1-Naphthalenemethylamine supplier

Name
1-Hydroxyisoquinoline
EINECS 204-244-0
CAS No. 118-31-0
Article Data90
CAS DataBase
Density 1.095 g/cm³
Solubility
Melting Point 262-269 °C
Formula C₁₁H₁₁N
Boiling Point 294.5 °C at 760 mmHg
Molecular Weight 157.215
Flash Point 148.3 °C
Transport Information UN 2735
Appearance Clear light yellow to yellow liquid
Safety 26-36/37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms 1-Naphthalenemethylamine(6CI,7CI,8CI);(Naphthalen-1-ylmethyl)amine;1-(1-Naphthyl)methanamine;1-(1-Naphthyl)methylamine;1-(Aminomethyl)naphthalene;1-Naphthylmethylamine;NSC 210425;Naphthalen-1-ylmethanamine;a-Naphthylmethylamine;
PSA 26.02000
LogP 2.99880

Synthetic route

: 55210-79-2
1-(azidomethyl)naphthalene

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
Stage #1: 1-(azidomethyl)naphthalene With 9-phenyl-9-phosphafluorene; phenylsilane In 1,4-dioxane at 101℃; for 16h; Staudinger reduction reaction; Inert atmosphere; Stage #2: With water In 1,4-dioxane at 20℃; Staudinger reduction reaction; Inert atmosphere;	99%
With ammonium chloride; zinc In ethanol; water

: 86-52-2
1-Chloromethylnaphthalene

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With copper(ll) sulfate pentahydrate; ammonium hydroxide In PEG1000-DIL; methyl cyclohexane at 60℃; for 3h;	98%
With ammonia fluess. Ammoniak;
With hydrogenchloride; hexamethylenetetramine 1) CH2Cl2, 12 h, 2) ethanol; Yield given. Multistep reaction;
Multi-step reaction with 2 steps 1: N,N-dimethyl-formamide / 10 h / 20 °C / Inert atmosphere 2: hydrazine hydrate / ethanol / 4 h / Inert atmosphere; Reflux View Scheme

: 86-53-3
1-Cyanonaphthalene

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With C19H34Cl2CoN2P; hydrogen; sodium ethanolate; sodium triethylborohydride In benzene at 135℃; under 22502.3 Torr; for 36h; Autoclave;	98%
With [Ru(H)(BH4)(CO)(PPh3)(3-(di-tert-butylphosphino)-N-((1-methyl-1H-imidazol-2 yl)methyl)propylamine)]; hydrogen In isopropyl alcohol at 50℃; for 3h; Inert atmosphere; Autoclave;	98%
With samarium diiodide; water In tetrahydrofuran for 0.0166667h; Ambient temperature;	95%

: 13504-46-6, 51873-97-3, 57207-33-7
1-naphtylaldehyde oxime

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With (pyridine)(tetrahydroborato)zinc In tetrahydrofuran for 0.4h; Heating;	98%
With sodium hydrogensulfate monohydrate; molybdenum(V) chloride; sodium cyanoborohydride In ethanol for 2h; Reflux;	97%
With sodium tetrahydroborate at 20℃; for 0.0333333h; neat (no solvent, solid phase);	96%

: 86328-84-9
4-methyl-N-(naphthalen-1-ylmethyl)benzenesulfonamide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
Stage #1: 4-methyl-N-(naphthalen-1-ylmethyl)benzenesulfonamide With n-butyllithium In tetrahydrofuran at 0℃; for 0.166667h; Inert atmosphere; Stage #2: With naphthalene; lithium In tetrahydrofuran at -78 - 25℃; Stage #3: With water In tetrahydrofuran	94%

