Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate supplier

Name
Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate
EINECS 1308068-626-2
CAS No. 2516-92-9
Article Data14
CAS DataBase
Density 1.12 at 22℃
Solubility
Melting Point 99.0 to 103.0 °C
Formula C₂₈H₅₀N₂O₆
Boiling Point 523.5°C at 760 mmHg
Molecular Weight 510.715
Flash Point 270.4°C
Transport Information
Appearance
Safety
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Piperidinooxy,4-hydroxy-2,2,6,6-tetramethyl-, sebacate (2:1) (ester) (8CI);Piperidinooxy,4-hydroxy-2,2,6,6-tetramethyl-, sebacate (7CI);Sebacic acid, diester with4-hydroxy-2,2,6,6-tetramethylpiperidinooxy (8CI);Bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl) sebacate;Bis(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) decanedioate;Bis(2,2,6,6-tetramethylpiperidin-1-oxyl-4-yl) sebacate;CXA 5415;Ciba 5415;MP1002;Prostab 5415;
PSA 59.08000
LogP 5.80360

Synthetic route

: 52829-07-9
bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions

Conditions	Yield
With sodium tungstate; dihydrogen peroxide; edetate disodium In methanol; acetonitrile	10%

: 52829-07-9
bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

A: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

B: 80004-15-5
C28H51N2O5

Conditions

Conditions	Yield
With 3-chloro-benzenecarboperoxoic acid In dichloromethane 1) 273 K, 1 h, 2) 1 h, reflux;

: 45985-24-8, 2226-96-2
TEMPOL

: 818-88-2
sebacic acid mono methyl ester

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions

Conditions	Yield
With sodium methylate In n-heptane Heating / reflux;

: 111-19-3
sebacoyl chloride

: 45985-24-8, 2226-96-2
TEMPOL

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

Conditions

Conditions	Yield
With dmap; triethylamine In dichloromethane at 0 - 20℃; for 18h;

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 111-65-9
octane

: bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate

Conditions

Conditions	Yield
With dihydrogen peroxide at 75 - 80℃; for 9h; Reagent/catalyst; Temperature;	89.7%
With iron(III) chloride; dihydrogen peroxide; acetic acid In water; acetonitrile at 76℃; for 4h; Heating / reflux;	31%

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 371756-16-0
di(1-phenoxy-2,2,6,6-tetramethyl-piperidin-4-yl) sebacate

Conditions

Conditions	Yield
With pyridine; tert.-butylnitrite; aniline In n-heptane; ethyl acetate	47.9%

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 110-82-7
cyclohexane

: bis(1-cyclohexyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate

Conditions

Conditions	Yield
With methanesulfonic acid; dihydrogen peroxide; iron(II) sulfate In water; acetonitrile at 55℃; for 5.5h; Heating / reflux;	43%

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 52829-07-9
bis-(2,2,6,6-tetramethyl-4-piperidinyl) sebacate

Conditions

Conditions	Yield
With ethanethiol In benzene	17%

: 292638-84-7
styrene

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

polymer, Mn (g/mol) = 20600, Mw/Mn = 1.68; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester: polymer, Mn (g/mol) = 20600, Mw/Mn = 1.68; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

Conditions

Conditions	Yield
With dibenzoyl peroxide at 130℃; for 2.5h;	53 % Turnov.

: 292638-84-7
styrene

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

polymer, Mn (g/mol) = 25000, Mw/Mn = 1.72; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester: polymer, Mn (g/mol) = 25000, Mw/Mn = 1.72; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

Conditions

Conditions	Yield
With dibenzoyl peroxide at 130℃; for 14h;	86 % Turnov.

: 292638-84-7
styrene

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

polymer, Mn (g/mol) = 26300, Mw/Mn = 1.60; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester: polymer, Mn (g/mol) = 26300, Mw/Mn = 1.60; monomer(s): styrene; decanedioic acid bis(1-oxy-2,2,6,6-tetramethylpiperidin-4-yl) ester

Conditions

Conditions	Yield
With dibenzoyl peroxide at 130℃; for 5h;	76 % Turnov.

