3-Butenenitrile supplier | CasNO.109-75-1

Name
3-Butenenitrile
EINECS 203-701-1
CAS No. 109-75-1
Article Data69
CAS DataBase
Density 0.807 g/cm³
Solubility 微溶于水，可混溶于乙醇、乙醚
Melting Point -87 °C
Formula C₄H₅N
Boiling Point 119 °C at 760 mmHg
Molecular Weight 67.0904
Flash Point 23.9 °C
Transport Information UN 1992 3/PG 3
Appearance Clear colourless to yellow liquid
Safety 26-36/37/39-45
Risk Codes 10-21-23/25-36/38
Molecular Structure
Hazard Symbols T
Synonyms 1-Butene-3-nitrile;1-Propene-3-nitrile;2-Propenyl cyanide;3-Butenonitrile;3-Butenylnitrile;3-Cyano-1-propene;3-Cyanopropene;Allyl cyanide;NSC 2583;Vinylacetonitrile;b-Butenonitrile;
PSA 23.79000
LogP 1.08608

Synthetic route

: 106-95-6
allyl bromide

: 65300-07-4
bis(triphenylphosphine)iminium cyanide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
In dichloromethane at 0℃; for 0.0833333h;	95%

: 143-33-9
sodium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With PEG400 for 5h; Heating;	94%
With hydrogenchloride; water; copper dichloride

: 773837-37-9
sodium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With tetrabutylammomium bromide In toluene at 60℃; for 6h;	93.5%

: 773837-37-9
sodium cyanide

: 107-05-1
3-chloroprop-1-ene

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With tetrabutylammomium bromide In toluene at 60℃; for 6h;	91.3%

: 106-95-6
allyl bromide

: 75-86-5
2-hydroxy-2-methylpropanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With potassium carbonate; dibenzo-18-crown-6 In benzene for 7h; Heating;	85%
With potassium hydroxide

: 7319-38-2
3-butenal

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With aluminum oxide; potassium fluoride; hydroxylamine hydrochloride In N,N-dimethyl-formamide at 100℃; for 10h;	79%

: 5314-34-1
crotonaldoxime

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With ethyl cyanoformate; triethylamine In acetonitrile Ambient temperature;	75%

: N2-<(E)-2-Propenyliden>glycinnitril

A: 109-97-7
pyrrole

B: 1190-76-7
(Z)-2-butenenitrile

C: 4786-20-3
crotononitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 650℃; under 0.2 Torr; Product distribution; Irradiation;	A 74% B 7% C 8% D 0.7%

...Expand

: but-3-enal oxime

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With potassium fluoride on basic alumina In N,N-dimethyl-formamide at 85℃; for 10h;	74%

: 75-21-8
oxirane

: 75-05-8
acetonitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With aluminum oxide at 315℃;

: 110-86-1
pyridine

: 628-20-6
4-Chlorobutyronitrile

: 109-75-1
but-3-enenitrile

: 91-22-5
quinoline

: 628-20-6
4-Chlorobutyronitrile

: 109-75-1
but-3-enenitrile

: 109-74-0
propyl cyanide

A: 4786-20-3
crotononitrile

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With chromium(III) oxide at 580 - 615℃;

: 556-56-9
allyl iodid

: 151-50-8
potassium cyanide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 110℃;

: 4476-02-2
2-hydroxybutanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With phosphorus pentoxide

: 4368-06-3
3-hydroxybutanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With chloroform; phosphorus pentoxide
With phosphorus pentoxide

: 4786-20-3
crotononitrile

: furan-2,3,5(4H)-trione pyridine (1:1)

A: 1190-76-7
(Z)-2-butenenitrile

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 15℃;

...Expand

: 17790-82-8
3-cyanopropanoyl chloride

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With quinoline
With pyridine

: 3952-98-5
sinigrin

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With silver nitrate Zerlegen des Niederschlages mit Schwefelwasserstoff;

: 74-90-8
hydrogen cyanide

: 107-18-6
allyl alcohol

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With ammonium bromide; water; copper(I) bromide
With ammonium chloride; water; copper(l) chloride
With ammonium bromide; water; copper(I) bromide
With ammonium chloride; water; copper(l) chloride

: 151-50-8
potassium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water durch 1 Monat langes Stehen;
With water at 110℃; im Bombenrohr;
With aluminum oxide In chlorobenzene at 50℃; for 8h; Irradiation; ultrasound;	55 % Chromat.

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With copper(l) cyanide

: 151-50-8
potassium cyanide

: 107-05-1
3-chloroprop-1-ene

A: 498-21-5, 636-60-2
2-methylbutanedioic acid

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water

...Expand

: 57-06-7
N-allyl isothiocyanate

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water
With zinc
With copper; paraffin oil

: 187737-37-7
propene

: 506-77-4
cyanogen chloride

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 660℃; beim Leiten durch ein Pyrex-Rohr;

: 106-98-9
1-butylene

: 460-19-5
ethanedinitrile

A: 187737-37-7
propene

B: 74-84-0
ethane

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
Irradiation; 13.56-MHz radio-frequency disharge; Further byproducts given;	A 23 % Chromat. B 26 % Chromat. C 8 % Chromat. D 12 % Chromat.

