Conditions | Yield |
---|---|
at 160℃; for 0.166667h; Inert atmosphere; | 94% |
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;; | A 50% B n/a |
With O2 In neat (no solvent) byproducts: SO2; at 500°C, O2-N2-mixtures with up to 60% O2;; | A 50% B n/a |
With oxygen byproducts: SO2; over 500°C; |
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: SO3(2-); thermal decompn., corundum crucible, 226°C, 260-375°C; |
Conditions | Yield |
---|---|
In water |
Conditions | Yield |
---|---|
In neat (no solvent) rapid oxidation to CuSO4;; | |
In neat (no solvent) oxidation;; | |
In neat (no solvent) rapid oxidation to CuSO4;; | |
In neat (no solvent) oxidation;; |
water
sodium sulfate
A
copper(II) sulfate
B
sodium hydroxide
Conditions | Yield |
---|---|
In not given Electrolysis; arrangement with diaphragms; Cu anode; liquid film between 2 porous walls of separation between anode and cathode region, regenaration by circulation;; |
A
copper
B
copper(II) sulfate
Conditions | Yield |
---|---|
In sulfuric acid diln. of H2SO4; | |
In sulfuric acid aq. H2SO4; diln. of H2SO4; |
Conditions | Yield |
---|---|
With sulfur dioxide; oxygen byproducts: Na2SO4; | |
With sulfur dioxide; oxygen byproducts: Na2SO4; |
Conditions | Yield |
---|---|
With oxygen byproducts: Na2SO4, SO2; | |
With oxygen byproducts: Na2SO4, SO2; |
Conditions | Yield |
---|---|
With oxygen byproducts: Na2SO4; slight prodn. of CuSO4 at the main react. of roasting of Cu2S between 250 and 350°C; | |
With oxygen byproducts: Na2SO4; slight prodn. of CuSO4 at the main react. of roasting of Cu2S between 250 and 350°C; |
copper(I) sulfide
sodium chloride
A
disulfur dichloride
C
copper(II) sulfate
Conditions | Yield |
---|---|
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.; | |
With oxygen byproducts: Na2SO4, SO2; information about the react. eqs. in detail and about dependence on temp.; |
Conditions | Yield |
---|---|
With oxygen between 350 and 375°C at roasting of Cu2S; oxidn. of CuCl, produced at lower temp. in the main react., in presence of NaCl and Na2SO4, latter produced at lower temp.; information about the react. eqs. in detail; | |
With oxygen between 350 and 375°C at roasting of Cu2S; oxidn. of CuCl, produced at lower temp. in the main react., in presence of NaCl and Na2SO4, latter produced at lower temp.; information about the react. eqs. in detail; |
Conditions | Yield |
---|---|
With sulfuric acid In sulfuric acid | A 0% B n/a |
Conditions | Yield |
---|---|
With air In water |
sulfuric acid
copper
A
hydrogenchloride
B
copper(II) sulfate
Conditions | Yield |
---|---|
With alkali chloride In not given byproducts: alkali hydroxide; Electrolysis; | |
With alkali chloride In not given byproducts: alkali hydroxide; Electrolysis; |
Conditions | Yield |
---|---|
In sulfuric acid byproducts: HCl, SO2; with concd. H2SO4;; |
copper(II) sulfate
Conditions | Yield |
---|---|
With air In not given |
sulfur trioxide
B
sulfur dioxide
C
sulfur
D
copper(II) sulfate
Conditions | Yield |
---|---|
360°C in vac.; |
Conditions | Yield |
---|---|
In not given |
Conditions | Yield |
---|---|
roasting at 200 - 300°C then product treated with H2SO4; | |
roasting at 200 - 300°C then product treated with H2SO4; | |
With air In not given |
