1-Chlorobutane supplier | CasNO.109-69-3

Name
1-Chlorobutane
EINECS 203-696-6
CAS No. 109-69-3
Article Data278
CAS DataBase
Density 0.873 g/cm³
Solubility Insoluble
Melting Point -123 °C
Formula C₄H₉Cl
Boiling Point 78.2 °C at 760 mmHg
Molecular Weight 92.5685
Flash Point 12 °F
Transport Information
Appearance water white liquid with a sharp odor
Safety 9-16-29
Risk Codes 11
Molecular Structure
Hazard Symbols F
Synonyms Butyl chloride;Chlorobutane;NSC 8419;n-Butyl chloride;n-Chlorobutane;n-Propylcarbinyl chloride;Butane,1-chloro-;
PSA 0.00000
LogP 2.02530

Synthetic route

: 71-36-3
butan-1-ol

A: 126-73-8
phosphoric acid tributyl ester

B: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With hydrogenchloride; water; oxygen; copper dichloride at 59.9℃; Product distribution; Mechanism; other alcohols, var. conc. of reagents, var. temperat.;	A 100% B n/a
With phosphan; chlorine Rate constant; Thermodynamic data; Ea, ΔS(excit.); also in the presence of pyridine;

: 592-34-7
carbonochloridic acid, butyl ester

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With hexabutylguanidinium chloride at 100℃; for 0.05h;	100%

: 542-69-8
1-iodo-butane

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With phosphorus pentachloride; trichlorophosphate for 0.5h; Heating; other alkyl and aryl iodides;	98%
With mercury dichloride

: 71-36-3
butan-1-ol

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With hydrogenchloride In water at 115℃; for 2h; Reagent/catalyst; Temperature;	96.9%
With hydrogenchloride; dimethyl sulfoxide In water at 85 - 95℃; for 20h; Temperature; Reagent/catalyst;	93.5%
With hydrogenchloride at 75 - 80℃; Concentration;	91.5%

: 71-36-3
butan-1-ol

A: 109-69-3
n-Butyl chloride

B: 142-96-1
dibutyl ether

Conditions

Conditions	Yield
With hydrogenchloride; tetrabutylphosphonium ion; silica gel at 170℃; under 760 Torr;	A 95% B 4 % Chromat.

n-butylbis(dimethylglyoximato)pyridinecobalt(III): n-butylbis(dimethylglyoximato)pyridinecobalt(III)

A: 109-69-3
n-Butyl chloride

B: 2386-60-9
perfluoro-1-butanesulfonyl fluoride

C chlorobis(dimethylglyoximato)pyridinecobalt(III): chlorobis(dimethylglyoximato)pyridinecobalt(III)

Conditions

Conditions	Yield
With Trichloromethanesulfonyl chloride In dichloromethane at 18℃; for 3.5h; Irradiation;	A n/a B 95% C n/a

...Expand

: 2712-93-8
dichlorofluoromethanesulphenyl chloride

: 106-97-8
n-butane

A: 109-69-3
n-Butyl chloride

B: 675-63-8
bis(dichlorofluoromethyl)disulfane

C: 68409-15-4
2-(Dichloro-fluoro-methylsulfanyl)-butane

Conditions

Conditions	Yield
	A 8.5% B 92.4% C 2.3%
	A 8.5% B 92.4% C 2.3%

...Expand

: 17487-60-4
1,1-dibutoxy-2,2-dichloro-ethene

A: 109-69-3
n-Butyl chloride

B: 118487-59-5
butoxycarbonyldichloromethanesulfenyl chloride

Conditions

Conditions	Yield
With sulfur monochloride In dichloromethane under Ar atmosphere, spontaneous heating to 45 deg C 30 min, 20 deg C 2,5 h;	A n/a B 90%

