Benzaldehyde,2,3,4,5,6-pentafluoro- supplier

Name
PENTAFLUOROBENZALDEHYDE
EINECS 211-502-6
CAS No. 653-37-2
Article Data34
CAS DataBase
Density 1.605 g/cm³
Solubility Sparingly Soluble in water (0.027 g/L at 25°C).
Melting Point 24-28 °C(lit.)
Formula C₇HF₅O
Boiling Point 166 °C at 760 mmHg
Molecular Weight 196.076
Flash Point 77.8 °C
Transport Information UN 2810 6.1/PG 3
Appearance Clear yellowish liquid after melting
Safety 26-37/39
Risk Codes 20/22-36/37/38
Molecular Structure
Hazard Symbols Xn,F,Xi
Synonyms Benzaldehyde,pentafluoro- (6CI,7CI,8CI,9CI);2,3,4,5,6-Pentafluorobenzaldehyde;Formylpentafluorobenzene;Pentafluorobenzaldehyde;Perfluorobenzaldehyde;
PSA 17.07000
LogP 2.19460

Synthetic route

pentafluorophenylmagnesium chloride: pentafluorophenylmagnesium chloride

: 93-61-8
N-methyl-N-phenylformamide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction under reflux, 4 hours;;	62.4%
In diethyl ether reaction under reflux, 4 hours;;	62.4%

: 773-82-0
Pentafluorobenzonitrile

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
With formic acid; nickel-aluminum alloy In water at 65℃; for 1h; Inert atmosphere; Large scale; Green chemistry;	61.5%
With hydrogenchloride; tin(ll) chloride

: 1076-44-4
pentafluorophenyl lithium

: 93-61-8
N-methyl-N-phenylformamide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction at -78°C, 2 hours;;	61%
In diethyl ether reaction at -78°C, 2 hours;;	61%

: 344-07-0
1-chloro-2,3,4,5,6-pentafluorobenzene

: 7440-66-6
zinc

A: 1094167-88-0
N,N-dimethyl-1,1-bis(perfluorophenyl)methanamine

B: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
Stage #1: 1-chloro-2,3,4,5,6-pentafluorobenzene; zinc In N,N-dimethyl-formamide Stage #2: With copper(l) iodide; Vilsmeier reagent In N,N-dimethyl-formamide at -10℃; for 4.5h; Enzymatic reaction; Stage #3: With water In N,N-dimethyl-formamide	A 9.5 %Spectr. B 57%

...Expand

: 440-60-8
(2,3,4,5,6-pentafluorophenyl)methanol

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene In dichloromethane at 35℃; for 0.075h; Flow reactor; chemoselective reaction;	51%
With tetrabutylammonium perchlorate; bromide In dichloromethane Ambient temperature; indirect electrooxidation;	67 % Chromat.
With oxygen In toluene at 100℃; for 0.283333h; Green chemistry;

: 344-04-7
bromopentafluorobenzene

: 109-94-4
formic acid ethyl ester

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether Stage #2: formic acid ethyl ester	38%
With n-butyllithium

: 97580-75-1
bis(α-pentafluoroanilino-2,3,4,5,6-pentafluorobenzyl)peroxide

A: 771-60-8
2,3,4,5,6-pentafluoroaniline

B: 653-37-2
perfluorobenzaldehyde

C: 853-75-8
N-pentafluorophenyl-pentafluorophenylaldimine

D: 19364-92-2
2,3,4,5,6-pentafluoro-N-(pentafluorophenyl)benzamide

Conditions

Conditions	Yield
In hexane at 20℃; for 6h; Product distribution; Irradiation;	A 23% B 27% C 32% D 7%

...Expand

: 2341-86-8
N-((perfluorophenyl)methylene)aniline

A: 653-37-2
perfluorobenzaldehyde

B: 58627-19-3
2,3,4,5,6-pentafluoro-N-phenylbenzamide

Conditions

Conditions	Yield
With trifluoroacetyl peroxide In dichloromethane at 20℃; for 1h; Title compound not separated from byproducts;

: 1765-40-8
(bromomethyl)pentafluorobenzene

A: 653-37-2
perfluorobenzaldehyde

B: 440-60-8
(2,3,4,5,6-pentafluorophenyl)methanol

Conditions

Conditions	Yield
With N,N,N',N'-tetramethyl-para-phenylenediamine; oxygen In acetonitrile for 15h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 344-04-7
bromopentafluorobenzene