Conditions | Yield |
---|---|
With sulfur In neat (no solvent) on heating with excess sulphur;; | A n/a B n/a C >1 |
Conditions | Yield |
---|---|
With sulfur In water boiling the colloid soln.; | |
With water; sulfur In neat (no solvent) triuration with sulphur and H2O, heating in a closed tube up to 100°C;; | |
With S In water boiling the colloid soln.; |
Conditions | Yield |
---|---|
With sulfur In neat (no solvent) on heating (excess of CuO);; |
Conditions | Yield |
---|---|
With sulfur dioxide In neat (no solvent) byproducts: Cu2O; heating CuO with SO2;; formation of SO3 and CuSO4;; | |
With SO2 In neat (no solvent) byproducts: Cu2O; heating CuO with SO2;; formation of SO3 and CuSO4;; |
1-acetyl-2-octanoylhydrazine
copper(II) sulfate
Conditions | Yield |
---|---|
With aq. NH3 In ethanol; water to aq. soln. of metal salt added aq. NH3 (pH 8-11); soln. of ligand in EtOH added (molar ratio metal:ligand = 1:1 or 1:2); after 5 min ppt. filtered; washed (EtOH); dried (air); | 99.8% |
Conditions | Yield |
---|---|
In ethanol for 0.5h; Reflux; | 99.5% |
Conditions | Yield |
---|---|
In water byproducts: H2SO4; pptn. of Cu2S (99.3%) and formation of FeSO4 and H2SO4 by reaction of 5%ic CuSO4- soln. with FeS2 at 200 °C in presence of quartz; quartz prevents formation of Fe2O3, Cu2O and CuS as by-products; formation of CuS with higher per cent FeS2;; | A 99.3% B n/a |
In water byproducts: H2SO4; pptn. of Cu2S (99.3%) and formation of FeSO4 and H2SO4 by reaction of 5%ic CuSO4- soln. with FeS2 at 200 °C in presence of quartz; quartz prevents formation of Fe2O3, Cu2O and CuS as by-products; formation of CuS with higher per cent FeS2;; | A 99.3% B n/a |
hydrogenchloride
copper(II) sulfate
A
sulfuric acid
B
chlorine
C
copper
Conditions | Yield |
---|---|
In water Electrolysis; | A n/a B 90% C 99% |
In water |
Conditions | Yield |
---|---|
In water Electrochem. Process; 0.075 M VOSO4 and 0.075 M CuSO4 oxidized at 25 °C E=1.0 V(Ag/AgCl); | 99% |
Conditions | Yield |
---|---|
In water Electrochem. Process; 0.075 M VOSO4 and 0.075 M CuSO4 oxidized at 97 °C E=0.5 V(Ag/AgCl); | 99% |
methanesulfonic acid
treosulfan
copper(II) sulfate
isobutyraldehyde
Conditions | Yield |
---|---|
With potassium carbonate In ethyl acetate; toluene | 98% |
N-phenyl-1H-benzo[d]imidazole-2-carbothioamide
copper(II) sulfate
Conditions | Yield |
---|---|
With sulfuric acid In methanol; water byproducts: C6H5NH2*H2SO4; soln. of CuSO4 in MeOH-H2O (10:1) added to soln. of org. ligand in MeOH;stirred; concd. H2SO4 added; stirred (1 h, room temp.); kept (24 h); ppt. filtered off; washed with hot and then cold MeOH; dried in desiccator (75°C, 5 h); elem. anal.; | 98% |
Conditions | Yield |
---|---|
Stage #1: 3,5-diiodo-l-tyrosine With sodium hydroxide In water for 1h; Stage #2: copper(II) sulfate In water at 20 - 40℃; for 2h; | 98% |
Conditions | Yield |
---|---|
In water aq. soln. of copper(II) sulphate added to aq. picrolonic acid at room temp.; ppt. filtered, washed with water, ethanol, ether, dried in vac. till constant weight, elem. anal.; | 97% |
copper(II) sulfate
Conditions | Yield |
---|---|