: 71-36-3
butan-1-ol

A: 126-73-8
phosphoric acid tributyl ester

B: 109-69-3
n-Butyl chloride

C: 142-96-1
dibutyl ether

Conditions

Conditions	Yield
With oxygen; phosphan; copper(l) chloride; copper dichloride at 24.9℃; Kinetics; Product distribution; Mechanism; ΔE(excit.), ΔS(excit.); other reagents, other catalysts;	A 90% B n/a C n/a
With oxygen; phosphan; copper(l) chloride; copper dichloride at 24.9℃;	A 90% B n/a C n/a

...Expand

: 56-23-5
tetrachloromethane

: 629-35-6
dibutylmercury

A: mercury(I) chloride

B: 109-69-3
n-Butyl chloride

C: 67-66-3
chloroform

D: 543-63-5
n-butylmercuric chloride

E: mercury

Conditions

Conditions	Yield
In neat (no solvent) 150°C, 25 h; further products;	A 2% B 87% C 105 % D 7% E 89%

...Expand

: 3027-56-3
Dibutylboran-butylester

: 10026-13-8, 874483-75-7
phosphorus pentachloride

A: 109-69-3
n-Butyl chloride

B: 1730-69-4
dibutylchloroborane

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
exothermic react.; removing C4H9Cl and OPCl3 at reduced pressure, distn. of residue;	A n/a B 89% C n/a

...Expand

: 109-65-9
1-bromo-butane

: 6974-77-2
1-bromo-3-chloro-2-methyl propane

A: 109-69-3
n-Butyl chloride

B: 28148-04-1
1,3-dibromo-2-methylpropane

Conditions

Conditions	Yield
With tetrabutylammomium bromide at 105 - 110℃; Inert atmosphere; Schlenk technique;	A n/a B 86%

...Expand

: 1809-19-4
dibutyl hydrogen phosphite

A: 109-69-3
n-Butyl chloride

B: phosphorous acid monobutyl ester zinc salt

Conditions

Conditions	Yield
With zinc(II) chloride at 125℃; for 1h; Product distribution; Rate constant; other time; the thermal stability of the product was investigated by DTA, DTG and TG;	A n/a B 85%

: 74724-76-8
butyldiphenylbismutane

A: 109-69-3
n-Butyl chloride

B: 108-90-7
chlorobenzene

Conditions

Conditions	Yield
With chlorine In tetrahydrofuran at 0℃; Product distribution;	A 14% B 84%
With chlorine In diethyl ether at 0℃;	A 84 % Chromat. B 14 % Chromat.

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 2449-19-6
1,4-bis(di-n-butoxy)-boryl-phenylene

A: 109-69-3
n-Butyl chloride

B: 71258-12-3
1,4-bis(dichloroboryl)benzene

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In tetrachloromethane boiled for 7 h using back-flow; distn. of CCl4, sublimation;	A n/a B 84% C n/a

...Expand

: 6940-78-9
4-chlorobutyl bromide

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With iron(III)-acetylacetonate; tert-butylmagnesium chloride In tetrahydrofuran at 0℃; for 1.5h; Inert atmosphere;	83%
With borohydride exchange resin; nickel diacetate In methanol for 3h; Ambient temperature;	95 % Chromat.
With Amberlite IRA-400; borohydride form; copper(II) sulfate In methanol at 20℃; for 1h; Reduction;	95 % Chromat.

: 1809-19-4
dibutyl hydrogen phosphite

A: 109-69-3
n-Butyl chloride

B: phosphorous acid monobutyl ester calcium salt

Conditions

Conditions	Yield
With calcium chloride at 122℃; for 1h; Product distribution; other time;	A n/a B 81%
With calcium chloride at 122℃; for 1h;	A n/a B 81%

: 17487-60-4
1,1-dibutoxy-2,2-dichloro-ethene

A: 109-69-3
n-Butyl chloride

B: 118487-60-8
C6H9Cl3O2S2

Conditions

Conditions	Yield
With sulfur dichloride In dichloromethane	A n/a B 81%

: 102-82-9
tributyl-amine

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With 2-chloro-4,6-dimethoxy-1 ,3,5-triazine In toluene Reflux;	81%

