Cylopropylmethyl chloride supplier

Name
Cylopropylmethyl chloride
EINECS 227-632-1
CAS No. 5911-08-0
Article Data35
CAS DataBase
Density 1.056 g/cm³
Solubility Not miscible in water.
Melting Point -91 °C
Formula C₄H₇Cl
Boiling Point 87.6 °C at 760 mmHg
Molecular Weight 90.5526
Flash Point 29 °F
Transport Information UN 1993 3/PG 2
Appearance COA
Safety 16-26-36/37/39
Risk Codes 11-36/37/38
Molecular Structure
Hazard Symbols F, Xi
Synonyms (Chloromethyl)cyclopropane;Chlorocyclopropylmethane;Cyclopropanemethyl chloride;Cyclopropylcarbinylchloride;Cyclopropylchloromethane;a-(Chloromethyl)cyclopropane;
PSA 0.00000
LogP 1.63520

Synthetic route

: 2516-33-8
Cyclopropylmethanol

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With phenylphosphorus tetrachloride In chloroform at 0℃; for 0.0833333h;	98%
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine at 0 - 20℃; for 3.25h;	95%
With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at -10 - 25℃; for 5h; Solvent; Temperature;	94%

: 56-23-5
tetrachloromethane

: 112057-32-6
tri(cyclopropylmethyl)phosphite

A: 927-73-1
3-butenyl chloride

B: 27301-78-6
Phosphoric acid tricyclopropylmethyl ester

C: 112142-26-4
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In toluene at 80℃; Further byproducts given;	A 16% B 2% C 80% D 64%

...Expand

: 2516-33-8
Cyclopropylmethanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
	A 15% B 18% C 80%

...Expand

: 2154-76-9
cyclopropylmethyl

A: 927-73-1
3-butenyl chloride

B: 1190-22-3
1,3-dichlorobutane

C: 1790-22-3
1,2,4-trichlorobutane

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine In benzene Rate constant; Product distribution; Irradiation; other chlorinating agents;	A 10.3% B 6.2% C 19.1% D 34.4%

...Expand

: 594-11-6
methylcyclopropane

A: 927-73-1
3-butenyl chloride

B: 1190-22-3
1,3-dichlorobutane

C: 1790-22-3
1,2,4-trichlorobutane

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; Irradiation;	A 10.3% B 6.2% C 19.1% D 34.4%
With tert-butylhypochlorite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; for 2.5h; Irradiation;	A 17% B 3.2% C 6.5% D 24.2%

...Expand

: 2516-33-8
Cyclopropylmethanol

: 2919-23-5
cyclobutanol

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With phosphorus pentachloride
With hydrogenchloride

: 594-11-6
methylcyclopropane

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine Irradiation;
With chlorine at -196.1℃; Quantum yield; Irradiation; var. magnetic field;

: 1120-57-6
chlorocyclobutane

: 127-08-2
potassium acetate

: 64-19-7
acetic acid

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 100℃; Rate constant; Solvolyse und Isomerisierung;

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 107-05-1
3-chloroprop-1-ene

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
Cu catalyst

: 310447-99-5, 310448-01-2
3,4-dichlorobut-1-ene

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
(i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH; Multistep reaction;

: 56-23-5
tetrachloromethane

: 112057-32-6
tri(cyclopropylmethyl)phosphite

A: 927-73-1
3-butenyl chloride

B: 6554-31-0
Dicyclopropylcarbinyl-phosphonat

C: 27301-78-6
Phosphoric acid tricyclopropylmethyl ester

D: 112142-26-4
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester

E: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In toluene at 80℃; for 4h; Product distribution; Mechanism;	A 16 % Chromat. B 2 % Chromat. C 2 % Chromat. D 80 % Chromat. E 64 % Chromat.

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 927-73-1
3-butenyl chloride

B: 44611-46-3
allylcarbinyl ethyl ether

C: 1120-57-6
chlorocyclobutane

D: 70097-82-4
cyclobutyl ethyl ether

E: 70097-81-3
cyclopropylcarbinyl ethyl ether

F: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In ethanol; acetonitrile at 25℃; Thermodynamic data; Kinetics; Product distribution; Ea, effect of solvents;

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 44611-46-3
allylcarbinyl ethyl ether

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Further byproducts given;	A 1 % Chromat. B 22 % Chromat. C 28 % Chromat. D 42 % Chromat.