: 66-77-3
1-naphthaldehyde

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With N,N'-bis(salicylidene)-1,2-phenylene-diaminocobalt(II); ammonia; hydrogen In tetrahydrofuran; water at 120℃; for 24h; Autoclave;	86%
With lithium borohydride; Rink amine resin; water; trifluoroacetic acid; trimethyl orthoformate solid phase synthesis; 1) RT, 2) THF, 70 deg C, 5 h, 3) CH2Cl2, RT, 5 h; Yield given. Multistep reaction;
Multi-step reaction with 3 steps 1: NaBH4 / ethanol; H2O / 20 °C 2: 2.7 g / PPh3; DEAD / tetrahydrofuran / 22 h / 0 - 20 °C 3: NaBH4; AcOH / propan-1-ol; H2O / 5 h / 80 - 90 °C View Scheme

: 86-53-3
1-Cyanonaphthalene

A: 118-31-0
(naphth-1-yl)methylamine

B: 5798-49-2
1-(naphthalen-1-yl)-N-(naphthalen-1-ylmethyl)methanamine

Conditions

Conditions	Yield
With sodium tetrahydroborate; nickel dichloride In ethanol at 20℃; for 0.0833333h;	A 82% B 7%
With tetralin; nickel at 190℃; under 15200 Torr; Hydrogenation;
With nickel; decalin at 190℃; under 15200 Torr; Hydrogenation;

: 4780-79-4
1-naphthalene methanol

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
Stage #1: 1-naphthalene methanol With resin-bound CH2OCONHCOOtBu; diethylazodicarboxylate In tetrahydrofuran for 12h; Solid phase reaction; Mitsunobu reaction; Stage #2: With trifluoroacetic acid In 1,2-dichloro-ethane for 4h; Decarboxylation;	80%
Multi-step reaction with 2 steps 1: 2.7 g / PPh3; DEAD / tetrahydrofuran / 22 h / 0 - 20 °C 2: NaBH4; AcOH / propan-1-ol; H2O / 5 h / 80 - 90 °C View Scheme
Multi-step reaction with 2 steps 1: acetic acid; hydrogen bromide / 0.5 h / 0 °C 2: ammonia / ethanol; water / 4 h / 20 °C View Scheme
Multi-step reaction with 2 steps 1: hydrogen bromide / acetic acid / 0.5 h / 0 °C 2: ammonium hydroxide / ethanol / 4 h / 20 °C View Scheme

: 67-56-1
methanol

: 55210-79-2
1-(azidomethyl)naphthalene

A: 118-31-0
(naphth-1-yl)methylamine

B: 16413-71-1
N,N-dimethyl(naphthalen-1-yl)methanamine

C: 14489-75-9
N-methyl-1-naphthalenemethylamine

Conditions

Conditions	Yield
With trans-RuCl(phenpyra-Me)(PPh3)2PF6; sodium hydroxide at 125℃; for 2.5h; Sealed tube; Inert atmosphere; Glovebox;	A 8 %Chromat. B 9 %Chromat. C 68%

...Expand

: 55210-79-2
1-(azidomethyl)naphthalene

A: 1-(naphthalen-1-yl)-N-(naphthalen-1-ylmethylene)methanamine

B: 118-31-0
(naphth-1-yl)methylamine

C: 95048-05-8
1-naphthaldimine

D: 86-53-3
1-Cyanonaphthalene

Conditions

Conditions	Yield
With tert-butylethylene; [IrClH(1,3-bis((di-tert-butylphosphino)methyl)benzene)]; sodium t-butanolate In para-xylene at 200℃; for 7h; Sealed tube;	A n/a B n/a C n/a D 64%

...Expand

: 13504-46-6, 51873-97-3, 57207-33-7
1-naphtylaldehyde oxime

A: 118-31-0
(naphth-1-yl)methylamine

B: 90-12-0
1-Methylnaphthalene

Conditions

Conditions	Yield
With ammonium formate; palladium on activated charcoal In methanol at 50℃; for 0.416667h;	A 56% B 40%

: 86-86-2
1-Naphthylacetamide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With sodium hydroxide; benzyltrimethylazanium tribroman-2-uide In water for 5h; Ambient temperature;	51%

