2-Amino-4,6-dichlorotriazine supplier

Name
2-Amino-4,6-dichlorotriazine
EINECS
CAS No. 933-20-0
Article Data50
CAS DataBase
Density 1.731 g/cm³
Solubility
Melting Point 239-242 °C
Formula C₃H₂Cl₂N₄
Boiling Point 428.8 °C at 760 mmHg
Molecular Weight 164.982
Flash Point 213.1 °C
Transport Information
Appearance
Safety 23-36/37/39
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms s-Triazine,2-amino-4,6-dichloro- (6CI,7CI,8CI);2,4-Dichloro-6-amino-1,3,5-triazine;2-Amino-4,6-dichloro-1,3,5-triazine;2-Amino-4,6-dichloro-s-triazine;4,6-Dichloro-1,3,5-triazin-2-amine;4,6-Dichloro-2-amino-s-triazine;4,6-Dichloro-s-triazin-2-amine;6-Amino-2,4-dichloro-1,3,5-triazine;Aminodichloro-s-triazine;NSC 267458;NSC71988;s-Dichloroaminotriazine;
PSA 64.69000
LogP 1.34180

Synthetic route

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With ammonium hydroxide In dichloromethane at 22 - 26℃;	99%
With ammonium hydroxide In water; acetone at 0 - 5℃; for 0.5h;	95%
With ammonia In water; acetone at 0℃; Heating;	93%

: 123-91-1
1,4-dioxane

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 629-14-1
monoethylene glycol diethyl ether

: 7664-41-7
ammonia

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
at 5 - 8℃;

...Expand

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 7664-41-7
ammonia

: 67-64-1
acetone

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
at -40 - 0℃;

...Expand

: 1336-21-6
ammonium hydroxide

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
In water	2.84 g, (86%)

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

A: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

B: 3397-62-4
2-Chloro-4,6-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With ammonia In diethyl ether 0°C;

: 107-10-8
propylamine

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 37019-16-2
6-chloro-N4-propyl-1,3,5-triazine-2,4-diamine

Conditions

Conditions	Yield
With sodium hydroxide In water; acetone at 0 - 50℃; for 1.5h;	100%
With sodium hydroxide In water; acetone at 0 - 20℃;	76%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 71-36-3
butan-1-ol

: 4-butoxy-6-chloro-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
Stage #1: butan-1-ol With sodium hydride In tetrahydrofuran; mineral oil at 0℃; for 5h; Inert atmosphere; Reflux; Stage #2: 4,6-dichloro-1,3,5-triazin-2-amine In tetrahydrofuran; mineral oil at -78 - 25℃; Inert atmosphere;	99%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: C10H10Cl2NO2(1-)*Li(1+)

: 849615-91-4
3-[(4-amino-6-chloro-[1,3,5]triazin-2-yl)-(3,4-dichlorobenzyl)amino]propionic acid

Conditions

Conditions	Yield
With potassium carbonate In acetone at 20℃;	95%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 108-46-3
recorcinol

: 1853-72-1
4-[4-amino-6-(2,4-dihydroxyphenyl)-1,3,5-triazin-2-yl]benzene-1,3-diol

Conditions

Conditions	Yield
Stage #1: 4,6-dichloro-1,3,5-triazin-2-amine With aluminum (III) chloride In 1,2-dichloro-benzene at 50℃; for 0.25h; Stage #2: recorcinol In 1,2-dichloro-benzene at 50 - 100℃; for 2h;	94.7%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 109-73-9
N-butylamine

: 37019-19-5
desethylterbuthylazine

Conditions

Conditions	Yield
With sodium hydroxide In water; acetone at 0 - 20℃;	94%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 100-46-9
benzylamine

: 189250-15-5
N-benzyl-6-chloro-[1,3,5]triazine-2,4-diamine

Conditions

Conditions	Yield
In 1,4-dioxane for 1h; Reflux;	94%
With potassium carbonate In 1,4-dioxane Reflux;

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 116-17-6
triisopropyl phosphite

