1,1,2,3-Tetrachloropropene supplier

Name
Tetrachloropropene
EINECS
CAS No. 10436-39-2
Article Data33
CAS DataBase
Density 1.539g/cm³
Solubility MISCIBLE
Melting Point 29-31°C(lit.)
Formula C3H2 Cl4
Boiling Point 173.8°Cat760mmHg
Molecular Weight 179.861
Flash Point 62.3°C
Transport Information
Appearance clear colorless to yellowish liquid after melting
Safety Poison by ingestion and skin contact. Moderately toxic by inhalation. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl⁻. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Risk Codes R37/38; R41; R36/37/38; R34
Molecular Structure
Hazard Symbols Xi,C
Synonyms Propene,1,1,2,3-tetrachloro- (6CI,7CI,8CI); 1,1,2,3-Tetrachloro-1-propene;1,1,2,3-Tetrachloropropene; 2,3,3-Trichloroallyl chloride; HCO 1230; HCO 1230xa
PSA 0.00000
LogP 3.11070

Synthetic route

: 16714-68-4
1,1,2,2,3-pentachloropropane

: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
With sodium hydroxide; cetylpyridinium bromide at 130℃; for 2h;	97%
With potassium hydroxide
With sodium hydroxide

: 24425-97-6
1,1,1,2,2,3-hexachloropropane

: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
With hydrogenchloride; zinc In 1,4-dioxane; water at 45℃; for 49h; Autoclave; Inert atmosphere;	90%

: 1070-78-6
1,1,1,3-tetrachloropropane

A: 21700-31-2
1,1,1,2,3-pentachloro-propane

B: 2567-14-8
3,3-dichloroallyl chloride

C: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
With iron(III) chloride; chlorine at 82℃; under 1277.21 Torr; for 15.33h; Product distribution / selectivity;	A 82.9% B 3.4% C 8.1%

...Expand

: 21700-31-2
1,1,1,2,3-pentachloro-propane

A: 10436-39-2
1,1,2,3-Tetrachloropropene

B: 16500-91-7
2,3,3,3-tetrachloropropene

Conditions

Conditions	Yield
With potassium hydroxide at 0℃;
With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h;
With potassium hydroxide; Aliquat 336 In water at 80℃; for 3h;
With potassium hydroxide; Aliquat 336 In water at 8℃; for 3h;

: 16500-91-7
2,3,3,3-tetrachloropropene

: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
at 180℃;
With aluminium trichloride at 0℃;
With antimonypentachloride
at 150 - 180℃;

: 67-56-1
methanol

: 3266-39-5
2,3,3-trichloro-2-propen-1-ol

A: 80-63-7
methyl 2-chloroacrylate

B: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
With sulfuric acid; water 1) 105 deg C, 4 h, 2) 30 min; Yield given. Multistep reaction. Yields of byproduct given;

...Expand

: 21700-31-2
1,1,1,2,3-pentachloro-propane

A: 2233-00-3
3,3,3-trichloro-1-propene

B: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
at 400℃; under 750.075 Torr; for 0.0130556h; Inert atmosphere;

: 21700-31-2
1,1,1,2,3-pentachloro-propane

A: 2252-87-1
2,3-dichloro-3,3-difluoroprop-1-ene

B: 10436-39-2
1,1,2,3-Tetrachloropropene

C: 666-27-3
1,1,2,3-tetrachloro-1-fluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride at 290℃; under 750.075 Torr; for 3h; Inert atmosphere; tubular reactor;

...Expand

: 74-99-7
prop-1-yne

A: 10436-39-2
1,1,2,3-Tetrachloropropene

B: 16500-91-7
2,3,3,3-tetrachloropropene

Conditions

Conditions	Yield
Stage #1: prop-1-yne With chlorine at 60 - 80℃; Stage #2: With chlorine; dibenzoyl peroxide at 40 - 50℃; Stage #3: With sodium hydroxide at 40 - 50℃;

: 67-66-3
chloroform

: 75-35-4
1,1-Dichloroethylene

: 10436-39-2
1,1,2,3-Tetrachloropropene

Conditions

Conditions	Yield
at 100 - 450℃; under 1018.63 Torr; Temperature; Reagent/catalyst; Pressure; Inert atmosphere;	8.1 %Spectr.

: 21700-31-2
1,1,1,2,3-pentachloro-propane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 677-21-4
1,1,1-trifluoropropylene

C: 10436-39-2
1,1,2,3-Tetrachloropropene

D: 16500-91-7
2,3,3,3-tetrachloropropene

E: 421-42-1
2,3,3-trichloro-3-fluoro-propene

Conditions

Conditions	Yield
With hydrogen fluoride at 350℃; under 750.075 Torr; Temperature;	A 77 %Chromat. B 11 %Chromat. C 42.7 %Spectr. D 22.3 %Spectr. E 6.6 %Spectr.