: 13504-46-6, 51873-97-3, 57207-33-7
1-naphtylaldehyde oxime

A: 118-31-0
(naphth-1-yl)methylamine

: (±)-1,2-di(naphthalen-1-yl)ethane-1,2-diamine

C: meso-1,2-di(1-naphthyl)-1,2-diaminoethane

Conditions

Conditions	Yield
With methanesulfonic acid; zinc In acetonitrile at 25℃; reduction;	A 44% B n/a C n/a
With titanium tetrachloride; zinc In tetrahydrofuran at 25℃; reduction;	A 5% B n/a C n/a

...Expand

: 2243-82-5
2-naphthamide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With sulfuric acid at 48℃; bei der elektrolytischen Reduktion an einer Bleikathode und hoher Stromdichte;

: 100-97-0
hexamethylenetetramine

: 86-52-2
1-Chloromethylnaphthalene

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With chloroform Erhitzen des Reaktionsproduts mit Aethanol und wss. Salzsaeure;

: 20300-10-1
1-naphthalenecarbothioamide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With hydrogenchloride; ethanol; zinc

: 86-53-3
1-Cyanonaphthalene

A: 118-31-0
(naphth-1-yl)methylamine

B: 20300-10-1
1-naphthalenecarbothioamide

Conditions

Conditions	Yield
With NaBH2S3 In tetrahydrofuran

: 7647-01-0
hydrogenchloride

: 64-17-5
ethanol

: 20300-10-1
1-naphthalenecarbothioamide

zinc dust: zinc dust

A: 118-31-0
(naphth-1-yl)methylamine

B α.β-di--ethane: α.β-di--ethane

...Expand

<1>naphthylamide: <1>naphthylamide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With lithium aluminium tetrahydride; diethyl ether

N-α-naphthylmethyl-phthalimide: N-α-naphthylmethyl-phthalimide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With sodium hydroxide Ansaeuern mit Salzsaeure, Verdampfung den Alkohol und erhitzt man bis zur vollstaendig Loesung;

N--phthalimide: N--phthalimide

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With hydrazine
With hydrogenchloride
With sodium hydroxide

naphthyl-(1)-methyl magnesium chloride: naphthyl-(1)-methyl magnesium chloride

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With chloroamine; diethyl ether anschliessesndes Behandeln mit wss. Salzsaeure;

thio-α-naphthoic acid amine: thio-α-naphthoic acid amine

A: 118-31-0
(naphth-1-yl)methylamine

B α.β-di--ethane: α.β-di--ethane

Conditions

Conditions	Yield
With hydrogenchloride; ethanol; zinc

: 6968-09-8
2-[(1-naphthyl)methyl]-1H-isoindole-1,3(2H)-dione

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With sodium tetrahydroborate; acetic acid In propan-1-ol; water at 80 - 90℃; for 5h;
With hydrazine hydrate In methanol for 1h; Heating;
With hydrazine In ethanol at 60℃; for 3h;
With hydrazine hydrate In ethanol for 4h; Inert atmosphere; Reflux;	609 mg

: 39110-74-2
(α-naphthylmethyl)ammonium chloride

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
With potassium carbonate In water; ethyl acetate

: 477710-75-1
(1-naphthyl)methylcarbamic acid

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
In toluene Heating;

: 946132-36-1
C23H18N2O2

A: 118-31-0
(naphth-1-yl)methylamine

B: 66-77-3
1-naphthaldehyde

C: 86-53-3
1-Cyanonaphthalene

Conditions

Conditions	Yield
In acetonitrile at 25 - 30℃; Irradiation;

...Expand

: C18H14N2O4

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Et3N / CH2Cl2 / 20 °C 2: acetonitrile / 25 - 30 °C / Irradiation View Scheme

: 66-77-3
1-naphthaldehyde

ethyl 2-halogeno-acetate: ethyl 2-halogeno-acetate

: 118-31-0
(naphth-1-yl)methylamine

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 99 percent / NH2OH*HCl; Na2CO3 / ethanol; H2O / 2 h / 20 °C 2: glacial AcOH; H2 / Pd/C / ethanol / 2 h / 20 °C View Scheme