...Expand

: 4786-20-3
but-2-enenitrile

A: 34557-54-5
methane

B: 74-90-8
hydrogen cyanide

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

E: 75-05-8
acetonitrile

F: 74-86-2
acetylene

Conditions

Conditions	Yield
at 926.9 - 1226.9℃; under 13680 - 15200 Torr; Product distribution; Kinetics; in argon in a single-pulse shock tube;

...Expand

: 590-18-1
(Z)-2-Butene

: 460-19-5
ethanedinitrile

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 109-75-1
but-3-enenitrile

D: 126-98-7
methacrylonitrile

Conditions

Conditions	Yield
Irradiation; 13.56-MHz radio-frequency disharge; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 590-18-1
(Z)-2-Butene

: 460-19-5
ethanedinitrile

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 4403-61-6
2-methyl-2-butene nitrile

D: 74-84-0
ethane

E: 109-75-1
but-3-enenitrile

F: 126-98-7
methacrylonitrile

Conditions

Conditions	Yield
Product distribution; Mechanism; Irradiation; power, flow rates dependence;

...Expand

: 187737-37-7
propene

: 506-78-5
cyanogen iodide

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
under 120 Torr; for 0.166667h; Product distribution; Irradiation; other alkenes;

...Expand

: 106-95-6
allyl bromide

: 65300-07-4
bis(triphenylphosphine)iminium cyanide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
In dichloromethane at 0℃; for 0.0833333h;	95%

: 143-33-9
sodium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With PEG400 for 5h; Heating;	94%
With hydrogenchloride; water; copper dichloride

: 773837-37-9
sodium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With tetrabutylammomium bromide In toluene at 60℃; for 6h;	93.5%

: 773837-37-9
sodium cyanide

: 107-05-1
3-chloroprop-1-ene

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With tetrabutylammomium bromide In toluene at 60℃; for 6h;	91.3%

: 106-95-6
allyl bromide

: 75-86-5
2-hydroxy-2-methylpropanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With potassium carbonate; dibenzo-18-crown-6 In benzene for 7h; Heating;	85%
With potassium hydroxide

: 7319-38-2
3-butenal

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With aluminum oxide; potassium fluoride; hydroxylamine hydrochloride In N,N-dimethyl-formamide at 100℃; for 10h;	79%

: 5314-34-1
crotonaldoxime

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With ethyl cyanoformate; triethylamine In acetonitrile Ambient temperature;	75%

: N2-<(E)-2-Propenyliden>glycinnitril

A: 109-97-7
pyrrole

B: 1190-76-7
(Z)-2-butenenitrile

C: 4786-20-3
crotononitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 650℃; under 0.2 Torr; Product distribution; Irradiation;	A 74% B 7% C 8% D 0.7%

...Expand

: but-3-enal oxime

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With potassium fluoride on basic alumina In N,N-dimethyl-formamide at 85℃; for 10h;	74%

: 75-21-8
oxirane

: 75-05-8
acetonitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With aluminum oxide at 315℃;

: 110-86-1
pyridine

: 628-20-6
4-Chlorobutyronitrile

: 109-75-1
but-3-enenitrile

: 91-22-5
quinoline

: 628-20-6
4-Chlorobutyronitrile

: 109-75-1
but-3-enenitrile

: 109-74-0
propyl cyanide

A: 4786-20-3
crotononitrile

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With chromium(III) oxide at 580 - 615℃;

: 556-56-9
allyl iodid

: 151-50-8
potassium cyanide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 110℃;

: 4476-02-2
2-hydroxybutanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With phosphorus pentoxide

: 4368-06-3
3-hydroxybutanenitrile

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With chloroform; phosphorus pentoxide
With phosphorus pentoxide

: 4786-20-3
crotononitrile

: furan-2,3,5(4H)-trione pyridine (1:1)

A: 1190-76-7
(Z)-2-butenenitrile

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 15℃;

...Expand

: 17790-82-8
3-cyanopropanoyl chloride

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With quinoline
With pyridine

: 3952-98-5
sinigrin

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With silver nitrate Zerlegen des Niederschlages mit Schwefelwasserstoff;

: 74-90-8
hydrogen cyanide

: 107-18-6
allyl alcohol

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With ammonium bromide; water; copper(I) bromide
With ammonium chloride; water; copper(l) chloride
With ammonium bromide; water; copper(I) bromide
With ammonium chloride; water; copper(l) chloride

: 151-50-8
potassium cyanide

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water durch 1 Monat langes Stehen;
With water at 110℃; im Bombenrohr;
With aluminum oxide In chlorobenzene at 50℃; for 8h; Irradiation; ultrasound;	55 % Chromat.

