Aluminium tri-sec-butoxide supplier

Name
Aluminium tri-sec-butoxide
EINECS 218-871-2
CAS No. 2269-22-9
Article Data8
CAS DataBase
Density 1.237 g/mL at 25 °C
Solubility Decomposes in water
Melting Point
Formula C₁₂H₂₇AlO₃
Boiling Point 40 °C
Molecular Weight 246.326
Flash Point 82 °F
Transport Information UN 1992
Appearance viscous colourless or pale yellow liquid
Safety 45-43-36/37/39-26-16
Risk Codes 40-21/22-10
Molecular Structure
Hazard Symbols Xi; Xn
Synonyms 2-Butanol,aluminum salt (9CI);Aluminum sec-butoxide (6CI,7CI);sec-Butyl alcohol,aluminum salt (8CI);ASB (salt);ASBD;Aluminum 2-butoxide;Aluminumsec-butanolate;Aluminum sec-butylate;Aluminum tri(sec-butylate);Aluminumtri-sec-butoxide;Aluminum tris(sec-butoxide);Tri-sec-butoxyaluminum;Tris(2-butanolato)aluminum;Tris(2-butoxy)aluminum;Tris(sec-butoxy)aluminum;trisec-butoxyalumane;Aluminum tri-sec-butoxide;
PSA 27.69000
LogP 3.79740

Synthetic route

: 589-40-2
sec-butyl formate

: 555-31-7
aluminum isopropoxide

A: 2269-22-9
aluminum tri-sec-butoxide

B isopropyl formate: isopropyl formate

...Expand

: 78-92-2, 15892-23-6
iso-butanol

amalgamated aluminium: amalgamated aluminium

: 2269-22-9
aluminum tri-sec-butoxide

: 555-31-7
aluminum isopropoxide

sec-butyl formate: sec-butyl formate

: 2269-22-9
aluminum tri-sec-butoxide

Conditions

Conditions	Yield
unter Abdestillieren von Isopropylformiat;

: 7429-90-5
aluminium

: 78-92-2, 15892-23-6
iso-butanol

: 2269-22-9
aluminum tri-sec-butoxide

Conditions

Conditions	Yield
In neat (no solvent) treatment of the metal with alcohol in the presence of HgCl2 or I2 as catalysts; identified by elem. anal. for Al and by comparison of the constants withpublished data;

: 64-18-6
formic acid

: 7732-18-5
water

: 2269-22-9
aluminum tri-sec-butoxide

: aluminium triformate trihydrate

Conditions

Conditions	Yield
In water addn. of water to Al(CH3CHOC2H5)3 (air), formation of hydroxide, addn. of formic acid and water, boiling and evapn., keeping at 60°C till complete evapn., drying (2 d over drierite); TGA, DTA;	100%

...Expand

: 2269-22-9
aluminum tri-sec-butoxide

: 123-54-6
acetylacetone

: aluminium(III) acetylacetonate

Conditions

Conditions	Yield
In ethanol at 0℃;	97%

: 1337458-59-9
1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-ol

: 2269-22-9
aluminum tri-sec-butoxide

: mer-[Al(1-(4,4-dimethyl-4,5-dihydrooxazol-2-yl)naphthalen-2-olate)3]

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;	95%

: 201230-82-2
carbon monoxide

: 2269-22-9
aluminum tri-sec-butoxide

: 939-26-4
2-bromomethylnaphthyl bromide

: 91759-49-8
Naphthalen-2-yl-acetic acid sec-butyl ester

Conditions

Conditions	Yield
1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h;	91%

...Expand

: 123-92-2
3-methyl-1-butyl acetate

: 2269-22-9
aluminum tri-sec-butoxide

: 25016-92-6
aluminium triisopentylate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: sec-Bu-OAc; N2 atmosphere; exchange reaction (111°C); distn. of butyl ester;	90%

: 2269-22-9
aluminum tri-sec-butoxide

: 7439-95-4
magnesium

: 78-92-2, 15892-23-6
iso-butanol

: Mg{Al(OCH(CH3)CH2CH3)4}2

Conditions

Conditions	Yield
With Hg2Cl2 In butan-1-ol byproducts: H2; under N2; addn. of Mg turnings and Hg2Cl2 to stirred soln. of 2 equiv. of Al(O-sec-Bu)3 in sec-butanol, refluxed (7 d); evapn. (vac.), fractional distn. at 140-165°C/0.03 Torr, elem. anal.;	86%

...Expand

: 7732-18-5
water

: 2269-22-9
aluminum tri-sec-butoxide

: alumina

Conditions

Conditions	Yield
Stage #1: water; aluminum tri-sec-butoxide With ammonium hydroxide In ethanol; iso-butanol at 70℃; for 25h; Stage #2: at 400℃; for 10h; Calcination;	82%