: 4509-90-4
5-bromovaleroyl chloride

: 118-31-0
(naphth-1-yl)methylamine

: 5-bromo-pentanoic acid (naphthalen-1-ylmethyl)-amide

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide for 1h;	100%

: 22809-37-6
6-bromohexanoyl chloride

: 118-31-0
(naphth-1-yl)methylamine

: 926310-50-1
6-bromo-hexanoic acid (naphthalen-1-ylmethyl)-amide

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide for 1h;	100%

: 118-31-0
(naphth-1-yl)methylamine

: 656822-35-4
2,4-dichloro-6-(3-methyl-butyl)-pyrimidine

: 1067679-25-7
2,4-dinaphthalen-1-ylmethylamino-6-isopentylpyrimidine

Conditions

Conditions	Yield
at 95℃; for 16h; Inert atmosphere; Autoclave;	100%

: 118-31-0
(naphth-1-yl)methylamine

: 83881-51-0
cetirizine

: C21H25ClN2O3*C11H11N

Conditions

Conditions	Yield
In methanol at 20℃; Sonication;	100%

: 118-31-0
(naphth-1-yl)methylamine

: 86-53-3
1-Cyanonaphthalene

Conditions

Conditions	Yield
With copper(I) chloride; 4 A molecular sieve; oxygen In pyridine at 60℃; for 24h;	99%
With dmap; copper(l) iodide; 9-azabicyclo[3.3.1]nonane N-oxyl; oxygen; 4,4'-di-tert-butyl-2,2'-bipyridine In acetonitrile at 20℃; under 760.051 Torr; for 15h; Reagent/catalyst;	98%
With potassium hydroxide; nickel copper formate; (Bu4N)2S2O8 In 1,2-dichloro-ethane at 20℃; for 12h; Oxidation;	90%

: 2739-98-2
ethyl 2-(pyridinyl-2)acetate

: 118-31-0
(naphth-1-yl)methylamine

: 1430074-85-3
ethyl 3-(naphthalen-1-yl)imidazo[1,5-α]pyridine-1-carboxylate

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; N-iodo-succinimide In N,N-dimethyl acetamide; water at 20℃; for 12h;	99%
With sulfur In dimethyl sulfoxide at 110℃; for 2h; Sealed tube;	84%

: 118-31-0
(naphth-1-yl)methylamine

: 41153-30-4, 57292-45-2, 79561-25-4, 129101-25-3
Boc-Phe(p-F)

: tert-butyl (S)-(3-(4-fluorophenyl)-1-((naphthalen-1-ylmethyl)amino)-1-oxopropan-2-yl)carbamate

Conditions

Conditions	Yield
Stage #1: (naphth-1-yl)methylamine; Boc-Phe(p-F) With 1-hydroxy-7-aza-benzotriazole; HATU In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0℃; for 1h;	99%
Stage #1: (naphth-1-yl)methylamine; Boc-Phe(p-F) With 1-hydroxy-7-aza-benzotriazole; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0℃; for 0.0833333h; Inert atmosphere; Stage #2: With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0℃; for 1h;	99%
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 0 - 20℃;
With benzotriazol-1-ol; N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate In N,N-dimethyl-formamide at 0℃; for 1.5h;

: 91-02-1
phenyl(pyridin-2-yl)methanone

: 118-31-0
(naphth-1-yl)methylamine

: 3-(naphthalen-1-yl)-1-phenylimidazo[1,5-a]pyridine

Conditions

Conditions	Yield
With iodine; sodium acetate In 1,2-dichloro-ethane for 6h; Reflux;	99%
With copper(II) acetate monohydrate In N,N-dimethyl-formamide at 110℃; for 8h;	90%

: 118-31-0
(naphth-1-yl)methylamine

: N,N',N''-tris(3-triethoxysilylpropyl) cis,cis-1,3,5-cyclohexanetricarboxamide

: N,N',N''-tris[(1-naphthyl)methyl] cis,cis-1,3,5-cyclohexanetricarboxamide

Conditions

Conditions	Yield
at 145℃; for 2h; Inert atmosphere;	99%

: 118-31-0
(naphth-1-yl)methylamine

: 99-61-6
3-nitro-benzaldehyde

: N-(1-naphthylmethyl)-N-[(3-nitrophenyl)methylene]amine

Conditions

Conditions	Yield
With magnesium sulfate In ethanol for 20h; Reflux;	99%
In chloroform at 40℃; for 9h;