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 1120-57-6
chlorocyclobutane

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Further byproducts given;	A 5 % Chromat. B 22 % Chromat. C 28 % Chromat. D 42 % Chromat.

...Expand

: 157-33-5
bicyclo[1.1.0]butane

A: 1120-57-6
chlorocyclobutane

B: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With sodium hydroxide; sodium tetrahydroborate; mercury dichloride 1.) CH2Cl2, 20 deg C, 2.) 20 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

: 75637-38-6
cyclopropylcarbinol hypochlorite

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With triphenyl phosphite In dichloromethane at -78℃;	A 1.5 % Chromat. B 8.5 % Chromat. C 90 % Chromat.

...Expand

: 75637-39-7
cyclobutyl hypochlorite

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With triphenyl phosphite In dichloromethane at -78℃;	A 5 % Chromat. B 29 % Chromat. C 66 % Chromat.

...Expand

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In acetonitrile at 25℃;	A 7 % Chromat. B 15 % Chromat. C 78 % Chromat.
With tetrabutylammonium tetrafluoroborate In acetonitrile at 25℃;	A 9 % Chromat. B 27 % Chromat. C 64 % Chromat.
With tetrabutylammonium tetrafluoroborate In acetonitrile at 25℃;	A 9 % Chromat. B 27 % Chromat. C 64 % Chromat.

...Expand

: 594-11-6
methylcyclopropane

: 7782-50-5
chlorine

A: 927-73-1
3-butenyl chloride

B: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at -20℃;
at 50℃;

...Expand

: 7719-09-7
thionyl chloride

: 2516-33-8
Cyclopropylmethanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

...Expand

: 110-86-1
pyridine

: 7719-09-7
thionyl chloride

: 2516-33-8
Cyclopropylmethanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

...Expand

: 7719-09-7
thionyl chloride

: 2919-23-5
cyclobutanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

...Expand

: 110-86-1
pyridine

: 7719-09-7
thionyl chloride

: 2919-23-5
cyclobutanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

...Expand

: 64-17-5
ethanol

: cyclopropylmethoxychlorocarbene

A: 1120-57-6
chlorocyclobutane

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Product distribution; Further Variations:; Solvents;

...Expand

: 64-17-5
ethanol

: 364612-99-7
cyclobutoxychlorocarbene

A: 1120-57-6
chlorocyclobutane

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Product distribution; Further Variations:; Solvents;

...Expand

: cyclopropylmethoxychlorocarbene

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In acetonitrile at 25℃; Product distribution; Kinetics; Further Variations:; Solvents;
In 1,2-dichloro-ethane at 25℃; Kinetics;
In acetonitrile at 25℃; Product distribution; Further Variations:; Solvents;	A 10 % Chromat. B 19 % Chromat. C 71 % Chromat.

...Expand

: 364612-99-7
cyclobutoxychlorocarbene

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In 1,2-dichloro-ethane at 25℃; Kinetics;
In acetonitrile at 25℃; Product distribution; Kinetics; Further Variations:; Solvents;
In acetonitrile at 25℃; Product distribution; Further Variations:; Solvents;	A 10 % Chromat. B 35 % Chromat. C 55 % Chromat.

...Expand

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 110-56-5
1,4-dichlorobutane

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 365℃; Product distribution;	A 4.9 % Chromat. B 22.9 % Chromat. C 28.9 % Chromat. D 43.4 % Chromat.

...Expand

: 225668-16-6
5,6-bis(3-fluoro-4-methoxyphenyl)-2H-pyridazin-3-one

: 5911-08-0
chloro(cyclopropyl)methane

: 5,6-bis(3-fluoro-4-methoxyphenyl)-2-cyclopropylmethyl-2H-pyridazin-3-one

Conditions

Conditions	Yield
	100%

: 91060-92-3
1-(4-hydroxy-2,6-dimethylphenyl)ethanone

: 5911-08-0
chloro(cyclopropyl)methane

: 1439935-91-7
1-(4-(cyclopropylmethoxy)-2,6-dimethylphenyl)ethanone

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 80℃; for 16h; Inert atmosphere;	99%