: 93-61-8
N-methyl-N-phenylformamide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
(i) Mg, (ii) /BRN= 636496/; Multistep reaction;

: 827-15-6
1,2,3,4,5-pentafluoro-6-iodobenzene

: 109-94-4
formic acid ethyl ester

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
(i) Mg, (ii) /BRN= 906769/; Multistep reaction;

: 66-71-7
1,10-Phenanthroline

: C7HF5O(1-)

A: 653-37-2
perfluorobenzaldehyde

B: 66-71-7
C12H9N2

Conditions

Conditions	Yield
In water Rate constant; Equilibrium constant; Irradiation; HClO4, H2KPO4, Na2HPO4, Na2B2O7, NaOH, t-BuOH;

...Expand

pentafluoro-phenyl magnesium bromide: pentafluoro-phenyl magnesium bromide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
With diethyl ether; orthoformic acid triethyl ester anschliessend mit wss.H2SO4;
With tetrahydrofuran; 1,6-dimethyl-3-p-tolyl-3,4-dihydro-quinazolinium; iodide anschliessend mit wss.HCl;

: 110-05-4
di-tert-butyl peroxide

: O-[3-(cyclohex-2-enyloxy)propionyl] pentafluorobenzaldoxime

A: 653-37-2
perfluorobenzaldehyde

B: 773-82-0
Pentafluorobenzonitrile

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With di-tert-butyl peroxide for 24h; Product distribution; Irradiation;

...Expand

: 440-60-8
(2,3,4,5,6-pentafluorophenyl)methanol

A: 653-37-2
perfluorobenzaldehyde

B: 602-94-8
Pentafluorobenzoic acid

Conditions

Conditions	Yield
With ammonium cerium(IV) nitrate; 1-ethyl-3-methylimidazolium triflate at 125℃; for 8h;
With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; laccase from Trametes versicolor; oxygen In water at 20℃; for 120h; Enzymatic reaction;	A 13 %Spectr. B 67 %Spectr.

: 652-31-3
2,3,4,5,6-pentafluorobenzamide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: P2O5 / 200 °C 2: SnCl2, HCl View Scheme

: 22006-44-6
difluoromethylpentafluorobenzene

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
Stage #1: difluoromethylpentafluorobenzene With hydrogen fluoride; antimony pentafluoride at 20℃; for 24h; Stage #2: With hydrogenchloride Further stages.;

: 64-18-6
formic acid

: 773-82-0
Pentafluorobenzonitrile

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
0.5 h heating to 75-80°C with moist Raney nickel;
0.5 h heating to 75-80°C with moist Raney nickel;

: 17318-00-2
(pentafluoro phenyl) magnesiumbromide

: 109-94-4
formic acid ethyl ester

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction at 0°C, 1 hour;;
In diethyl ether reaction at 0°C, 1 hour;;

: 1076-44-4
pentafluorophenyl lithium

: 109-94-4
formic acid ethyl ester

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction at -78°C, 5 minutes;;
In diethyl ether reaction at -78°C, 5 minutes;;

: C6H5NCHONHCH3

: 879-05-0
2,3,4,5,6-pentafluorophenylmagnesium bromide

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction at 20 - 25°C (1.6 hours), then 4h reflux;
In diethyl ether reaction at 20 - 25°C (1.6 hours), then 4h reflux;

: 879-05-0
2,3,4,5,6-pentafluorophenylmagnesium bromide

: 122-51-0
orthoformic acid triethyl ester

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
In diethyl ether reaction under reflux, 10 hours;;
In diethyl ether reaction under reflux, 10 hours;;

: 1582-24-7
pentafluorophenylboronic acid

: 298-12-4
Glyoxilic acid

: 653-37-2
perfluorobenzaldehyde

Conditions

Conditions	Yield
With 1,2,3,4-tetrahydroisoquinoline In acetonitrile at 20℃; Green chemistry;	51 %Spectr.