: 118-31-0
(naphth-1-yl)methylamine

: 2421-28-5
dianhydride of benzophenone-3,4,3',4'-tetracarboxy acid

: 4,4'-carbonylbis(2-(naphthalen-1-ylmethylcarbamoyl)benzoic acid)

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 0℃; for 3h;	99%

: 118-31-0
(naphth-1-yl)methylamine

: 187808-48-6
methyl 5-(N,N-dimethylamino)-2,4-pentadienoate

: methyl 5-(1-naphthalenemethylamino)-2,4-pentadienoate

Conditions

Conditions	Yield
In tetrahydrofuran for 120h; Heating;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 762-42-5
dimethyl acetylenedicarboxylate

: 1663-67-8
malonoyl dichloride

: C20H17NO6

Conditions

Conditions	Yield
In dichloromethane at 20℃;	98%

...Expand

: 79-37-8
oxalyl dichloride

: 118-31-0
(naphth-1-yl)methylamine

: 762-42-5
dimethyl acetylenedicarboxylate

: 1044520-87-7
C19H17NO7

Conditions

Conditions	Yield
In dichloromethane at 20℃;	98%

...Expand

: 118-31-0
(naphth-1-yl)methylamine

: 79-04-9
chloroacetyl chloride

: 204253-07-6
2-chloro-N-naphthalen-1-yl-methyl-acetamide

Conditions

Conditions	Yield
With potassium carbonate In water; ethyl acetate at 20℃; for 2h;	98%

: 1094780-05-8
(2S)-6-{[(benzyloxy)carbonyl]amino}-2-[(4R)-3-oxo-4-[(phenylacetyl)amino]-3,4,5,10-tetrahydroazepino[3,4-b]indol-2(1H)-yl]hexanoic acid

: 118-31-0
(naphth-1-yl)methylamine

: 1094780-13-8
benzyl (5S)-6-[(1-naphthylmethyl)amino]-6-oxo-5-[(4R)-3-oxo-4-[(phenylacetyl)amino]-3,4,5,10-tetrahydroazepino[3,4-b]indol-2(1H)-yl]hexylcarbamate

Conditions

Conditions	Yield
Stage #1: (2S)-6-{[(benzyloxy)carbonyl]amino}-2-[(4R)-3-oxo-4-[(phenylacetyl)amino]-3,4,5,10-tetrahydroazepino[3,4-b]indol-2(1H)-yl]hexanoic acid With O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine In dichloromethane at 20℃; for 0.166667h; Stage #2: (naphth-1-yl)methylamine In dichloromethane for 1h; pH=8;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 1084-95-3
2-(2'-phenylethynyl)benzoic acid

: 1246168-30-8
3-benzyl-3-hydroxy-2-(naphthalen-1-ylmethyl)isoindolin-1-one

Conditions

Conditions	Yield
Stage #1: 2-(2'-phenylethynyl)benzoic acid With tetrabutylammonium acetate In water at 100℃; for 0.166667h; Microwave irradiation; Inert atmosphere; Stage #2: (naphth-1-yl)methylamine In water at 100℃; for 0.333333h; Microwave irradiation; Inert atmosphere; regioselective reaction;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 859829-95-1
2-((4-methoxyphenyl)ethynyl)benzoic acid

: 1246168-39-7
3-hydroxy-3-(4-methoxybenzyl)-2-(naphthalen-1-ylmethyl)isoindolin-1-one

Conditions

Conditions	Yield
Stage #1: 2-((4-methoxyphenyl)ethynyl)benzoic acid With tetrabutylammonium acetate In water at 100℃; for 0.166667h; Microwave irradiation; Inert atmosphere; Stage #2: (naphth-1-yl)methylamine In water at 100℃; for 0.333333h; Microwave irradiation; Inert atmosphere; regioselective reaction;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 87751-69-7
rac-(E)-1,3-diphenyl-3-acetoxy-prop-1-ene