: 767-00-0
4-cyanophenol

chloro(cyclopropyl)methane: chloro(cyclopropyl)methane

: 4-(cyclopropylmethoxy)benzonitrile

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide; potassium carbonate In N,N-dimethyl-formamide at 50℃; for 24h;	98%

: 22246-16-8
6-nitro-3,4-dihydro-1H-quinolin-2-one

: 5911-08-0
chloro(cyclopropyl)methane

: 1-(cyclopropylmethyl)-6-nitro-3,4-dihydroquinolin-2(1H)-one

Conditions

Conditions	Yield
Stage #1: 6-nitro-3,4-dihydro-1H-quinolin-2-one With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: chloro(cyclopropyl)methane With potassium iodide In N,N-dimethyl-formamide at 120℃; for 2h; Inert atmosphere;	94%
Stage #1: 6-nitro-3,4-dihydro-1H-quinolin-2-one With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: chloro(cyclopropyl)methane With potassium iodide In N,N-dimethyl-formamide at 120℃; for 2h;	94%
With potassium carbonate; potassium iodide In N,N-dimethyl-formamide at 120℃; for 2h; Inert atmosphere;	94%
Stage #1: 6-nitro-3,4-dihydro-1H-quinolin-2-one With potassium carbonate In N,N-dimethyl-formamide at 20℃; for 0.0833333h; Inert atmosphere; Stage #2: chloro(cyclopropyl)methane With potassium iodide In N,N-dimethyl-formamide at 120℃; Inert atmosphere;	94%

: 225668-09-7
5-(3-fluoro-4-methoxyphenyl)-6-(4-methoxyphenyl)-2H-pyridazin-3-one

: 5911-08-0
chloro(cyclopropyl)methane

: 2-cyclopropylmethyl-5-(3-fluoro-4-methoxyphenyl)-6-(4-methoxyphenyl)-2H-pyridazin-3-one

Conditions

Conditions	Yield
	93.8%

: 14648-14-7
N-norcodeine hydrochloride

: 5911-08-0
chloro(cyclopropyl)methane

: 77794-51-5
17-(cyclopropylmethyl)-7,8-didehydro-4,5α-epoxy-3-methoxymorphinan-6α-ol

Conditions

Conditions	Yield
With sodium hydrogencarbonate In N,N-dimethyl-formamide at 100℃; for 18h;	93%

: 225668-02-0
6-(3-fluoro-4-methoxyphenyl)-5-(4-methoxyphenyl)-2H-pyridazine-3-one

: 5911-08-0
chloro(cyclopropyl)methane

: 6-(3-fluoro-4-methoxyphenyl)-2-isobutyl-5-(4-methoxyphenyl)-2H-pyridazin-3-one

Conditions

Conditions	Yield
	93%

: 142529-02-0
11-oxo(10H)-pyrrolo<2,1-c><1,2,5>benzothiadiazepine 5,5-dioxide

: 5911-08-0
chloro(cyclopropyl)methane

: 9-Cyclopropylmethyl-4,4-dioxo-4,9-dihydro-4λ6-thia-3a,9-diaza-benzo[f]azulen-10-one

Conditions

Conditions	Yield
With potassium carbonate; potassium iodide In acetone for 24h; Ambient temperature;	90%

: 100-58-3
phenylmagnesium bromide

: 5911-08-0
chloro(cyclopropyl)methane

: 1667-00-1
benzylcyclopropane

Conditions

Conditions	Yield
With 1-Phenylprop-1-yne; copper dichloride In tetrahydrofuran at 70℃; for 12h;	90%

: 5911-08-0
chloro(cyclopropyl)methane

: 1070294-27-7
6-bromo-2-(2-cyclopropanemethyl)isoquinolin-1(2H)-one

Conditions

Conditions	Yield
With caesium carbonate In N,N-dimethyl-formamide at 50℃; for 3h;	90%

: 5911-08-0
chloro(cyclopropyl)methane

: 70768-88-6
5,6-bis(4-Methoxyphenyl)-4-ethoxy-carbonyl-2H-pyridazin-3-one

: 288586-95-8
5,6-bis(4-methoxyphenyl)-2-cyclopropylmethyl-4-ethoxycarbonyl-2H-pyridazin-3-one