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 71-36-3
butan-1-ol

A: 109-69-3
n-Butyl chloride

B: 592-84-7
n-butyl formate

Conditions

Conditions	Yield
With benzoyl chloride at 80℃; for 2h;	A 81% B n/a

...Expand

: 75-44-5
phosgene

: 807292-23-5
vinylphosphonic acid-di-n-butyl ester

A: 109-69-3
n-Butyl chloride

B: 1438-74-0
vinyldichlorophosphine oxide

Conditions

Conditions	Yield
	A n/a B 80.5%

...Expand

: 993-38-4
chlorodifluoromethansulfenylchloride

: 106-97-8
n-butane

A: 78-86-4, 53178-20-4
s-butyl chloride

B: 109-69-3
n-Butyl chloride

C: 15520-09-9
2-(Chloro-difluoro-methylsulfanyl)-butane

D: 15520-08-8
n-C4H9SCF2Cl

E: 692-58-0
bis(chlorodifluoromethyl)disulfane

Conditions

Conditions	Yield
	A 21.8% B 2.8% C 12.7% D 7% E 80.3%
	A 21.8% B 2.8% C 12.7% D 7% E 80.3%

...Expand

: 109-65-9
1-bromo-butane

: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With Cl*2H2O In toluene at 150℃;	80%
With chloride ions In gas at 125℃; under 640 Torr; Rate constant; nitrogen buffer gas;
With chloride at 30.9℃; under 760 Torr; Kinetics; Thermodynamic data; Equilibrium constant; ΔE0, ΔG0, mechanism;
With chloride In gas at 35 - 150℃; under 640 Torr; Thermodynamic data; Ea; var. pressure;
With 1,1,2,2-tetrachloroethylene at 90℃; for 24h; Inert atmosphere;

: 10026-13-8, 874483-75-7
phosphorus pentachloride

: 7330-44-1
1,3-bis(di-n-butoxy)-boryl-phenylene

A: 109-69-3
n-Butyl chloride

B: 116865-44-2
1,3-(BCl2)2-C6H4

C: 10025-87-3, 12599-09-6, 63736-95-8
trichlorophosphate

Conditions

Conditions	Yield
In tetrachloromethane boiled for 7 h using back-flow; distn.;	A n/a B 79% C n/a

...Expand

: 71-36-3
butan-1-ol

A: 78-86-4, 53178-20-4
s-butyl chloride

B: 109-69-3
n-Butyl chloride

C alkenes: alkenes

Conditions

Conditions	Yield
With hydrogenchloride; aluminium trichloride; silica gel at 170℃; under 760 Torr; Product distribution; other catalysts, other alcohols, other products;	A 7 % Chromat. B 78% C n/a

...Expand

: 71-36-3
butan-1-ol

A: 1499-17-8
o-phenylene chlorophosphate

B: 109-69-3
n-Butyl chloride

Conditions

Conditions	Yield
With CPT	A n/a B 77%

: 693-00-5
Butyl phosphorodifluoridite

: 3188-13-4
ethyl chloromethyl ether

A: 109-69-3
n-Butyl chloride

B: 67974-15-6
(ethoxymethyl)phosphonic difluoride

Conditions

Conditions	Yield
With iron(III) chloride for 1.5h; Heating;	A n/a B 76%

...Expand

: 3582-11-4
trichloromethylphosphonous dichloride

: 71-36-3
butan-1-ol

A: 1809-19-4
dibutyl hydrogen phosphite

B: 109-69-3
n-Butyl chloride

C: 67-66-3
chloroform

Conditions

Conditions	Yield
	A 75.4% B n/a C n/a

...Expand

: 17640-25-4
methyl 2,2-dichloro-2-methoxyacetate

: 693-00-5
Butyl phosphorodifluoridite

A: 109-69-3
n-Butyl chloride

B: 66298-77-9
phosphonic difluoride

Conditions

Conditions	Yield
With iron(III) chloride at 60 - 80℃; for 0.75h;	A n/a B 75%

...Expand

: 109-69-3
n-Butyl chloride

: 62-53-3
aniline

: 1126-78-9
N-(n-butyl)aniline

Conditions

Conditions	Yield
With 1-n-butyl-3-(methoxyethoxymethyl)imidazolium chloride at 90℃; for 3h; Solvent; Inert atmosphere; Green chemistry;	100%
With tetrabutyl ammonium fluoride at 80℃; for 12h;	70%
durch Erhitzen molekularer Mengen auf dem Wasserbad;

