9-Bromophenanthrene supplier

Name
9-Bromophenanthrene
EINECS 209-351-6
CAS No. 573-17-1
Article Data39
CAS DataBase
Density 1.479 g/cm³
Solubility chloroform: 50 mg/mL, clear
Melting Point 60-64 °C(lit.)
Formula C₁₄H₉Br
Boiling Point 389.7 °C at 760 mmHg
Molecular Weight 257.129
Flash Point 190.3 °C
Transport Information
Appearance yellow cystalline powder
Safety 22-24/25-36-26
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xi, Xn
Synonyms 9-Phenanthryl bromide;NSC 400708;
PSA 0.00000
LogP 4.75550

Synthetic route

: 85-01-8
phenanthrene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
With aluminum oxide; copper(ll) bromide In chlorobenzene at 80℃; for 2h;	97%
With aluminum oxide; copper(ll) bromide In tetrachloromethane at 80℃; for 2h;	95%
With bromine In chloroform for 17h; Reflux; Inert atmosphere;	93%

: 85-01-8
phenanthrene

A: 573-17-1
9-bromophenanthrene

: 9,10-dibromo-9,10-dihydrophenanthrene

Conditions

Conditions	Yield
With bromine In Hexadecane for 480h; Cooling;	A 32% B 42%
With tri(decyl)(methyl)phosphonium tribromide; bromine In Hexadecane; tetradecafluorohexane for 480h;	A 36% B 7%

: 17024-12-3
9-iodo-phenanthrene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
In tetrahydrofuran at 25℃; for 60h;	18%

: 56-23-5
tetrachloromethane

: 128-08-5
N-Bromosuccinimide

: 85-01-8
phenanthrene

: 573-17-1
9-bromophenanthrene

...Expand

: 17533-18-5
9,10-dibromo-9,10-dihydro-phenanthrene

: 563-63-3
silver(I) acetate

: 64-19-7
acetic acid

: 573-17-1
9-bromophenanthrene

...Expand

: Phenanthrene-9-carbonyl bromide

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
With RhCl(PPh3)3 at 300℃;

phenanthrene dibromide: phenanthrene dibromide

: 573-17-1
9-bromophenanthrene

α-tetrahydrophenanthrene: α-tetrahydrophenanthrene

A: 573-17-1
9-bromophenanthrene

B: 62325-30-8
2,7-dibromophenanthrene

Conditions

Conditions	Yield
With chloroform; bromine

: 56-23-5
tetrachloromethane

: 85-01-8
phenanthrene

bromine (2 or 3 atoms): bromine (2 or 3 atoms)

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
at 0 - 76℃;

...Expand

: 67-66-3
chloroform

: 85-01-8
phenanthrene

bromine (2 or 3 atoms): bromine (2 or 3 atoms)

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
at 0 - 76℃;

...Expand

: 85-01-8
phenanthrene

: 7726-95-6
bromine

A: 573-17-1
9-bromophenanthrene

B: 17533-18-5
9,10-dibromo-9,10-dihydro-phenanthrene

C 1.9-,2.7-,2(?).10-,3.9-or 4.10-dibromo-phenanthrene: 1.9-,2.7-,2(?).10-,3.9-or 4.10-dibromo-phenanthrene

...Expand

: 17533-18-5
9,10-dibromo-9,10-dihydro-phenanthrene

A: 573-17-1
9-bromophenanthrene

B: 10035-10-6, 12258-64-9
hydrogen bromide

Conditions

Conditions	Yield
beim Erhitzen fuer sich;

: 17533-18-5
9,10-dibromo-9,10-dihydro-phenanthrene

: 7732-18-5
water

A: 573-17-1
9-bromophenanthrene

B: 10035-10-6, 12258-64-9
hydrogen bromide

Conditions

Conditions	Yield
im geschlossenen Rohr;

...Expand

: 776-35-2
9,10-dihydrophenanthrene

A: 573-17-1
9-bromophenanthrene

B: 85-01-8
phenanthrene

Conditions

Conditions	Yield
With N-Bromosuccinimide; biphenyl In benzene at 20℃; for 2h; Product distribution; Further Variations:; time dependence; Irradiation;	A 5.5 % Chromat. B 94.5 % Chromat.