Conditions

Conditions	Yield
	89.1%

: (1r,4r)-4-(tritylamino)cyclohexanol

: 5911-08-0
chloro(cyclopropyl)methane

: C29H33NO

Conditions

Conditions	Yield
Stage #1: (1r,4r)-4-(tritylamino)cyclohexanol With sodium hydride In tetrahydrofuran at 0℃; for 1h; Stage #2: chloro(cyclopropyl)methane In tetrahydrofuran at 20℃; for 6h;	86.4%

: 5911-08-0
chloro(cyclopropyl)methane

: (-)-3,14β-dimethoxy-4,5-α-epoxy-5β-methylmorphinan-6-one hydrochloride

: 159022-20-5
(-)-17-(cyclopropylmethyl)-3,14β-dimethoxy-4,5-α-epoxy-5β-methylmorphinan-6-one

Conditions

Conditions	Yield
With potassium carbonate In N,N-dimethyl-formamide at 100℃; for 22h;	86%

: 5911-08-0
chloro(cyclopropyl)methane

: 209808-01-5
AR-M390

: 4-[(1-cyclopropylmethyl-piperidin-4-ylidene)-phenyl-methyl]-N,N-diethyl-benzamide

Conditions

Conditions	Yield
With potassium carbonate In acetonitrile at 25℃; for 0.5h;	86%

: 2516-33-8
Cyclopropylmethanol

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With phenylphosphorus tetrachloride In chloroform at 0℃; for 0.0833333h;	98%
With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine at 0 - 20℃; for 3.25h;	95%
With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at -10 - 25℃; for 5h; Solvent; Temperature;	94%

: 56-23-5
tetrachloromethane

: 112057-32-6
tri(cyclopropylmethyl)phosphite

A: 927-73-1
3-butenyl chloride

B: 27301-78-6
Phosphoric acid tricyclopropylmethyl ester

C: 112142-26-4
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In toluene at 80℃; Further byproducts given;	A 16% B 2% C 80% D 64%

...Expand

: 2516-33-8
Cyclopropylmethanol

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
	A 15% B 18% C 80%

...Expand

: 2154-76-9
cyclopropylmethyl

A: 927-73-1
3-butenyl chloride

B: 1190-22-3
1,3-dichlorobutane

C: 1790-22-3
1,2,4-trichlorobutane

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine In benzene Rate constant; Product distribution; Irradiation; other chlorinating agents;	A 10.3% B 6.2% C 19.1% D 34.4%

...Expand

: 594-11-6
methylcyclopropane

A: 927-73-1
3-butenyl chloride

B: 1190-22-3
1,3-dichlorobutane

C: 1790-22-3
1,2,4-trichlorobutane

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; Irradiation;	A 10.3% B 6.2% C 19.1% D 34.4%
With tert-butylhypochlorite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; for 2.5h; Irradiation;	A 17% B 3.2% C 6.5% D 24.2%

...Expand

: 2516-33-8
Cyclopropylmethanol

: 2919-23-5
cyclobutanol

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With phosphorus pentachloride
With hydrogenchloride

: 594-11-6
methylcyclopropane

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With chlorine Irradiation;
With chlorine at -196.1℃; Quantum yield; Irradiation; var. magnetic field;

: 1120-57-6
chlorocyclobutane

: 127-08-2
potassium acetate

: 64-19-7
acetic acid

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 100℃; Rate constant; Solvolyse und Isomerisierung;

...Expand

: 186581-53-3, 908094-01-9
diazomethane

: 107-05-1
3-chloroprop-1-ene

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
Cu catalyst

: 310447-99-5, 310448-01-2
3,4-dichlorobut-1-ene

: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
(i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH; Multistep reaction;

: 56-23-5
tetrachloromethane

: 112057-32-6
tri(cyclopropylmethyl)phosphite

A: 927-73-1
3-butenyl chloride

B: 6554-31-0
Dicyclopropylcarbinyl-phosphonat

C: 27301-78-6
Phosphoric acid tricyclopropylmethyl ester

D: 112142-26-4
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester

E: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In toluene at 80℃; for 4h; Product distribution; Mechanism;	A 16 % Chromat. B 2 % Chromat. C 2 % Chromat. D 80 % Chromat. E 64 % Chromat.