: 95-14-7
1,2,3-Benzotriazole

: 653-37-2
perfluorobenzaldehyde

: 103-49-1
dibenzylamine

: 1-(1-benzotriazol-1-yl)-1-dibenzylamino-1-pentafluorophenylmethane

Conditions

Conditions	Yield
In benzene Ambient temperature;	100%

...Expand

: 653-37-2
perfluorobenzaldehyde

: 440-60-8
(2,3,4,5,6-pentafluorophenyl)methanol

Conditions

Conditions	Yield
Stage #1: perfluorobenzaldehyde With C24H20Cl2F5NRuS; isopropyl alcohol at 82℃; for 0.166667h; Stage #2: With potassium hydroxide at 82℃; for 0.5h;	100%
With sodium tetrahydroborate; 1,4,8,11,15,18,22,25-octapentyloxyphthalocyaninato nickel In pentan-1-ol at 25℃; for 0.416667h; Catalytic behavior;	87%
With tris(pentafluorophenyl)borate; hydrogen In 1,4-dioxane at 80℃; under 3750.38 Torr; for 24h; Glovebox; Inert atmosphere;	74%

: 653-37-2
perfluorobenzaldehyde

: 2393-23-9
4-methoxy-benzylamine

: 730992-49-1
(E)-4-methoxy-N-(pentafluorobenzylidene)benzylamine

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 3h;	100%

: 653-37-2
perfluorobenzaldehyde

: 1067-52-3
tributyltin methoxide

: 14630-18-3
α-Methoxy-α--pentafluortoluol

Conditions

Conditions	Yield
1:1.1;	100%
	100%
	100%

: 653-37-2
perfluorobenzaldehyde

: 688-73-3
tri-n-butyl-tin hydride

A: 20749-43-3
Perfluorphenylmethoxytributylzinn

B: 20428-47-1
Perfluorphenylmethyl-(perfluorphenyl-tributylstannoxymethyl)-ether

Conditions

Conditions	Yield
In neat (no solvent) 2:3 mole ratio of (C4H9)3SnH and aldehyde, 20. degree.C; 2.6:1 mixt. of (C4H9)3SnOCH2C6F5 and the 1:2 adduct (C4H9)3SnOCH(C6F5)OCH2C5F6;	A 100% B n/a
In neat (no solvent) 2:3 mole ratio of (C4H9)3SnH and aldehyde, 20. degree.C; 2.6:1 mixt. of (C4H9)3SnOCH2C6F5 and the 1:2 adduct (C4H9)3SnOCH(C6F5)OCH2C5F6;	A 100% B n/a
In not given reaction at 20°C;;

...Expand

: 653-37-2
perfluorobenzaldehyde

: 602-94-8
Pentafluorobenzoic acid

Conditions

Conditions	Yield
With cobalt(II) 2,9,16,23-phthalocyanine tetrasulfonic acid In water; acetonitrile at 20℃; under 760.051 Torr; for 150h; UV-irradiation;	100%
With 9-oxyl-9-azabicyclo<3.3.1>nonan-3-one; oxygen; nitric acid; sodium nitrite In water; acetonitrile at 23℃; under 760.051 Torr; for 8h; Sealed tube;	85%
Multi-step reaction with 2 steps 1: pyridine / benzene 2: H2SO4 View Scheme

: 653-37-2
perfluorobenzaldehyde

: 82479-12-7
3-((4-chlorophenyl)thio)-3-oxopropanoic acid

: rac-S-4-chlorophenyl 3-(pentafluorophenyl)-3-hydroxypropanethioate

Conditions

Conditions	Yield
With tetrabutylammomium bromide In chloroform; water	100%

: 653-37-2
perfluorobenzaldehyde

: 95-54-5
1,2-diamino-benzene

: C14H7F5N2

Conditions

Conditions	Yield
With C23H3BF16N2O In toluene at 25℃; for 3h; Green chemistry;	100%

: 653-37-2
perfluorobenzaldehyde

: 76179-40-3
2-amino-4,5-difluoroaniline

: C14H5F7N2

Conditions

Conditions	Yield
With C23H3BF16N2O In toluene at 25℃; for 3h; Green chemistry;	100%

: 653-37-2
perfluorobenzaldehyde

: tert-butyl 1-(2-bromobenzyl)hydrazine-1-carboxylate

: C19H16BrF5N2O2

Conditions

Conditions	Yield
In ethanol at 20℃;	100%

: 109-97-7
pyrrole

: 653-37-2
perfluorobenzaldehyde

: 167482-91-9
5-(pentafluorophenyl)dipyrromethane

Conditions

Conditions	Yield
With indium(III) chloride at 20℃; for 1.5h; Inert atmosphere; Schlenk technique;	99%
Stage #1: pyrrole; perfluorobenzaldehyde for 0.333333h; Inert atmosphere; Darkness; Stage #2: With indium(III) chloride at 20℃; for 1.5h; Inert atmosphere; Darkness;	93%
With trifluoroacetic acid at 20℃; for 0.416667h;	92%