...Expand

: 21700-31-2
1,1,1,2,3-pentachloro-propane

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 677-21-4
1,1,1-trifluoropropylene

C: 10436-39-2
1,1,2,3-Tetrachloropropene

D: 421-42-1
2,3,3-trichloro-3-fluoro-propene

E: 666-27-3
1,1,2,3-tetrachloro-1-fluoro-propane

Conditions

Conditions	Yield
With hydrogen fluoride at 275℃; under 750.075 Torr;	A 80 %Chromat. B 13 %Chromat. C 53.3 %Spectr. D 6.9 %Spectr. E 6.9 %Spectr.

...Expand

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 100-97-0
hexamethylenetetramine

: N-β,γ,γ-trichloroallylhexamethylenetetramine chloride

Conditions

Conditions	Yield
In chloroform at 60℃; for 12h;	99.6%

: 110-85-0
piperazine

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 137554-28-0
N,N'-bis(1,2,2-trichloroallyl)piperazine

Conditions

Conditions	Yield
In isopropyl alcohol at 90 - 95℃; for 4h;	86.8%

: 5464-28-8
1,3-dioxolane-4-methanol

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 127719-54-4
4-(2,3,3-Trichloro-allyloxymethyl)-[1,3]dioxolane

Conditions

Conditions	Yield
With potassium hydroxide; 18-crown-6 ether for 4h; Ambient temperature;	80%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 42967-74-8
dithiobenzoic acid triethylammonium salt

: 154424-51-8
dithiobenzoic acid β,γ,γ-trichloroallyl ester

Conditions

Conditions	Yield
In acetone	78%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 2730-62-3
2-chloro-1,1,1-trifluoropropene

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 132.1℃; under 6000.6 Torr; Product distribution / selectivity;	72.6%
With hydrogen fluoride; diisopropylamine; chromium(III) oxide at 200 - 300℃; under 760.051 Torr; for 0.000569444 - 0.00277778h; Product distribution / selectivity;
With methoxyhydroquinone; hydrogen fluoride; chromium(III) oxide at 243 - 254℃; under 760.051 Torr; for 66.75h; Product distribution / selectivity;

: 140-31-8
aminoethylpiperazine

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 137554-29-1
N-(1,1,2-trichloroallyl)-N'-(β-1,2,2-trichloroallylaminoethyl)piperazine

Conditions

Conditions	Yield
In isopropyl alcohol Heating;	70%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 930-69-8
sodium thiophenolate

: 38491-40-6
phenyl-(2,3,3-trichloro-allyl)-sulfide

Conditions

Conditions	Yield
In N,N-dimethyl-formamide	70%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 111-40-0
1,5-diamino-3-azapentane

: 137554-22-4
N,N'-bis(1,2,3-trichloroallyl)diethylenetriamine

Conditions

Conditions	Yield
In isopropyl alcohol Heating;	65%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 431-31-2
1,1,1,2,3-pentafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride at 150℃; under 47821.8 Torr; for 8h; Product distribution / selectivity;	59%

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 421-73-8
2-chloro-1,1,1,2-tetrafluoropropane

C: 431-31-2
1,1,1,2,3-pentafluoropropane

D: 338-75-0
2,3-dichloro-1,1,1-trifluoropropane

E: 151771-09-4
1-chloro-2,3,3,3-tetrafluoropropane

F: 117970-90-8
2-chloro-1,1,1,3-tetrafluoropropane

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride at 100 - 125℃; under 33082.7 - 39185.2 Torr; for 12h; Product distribution / selectivity;	A n/a B n/a C 53% D n/a E n/a F n/a

...Expand

: 106-44-5
p-cresol

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 106119-06-6
4-methyl-2-(2,3,3-trichloro-2-propenyl)phenol

Conditions

Conditions	Yield
	31%

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 2730-62-3
2-chloro-1,1,1-trifluoropropene

B: 374-06-1
2-chloro-2,3,3-trifluoro-butane

Conditions

Conditions	Yield
With hydrogen fluoride; antimonypentachloride; chlorine; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In 1,1,2-trichloro-2,2-difluoroethane at 133.2℃; under 6000.6 Torr; Product distribution / selectivity;	A 25.5% B 6.6%

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 124-41-4
sodium methylate

: 63578-64-3
methyl-(2,3,3-trichloro-allyl)-ether

Conditions

Conditions	Yield
With methanol

: 10436-39-2
1,1,2,3-Tetrachloropropene

A: 56-23-5
tetrachloromethane

B: 67-72-1
hexachloroethane

Conditions

Conditions	Yield
With chlorine at 400℃; under 36775.4 Torr;

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 6066-14-4
3-bromo-1,1,2-trichloro-propene

Conditions

Conditions	Yield
With acetone; sodium bromide
With hydrogen bromide; iron(III) chloride

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 21400-25-9
1,1,2-trichloropropene

Conditions

Conditions	Yield
With tetrahydrofuran; lithium aluminium tetrahydride
With ethanol; zinc