Stage #1: (8S,23S,27S)-8-carbamoyl-2,10,17,25-tetraoxo-1-((lanthanum(3+))-4,7,10-tris(carboxymethyl)-1,4,7,10-tetraazacyclododecan-1-yl)-3,9,18,24,26-pentaazanonacosane-23,27,29-tricarboxylic acid With trifluoroacetic acid In water for 16h; Stage #2: copper(II) sulfate In water for 0.5h; | 97% |
Octanoic acid
copper(II) sulfate
copper(II) octanoate
Conditions | Yield |
---|---|
Stage #1: Octanoic acid In water at 30℃; for 0.5h; Stage #2: With sodium hydroxide In water at 55℃; for 0.5h; Stage #3: copper(II) sulfate for 2h; | 96.57% |
Conditions | Yield |
---|---|
In ethanol; water refluxing (EtOH/water 1:1, 1 h), pptn.; sepn. (hot filtration), washing (hot EtOH), drying (vac., over CaCl2); elem. anal.; | 96% |
Conditions | Yield |
---|---|
In methanol soln. of ligand in MeOH was stirred with soln. of metal salt in MeOH overnight; solvent was removed in vacuo, recrystd. from hexane-diisopropyl ether; elem. anal.; | 96% |
diethyl ether
copper(II) sulfate
{(Z)-1,3-Diphenyl-3-[(Z)-trimethylsilanyl-imino]-propenyl}-trimethylsilanyl-amine
Conditions | Yield |
---|---|
In diethyl ether; water (Ar); using Schlenk techniques; addn. of soln. of (H(N(SiMe3)C(Ph))2CH) in Et2O to suspn. of CuSO4 in H2O; stirring at room temp. for 18 h; washing with light petroleum (b.p. 60-80°C); crystn. from Et2O; | 96% |
Conditions | Yield |
---|---|
In ethanol Kinetics; byproducts: I2, K2SO4; dehydrated solns. of CuSO4 (0.0008 mol/l) and KI (0.0081 mol/l) in EtOH were mixed under protective dried N2 atm.; optimized temp. was 291.15 K,feed flow rate - 2.3 ml/min; suspn. filtered by vac. extract filter; ppt. dried in oven at 353 K for 2-3 h; | 95.39% |
With SiW12O40(4-) In ethanol Irradiation (UV/VIS); SiW12O40(4-) in deaerated EtOH UV-irradiated for 3 h, added to CuSO4 andKI in deaerated EtOH (N2) under stirring; centrifuged, washed (H2O) several times, dried (vac.) at 80°C for5 h; |
copper(II) sulfate
copper
Conditions | Yield |
---|---|
With magnesium In water | 95% |
With formic acid In water byproducts: CO2; High Pressure; hydrothermal reaction at 200°C for 18 h; mechanism discussed;; | 90% |
With sulfur dioxide In not given heating; no reaction at ambient temp.; | 12% |
copper(II) sulfate
3-amino-4-hydroxytoluene
4-Bromophenyl isothiocyanate
N-(4-bromophenyl)-N-(5-methyl-1,3-benzoxazol-2-yl)amine
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran; acetonitrile | 95% |
With triethylamine In tetrahydrofuran; acetonitrile | 95% |
Conditions | Yield |
---|---|
With NaOH In water equimolar mixt. of nicotinic acid and NaOH added to aq. soln. of CuSO4, refluxed for 15 min; filtered, elem. anal.; | 95% |
potassium tetrakis(1H-4-methyl-pyrazol-1-yl)borate
copper(II) sulfate
Conditions | Yield |
---|---|
In water byproducts: K2SO4; elem. anal.; | 95% |
Conditions | Yield |
---|---|
In methanol High Pressure; CuSO4, fluconazole, KSCN in stoichiometric ratio 1:1:3 and methanol heated in Teflon-lined autoclaves at 120 °C for 3 days; followed by slow cooling to room temp.; crystals filtered off; elem. anal.; | 95% |
In water High Pressure; CuSO4, fluconazole, KSCN in stoichiometric ratio 1:1:3 and water heated in Teflon-lined autoclaves at 120 °C for 3 days; followed by slowcooling to room temp.; crystals filtered off; elem. anal.; | 90% |
Conditions | Yield |
---|---|