: 653-37-2
perfluorobenzaldehyde

: 1576-35-8
toluene-4-sulfonic acid hydrazide

: 16096-88-1
2,3,4,5,6-pentafluorobenzaldehyde p-tosylhydrazone

Conditions

Conditions	Yield
In ethanol at 20℃; for 48h;	99%
In ethanol for 48h; Ambient temperature;	89%
In ethanol for 48h; Ambient temperature;	87%
In methanol at 20℃; for 3h;	82%

: 653-37-2
perfluorobenzaldehyde

: 91-00-9
Benzhydrylamine

: N-pentafluorobenzylidene-1,1-diphenylmethylamine

Conditions

Conditions	Yield
With potassium carbonate at 0 - 20℃; Condensation;	99%
In toluene for 5h; Inert atmosphere; Reflux; Dean-Stark;

: 653-37-2
perfluorobenzaldehyde

: 82565-66-0
(5E)-2-methyl-6-phenylhex-5-en-3-yn-2-ol

: (E)-1-Pentafluorophenyl-5-phenyl-pent-4-en-2-yn-1-ol

Conditions

Conditions	Yield
Stage #1: (5E)-2-methyl-6-phenylhex-5-en-3-yn-2-ol With (o,o'-biphenylenedioxy)methylaluminium In hexane; dichloromethane at 20℃; for 0.5h; Stage #2: perfluorobenzaldehyde In hexane; dichloromethane at 20℃; for 1.5h; Meerwein-Ponndorf-Verley alkynylation;	99%

: 653-37-2
perfluorobenzaldehyde

: 39085-59-1
trisylhydrazine

: 908838-30-2
2,3,4,5,6-pentafluorobenzaldehyde 2,4,6-triisopropylbenzenesulphonyl hydrazone

Conditions

Conditions	Yield
In methanol at 20℃; for 48h;	99%
In tetrahydrofuran at 0℃; for 3h;	73%

: 653-37-2
perfluorobenzaldehyde

: 108-94-1
cyclohexanone

: (S)-2-[(R)-hydroxy(perfluorophenyl)methyl]cyclohexanone

Conditions

Conditions	Yield
With cis-4-(2-(3-methyl-imidazol-3-ium-1-yl)acetoxy)proline bistriflimide; water at 25℃; for 4h; Neat (no solvent); optical yield given as %ee; stereoselective reaction;	99%
With L-proline In [1,3]-dioxolan-2-one; water at 20℃; for 24h; Aldol condensation; Inert atmosphere; optical yield given as %ee; enantioselective reaction;	99%
With (2S,4R)-4-(2,2-diphenylacetoxy)pyrrolidine-2-carboxylic acid In water at 20℃; for 24h; stereoselective reaction;	99%

: 653-37-2
perfluorobenzaldehyde

: 108-94-1
cyclohexanone

: (2R,1'S)-2-[(2,3,4,5,6-pentafluorophenyl)hydroxy methyl]cyclohexan-1-one

Conditions

Conditions	Yield
With 1,6-di(trans-4-tertbutlydiphenylsiloxy-L-prolinamide)hexane In water at 20℃; for 72h; Aldol condensation; optical yield given as %ee;	99%
With water; (R)-1,2-propylene carbonate; D-Prolin at 20℃; for 24h; Hajos-Parrish-Eder-Sauer-Wiechert reaction; Inert atmosphere; optical yield given as %ee; enantioselective reaction;	98%
With C10H14N2*CHF3O2S at 20℃; for 30h; Aldol Addition; Green chemistry;	88%

: 653-37-2
perfluorobenzaldehyde

: 492-41-1
(1R,2S)-norephedrine

: 1242079-32-8
(1R, 2S)-2-perfluorophenylmethylideneamino-1-phenylpropanol

Conditions

Conditions	Yield
	99%

: 653-37-2
perfluorobenzaldehyde

: 37577-28-9
(1S,2R)-(+)-norphedrine

: 1242079-31-7
(1S, 2R)-2-perfluorophenylmethylideneamino-1-phenylpropanol

Conditions

Conditions	Yield
	99%

: 653-37-2
perfluorobenzaldehyde

: 67-64-1
acetone

: (R)-4-hydroxy-4-(pentafluorophenyl)-butan-2-one

Conditions

Conditions	Yield
With L-proline In [1,3]-dioxolan-2-one at 20℃; for 24h; Aldol condensation; Inert atmosphere; optical yield given as %ee; enantioselective reaction;	99%