: 85-01-8
phenanthrene

A: 573-17-1
9-bromophenanthrene

B: 947-72-8
9-chlorophenanthrene

Conditions

Conditions	Yield
With bromine at 100℃; for 4h; Reflux; Ionic liquid;

: 91-20-3
naphthalene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere 2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 3: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 4 steps
1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
3: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme

: 90-11-9
1-Bromonaphthalene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 2: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 3: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

: 83164-98-1
1,4-dihydro-1,4-epoxyphenanthrene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 2: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

: 71-43-2
benzene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 7 steps 1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 24 h / 80 °C / Inert atmosphere 2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 3: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere 4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere 5: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 6: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 7: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 7 steps
1: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 24 h / 80 °C / Inert atmosphere
2: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
3: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
4: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
5: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
6: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
7: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme

: 108-86-1
bromobenzene

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 6 steps 1: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 2: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere 3: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere 4: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 5: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 6: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 6 steps
1: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
2: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
3: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
4: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
5: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
6: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme

: 573-57-9
1,4-dihydronaphthalene-1,4-epoxide

: 573-17-1
9-bromophenanthrene

Conditions

Conditions	Yield
Multi-step reaction with 5 steps 1: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere 2: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere 3: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere 4: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere 5: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere View Scheme

Yield

Multi-step reaction with 5 steps
1: ammonium perrhenate; triphenyl phosphite / toluene / 18 h / 80 °C / Inert atmosphere
2: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
3: sodium amide; potassium tert-butylate / tetrahydrofuran / 15 h / 50 °C / Inert atmosphere
4: perrhenic acid anhydride; triphenyl phosphite / toluene / 80 °C / Inert atmosphere
5: N-Bromosuccinimide; gold(III) chloride / 1,2-dichloro-ethane / 15 h / 80 °C / Inert atmosphere
View Scheme

: 494-19-9
9,10-dihydrodibenzazepine

: 573-17-1
9-bromophenanthrene

: N-(9-phenanthryl)iminodibenzyl

Conditions

Conditions	Yield
With C30H43O2PC13H12N(1-)CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;	100%

: 573-17-1
9-bromophenanthrene

: 100379-00-8
2,6-dimethylbenzene boronic acid

: 9-(2,6-dimethyl-phenyl)-phenanthrene

Conditions

Conditions	Yield
With potassium phosphate; N,N-diisopropyl 2-dicyclohexylphosphino-4-phenylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In N,N-dimethyl-formamide at 110℃; for 9h; Suzuki cross-coupling;	99.5%

: 573-17-1
9-bromophenanthrene

: 85-01-8
phenanthrene

Conditions

Conditions	Yield
With potassium fluoride In tetrahydrofuran; water at 80℃; for 4h; Catalytic behavior; Reagent/catalyst; Solvent; Temperature; Schlenk technique; Sealed tube; Inert atmosphere;	99%
With 4-methyl-morpholine; tetrahydroxydiboron; 5%-palladium/activated carbon In 1,2-dichloro-ethane at 50℃; for 1.5h; Reagent/catalyst; Solvent; Temperature;	99%
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;	99%

: 573-17-1
9-bromophenanthrene

: 4819-99-2
9-deuteriophenanthrene

Conditions

Conditions	Yield
With 4-methyl-morpholine; tetrahydroxydiborane(4); 5%-palladium/activated carbon; DMAP-d6 In 1,2-dichloro-ethane at 50℃; for 3.5h; Solvent; Reagent/catalyst;	99%
With potassium phosphate; d(4)-methanol; palladium diacetate; catacxium A In toluene at 80℃; for 16h;	94%
With 2,2'-azobis(isobutyronitrile); C11H24(2)HN2P In (2)H8-toluene at 90℃; for 5h; Mechanism;	90%
With n-butyllithium; water-d2 1.) ehter, hexane, 2.) ether, hexane, from 0 to 5 deg C, 1 h; Yield given. Multistep reaction;
With deuteromethanol; tetraethylammonium perchlorate; triethylamine In dimethyl sulfoxide at 20℃; for 32h; Reagent/catalyst; Electrolysis; Green chemistry;	96 %Spectr.