: 1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane

: 2269-22-9
aluminum tri-sec-butoxide

: [Al2(1,2-bis[2-(4,4,4-trifluoro-1-hydroxy-3-oxobut-1-enyl)phenoxy]ethane)3]

Conditions

Conditions	Yield
In hexane; chloroform for 72h;	75%

: 2269-22-9
aluminum tri-sec-butoxide

: 74-88-4
methyl iodide

: 6795-87-5
2-butyl methyl ether

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 59 - 70℃; for 48h;	70%

: 201230-82-2
carbon monoxide

: 100-39-0
benzyl bromide

: 2269-22-9
aluminum tri-sec-butoxide

: 5436-58-8
phenyl-acetic acid sec-butyl ester

Conditions

Conditions	Yield
1,5-hexadienerhodium(I)-chloride dimer In n-heptane at 75℃; for 14h;	68%

...Expand

: 1104058-34-5
2-[(S)-4-isopropyl-4,5-dihydro-oxazol-2-yl]-6-methylphenol

: 2269-22-9
aluminum tri-sec-butoxide

: mer-[Al((S)-2-(4-isopropyl-4,5-dihydrooxazol-2-yl)-6-methylphenolate)3]

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;	40%

: 546-68-9
titanium(IV) isopropylate

: calcium(II) nitrate tetrahydrate

: 876504-21-1
hafnium tetra(n-butoxide)

: gadolinium(III) nitrate hexahydrate

: 2269-22-9
aluminum tri-sec-butoxide

A: Al1.96Ti1.02O5

B: Ca0.25Gd0.77Hf0.06Al0.65Ti2.26O7

C: (Ca0.12Hf0.06Al0.09Gd1.73)Ti2.02O7

Conditions

Conditions	Yield
In ethanol; water Ti and Hf alkoxides in EtOH and Ca and Gd nitrates (Ca:Gd:Hf:Al:Ti=0.1:1.5:0.1:0.3:1.85) in H2O mixed for 15 min; dried; calcined at 700°C for 1 h; ball milled for 18 h in water; pelletized at 30 MPa; sinteredin air (1500°C, 96 h); detd. by energy dispersive X-ray spectrometry and X-ray diffraction;	A n/a B 2% C n/a

...Expand

: 546-68-9
titanium(IV) isopropylate

: calcium(II) nitrate tetrahydrate

: 876504-21-1
hafnium tetra(n-butoxide)

: gadolinium(III) nitrate hexahydrate

: 2269-22-9
aluminum tri-sec-butoxide

A: Al2.02Gd0.01Ti0.97O5

B: (Ca0.19Hf0.16Al0.09Gd1.59)Ti2.00O7

C: Ca0.16Gd0.87Hf0.04Al0.93Ti4.00O11

Conditions

Conditions	Yield
In ethanol; water Ti and Hf alkoxides in EtOH and Ca and Gd nitrates (Ca:Gd:Hf:Al:Ti=0.2:1.4:0.2:0.2:1.9) in H2O mixed for 15 min; dried; calcined at 700°Cfor 1 h; ball milled for 18 h in water; pelletized at 30 MPa; sintered in air (1500°C, 96 h); detd. by energy dispersive X-ray spectrometry and X-ray diffraction;	A n/a B n/a C 2%

...Expand

: 143-07-7
lauric acid

: 2269-22-9
aluminum tri-sec-butoxide

: lauric acid ; aluminium-hydroxide-dil aurate

: 141-79-7
4-methyl-pent-3-en-2-one

: 2269-22-9
aluminum tri-sec-butoxide

A: 4325-82-0
4-methyl pent-3-en-2-ol

B: 926-56-7
4-methyl-1,3-pentadiene

C: 1118-58-7
1,3-Dimethyl-1,3-butadien

...Expand

: 486-25-9
9-fluorenone

: 2269-22-9
aluminum tri-sec-butoxide

: 1689-64-1
9-Fluorenol

Conditions

Conditions	Yield
at 105 - 110℃;