: 154806-63-0
tetraisopropyl 6-amino-1,3,5-triazine-2,4-diyldiphosphonate

Conditions

Conditions	Yield
at 150℃; for 0.166667h; Michaelis-Arbuzov reaction; Inert atmosphere; Microwave irradiation; Closed vessel;	93%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 74-89-5
methylamine

: 5425-82-1
N2-methyl-2,4-diamino-6-chloro-[1,3,5]triazine

Conditions

Conditions	Yield
With sodium hydroxide In water at 0 - 20℃; for 2h;	92%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 124-40-3
dimethyl amine

: 2827-47-6
2-amino-4,6-bis(dimethylamino)-1,3,5-triazine

Conditions

Conditions	Yield
With sodium hydroxide In water for 2h; Reflux;	92%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 156-87-6
propan-1-ol-3-amine

: 1147548-17-1
N2-hydroxypropy-6-chloro-2,4-diamino-[1,3,5]-triazine

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at -20 - 20℃;	91%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 124-22-1
n-Dodecylamine

: 4-Amino-2,6-didodecylamino-1,3,5-triazine

Conditions

Conditions	Yield
With sodium hydrogencarbonate In 1,4-dioxane for 24h; Heating;	90%
With sodium hydrogencarbonate In 1,4-dioxane at 100℃; for 24h;

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 123324-71-0
4-tert-butylphenylboronic acid

: 4,6-bis(4-tert-butylphenyl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	90%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 98-80-6
phenylboronic acid

: 5418-07-5
4,6-diphenyl-[1,3,5]triazin-2-ylamine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	90%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 4-amino-1-ethyl-1H-pyrrole-2-carbonitrile

: 4-[(4-amino-6-chloro-1,3,5-triazin-2-yl)amino]-1-ethyl-1H-pyrrole-2-carbonitrile

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 0℃; for 1h;	89%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 4-amino-1-isopropyl-1H-pyrrole-2-carbonitrile

: 4-[(4-amino-6-chloro-1,3,5-triazin-2-yl)amino]-1-isopropyl-1H-pyrrole-2-carbonitrile

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 0℃; for 1h;	89%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 1163297-70-8
(2S,5S)-2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-5-aminomethyl-1,4-dioxane

: 1163297-76-4
2-chloro-4-amino-6-{[[(2S,5S)-2-[(4S)-2,2-dimethyl-1,3-dioxolan-4-yl]-1,4-dioxan-5-yl]methyl]amino}-1,3,5-triazine

Conditions

Conditions	Yield
With triethylamine In N,N-dimethyl-formamide at 20℃;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 60-32-2
6-aminohexanoic acid

: 6-(4-amino-6-chloro-1,3,5-triazin-2-yl-amino)hexanoic acid hydrochloride

Conditions

Conditions	Yield
Stage #1: 4,6-dichloro-1,3,5-triazin-2-amine; 6-aminohexanoic acid With sodium hydrogencarbonate In ethanol; water at 2 - 35℃; Stage #2: With hydrogenchloride In ethanol; water	88%

: 109-01-3
1-methyl-piperazine

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 4-chloro-6-(4-methylpiperazin-1-yl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
In tetrahydrofuran at 65℃; for 1h;	88%

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 27315-39-5
4,6-dichloro-N-(4,6-dichloro-1,3,5-triazin-2-yl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With sodium hydroxide In water; acetone at 15℃; for 15h;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 333432-28-3
9,9-dimethyl-9H-fluoren-2-yl-2-boronic acid

: 4,6-bis(9,9-dimethyl-9H-fluoren-2-yl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 32316-92-0
naphthalene-2-boronic acid

: 4,6-bis(naphthalene-2-yl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 5122-95-2
3-Biphenylboronic acid

: 4,6-bis([1,1'-biphenyl]-3-yl)-1,3,5-triazine-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 108-38-3
m-xylene

: 4,6-bis(2,4-dimethylphenyl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With aluminum (III) chloride In 1,2-dichloro-benzene at 50 - 110℃; for 3h;	88%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: dibenzofuran-2-ylboronic acid

: 4,6-bis(dibenzofuran-2-yl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	87%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 1245943-60-5
(dibenzo[b,d]thiophen-1-yl)boronic acid