: 573-17-1
9-bromophenanthrene

: 77-78-1
dimethyl sulfate

: 883-20-5
9-methylphenanthrene

Conditions

Conditions	Yield
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether at 20℃; for 1h; Stage #2: dimethyl sulfate In diethyl ether for 5h; Heating; Further stages.;	99%
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether; hexane at 20℃; Inert atmosphere; Cooling with ice; Stage #2: dimethyl sulfate In diethyl ether; hexane at 0℃; Inert atmosphere; Reflux;	99%
Stage #1: 9-bromophenanthrene With n-butyllithium In diethyl ether; hexane at 0 - 23℃; for 0.333333h; Inert atmosphere; Stage #2: dimethyl sulfate In diethyl ether; hexane at 0℃; for 5.5h; Reflux; Inert atmosphere;	72%
With n-butyllithium 1)room temp., 2h,ether, hexane 2)reflux, 8h; Yield given. Multistep reaction;

: 573-17-1
9-bromophenanthrene

: 98-80-6
phenylboronic acid

: 844-20-2
9-phenylphenanthrene

Conditions

Conditions	Yield
With potassium fluoride; o-(dicyclohexylphosphino)diisopropylbenzamide; tris(dibenzylideneacetone)dipalladium (0) In N,N-dimethyl-formamide at 60℃; for 4h; Suzuki cross-coupling;	99%
With 1,2,4,5-[3-(2,6-(iPr)2C6H3)imidazol-1-yl-CH2]4-Ph(4+)*4Br(-); potassium carbonate; palladium diacetate In ethanol at 20℃; for 22h; Suzuki cross-coupling;	97%
Stage #1: 9-bromophenanthrene With [Pd(2-phenylpyridine)(Bmim)(saccharinate)] In toluene at 80℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: phenylboronic acid With sodium carbonate In water at 80℃; for 12h; Catalytic behavior; Temperature; Reagent/catalyst; Concentration; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;	96%

: 573-17-1
9-bromophenanthrene

: 552-16-9
ortho-nitrobenzoic acid

: 911217-05-5
1-(9-phenanthryl)-2-nitrobenzene

Conditions

Conditions	Yield
Stage #1: ortho-nitrobenzoic acid With potassium carbonate In various solvent(s) at 120℃; for 0.5h; Stage #2: 9-bromophenanthrene With 1,10-Phenanthroline; copper(l) iodide In various solvent(s) at 160℃; for 24h; Further stages.;	99%
With potassium fluoride; copper(II) carbonate; bis(acetylacetonato)palladium(II); isopropyldiphenylphosphine In 1-methyl-pyrrolidin-2-one at 120℃; for 24h; Product distribution / selectivity; Molecular sieve;	86 %Chromat.
copper(l) iodide; Phenanthroline; bis(acetylacetonato)palladium(II) In 1-methyl-pyrrolidin-2-one at 160℃; for 24h; Product distribution / selectivity; Molecular sieve;	99 %Chromat.

: 573-17-1
9-bromophenanthrene

: 13922-41-3
1-Naphthylboronic acid

: 119925-45-0
9-(naphthalen-1-yl) phenanthrene

Conditions

Conditions	Yield
With potassium phosphate; 2C32H41O4PPd(2+)2Cl(1-) In toluene at 110℃; for 16h; Suzuki-Miyaura Coupling; Inert atmosphere;	99%
With [Pd{C6H2(CH2CH2NH2)-(OMe)2,3,4} (μ-Br)]2; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 0.333333h; Suzuki-Miyaura coupling; Microwave irradiation;	80%
With dichloro[1,1'-bis(di-t-butylphosphino)ferrocene]palladium(II); triethylamine In water at 20℃; for 24h; Suzuki-Miyaura reaction; Inert atmosphere; Micellar solution;	78%