: 109-69-3
n-Butyl chloride

: 95-68-1
2,4-Xylidine

: 41115-19-9
N-butyl(2,4-dimethyl)aniline

Conditions

Conditions	Yield
With 3-(2-ethoxy-2-oxoethyl)-1-methyl-1H-imidazol-3-ium chloride at 90℃; for 3h; Inert atmosphere; Green chemistry;	100%

: 109-69-3
n-Butyl chloride

: 100-61-8
N-methylaniline

: 3416-49-7
N-butyl-N-methylaniline

Conditions

Conditions	Yield
With 3-(2-ethoxy-2-oxoethyl)-1-methyl-1H-imidazol-3-ium chloride at 90℃; for 3h; Inert atmosphere; Green chemistry;	100%

: 109-69-3
n-Butyl chloride

: 124-38-9
carbon dioxide

: 592-84-7
n-butyl formate

Conditions

Conditions	Yield
With hydrogen; sodium hydrogencarbonate; {W(CO)5Cl}(1-) In tetrahydrofuran at 150℃; under 80 - 85 Torr; for 24h;	100%

: 109-69-3
n-Butyl chloride

: 90606-10-3
(E)-N-(phenylmethylene)-1-(trimethylsilyl)methylamine

: 624-49-7
dimethylfumarate

: 82959-82-8, 82959-83-9, 82959-84-0, 82959-85-1
(3R,4R)-2-Phenyl-pyrrolidine-3,4-dicarboxylic acid dimethyl ester

Conditions

Conditions	Yield
In N,N,N,N,N,N-hexamethylphosphoric triamide at 40 - 45℃;	100%

...Expand

: 616-47-7
1-methyl-1H-imidazole

: 109-69-3
n-Butyl chloride

: 79917-90-1
1-butyl-3-methylimidazolium chloride

Conditions

Conditions	Yield
Alkylation;	100%
In toluene at 112 - 113℃; for 3h;	100%
at 170℃; Microwave irradiation;	99%

: 109-69-3
n-Butyl chloride

: 92491-22-0
tert-butyl 2-phenyldiazene-1-carboxylate

: tert-butyl 2-butyl-2-phenylhydrazinecarboxylate

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With zinc(II) chloride In tetrahydrofuran Stage #2: tert-butyl 2-phenyldiazene-1-carboxylate In tetrahydrofuran at -80℃;	100%

: 109-69-3
n-Butyl chloride

: 6674-22-2
1,8-diazabicyclo[5.4.0]undec-7-ene

: 1-butyl-2,3,4,6,7,8,9,10-octahydro-pyrimido[1,2-a]azepin-1-ium chloride

Conditions

Conditions	Yield
for 5h; Heating;	100%
In acetonitrile at 75℃; for 24h; Inert atmosphere;	99%
at 50℃; for 24h; Inert atmosphere;	87%
In acetonitrile for 96h; Reflux;	56%

: 109-69-3
n-Butyl chloride

: 4532-96-1
1-isopropyllimidazole

: 1174062-48-6
1-butyl-3-isopropylimidazolium chloride

Conditions

Conditions	Yield
at 75℃; for 12h; Inert atmosphere; neat (no solvent);	100%

: 109-69-3
n-Butyl chloride

: 16650-76-3
[1',1',1'-d3]-1-methyl-1H-imidazole

: 1337571-71-7
[1”,1”,1”-d3]-1-n-butyl-3-methylimidazolium chloride

Conditions

Conditions	Yield
at 95℃;	100%

: 110-91-8
morpholine

: 109-69-3
n-Butyl chloride

: 1005-67-0
N-butylmorpholine

Conditions

Conditions	Yield
With C11H19N2O2(1+)*Cl(1-) at 90℃; for 3h; Inert atmosphere; Green chemistry;	100%
With tetrabutylammomium bromide; sodium hydroxide In water at 100℃; for 2h;	93 %Chromat.