: 75-52-5
nitromethane

: 653-37-2
perfluorobenzaldehyde

: (R)-2-nitro-1-(perfluorophenyl)ethan-1-ol

Conditions

Conditions	Yield
With copper(II) acetate monohydrate; (S,S)-4,4'-bis(phenylmethyl)-2,2',5,5'-tetrahydro-2,2'-bioxazole In dichloromethane at 25℃; for 48h; Henry Nitro Aldol Condensation; enantioselective reaction;	99%
With heterogeneous pyridine-based chiral covalent organic framework prepared by 2,4,6-(4′-triaminophenyl)pyridine with 2-hydroxyltribenzaldehyde salted with (R)-prolinol bromoacetate at 20℃; for 24h; Henry Nitro Aldol Condensation; enantioselective reaction;	78%

: 653-37-2
perfluorobenzaldehyde

: 107-21-1
ethylene glycol

: 2-(pentafluorophenyl)-1,3-dioxolane

Conditions

Conditions	Yield
With pyridinium p-toluenesulfonate In benzene at 80℃; for 20h; regioselective reaction;	99%
With pyridinium p-toluenesulfonate In benzine at 80℃; for 20h;	83%

: 653-37-2
perfluorobenzaldehyde

: N,N,N',N'-tetramethyl-7-(2-thienyl)acenaphtho[1,2-c]pyrrole-3,4-dicarboxamide

: 7-[3,4-bis(N,N-dimethylcarbamoyl)-9-(2-thienyl)-8H-acenaphtho[1,2-c]pyrrol-7-ylidene(pentafluorophenyl)-methyl]-N,N,N',N'-tetramethyl-9-(2-thienyl)-2H-acenaphtho[1,2-c]pyrrole-3,4-dicarboxamide

Conditions

Conditions	Yield
Stage #1: perfluorobenzaldehyde; N,N,N',N'-tetramethyl-7-(2-thienyl)acenaphtho[1,2-c]pyrrole-3,4-dicarboxamide With trifluoroacetic acid In dichloromethane for 17h; Reflux; Stage #2: With 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane for 1h; Reflux;	99%

: 653-37-2
perfluorobenzaldehyde

: 104-94-9
4-methoxy-aniline

: 153255-91-5
(E)-N-(4-methoxyphenyl)-1-(perfluorophenyl) methanimine

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 3h;	98%
In dichloromethane for 0.25h; Ambient temperature;	97%
With DOWEX 50W X8-400 In benzene Heating;	97%
for 0.0833333h; Microwave irradiation;	92%
With benzotriazol-1-ol; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 4h;	80%

: 7677-24-9
trimethylsilyl cyanide

: 653-37-2
perfluorobenzaldehyde

: 75853-10-0
(+/-)-2-hydroxy-2-(pentafluorophenyl)acetonitrile

Conditions

Conditions	Yield
Stage #1: trimethylsilyl cyanide; perfluorobenzaldehyde With zinc dibromide In acetonitrile at 20℃; for 40h; Addition; Stage #2: With hydrogenchloride In acetonitrile at 0 - 5℃; for 1h; desilylation;	98%
Stage #1: trimethylsilyl cyanide; perfluorobenzaldehyde With zinc dibromide In acetonitrile at 20℃; for 40h; Addition; Stage #2: With hydrogenchloride In acetonitrile at 0 - 5℃; for 1h; desilylation; Further stages.;	98%