: 4,6-bis(dibenzothiophen-1-yl)-1,3.,5-triazin-2-amine

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 85℃; for 12h; Inert atmosphere;	87%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 92-52-4
biphenyl

: 4,6-bis(4-phenylphenyl)-1,3,5-triazin-2-amine

Conditions

Conditions	Yield
With aluminum (III) chloride In 1,2-dichloro-benzene at 50 - 110℃; for 3h;	87%
With aluminum (III) chloride In 1,2-dichloro-benzene at 50 - 110℃; for 3h;	87%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 71-43-2
benzene

: 5418-07-5
4,6-diphenyl-[1,3,5]triazin-2-ylamine

Conditions

Conditions	Yield
With aluminum (III) chloride In 1,2-dichloro-benzene at 50 - 110℃; for 3h;	87%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 75178-96-0
N-Boc-1,3-diaminopropane

: tert-butyl (3-((4-amino-6-chloro-1,3,5-triazin-2-yl)amino)propyl)carbamate

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 12h; Inert atmosphere;	86%

: 933-20-0
4,6-dichloro-1,3,5-triazin-2-amine

: 51644-96-3
5-tert-butoxycarbonylamino-1-aminopentane

: C13H23ClN6O2

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In acetonitrile at 20℃; for 12h; Inert atmosphere;	86%

2-Amino-4,6-dichlorotriazine Chemical Properties

Molecular structure of 2-Amino-4,6-dichlorotriazine (CAS NO.933-20-0) is:

Product Name: 2-Amino-4,6-dichlorotriazine
CAS Registry Number: 933-20-0
IUPAC Name: 4,6-Dichloro-1,3,5-triazin-2-amine
Molecular Weight: 164.98078 [g/mol]
Molecular Formula: C₃H₂Cl₂N₄
XLogP3-AA: 1.5
H-Bond Donor: 1
H-Bond Acceptor: 4
Melting Point:239-242 °C
Index of Refraction: 1.645
Molar Refractivity: 34.55 cm³
Molar Volume: 95.2 cm³
Surface Tension: 82.6 dyne/cm
Density: 1.731 g/cm³
Flash Point: 213.1 °C
Enthalpy of Vaporization: 68.4 kJ/mol
Boiling Point: 428.8 °C at 760 mmHg
Vapour Pressure: 1.47E-07 mmHg at 25 °C
Product Categories: monomer;Agro Products;Agro-Products;Aromatics;Intermediates
Canonical SMILES: C1(=NC(=NC(=N1)Cl)Cl)N
InChI: InChI=1S/C3H2Cl2N4/c4-1-7-2(5)9-3(6)8-1/h(H2,6,7,8,9)
InChIKey: MCLXKFUCPVGZEN-UHFFFAOYSA-N

2-Amino-4,6-dichlorotriazine Uses

2-Amino-4,6-dichlorotriazine (CAS NO.933-20-0) can be used as an aromatic intermediate compound useful for the preparation of substituted melamine, ammelides, and ammelines.

2-Amino-4,6-dichlorotriazine Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intravenous	320mg/kg (320mg/kg)		U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. Vol. NX#03986,

2-Amino-4,6-dichlorotriazine Safety Profile

Safty information about 2-Amino-4,6-dichlorotriazine (CAS NO.933-20-0) is:
Risk Statements: 20/21/22-36/37/38
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 23-36/37/39
S23:Do not breathe vapour.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
HazardClass: IRRITANT

2-Amino-4,6-dichlorotriazine Specification

2-Amino-4,6-dichlorotriazine , its cas register number is 933-20-0. It also can be called 1,3,5-Triazin-2-amine, 4,6-dichloro- ; 1,3,5-Triazin-2-amine, 4,6-dichloro- (9CI) ; s-Triazine, 2-amino-4,6-dichloro- .It is a white crystalline solid.

Product Name

2-Amino-4,6-dichlorotriazine

Synthetic route

2-Amino-4,6-dichlorotriazine Chemical Properties

2-Amino-4,6-dichlorotriazine Uses

2-Amino-4,6-dichlorotriazine Toxicity Data With Reference

2-Amino-4,6-dichlorotriazine Safety Profile

2-Amino-4,6-dichlorotriazine Specification

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