Di-tert-butyl peroxide supplier

Name
Di-tert-butyl peroxide
EINECS 203-733-6
CAS No. 110-05-4
Article Data64
CAS DataBase
Density 0.796 g/cm³
Solubility immiscible with water
Melting Point -30 °C
Formula C₈H₁₈O₂
Boiling Point 111 °C at 760 mmHg
Molecular Weight 146.23
Flash Point 29.7 °C
Transport Information UN 3107
Appearance colourless liquid
Safety 14-16-3/7-36/37/39-14A
Risk Codes 7-11
Molecular Structure
Hazard Symbols O,F
Synonyms tert-Butyl peroxide;Bis(tert-butyl) peroxide;Perossido di butile terziario;Peroxyde de butyle tertiaire;Cadox;Peroximon DB;Cadox TBP;Trigonox B;Di-tert-butylperoxid;Peroxide, bis (1, 1-dimethylethyl);Di tert butyl peroxide;Di-tert-butyl peroxyde;2-methyl-2-tert-butylperoxy-propane;Di-tert-Butyl hydroperoxide;Peroxide,bis(1,1-dimethylethyl);DTBP;Ditert-butyl Peroxide;Di-(tert.butyl)-peroxide;tert-Butylperoxide;sell: Di-tert-butyl peroxide;Initiating agent A;Di-tertbutylperoxide;Initiator C DTBP;
PSA 18.46000
LogP 2.53160

Synthetic route

: 75-64-9
tert-butylamine

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
Stage #1: tert-butylamine With potassium sulfate; aluminum isopropoxide at 10℃; for 2h; Stage #2: With nickel(II) fluoride for 4h; Temperature; Concentration;	98.2%

: 75-65-0
tert-butyl alcohol

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide at 35 - 45℃; for 2h;	96%
With dihydrogen peroxide In Petroleum ether at 70 - 80℃; for 4h; Reagent/catalyst; Temperature;	95.3%
With sulfuric acid; dihydrogen peroxide at 29 - 39℃; for 2h; Cooling;
With dihydrogen peroxide at 60℃; Temperature; Large scale;

: 75-91-2
tert.-butylhydroperoxide

: 32133-82-7
Martins sulfurane

A: 110-05-4
di-tert-butyl peroxide

B: 139-66-2
diphenyl sulfide

C: 945-51-7
1,1'-sulfinylbisbenzene

D: 127-63-9
diphenyl sulphone

E: 718-64-9
1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

F: 115-11-7
isobutene

Conditions

Conditions	Yield
With 2,2-diphenyl-1-picrylhydrazine In chloroform-d1 at -78℃; Product distribution; chemiluminescence, other peroxides;	A n/a B 2% C 94% D 2% E n/a F n/a

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 98946-18-0
tert-Butyl 2,2,2-trichloroacetimidate

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In pentane 1.) -5 deg C, 15 min, 2.) up to r.t.;	63%

: 75-91-2
tert.-butylhydroperoxide

: 17011-26-6
tert-butyl hydrogen sulfate

: 110-05-4
di-tert-butyl peroxide

: 75-91-2
tert.-butylhydroperoxide

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With sulfuric acid

: 17011-26-6
tert-butyl hydrogen sulfate

A: 75-91-2
tert.-butylhydroperoxide

B: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide at 0℃;
With dihydrogen peroxide In water at 25℃; for 7.91667h; Temperature;	A 65.94 %Chromat. B 23.92 %Chromat.

: 17011-26-6
tert-butyl hydrogen sulfate

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With sulfuric acid; dihydrogen peroxide

: 75-28-5
Isobutane

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With hydrogen bromide; oxygen at 158℃;
With hydrogen bromide; oxygen at 158℃;

: 75-65-0
tert-butyl alcohol

A: 75-91-2
tert.-butylhydroperoxide

B: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With dihydrogen peroxide; acid
With sulfuric acid; water; dihydrogen peroxide

: 75-91-2
tert.-butylhydroperoxide

A: 67-56-1
methanol

B: 110-05-4
di-tert-butyl peroxide

C: 67-64-1
acetone

D: 115-11-7
isobutene

Conditions

Conditions	Yield
With antimonypentachloride In acetonitrile at 52℃; Product distribution; Thermodynamic data; other time, other reagents, activation energy of total decomposition and of homolysis;

...Expand

: 75-91-2
tert.-butylhydroperoxide

A: 34557-54-5
methane

B: 110-05-4
di-tert-butyl peroxide

C: 67-64-1
acetone

D: 115-11-7
isobutene

Conditions

Conditions	Yield
With perchloric acid; cyclohexanone In acetonitrile at 302℃; Rate constant; Mechanism; kinetic curves of decomposition; in presence of methyl ethyl ketone instead of cyclohexanone;

...Expand

: 75-91-2
tert.-butylhydroperoxide

A: 6163-66-2
2,2'-oxybis(2-methyl-propane)

B: 110-05-4
di-tert-butyl peroxide

C: 67-64-1
acetone

D: 115-11-7
isobutene

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With vanadia; silica gel In benzene at 60℃; for 2h; Rate constant; Mechanism; other metal catalysts;