: lithium trimethoxy(1,2,2-trifluorovinyl)borate

: 573-17-1
9-bromophenanthrene

: 9-(1,2,2-trifluorovinyl)phenanthrene

Conditions

Conditions	Yield
With potassium phosphate; tris-(dibenzylideneacetone)dipalladium(0); XPhos In tetrahydrofuran at 20 - 60℃; for 15.25h; Suzuki coupling; Inert atmosphere;	99%

: 573-17-1
9-bromophenanthrene

: 361543-99-9
4-methoxy-2,6-dimethylphenylboronic acid

: 1392512-39-8
C23H20O

Conditions

Conditions	Yield
With Pd-PEPPSI-IPrAn; potassium tert-butylate In 1,4-dioxane at 80℃; for 24h; Suzuki coupling; Inert atmosphere;	99%

: 573-17-1
9-bromophenanthrene

: 56741-04-9
S-phenyl tert-butylcarbamothioate

A: 1579273-93-0
N-(tert-butyl)phenanthrene-9-carboxamide

B: 882-33-7
diphenyldisulfane

Conditions

Conditions	Yield
Stage #1: 9-bromophenanthrene With iodine; magnesium In 2-methyltetrahydrofuran at 60℃; for 1h; Schlenk technique; Inert atmosphere; Stage #2: S-phenyl tert-butylcarbamothioate In 2-methyltetrahydrofuran at 0 - 20℃; for 2h; Inert atmosphere; Schlenk technique; Stage #3: With ammonium hydroxide; oxygen In 2-methyltetrahydrofuran; water under 760.051 Torr; for 18h;	A 76% B 99%

...Expand

: 573-17-1
9-bromophenanthrene

: C28H37AgF2N2S

: (difluoromethyl)(phenanthren-9-yl)thioether

Conditions

Conditions	Yield
With dicyclohexyl-(2′,4′,6′-triisopropyl-3,6-dimethoxy-[1,1′-biphenyl]-2-yl)phosphine; [(2-di-cyclohexylphosphino-3,6-dimethoxy-2’,4’,6’-triisopropyl-1,1‘-biphenyl)-2-(2‘-amino-1,1’-biphenyl)]palladium(II) methanesulfonate In tetrahydrofuran at 50℃; for 2h; Inert atmosphere; Schlenk technique;	99%

: 534-22-5
2-methylfuran

: 573-17-1
9-bromophenanthrene

: 2-methyl-5-(phenanthren-9-yl)furan

Conditions

Conditions	Yield
With [Pd(IPr*IMe)An(3-Cl-pyridinyl)Cl2]; potassium carbonate; acetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;	99%

: 3777-69-3
2-pentylfuran

: 573-17-1
9-bromophenanthrene

: 2-pentyl-5-(phenanthren-9-yl)furan

Conditions

Conditions	Yield
With [Pd(IPr*IMe)An(3-Cl-pyridinyl)Cl2]; potassium carbonate; Trimethylacetic acid In N,N-dimethyl acetamide at 130℃; for 12h; regioselective reaction;	99%

: 573-17-1
9-bromophenanthrene

: 148839-33-2
(5-chloro-2-methylphenyl)boronic acid

: C21H15Cl

Conditions

Conditions	Yield
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate In ethanol; water; toluene at 90℃; for 4.5h; Inert atmosphere;	98.6%

: 67-56-1
methanol

: 573-17-1
9-bromophenanthrene

: 5085-74-5
9-methoxyphenanthrene

Conditions

Conditions	Yield
Stage #1: methanol With pyridine; copper(l) iodide; sodium at 80℃; Inert atmosphere; Stage #2: 9-bromophenanthrene With pyridine for 42.1667h; Reflux; Inert atmosphere;	98%
Stage #1: methanol With sodium Stage #2: 9-bromophenanthrene With pyridine; copper(l) iodide at 80℃; for 48h;	89%
With pyridine; copper(l) iodide; sodium for 18h; Heating;	86%

: 931-49-7
1-ethenylcyclohexene

: 573-17-1
9-bromophenanthrene

: 1052216-08-6
9-(cyclohex-1-enylethynyl)phenanthrene

Conditions

Conditions	Yield
With dichloro bis(acetonitrile) palladium(II); triethylamine; XPhos In water at 20℃; Sonogashira coupling; Inert atmosphere; Micellar solution;	98%