: 112-80-1
cis-Octadecenoic acid

: 2269-22-9
aluminum tri-sec-butoxide

: oleic acid ; aluminium dioleate

Conditions

Conditions	Yield
With 1,4-dioxane
With butan-1-ol
With benzene

: 99-61-6
3-nitro-benzaldehyde

: 2269-22-9
aluminum tri-sec-butoxide

: 78-92-2, 15892-23-6
iso-butanol

: 619-25-0
3-Nitrobenzyl alcohol

...Expand

: 555-16-8
4-nitrobenzaldehdye

: 2269-22-9
aluminum tri-sec-butoxide

: 619-73-8
4-nitrobenzyl chloride

Conditions

Conditions	Yield
With iso-butanol

: 555-16-8
4-nitrobenzaldehdye

: 2269-22-9
aluminum tri-sec-butoxide

: 78-92-2, 15892-23-6
iso-butanol

: 619-73-8
4-nitrobenzyl chloride

...Expand

: 2269-22-9
aluminum tri-sec-butoxide

: 1896-62-4
(E)-benzalacetone

: 78-92-2, 15892-23-6
iso-butanol

: 36004-04-3
ethyl (E)-1-phenylbut-1-en-3-ol

...Expand

: 2269-22-9
aluminum tri-sec-butoxide

: 552-89-6
2-nitro-benzaldehyde

: 612-25-9
2-Nitrobenzyl alcohol

Conditions

Conditions	Yield
With iso-butanol

: 2269-22-9
aluminum tri-sec-butoxide

: 552-89-6
2-nitro-benzaldehyde

: 78-92-2, 15892-23-6
iso-butanol

: 612-25-9
2-Nitrobenzyl alcohol

...Expand

: 486-25-9
9-fluorenone

: 2269-22-9
aluminum tri-sec-butoxide

: 78-92-2, 15892-23-6
iso-butanol

: 1689-64-1
9-Fluorenol

...Expand

: 10458-14-7, 14073-97-3
(2R,5S)-menthone

: 2269-22-9
aluminum tri-sec-butoxide

: 78-92-2, 15892-23-6
iso-butanol

A: 2216-51-5
(-)-menthol

B: 2216-52-6
Neomenthol

...Expand

: 2269-22-9
aluminum tri-sec-butoxide

: 86-84-0
1-Naphthyl isocyanate

: 6229-90-9
N-<1>Naphthylcarbamoyl-<1>naphthylcarbamidsaeure-sec-butylester

: 161111-61-1
2,3-epoxy-2-methylpropionaldehyde

: 2269-22-9
aluminum tri-sec-butoxide

: 1-methylpropyl-2,3-epoxy-2-methylpropanoate

Conditions

Conditions	Yield
In benzene at 20℃; for 120h;	2.9 g

: 161111-61-1
2,3-epoxy-2-methylpropionaldehyde

: 2269-22-9
aluminum tri-sec-butoxide

: α-methyl-α-(1-sec-butoxy-2-methyl-2,3-epoxypropyloxy)-β-propiolactone

Conditions

Conditions	Yield
In benzene at 20℃; for 120h;

: 123-91-1
1,4-dioxane

: 112-80-1
cis-Octadecenoic acid

: 2269-22-9
aluminum tri-sec-butoxide

aluminium oleate/s: aluminium oleate/s

...Expand

: 112-80-1
cis-Octadecenoic acid

: 2269-22-9
aluminum tri-sec-butoxide

: 78-92-2, 15892-23-6
iso-butanol

aluminium oleate/s: aluminium oleate/s

...Expand

Aluminium tri-sec-butoxide Specification

The Aluminium tri-sec-butoxide, with the CAS registry number 2269-22-9 and EINECS registry number 218-871-2, has the systematic name of trisec-butoxyalumane. And the molecular formula of this chemical is C₁₂H₂₇AlO₃. It is a kind of viscous colourless or pale yellow liquid, and belongs to the following product categories: Organic-metal salt; Al (Alminum) Compounds; Classes of Metal Compounds; Typical Metal Compounds; Aluminum; Micro/Nanoelectronics; Solution Deposition Precursors. What's more, it is used as active catalyst, reducer of aldehydes and ketones, gelling agent of paint and ink, and water repellent substance of woof.

The physical properties of Aluminium tri-sec-butoxide are as following: (1)#H bond acceptors: 3; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 9; (4)Polar Surface Area: 27.69 Å².

You should be cautious while dealing with this chemical. It is a kind of flammable chemical which is harmful in contact with skin and if swallowed. What's more, there's limited evidence of a carcinogenic effect. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice; Keep away from sources of ignition - No smoking; In case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: CCC(C)O[Al](OC(C)CC)OC(C)CC
(2)InChI: InChI=1/3C4H9O.Al/c3*1-3-4(2)5;/h3*4H,3H2,1-2H3;/q3*-1;+3/rC12H27AlO3/c1-7-10(4)14-13(15-11(5)8-2)16-12(6)9-3/h10-12H,7-9H2,1-6H3
(3)InChIKey: WOZZOSDBXABUFO-DYGDCWSTAN

Product Name

Aluminium tri-sec-butoxide

Synthetic route

Aluminium tri-sec-butoxide Specification

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