 0 - 10 °C 2.1: palladium 10% on activated carbon; hydrogen / methanol 3.1: acetic acid; hydrogenchloride; dihydrogen peroxide / 5 - 20 °C View Scheme | |
Multi-step reaction with 4 steps 1: pyrographite; hydrazine hydrate; sodium hydroxide; iron(III) chloride hexahydrate / water / 70 °C 2: pyridine / acetonitrile / 4 h / 50 - 60 °C 3: acetic acid / water; acetonitrile / 1 h / Reflux 4: thionyl chloride / acetonitrile / 40 - 50 °C View Scheme |
m-Toluic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: nitric acid / -10 - -5 °C 2.1: thionyl chloride / toluene / 90 - 100 °C 2.2: 0 - 10 °C 3.1: palladium 10% on activated carbon; hydrogen / methanol 4.1: acetic acid; hydrogenchloride; dihydrogen peroxide / 5 - 20 °C View Scheme |
N,3-dimethyl-2-nitrobenzamide
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: palladium 10% on activated carbon; hydrogen / methanol 2: acetic acid; hydrogenchloride; dihydrogen peroxide / 5 - 20 °C View Scheme |
6-methylisatoic anhydride
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: acetic acid / water; acetonitrile / 1 h / Reflux 2: thionyl chloride / acetonitrile / 40 - 50 °C View Scheme |
5-chloro-7-methyl-1H-indole-2,3-dione
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sulfuric acid; acetic acid; dihydrogen peroxide / 60 - 65 °C 2: ethyl acetate / 20 °C View Scheme |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sulfuric acid / 60 - 65 °C 2: sulfuryl dichloride; acetic acid; dihydrogen peroxide / 60 - 125 °C 3: ethyl acetate / 20 °C View Scheme | |
Multi-step reaction with 4 steps 1: sulfuric acid / 60 - 65 °C 2: sulfuryl dichloride; acetic acid / 120 - 125 °C 3: sulfuric acid; acetic acid; dihydrogen peroxide / 60 - 65 °C 4: ethyl acetate / 20 °C View Scheme |
3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxylic acid
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
rynaxypyr
Conditions | Yield |
---|---|
With 3-Methylpyridine; methanesulfonyl chloride In propiononitrile at -5 - 20℃; for 4h; Product distribution / selectivity; | 97% |
With 3-Methylpyridine; methanesulfonyl chloride In acetone at -5 - 5℃; for 3h; Product distribution / selectivity; | 96.4% |
With pyridine; methanesulfonyl chloride In acetonitrile at -5 - 20℃; for 4h; Product distribution / selectivity; | 96.8% |
Conditions | Yield |
---|---|
With pyridine; methanesulfonyl chloride In acetonitrile at -5℃; for 2.16h; | 95.6% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
acetone
6-chloro-2,2,3,8-tetramethyl-2,3-dihydroquinazolin-4(1H)-one
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid for 1h; Reflux; | 95% |
furfural
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
6-chloro-2-(furan-2-yl)-3,8-dimethyl-2,3-dihydroquinazolin-4(1H)-one
Conditions | Yield |
---|---|
With β-cyclodextrine-SO3H In water at 50℃; for 0.416667h; Green chemistry; | 94% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5-carboxaldehyde
C18H14BrCl2N5O
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 1h; Reflux; | 92% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carbonyl chloride
rynaxypyr
Conditions | Yield |
---|---|
Stage #1: 2-amino-3-methyl-5-chlorobenzoyl-N-methylamine With 3-Methylpyridine In acetonitrile at 25 - 35℃; Stage #2: 3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carbonyl chloride In acetonitrile at 25 - 35℃; Solvent; Temperature; | 91.1% |
With N-ethyl-N,N-diisopropylamine In dichloromethane at 20℃; for 12h; Cooling with ice; | 89.3% |
Stage #1: 2-amino-3-methyl-5-chlorobenzoyl-N-methylamine; 3-bromo-1-(3-chloropyridin-2-yl)-1H-pyrazole-5-carbonyl chloride In acetonitrile at 20℃; for 1.16667h; Reflux; Stage #2: With sodium hydrogencarbonate In acetonitrile Product distribution / selectivity; |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
cyclohexanone
6'-chloro-3',8'-dimethyl-1'H-spiro[cyclohexane-1,2'-quinazolin]-4'(3'H)-one
Conditions | Yield |
---|---|
With β-cyclodextrine-SO3H In water at 50℃; for 0.416667h; Green chemistry; | 90% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
rynaxypyr
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 3.16667h; Reflux; | 84% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
dicyanozinc
Conditions | Yield |
---|---|
With zinc; bis(tri-tert-butylphosphine)palladium(0) In 1,4-dioxane for 11h; Product distribution / selectivity; Heating / reflux; | 83% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
potassium cyanide
Conditions | Yield |
---|---|
chloro(1-naphthyl)bis(triphenylphosphine)nickel(II); chloro(2-naphthalenyl)bis(triphenylphosphine)nickel In ethanol; xylene at 45℃; Product distribution / selectivity; | 82.5% |
With zinc; bis(tri-tert-butylphosphine)palladium(0); 18-crown-6 ether In 1,4-dioxane for 24h; Product distribution / selectivity; Heating / reflux; | 65% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
C9H6ClN3O
6-chloro-2-(3-chloro-1-(pyridin-2-yl)-1H-pyrazol-5-yl)-3-cyclopropyl-8-methyl-2,3-dihydroquinazolin-4(1H)-one
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In toluene for 1h; Reflux; | 82% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
C19H13Cl3F3N5O2
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 3h; | 81% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
1-(3,5-dichloropyridin-2-yl)-3-(prop-2-ynyloxy)-1H-pyrazole-5-carbonyl chloride
C21H16Cl3N5O3
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 3h; | 81% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With triethylamine In acetonitrile | 76% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With triethylamine In acetonitrile | 75% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 12h; | 75% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 0 - 20℃; | 73.5% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
chloroacetyl chloride
5-chloro-2-(2-chloroacetamido)-N,3-dimethylbenzamide
Conditions | Yield |
---|---|
With triethylamine In dichloromethane at 20℃; for 3.6h; | 73% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 12h; | 73% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With triethylamine In acetonitrile | 72% |
2-amino-3-methyl-5-chlorobenzoyl-N-methylamine
Conditions | Yield |
---|---|
With triethylamine In acetonitrile | 71% |
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