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 927-73-1
3-butenyl chloride

B: 44611-46-3
allylcarbinyl ethyl ether

C: 1120-57-6
chlorocyclobutane

D: 70097-82-4
cyclobutyl ethyl ether

E: 70097-81-3
cyclopropylcarbinyl ethyl ether

F: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In ethanol; acetonitrile at 25℃; Thermodynamic data; Kinetics; Product distribution; Ea, effect of solvents;

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 44611-46-3
allylcarbinyl ethyl ether

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Further byproducts given;	A 1 % Chromat. B 22 % Chromat. C 28 % Chromat. D 42 % Chromat.

...Expand

: 64-17-5
ethanol

: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 1120-57-6
chlorocyclobutane

B: 70097-82-4
cyclobutyl ethyl ether

C: 70097-81-3
cyclopropylcarbinyl ethyl ether

D: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
at 25℃; Further byproducts given;	A 5 % Chromat. B 22 % Chromat. C 28 % Chromat. D 42 % Chromat.

...Expand

: 157-33-5
bicyclo[1.1.0]butane

A: 1120-57-6
chlorocyclobutane

B: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With sodium hydroxide; sodium tetrahydroborate; mercury dichloride 1.) CH2Cl2, 20 deg C, 2.) 20 deg C; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;

: 75637-38-6
cyclopropylcarbinol hypochlorite

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With triphenyl phosphite In dichloromethane at -78℃;	A 1.5 % Chromat. B 8.5 % Chromat. C 90 % Chromat.

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: 75637-39-7
cyclobutyl hypochlorite

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
With triphenyl phosphite In dichloromethane at -78℃;	A 5 % Chromat. B 29 % Chromat. C 66 % Chromat.

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: 122651-94-9
3-cyclopropylmethoxy-3-chlorodiaziridine

A: 927-73-1
3-butenyl chloride

B: 1120-57-6
chlorocyclobutane

C: 5911-08-0
chloro(cyclopropyl)methane

Conditions

Conditions	Yield
In acetonitrile at 25℃;	A 7 % Chromat. B 15 % Chromat. C 78 % Chromat.
With tetrabutylammonium tetrafluoroborate In acetonitrile at 25℃;	A 9 % Chromat. B 27 % Chromat. C 64 % Chromat.
With tetrabutylammonium tetrafluoroborate In acetonitrile at 25℃;	A 9 % Chromat. B 27 % Chromat. C 64 % Chromat.

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Cylopropylmethyl chloride Chemical Properties

IUPAC Name:chloromethylcyclopropane
Molecular Formula:C₄H₇Cl
Molecular Weight:90.551380 g/mol
Appearance:colorless liquid
Melting Point:-91°C
Boiling Point:87-89 °C(lit.)
Flash Point:29 °F
Water Solubility:1165 mg/L at 25 °C
Density:0.98 g/mL at 25 °C(lit.)
Refractive index:n20/D 1.435(lit.)
BRN:635697
EINECS:227-632-1
Synonyms of Cylopropylmethyl chloride(5911-08-0):
CYCLOPROPYLMETHYL CHLORIDE;(CHLOROMETHYL)CYCLOPROPANE;Cyclopropane, (chloromethyl)-;Cyclopropane,(chloromethyl);Cylopropylmethylchloride;Cyclopropylmethychloride;Cyclopropylmethyl Chloride, Pract.;CPMCl
Categories of Cylopropylmethyl chloride(5911-08-0):
Cycloalkanes;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks

Cylopropylmethyl chloride Safety Profile

Safety Information of Cylopropylmethyl chloride(5911-08-0):
Hazard Codes:F

,Xi

Risk Statements:11-36/37/38
11:Highly Flammable
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:16-26-36/37/39
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
RIDADR:UN 1993 3/PG 2
WGK Germany:3
HazardClass:3
PackingGroup:II
HS Code:29035990

Cylopropylmethyl chloride Specification

First Aid Measures of Cylopropylmethyl chloride(5911-08-0):
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Storage of Cylopropylmethyl chloride(5911-08-0):
Keep away from heat, sparks, and flame. Flammables-area.

Product Name

Cylopropylmethyl chloride

Synthetic route

Cylopropylmethyl chloride Chemical Properties

Cylopropylmethyl chloride Safety Profile

Cylopropylmethyl chloride Specification

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