: C26H23N

Conditions

Conditions	Yield
With N,O-bis-(trimethylsilyl)-acetamide; bis(η3-allyl-μ-chloropalladium(II)); N-[(S)-1-(2-(diphenylphosphino)phenyl)ethyl]-1,7,7-trimethylbicyclo[2,2,1]heptan-2-imine In toluene at 20℃; enantioselective reaction;	98%

: 33265-60-0
1-(2-nitrophenyl)-1H-pyrrole

: 118-31-0
(naphth-1-yl)methylamine

: 4-(naphthalen-1-yl)pyrrolo[1,2-a]quinoxaline

Conditions

Conditions	Yield
With water; pyrographite at 140℃; for 20h; Inert atmosphere;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 933-88-0
ortho-toluoyl chloride

: 2-methyl-N-(naphth-1-ylmethyl)benzamide

Conditions

Conditions	Yield
In tetrahydrofuran for 48h;	98%

: 118-31-0
(naphth-1-yl)methylamine

: 287177-06-4
2'-azido-6-chloro-2'-deoxyadenosine

: 287177-08-6
2'-azido-2'-deoxy-N6-(1-naphthylmethyl)adenosine

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In propan-1-ol at 50℃; for 16h; Substitution; aminolysis;	97%
In propan-1-ol at 50℃; for 16h;

: 118-31-0
(naphth-1-yl)methylamine

: 3123-46-4
4-oxo-1,2,3,4-tetrahydronaphthalene-1-carboxylic acid

: 4-Oxo-1,2,3,4-tetrahydronaphthalene-1-carboxylic acid-(naphthalene-1-ylmethyl)-amide

Conditions

Conditions	Yield
With dmap In methanol; CH3Cl; dichloromethane	97%

: 118-31-0
(naphth-1-yl)methylamine

: 79-22-1
methyl chloroformate

: 92277-77-5
methyl N-(1-naphthalenylmethyl)carbamate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 20℃; for 2h;	97%
With triethylamine at 20℃; for 2h;

: 118-31-0
(naphth-1-yl)methylamine

: 3392-05-0
Boc-Ala-O-N-hydroxysuccinimide

: tert-butyl (S)-(1-((naphthalen-1-ylmethyl)amino)-1-oxopropan-2-yl)carbamate

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃;	97%

: 32703-87-0
N-tertiarybutoxycarbonyl-β-alanine N-hydroxysuccinimide ester

: 118-31-0
(naphth-1-yl)methylamine

: C19H24N2O3

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 0 - 20℃; for 2h;	97%

1-Naphthalenemethylamine Chemical Properties

Product Name: 1-Naphthalenemethylamine
The MF of 1-Naphthalenemethylamine (118-31-0) is C₁₁H₁₁N.

The MW of 1-Naphthalenemethylamine (118-31-0) is 157.21.
Synonyms of 1-Naphthalenemethylamine (118-31-0): 1-Naphthylmethanamine ; Alpha-naphthylmethylamine ; A-menaphthylamine ; 1-Aminomethylnaphthalene ; C-Naphthalen-1-yl-methylamine
Product Categories: Naphthalene derivatives;API intermediates
Form: Clear light yellow to yellow liquid
Index of Refraction: 1.653
EINECS: 204-244-0
Density: 1.095 g/cm³
Flash Point: 148.3 °C
Boiling Point: 294.5 °C
Melting Point: 262-269 °C
Sensitive: Air Sensitive
BRN: 2206459

1-Naphthalenemethylamine Safety Profile

Safety information of 1-Naphthalenemethylamine (118-31-0):
Hazard Codes Xi
Risk Statements 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin
Safety Statements 26-36/37/39
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
RIDADR 2735
WGK Germany 3
F 10-34
HazardClass 8
PackingGroup III

Product Name

1-Hydroxyisoquinoline

Synthetic route

1-Naphthalenemethylamine Chemical Properties

1-Naphthalenemethylamine Safety Profile

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