: 124-19-6
nonan-1-al

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: bis(1-octyloxy-2,2,6,6-tetramethyl-4-piperidyl)sebacate

Conditions

Conditions	Yield
With dihydrogen peroxide; acetic acid; calcium chloride; copper dichloride In water; toluene at 20 - 40℃; for 11h; Product distribution / selectivity;
With dihydrogen peroxide; acetic acid; copper dichloride In water; toluene; tert-butyl alcohol at 25 - 40℃; for 12h; Product distribution / selectivity;

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 142-82-5
n-heptane

: bis(1-heptyloxy-2,2,6,6-tetramethylpiperidin-4-yl) sebacate

Conditions

Conditions	Yield
With hydrogenchloride; iron(III) chloride; dihydrogen peroxide In water; acetonitrile at 33 - 68℃; for 6.5h;

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 111-66-0
oct-1-ene

A: C44H80N2O6

B: 865710-98-1
C44H80N2O6

Conditions

Conditions	Yield
With tert.-butylhydroperoxide; copper(ll) bromide In water at 60℃; for 0.5h; Product distribution / selectivity;
With tert.-butylhydroperoxide; tetra-(n-butyl)ammonium iodide In water at 60℃; for 2.5 - 5.25h; Product distribution / selectivity;
With tert.-butylhydroperoxide; copper dichloride In water at 60℃; for 3h; Product distribution / selectivity;

...Expand

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 627-18-9
1-bromo-3-propanol

: 1098596-25-8
bis[1-(3-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl] Sebacate

Conditions

Conditions	Yield
With tri-n-butyl-tin hydride In chlorobenzene

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 3344-77-2
12-bromododecanol

: 1098596-19-0
Bis[1-(12-hydroxy-1-dodecyloxy)-2,2,6,6-tetramethylpiperidin-4-yl] Sebacate

Conditions

Conditions	Yield
With tri-n-butyl-tin hydride In chlorobenzene

: 19686-73-8
1-bromo-2-propanol

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 1098596-20-3
bis[1-(2-hydroxypropoxy)-2,2,6,6-tetramethylpiperidin-4-yl] Sebacate

Conditions

Conditions	Yield
With tri-n-butyl-tin hydride In chlorobenzene

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 109-63-7
boron trifluoride diethyl etherate

: 4,4'-[(1,10-dioxo-1,10-decanediyl)bis(oxy)]bis[2,2,6,6-tetramethyl-1-oxo-piperidinium] tetrafluoroborate

Conditions

Conditions	Yield
Stage #1: boron trifluoride diethyl etherate With isopentyl nitrite In diethyl ether for 0.0833333h; Inert atmosphere; Stage #2: bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate In diethyl ether for 0.5h; Inert atmosphere;

: 2516-92-9
bis(1-oxyl-2,2,6,6-tetramethylpiperidin-4-yl)sebacate

: 30538-92-2
1,10-bis(1-hydroxy-2,2,6,6-tetramethyl-4-piperidinyl) decanedioate

Conditions

Conditions	Yield
With ascorbic acid In 1,4-dioxane; water at 20℃; for 1h; Inert atmosphere;

Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate Specification

The Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate is an organic compound with the formula C₂₈H₅₀N₂O₆. With the CAS registry number 2516-92-9, it is also named as 1-Piperidinyloxy, 4,4'-((1,10-dioxo-1,10-decanediyl)bis(oxy))bis(2,2,6,6-tetramethyl-. The product's category is Pharmaceutical Intermediates.

You can still convert the following datas into molecular structure:
(1)SMILES: CC1(CC(CC(N1[O])(C)C)OC(=O)CCCCCCCCC(=O)OC2CC(N(C(C2)(C)C)[O])(C)C)C
(2)InChI: InChI=1/C28H50N2O6/c1-25(2)17-21(18-26(3,4)29(25)33)35-23(31)15-13-11-9-10-12-14-16-24(32)36-22-19-27(5,6)30(34)28(7,8)20-22/h21-22H,9-20H2,1-8H3
(3)InChIKey: XVJWWMHPPKXKRU-UHFFFAOYAB
(4)Std. InChI: InChI=1S/C28H50N2O6/c1-25(2)17-21(18-26(3,4)29(25)33)35-23(31)15-13-11-9-10-12-14-16-24(32)36-22-19-27(5,6)30(34)28(7,8)20-22/h21-22H,9-20H2,1-8H3
(5)Std. InChIKey: XVJWWMHPPKXKRU-UHFFFAOYSA-N

Product Name

Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate

Synthetic route

Bis(2,2,6,6-tetramethyl-1-piperidinyloxy-4-yl) sebacate Specification

Related Products

Hot Products