: 653-37-2
perfluorobenzaldehyde

: 1099-45-2
ethyl (triphenylphosphoranylidene)acetate

: 81069-65-0, 83004-28-8
(E)-ethyl 3-(perfluorophenyl)acrylate

Conditions

Conditions	Yield
at 100℃; Wittig olefination;	98%

: 653-37-2
perfluorobenzaldehyde

: 15097-38-8
(carbobenzyloxymethylene)triphenylphosphorane

: 3-(pentafluorophenyl)-(E)-propenoic acid benzyl ester

Conditions

Conditions	Yield
at 100℃; Wittig olefination;	98%

: 625-82-1
2,4-dimethyl-1H-pyrrole

: 653-37-2
perfluorobenzaldehyde

: 5-pentafluorophenyl-1,3,7,9-tetramethyldipyrromethane

Conditions

Conditions	Yield
Stage #1: 2,4-dimethyl-1H-pyrrole; perfluorobenzaldehyde With trifluoroacetic acid In dichloromethane at 20℃; for 2h; Inert atmosphere; Stage #2: With triethylamine In dichloromethane for 0.0833333h; Inert atmosphere;	98%
With trifluoroacetic acid In dichloromethane Inert atmosphere;
With boron trifluoride diethyl etherate In dichloromethane at 20℃; for 48h; Inert atmosphere;
With trifluoroacetic acid In dichloromethane at 20℃; Inert atmosphere;

: 653-37-2
perfluorobenzaldehyde

: 141-97-9
ethyl acetoacetate

: 7803-57-8
hydrazine hydrate

: 109-77-3
malononitrile

: 354538-52-6, 879454-49-6
6-amino-3-methyl-4-(2,3,4,5,6-pentafluorophenyl)-2,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile

Conditions

Conditions	Yield
With silica-supported tetramethylguanidine In neat (no solvent) at 100℃; for 0.25h;	98%

...Expand

: 653-37-2
perfluorobenzaldehyde

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 2-((2,3,4,5,6-pentafluorobenzyl)oxy)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Conditions

Conditions	Yield
With C19H25AsN2O In benzene-d6 at 20℃; for 0.5h; Inert atmosphere; Glovebox; Schlenk technique;	98%
With [Co{κ2N,N′-5-(2,4,6-iPr3-C6H2)-NC4H2-2-C(H)=N(2,6-iPr2-C6H3)}(PMe3)2] In benzene-d6 at 25℃; for 1h; Schlenk technique; Inert atmosphere; Glovebox;	94%
With Zr6(μ3-O)4(μ3-OMgMe)4(3'-nitro-[1,1':4',1'':4'',1'''-tetraphenyl]-4,4'''-dicarboxylate)6 In hexane at 23℃; for 12h; Inert atmosphere; Glovebox; Schlenk technique;	100 %Spectr.

Benzaldehyde,2,3,4,5,6-pentafluoro- Specification

The CAS register number of Benzaldehyde,2,3,4,5,6-pentafluoro- is 653-37-2. It also can be called as 2,3,4,5,6-Pentafluorobenzaldehyde and the systematic name about this chemical is pentafluorobenzaldehyde. The molecular formula about this chemical is C₇HF₅O and the molecular weight is 196.07. It belongs to the following product categories which include Aromatic Aldehydes & Derivatives (substituted); Benzaldehyde; Aldehydes; C₇; Carbonyl Compounds and so on.

Physical properties about Benzaldehyde,2,3,4,5,6-pentafluoro- are: (1)ACD/LogP: 2.23; (2)ACD/LogD (pH 5.5): 2.23; (3)ACD/LogD (pH 7.4): 2.23; (4)ACD/BCF (pH 5.5): 29.29; (5)ACD/BCF (pH 7.4): 29.29; (6)ACD/KOC (pH 5.5): 390.37; (7)ACD/KOC (pH 7.4): 390.37; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 1; (10)Polar Surface Area: 17.07 Å²; (11)Index of Refraction: 1.452; (12)Molar Refractivity: 32.97 cm³; (13)Molar Volume: 122.1 cm³; (14)Polarizability: 13.07x10^-24cm³; (15)Surface Tension: 30.8 dyne/cm; (16)Density: 1.605 g/cm³; (17)Flash Point: 77.8 °C; (18)Enthalpy of Vaporization: 40.25 kJ/mol; (19)Boiling Point: 166 °C at 760 mmHg; (20)Vapour Pressure: 1.82 mmHg at 25 °C.

Uses of Benzaldehyde,2,3,4,5,6-pentafluoro-: it can be used to produce 1-(4'-formyltetrafluorophenyl)imidazole with 1H-imidazole. This reaction will need reagent of tetrahydrofuran. The reaction time is 20 hours with reaction temperature of 13 - 16 °C. The yield is about 83.5%.

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation and if swallowed. It is irritating to eyes, respiratory system and skin. If you want to use this chemical, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: Fc1c(C=O)c(F)c(F)c(F)c1F

Product Name

PENTAFLUOROBENZALDEHYDE

Synthetic route

Benzaldehyde,2,3,4,5,6-pentafluoro- Specification

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