Stage #1: copper(II) sulfate; monosodium glutamate With sodium hydroxide In water at 5℃; for 18h; Heating / reflux; Stage #2: With water | 94.2% |
copper(II) sulfate
Conditions | Yield |
---|---|
With sodium hydrogencarbonate In dichloromethane; water 23°C; | 94% |
Conditions | Yield |
---|---|
at 80℃; for 2h; | 93.6% |
Conditions | Yield |
---|---|
With potassium cyanide; sodium metabisulfite In water at 70℃; for 0.2h; | 93.3% |
With sodium metabisulfite |
N-benzoyl-beta-alanine
copper(II) sulfate
[Cu2(μ(2)-O2CCH2CH2NHCOC6H5)4]
Conditions | Yield |
---|---|
With NaOH In water org. ligand dissolved in H2O with NaOH; CuSO4 in H2O added; mixt. heatedfor 12 h at 50°C; ppt. filtered; washed (EtOH, Et2O); dried (vac.); elem. anal.; | 93% |
L-Tartaric acid
copper(II) sulfate
copper(II) d-tartrate trihydrate
Conditions | Yield |
---|---|
With sodium hydroxide In water to a soln. of (+)-L-tartaric acid in aq. NaOH an aq. soln. of CuSO4 (equimolar to tartaric acid) was added and the mixt. kept at 20°C overnight;; pptd. was collected, washed with acetone and dried in vac.;; | 93% |
Conditions | Yield |
---|---|
With sodium hydroxide In water at 90℃; for 2h; pH=9; | 92.6% |
potassium hydridotris(1H-4-methyl-pyrazol-1-yl)borate
copper(II) sulfate
Conditions | Yield |
---|---|
In water byproducts: K2SO4; elem. anal.; | 92% |
Copper and its compounds are on the Community Right-To-Know List.
ACGIH TLV: TWA (fume) 0.2 mg/m3; (dust, mist) 1 mg(Cu)/m3
The Copper sulfate pentahydrate, with the CAS registry number 7758-99-8, is also known as Copper (II) sulfate.It belongs to the product categories of Metabolites;Metal and Ceramic Science;Molluscicides;Pesticides;Pesticides &;Salts;Ultra-High Purity Materials. This chemical's molecular formula is CuSO4.5(H2O) and molecular weight is 249.68. What's more,Its systematic name is Copper sulfate pentahydrate.
Physical properties about Copper sulfate pentahydrate are: (1)mp: 110 °C (dec.)(lit.); (2)density: 2.284; (3)vapor pressure: 7.3 mm Hg ( 25 °C); (4)storage temp: Store at RT; (5)solubility: 320 g/L (20°C); (6)Water Solubility: 320 g/L (20 oC); (7)Merck: 14,2653.
Copper sulfate pentahydrate can be dehydrated by heating. Serves as a weak oxidizing agent. Causes hydroxylamine to ignite. Gains water readily. The hydrated salt is vigorously reduced by hydroxylamine [Mellor 8:292(1946-1947)]. Both forms are incompatible with finely powdered metals. Both are incompatible with magnesium, corrode steel and iron, may react with alkalis, phosphates, acetylene gas, hydrazine, or nitromethane, and may react with beta-naphthol, propylene glycol, sulphathiazole and triethanolamine if the pH exceeds 7 . Both act as acidic salts, corrode metals and irritate tissues.
The Copper sulfate pentahydrate is harmful by inhalation, in contact with skin and if swallowed. It is irritating to eyes, respiratory system and skin.The Copper sulfate pentahydrate is very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment, so it should be avoided release to the environment. Refer to special instructions safety data sheet .This material and/or its container must be disposed of as hazardous waste.When you use it,wear suitable protective clothing.In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Do not breathe dust.