: 109-69-3
n-Butyl chloride

: 106-47-8
4-chloro-aniline

: 5441-81-6
N-butyl-N-(4-chlorophenyl)amine

Conditions

Conditions	Yield
With C11H19N2O2(1+)*Cl(1-) at 90℃; for 3h; Inert atmosphere; Green chemistry;	100%

: 7440-31-5
tin

: 109-69-3
n-Butyl chloride

A: 683-18-1
dibutyltin chloride

B: 1461-22-9
tributyltin chloride

Conditions

Conditions	Yield
With catalyst: dicyclohexyl-18-crown-6/n-C4H9I In N,N-dimethyl-formamide 120°C; 24 h; excess KI;; analyzed by GLC;;	A 99% B 1%
With catalyst: dibenzo-18-crown-6/n-C4H9I In N,N-dimethyl-formamide 120°C; 24 h; excess KI;; analyzed by GLC;;	A 98% B 2%
With catalyst: dibenzo-18-crown-6/n-C8H17I In N,N-dimethyl-formamide 120°C; 24 h; excess KI;; analyzed by GLC;;	A 98% B 2%

...Expand

: 109-69-3
n-Butyl chloride

: 1059044-11-9
(-)-(2S)-(nonafluorobutane-1-sulfonyloxy)-propionic acid tert-butyl ester

: 1059043-96-7
(+)-(2S)-methyl-hexanoic acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With magnesium Inert atmosphere; Stage #2: (-)-(2S)-(nonafluorobutane-1-sulfonyloxy)-propionic acid tert-butyl ester With zinc(II) chloride at 0℃; for 3h; Inert atmosphere; optical yield given as %ee; enantiospecific reaction;	99%

: 109-69-3
n-Butyl chloride

: 1059044-37-9
(-)-(2S)-trifluoromethanesulfonyloxy-3-methyl-butyric acid tert-butyl ester

: 1059044-25-5
(+)-(2R)-isopropyl-hexanoic acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With magnesium In tetrahydrofuran Inert atmosphere; Stage #2: (-)-(2S)-trifluoromethanesulfonyloxy-3-methyl-butyric acid tert-butyl ester With zinc(II) chloride In tetrahydrofuran at 0℃; for 3h; Inert atmosphere; optical yield given as %ee; enantiospecific reaction;	99%

: 109-69-3
n-Butyl chloride

: 1059044-38-0
(-)-(2S)-trifluoromethanesulfonyloxy-(3S)-methyl-pentanoic acid tert-butyl ester

: 1059044-28-8
(+)-(2R)-[propyl-(1'S)-methyl]-hexanoic acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With magnesium Inert atmosphere; Stage #2: (-)-(2S)-trifluoromethanesulfonyloxy-(3S)-methyl-pentanoic acid tert-butyl ester With zinc(II) chloride at 0℃; for 3h; Inert atmosphere; optical yield given as %ee; enantiospecific reaction;	99%

: 109-69-3
n-Butyl chloride

: 111757-80-3
(-)-(2S)-trifluoromethanesulfonyloxy-propionic acid tert-butyl ester

: 1059043-96-7
(+)-(2S)-methyl-hexanoic acid tert-butyl ester

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With magnesium In tetrahydrofuran Inert atmosphere; Stage #2: (-)-(2S)-trifluoromethanesulfonyloxy-propionic acid tert-butyl ester With zinc(II) chloride In tetrahydrofuran at 0℃; for 3h; Inert atmosphere; optical yield given as %ee; enantiospecific reaction;	99%