: 106-95-6
allyl bromide

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With copper(l) cyanide

: 151-50-8
potassium cyanide

: 107-05-1
3-chloroprop-1-ene

A: 498-21-5, 636-60-2
2-methylbutanedioic acid

B: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water

...Expand

: 57-06-7
N-allyl isothiocyanate

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
With water
With zinc
With copper; paraffin oil

: 187737-37-7
propene

: 506-77-4
cyanogen chloride

: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
at 660℃; beim Leiten durch ein Pyrex-Rohr;

: 106-98-9
1-butylene

: 460-19-5
ethanedinitrile

A: 187737-37-7
propene

B: 74-84-0
ethane

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
Irradiation; 13.56-MHz radio-frequency disharge; Further byproducts given;	A 23 % Chromat. B 26 % Chromat. C 8 % Chromat. D 12 % Chromat.

...Expand

: 4786-20-3
but-2-enenitrile

A: 34557-54-5
methane

B: 74-90-8
hydrogen cyanide

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

E: 75-05-8
acetonitrile

F: 74-86-2
acetylene

Conditions

Conditions	Yield
at 926.9 - 1226.9℃; under 13680 - 15200 Torr; Product distribution; Kinetics; in argon in a single-pulse shock tube;

...Expand

: 590-18-1
(Z)-2-Butene

: 460-19-5
ethanedinitrile

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 109-75-1
but-3-enenitrile

D: 126-98-7
methacrylonitrile

Conditions

Conditions	Yield
Irradiation; 13.56-MHz radio-frequency disharge; Yield given. Further byproducts given. Yields of byproduct given;

...Expand

: 590-18-1
(Z)-2-Butene

: 460-19-5
ethanedinitrile

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 4403-61-6
2-methyl-2-butene nitrile

D: 74-84-0
ethane

E: 109-75-1
but-3-enenitrile

F: 126-98-7
methacrylonitrile

Conditions

Conditions	Yield
Product distribution; Mechanism; Irradiation; power, flow rates dependence;

...Expand

: 187737-37-7
propene

: 506-78-5
cyanogen iodide

A: 1190-76-7
(Z)-2-butenenitrile

B: 4786-20-3
crotononitrile

C: 107-13-1
acrylonitrile

D: 109-75-1
but-3-enenitrile

Conditions

Conditions	Yield
under 120 Torr; for 0.166667h; Product distribution; Irradiation; other alkenes;

...Expand

3-Butenenitrile Chemical Properties

IUPAC Name: 3-Butenenitrile
The MF of 3-Butenenitrile (109-75-1) is C₄H₅N.

The MW of 3-Butenenitrile (109-75-1) is 67.09.
Synonyms of 3-Butenenitrile (109-75-1): Allyl cyanide ; 3-Butenenitrile ; Vinylacetonitrile ; But-3-enenitrile
Product Categories: Small molecule
Form: clear colourless to yellow liquid
Index of Refraction: 1.401
EINECS: 203-701-1
Density: 0.807 g/ml
Flash Point: 23.9 °C
Boiling Point: 119 °C
Melting Point: -87 °C
Merck: 14,290
BRN: 605352

3-Butenenitrile Uses

3-Butenenitrile (109-75-1) is used in organic Synthesis.

3-Butenenitrile Toxicity Data With Reference

1.	skn-rbt 10 mg/24H open MLD	AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.
2.	orl-rat LD50:115 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 30 (1969),470.
3.	scu-rat LD50:150 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,18.
4.	skn-rbt LD50:1410 mg/kg	AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95.
5.	ihl-gpg LC50:2500 mg/m3/4H	GISAAA Gigiena i Sanitariya. 34 (4)(1969),36.

3-Butenenitrile Consensus Reports

Reported in EPA TSCA Inventory. Cyanide and its compounds are on the Community Right-To-Know List.

3-Butenenitrile Safety Profile

A poison by ingestion and subcutaneous routes. Moderately toxic by inhalation and skin contact. Experimental reproductive effects. A skin irritant. See also NITRILES. Dangerous; emits highly toxic fumes of NO_x and CN⁻ when heated to decomposition or on contact with acids or acid fumes. To fight fire, use alcohol foam, mist.
Safety information of 3-Butenenitrile (109-75-1):
Hazard Codes T
Risk Statements
10 Flammable
21 Harmful in contact with skin
23/25 Toxic by inhalation and if swallowed
36/38 Irritating to eyes and skin
Safety Statements
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
45 In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
RIDADR UN 1992 3/PG 3
WGK Germany 3
RTECS EM8050000
F 10
HazardClass 3
PackingGroup III

Product Name

3-Butenenitrile

Synthetic route

3-Butenenitrile Chemical Properties

3-Butenenitrile Uses

3-Butenenitrile Toxicity Data With Reference

3-Butenenitrile Consensus Reports

3-Butenenitrile Safety Profile

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