: 58-08-2
3,7-dihydro-1,3,7-trimethyl-1H-purine-2,6-dione

: 573-17-1
9-bromophenanthrene

: 99765-06-7
3,7-Dihydro-1,3,7-trimethyl-8-(9-phenanthryl)-1H-purin-2,6-dion

Conditions

Conditions	Yield
With potassium phosphate; palladium diacetate; Trimethylacetic acid In N,N-dimethyl-formamide at 20 - 120℃; for 7.16667h; Inert atmosphere;	98%
With potassium phosphate; copper(l) iodide; 1,10-Phenanthroline In 5,5-dimethyl-1,3-cyclohexadiene; N,N-dimethyl-formamide at 20 - 140℃; for 36.1667h; Inert atmosphere; regioselective reaction;	95%

: 573-17-1
9-bromophenanthrene

: 172975-69-8
3,5-dimethylphenyl boronic acid

: 9-(3,5-dimethylphenyl)phenanthrene

Conditions

Conditions	Yield
Stage #1: 9-bromophenanthrene With [Pd(2-phenylpyridine)(Bmim)(saccharinate)] In toluene at 80℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Stage #2: 3,5-dimethylphenyl boronic acid With sodium carbonate In water at 80℃; for 12h; Suzuki-Miyaura Coupling; Inert atmosphere; Schlenk technique;	98%

: 573-17-1
9-bromophenanthrene

: C68H72B4N4O8Zn

: C100H60N4Zn

Conditions

Conditions	Yield
With pyridine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; sodium t-butanolate In toluene at 130℃; under 2250.23 Torr; for 1h; Suzuki-Miyaura Coupling; Microwave irradiation; Inert atmosphere; Sealed tube;	98%

: 256-96-2
dibenzoazepine

: 573-17-1
9-bromophenanthrene

: N-(9-phenanthryl)iminostilbene

Conditions

Conditions	Yield
With C30H43O2PC13H12N(1-)CH3O3S(1-)*Pd(2+); lithium hexamethyldisilazane In 1,4-dioxane at 100℃; for 16h; Inert atmosphere;	98%

9-Bromophenanthrene Chemical Properties

Product Name: 9-Bromophenanthrene (CAS NO.573-17-1)

IUPAC Name: 9-bromophenanthrene
Molecular Formula: C₁₄H₉Br
Molecular Weight: 257.125260 g/mol
Appearance: Very slightly yellow solid
Density: 1.479g/cm³
Melting Point: 60-64 °C(lit.)
Boiling Point: 180-190 °C 2 mm Hg(lit.)
Flash Point: 110 °C
Solubility:chloroform: 50 mg/mL, clear
BRN: 1869927
EINECS: 209-351-6
Index of Refraction: 1.733
Molar Refractivity: 69.62 cm³
Molar Volume: 173.8 cm³
Categories: Aromatic Compounds; blocks; Bromides; Miscellaneous; Aryl; C13 to C37+; Halogenated Hydrocarbons

9-Bromophenanthrene Uses

9-Bromophenanthrene (CAS NO.573-17-1) is used in organic synthesis.

9-Bromophenanthrene Safety Profile

Safety Information of 9-Bromophenanthrene (CAS NO.573-17-1):
Hazard Codes:Xi Irritant ,Xn Harmful
Risk Statements:20/21/22-36/37/38
20/21/22:Harmful by inhalation, in contact with skin and if swallowed
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:22-24/25-36-26
22:Do not breathe dust
24/25:Avoid contact with skin and eyes
36:Wear suitable protective clothing
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
WGK Germany:3
RTECS:SF7197000
F:8
Hazard Note:Irritant
HS Code:29036990

9-Bromophenanthrene Specification

9-Bromophenanthrene , its CAS NO. is 573-17-1, the synonyms are 9-Phenathryl bromide ; Phenanthrene, 9-bromo- .

Product Name

9-Bromophenanthrene

Synthetic route

9-Bromophenanthrene Chemical Properties

9-Bromophenanthrene Uses

9-Bromophenanthrene Safety Profile

9-Bromophenanthrene Specification

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