: 109-69-3
n-Butyl chloride

: C41H60N2S

: S-butyl-N,N'-bis(dehydroabietyl)thiouronium chloride

Conditions

Conditions	Yield
In ethanol at 90℃; for 24h; Sealed tube;	99%

: 25372-02-5
1-(3-bromophenyl)-1H-imidazole

: 109-69-3
n-Butyl chloride

: 1-(3-bromophenyl)-3-butylimidazol-3-ium chloride

Conditions

Conditions	Yield
In acetonitrile at 120℃; for 16h; Sealed tube;	99%

: 109-69-3
n-Butyl chloride

: bis[3-(3'-(dibutyloxyphosphorothioyl)thio-2'-methylpropanyloxy)-2-hydroxypropyl] undecanedioate

: C49H94O14P2S4

Conditions

Conditions	Yield
With triethylamine at 25℃; for 16h;	99%

: 109-69-3
n-Butyl chloride

: C33H62O14P2S4

: C41H78O14P2S4

Conditions

Conditions	Yield
With triethylamine at 25℃; for 16h;	99%

: 86-73-7
9H-fluorene

: 109-69-3
n-Butyl chloride

: 15069-42-8
9,9-bis(n-butyl)fluorene

Conditions

Conditions	Yield
With sodium hydroxide In 1,4-dioxane	99%
With tetrabutylammomium bromide; sodium hydroxide In water at 20 - 60℃; for 1h;

: 109-69-3
n-Butyl chloride

: 79917-90-1
1-butyl-3-methylimidazolium chloride

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole	98%

: 109-69-3
n-Butyl chloride

: 7646-78-8
tin(IV) chloride

: 1461-25-2
tetra-n-butyltin(IV)

Conditions

Conditions	Yield
With magnesium In diethyl ether; toluene at 50 - 60℃; Solvent; Inert atmosphere; Flow reactor;	98%
With sodium In Petroleum ether (Ar); vigorous stirred suspn. of Na was maintained at 115°C for 30 min, then one drop of SnCl4 was added and ClC4H9 was added dropwise within 3 h at 0-5°C, after 75 min stirring SnCl4 was dropped into mixt. at the same temp. within 2 h; after stirring for a further 2 h at 20-25°C mixt. was filtered off and residue treated with tBuOH, solvents were distd. off from filtrate; identification by GC after methylation;	91%
With magnesium In 2-methyltetrahydrofuran for 5h; Solvent; Reflux;	77.87%
Stage #1: n-Butyl chloride With magnesium for 0.5h; Reflux; Stage #2: tin(IV) chloride for 3h; Reflux;

: 109-69-3
n-Butyl chloride

: 100-52-7
benzaldehyde

: 33652-83-4
(S)-(-)-1-phenylpentanol

Conditions

Conditions	Yield
Stage #1: n-Butyl chloride With magnesium; lithium chloride In diethyl ether at 35℃; for 12h; Stage #2: With sodium methylate; zinc(II) chloride In diethyl ether at 0℃; Inert atmosphere; Stage #3: benzaldehyde With (S)-N-(3-methyl-1-(1-pyrrolidin-1-yl)butan-2-yl)-P,P-di(naphthalen-1-yl)phosphinic amideamine at 20℃; for 2h; Neat (no solvent); optical yield given as %ee;	98%
Stage #1: n-Butyl chloride With magnesium In diethyl ether Inert atmosphere; Stage #2: benzaldehyde With titanium(IV) isopropylate; (Sa)-2'-[(R)-hydroxy(phenyl)methyl]-(1,1'-binaphthalen)-2-ol In toluene at -40℃; for 4.16h; Grignard reaction; Inert atmosphere; optical yield given as %ee; enantioselective reaction;	41%

: 109-69-3
n-Butyl chloride

: 1-(3-(1H-imidazol-1-yl)phenyl)-2-phenylimidazole

: 3-butyl-1-(3-(3-butylimidazol-3-ium-1-yl)phenyl)-2-phenylimidazol-3-ium chloride