You can still convert the following datas into molecular structure:
(1)SMILES:O.O.O.O.O.[O-]S(=O)(=O)[O-].[Cu+2];
(2)Std. InChI:InChI=1S/Cu.H2O4S.5H2O/c;1-5(2,3)4;;;;;/h;(H2,1,2,3,4);5*1H2/q+2;;;;;;/p-2;
(3)Std. InChIKey:JZCCFEFSEZPSOG-UHFFFAOYSA-L;
The toxicity data of Copper sulfate pentahydrate as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
bird - wild | LDLo | oral | 300mg/kg (300mg/kg) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. | |
bird - wild | LDLo | oral | 300mg/kg (300mg/kg) | BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
dog | LDLo | oral | 60mg/kg (60mg/kg) | "Abdernalden's Handbuch der Biologischen Arbeitsmethoden." Vol. 4, Pg. 1289, 1935. | |
domestic animals - goat/sheep | LDLo | oral | 5mg/kg (5mg/kg) | GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" BLOOD: HEMORRHAGE BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Journal of Comparative Pathology. Vol. 82, Pg. 47, 1972. |
duck | LDLo | oral | 600mg/kg (600mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: COMA | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
guinea pig | LDLo | subcutaneous | 62mg/kg (62mg/kg) | BEHAVIORAL: COMA GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" AUTONOMIC NERVOUS SYSTEM: OTHER (DIRECT) PARASYMPATHOMIMETIC | British Medical Journal. Vol. 2, Pg. 217, 1913. |
human | LDLo | oral | 1088mg/kg (1088mg/kg) | BEHAVIORAL: COMA BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA | Indian Practitioner. Vol. 18, Pg. 807, 1965. |
human | TDLo | oral | 272mg/kg (272mg/kg) | KIDNEY, URETER, AND BLADDER: OTHER CHANGES BLOOD: OTHER HEMOLYSIS WITH OR WITHOUT ANEMIA | Indian Practitioner. Vol. 18, Pg. 807, 1965. |
mammal (species unspecified) | LD50 | intraperitoneal | 7500ug/kg (7.5mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: NAUSEA OR VOMITING | Journal of Animal Science. Vol. 55, Pg. 337, 1982. |
man | LDLo | unreported | 221mg/kg (221mg/kg) | "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M., Springfield, IL, C.C. Thomas, 1970Vol. 2, Pg. 73, 1970. | |
man | TDLo | oral | 429mg/kg (429mg/kg) | VASCULAR: BP LOWERING NOT CHARACTERIZED IN AUTONOMIC SECTION BEHAVIORAL: SLEEP | Gekkan Yakuji. Pharmaceuticals Monthly. Vol. 41, Pg. 193, 1999. |
mouse | LD50 | intraperitoneal | 33mg/kg (33mg/kg) | Biochemical Pharmacology. Vol. 14, Pg. 289, 1965. | |
pigeon | LDLo | oral | 1gm/kg (1000mg/kg) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. | |
pigeon | LDLo | oral | 1gm/kg (1000mg/kg) | BEHAVIORAL: COMA BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) | Australian Veterinary Journal. Vol. 16, Pg. 147, 1940. |
rat | LD50 | intraperitoneal | 18700ug/kg (18.7mg/kg) | Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 53(4), Pg. 78, 1988. | |
rat | LD50 | oral | 300mg/kg (300mg/kg) | "Agricultural Chemicals," Thomson, W.T., 4 vols., Fresno, CA, Thomson Publications, 1976/77 revisionVol. 2, Pg. 182, 1977. | |
rat | LD50 | skin | > 2gm/kg (2000mg/kg) | Nippon Noyaku Gakkaishi. Journal of the Pesticide Science Society of Japan. Vol. 18, Pg. S161, 1993. |
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