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 24425-97-6
1,1,1,2,2,3-hexachloropropane

Conditions

Conditions	Yield
With chlorine Irradiation.mit UV-Licht;

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 3266-39-5
2,3,3-trichloro-2-propen-1-ol

Conditions

Conditions	Yield
With sodium carbonate

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 17078-21-6
1,1,2-trichloro-3-phenyl-propene

Conditions

Conditions	Yield
With aluminium trichloride; benzene

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 109-89-7
diethylamine

: 118378-57-7
diethyl-(2,3,3-trichloro-allyl)-amine

Conditions

Conditions	Yield
With methanol

: 110-91-8
morpholine

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 15111-02-1
4-(2,3,3-trichloro-allyl)-morpholine

Conditions

Conditions	Yield
In methanol Heating;

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 141-52-6
sodium ethanolate

: 15111-07-6
1,1,2-trichloro-3-ethoxy-propene

Conditions

Conditions	Yield
With phenol In ethanol

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 540-72-7
sodium thiocyanide

: 3266-21-5
2,3,3-Trichlor-allyl-thiocyanat

Conditions

Conditions	Yield
In ethanol

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 996-82-7
sodium diethylmalonate

: 31000-94-9
Bis(β.γ.γ-trichlorallylmalonic Acid)-Diethyl Ester

Conditions

Conditions	Yield
In ethanol

: 10436-39-2
1,1,2,3-Tetrachloropropene

: 996-82-7
sodium diethylmalonate

: 31000-93-8
β.γ.γ-Trichlorallylmalonic Acid-Diethyl Ester

Conditions

Conditions	Yield
In ethanol

1,1,2,3-Tetrachloropropene Chemical Properties

IUPAC Name: 1,1,2,3-Tetrachloroprop-1-ene
The MF of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is C₃H₂Cl₄.

The MW of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is 179.86.
Synonyms of 1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2): Tetrachloropropene ; 1,1,2,3-Tetrachloropropene ; 1,1,2,3-Tetrachloro-1-propene ; 1,1,2,3-Tetrachloro-propen ; 2,3,3-Trichloroallyl chloride
Apperance: Colorless oily liquid
Index of Refraction: 1.512
EINECS: 233-920-8
Density: 1.539 g/ml
Flash Point: 62.3 °C
Boiling Point: 173.8 °C

1,1,2,3-Tetrachloropropene Uses

1,1,2,3-Tetrachloropropene (CAS NO.10436-39-2) is Ye Yan fear herbicide intermediate and used for the synthesis of heat-resistant plastic.

1,1,2,3-Tetrachloropropene Production

A dehydrochlorination: tirring 1,1,2,3 - Tetrachloro-propane,calcium hydroxide and a certain amount of water in the reactors, to a certain reaction temperature for several hours, add 1:1 hydrochloric acid and in to acidic deposition layered collection of mixed-bit three allyl chloride.
Secondary chloride: reaction equipment is the same chlorination, mixed with bits into three allyl chloride, were mixed with bits 5-chloropropane.
Second dehydrochlorination: Production equipment is the same dehydrochlorination in the reaction vessel into position five chlorine mixed with propane, adding calcium hydroxide, dehydrochlorination was four allyl chloride.
                         ClCH=CHCH₂Cl+Cl₂→ClCH₂CHClCHCl₂
                         ClCH₂CHClCHCl₂+OH^-→ClCH₂ClG=CHCl
                         ClCH₂ClC=CHCl+Cl₂→Cl₂CHCCl₂CH₂Cl
                         Cl₂CHCCl₂CH₂Cl+OH^-→Cl₂C=CClCH₂Cl

1,1,2,3-Tetrachloropropene Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	3200mg/m3 (3200mg/m3)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979.
mouse	LD50	oral	800mg/kg (800mg/kg)	LIVER: OTHER CHANGES	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(4), Pg. 15, 1978.
rabbit	LD50	oral	477mg/kg (477mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979.
rabbit	LD50	skin	400uL/kg (0.4mL/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
rat	LC50	inhalation	1500mg/m3 (1500mg/m3)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 23(10), Pg. 51, 1979.
rat	LD50	oral	350mg/kg (350mg/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

1,1,2,3-Tetrachloropropene Consensus Reports

Reported in EPA TSCA Inventory.

1,1,2,3-Tetrachloropropene Safety Profile

Poison by ingestion and skin contact. Moderately toxic by inhalation. Experimental reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl⁻. See also CHLORINATED HYDROCARBONS, ALIPHATIC.

Product Name

Tetrachloropropene

Synthetic route

1,1,2,3-Tetrachloropropene Chemical Properties

1,1,2,3-Tetrachloropropene Uses

1,1,2,3-Tetrachloropropene Production

1,1,2,3-Tetrachloropropene Toxicity Data With Reference

1,1,2,3-Tetrachloropropene Consensus Reports

1,1,2,3-Tetrachloropropene Safety Profile

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