Conditions

Conditions	Yield
In acetonitrile at 120℃; for 16h; Sealed tube;	98%
In acetonitrile at 150℃; for 24h;	98%

: 124-09-4
1,6-Hexanediamine

: 109-69-3
n-Butyl chloride

: 17351-61-0
tetraethylammonium bicarbonate

: 3066-67-9
1,6-bis-(n-butoxycarbonyl-amino)-hexane

Conditions

Conditions	Yield
Stage #1: 1,6-Hexanediamine; tetraethylammonium bicarbonate In acetonitrile at 20℃; for 1h; Stage #2: n-Butyl chloride In acetonitrile at 80℃; for 3h;	98%
Stage #1: 1,6-Hexanediamine; tetraethylammonium bicarbonate In acetonitrile at 20℃; for 2h; Green chemistry; Stage #2: n-Butyl chloride In acetonitrile at 80℃; for 3h; Green chemistry;	90%

...Expand

1-Chlorobutane Specification

1-Chlorobutane, its cas register number is 109-69-3. It also can be called Butyl chloride; n-Butyl chloride; Butane, 1-chloro-; Chlorure de butyle; N-Propylcarbinyl chloride. It is a water white liquid with a sharp odor. It slightly soluble in water. Its vapors are heavier than air. It is highly flammable. It may react with atmospheric moisture over prolonged periods of exposure. 1-Chlorobutane can be used in the manufacture of a variety of organic chemicals.

Physical properties about 1-Chlorobutane are: (1)ACD/LogP: 2.641; (2)ACD/LogD (pH 5.5): 2.64; (3)ACD/LogD (pH 7.4): 2.64; (4)ACD/BCF (pH 5.5): 59.91; (5)ACD/BCF (pH 7.4): 59.91; (6)ACD/KOC (pH 5.5): 651.58; (7)ACD/KOC (pH 7.4): 651.58; (8)#Freely Rotating Bonds: 2; (9)Index of Refraction: 1.396; (10)Molar Refractivity: 25.43 cm³; (11)Molar Volume: 105.947 cm³; (12)Polarizability: 10.081 10-24cm³; (13)Surface Tension: 22.1079998016357 dyne/cm; (14)Density: 0.874 g/cm³; (15)Flash Point: -6.667 °C ; (16)Enthalpy of Vaporization: 30.39 kJ/mol; (17)Boiling Point: 78.211 °C at 760 mmHg; (18)Vapour Pressure: 103.426002502441 mmHg at 25°C

When you are using this chemical, please be cautious about it as the following:
1. Keep container in a well-ventilated place;
2. Keep away from sources of ignition - No smoking;
3. Do not empty into drains;

You can still convert the following datas into molecular structure:
(1)InChI=1S/C4H9Cl/c1-2-3-4-5/h2-4H2,1H3;
(2)InChIKey=VFWCMGCRMGJXDK-UHFFFAOYSA-N;
(3)SmilesC(CC)CCl;

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Source
guinea pig	LD50	unreported	8gm/kg (8000mg/kg)	Vrachebnoe Delo. Medical Practice. Vol. (7), Pg. 105, 1979.
mouse	LD50	unreported	5600mg/kg (5600mg/kg)	Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 44(3), Pg. 11, 1979.
rabbit	LDLo	skin	20gm/kg (20000mg/kg)	"Toxicology of Drugs and Chemicals," Deichmann, W.B., New York, Academic Press, Inc., 1969Vol. -, Pg. 745, 1969.
rat	LCLo	inhalation	8000ppm/4H (8000ppm)	AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat	LD50	oral	2670mg/kg (2670mg/kg)	AMA Archives of Industrial Hygiene and Occupational Medicine. Vol. 10, Pg. 61, 1954.
rat	LD50	unreported	2200mg/kg (2200mg/kg)	Vrachebnoe Delo. Medical Practice. Vol. (7), Pg. 105, 1979.

Product Name

1-Chlorobutane

Synthetic route

1-Chlorobutane Specification

Related Products

Hot Products