...Expand

: 75-91-2
tert.-butylhydroperoxide

A: 110-05-4
di-tert-butyl peroxide

B: 67-64-1
acetone

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With dicobalt octacarbonyl In benzene at 6 - 8℃; for 0.5h; Product distribution; various amounts of Co2(CO)8, Fe(CO)5; various amounts of educt;	A 1 % Chromat. B 2 % Chromat. C 88 % Chromat.
With 3,5-di-tert-butyl-1,2-benzoquinone In toluene at 70℃; Reduction; addition;

...Expand

: 75-91-2
tert.-butylhydroperoxide

A: 110-05-4
di-tert-butyl peroxide

B: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
cobalt(II) phthalocyanine In various solvent(s) at 40℃; Rate constant; Product distribution; use of iron phthalocyanine, 20 deg C, effects of added various solvents;
With water; oxygen In chlorobenzene at 70℃; for 2h; Product distribution; Further Variations:; Reagents; Decomposition;

: 3965-63-7
tert-butylperoxytrimethylsilane

A: 75-91-2
tert.-butylhydroperoxide

B: 507-20-0
tertiary butyl chloride

C: 110-05-4
di-tert-butyl peroxide

D: 107-46-0
Hexamethyldisiloxane

E: 115-11-7
isobutene

F: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With phosphorus trichloride In nonane Kinetics; Mechanism; other solvent : butyl methacrylate;	A 0.56 (unit not given) B 0.04 (unit not given) C 0.11 (unit not given) D 0.46 (unit not given) E 0.09 (unit not given) F 0.04 (unit not given)

...Expand

: 927-83-3
di-t-butyldiazene

A: 67-56-1
methanol

B: 75-91-2
tert.-butylhydroperoxide

C: 110-05-4
di-tert-butyl peroxide

D: 67-64-1
acetone

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With oxygen at 59.9℃; Quantum yield; Mechanism; Irradiation; Other temperatures (298, 373 K), the effect of added t-butyl hydroperoxide.;

...Expand

: 3395-62-8
tert-butylperoxyl

A: 67-56-1
methanol

B: 50-00-0
formaldehyd

C: 51392-67-7
methyl tert-butyl peroxide

D: 110-05-4
di-tert-butyl peroxide

E: 67-64-1
acetone

F: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
In water at 19.9℃; Rate constant; Product distribution; Mechanism;	A 0.01 mmol B 0.37 mmol C 0.08 mmol D 0.08 mmol E 0.98 mmol F 0.56 mmol

...Expand

: 14976-54-6, 82554-97-0
di-tert-butoxydiazene

: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
In tert-butyl alcohol at 70℃; var solv.: c-C6D12 at 62.2 degC; cage effect determined;

: 14976-54-6, 82554-97-0
di-tert-butyl hyponitrite

A: 110-05-4
di-tert-butyl peroxide

B: 67-64-1
acetone

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With oxygen; sodium chloride; egg lecithin at 30℃; under 760 Torr; for 600h; Product distribution; other solvent, reagent, concentrations;

...Expand

: 52946-63-1
tert-Butyl-(tert-butylphenoxy)peracetat

A: 50-00-0
formaldehyd

B: 110-05-4
di-tert-butyl peroxide

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
In various solvent(s) at 40 - 60℃; Rate constant; Thermodynamic data; E(activ.) and preexponential factor;

...Expand

: 54156-75-1
2-tert-butylperoxy-2-methyl-propyl

A: 558-30-5
2-methyl-1,2-epoxypropane

B: 110-05-4
di-tert-butyl peroxide

Conditions

Conditions	Yield
With tri-n-butyl-tin hydride In benzene at 24.9℃; Rate constant; Irradiation;

: 54749-42-7
2,6-Di-tert-butyl-(N-tert-butylnitrono)phenoxyl

A: 110-05-4
di-tert-butyl peroxide

B: 67-64-1
acetone

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With tert.-butylhydroperoxide In benzene for 4h; Product distribution; Ambient temperature; other solvents: chlorbenzene, freone-1,1,3; other temperatures: 70 deg C for 30 min;

...Expand

: 75-91-2
tert.-butylhydroperoxide

A: 67-56-1
methanol

B: 110-05-4
di-tert-butyl peroxide

C: 67-64-1
acetone

D: 115-11-7
isobutene

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With aluminium trichloride In ethyl acetate at 69.9℃; Product distribution; Kinetics; Thermodynamic data; variation of temperature, further chlorides of elements of group III or IV;

...Expand

: 815-24-7
Di-t-butyl ketone

A: 594-82-1
tetramethyl-2,2,3,3 butane

B: 75-28-5
Isobutane

C: 110-05-4
di-tert-butyl peroxide

D: 115-11-7
isobutene

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With oxygen In decane at 323℃; Product distribution; Mechanism; Kinetics; Irradiation; other temperatures: 348, 373, 398 K;

...Expand

: 15464-01-4
azo-t-butane

A: 594-82-1
tetramethyl-2,2,3,3 butane

B: 75-28-5
Isobutane

C: 110-05-4
di-tert-butyl peroxide

D: 115-11-7
isobutene

E: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With oxygen In decane at 323℃; Product distribution; Mechanism; Kinetics; Irradiation; other temperatures: 298, 348 K;

...Expand

: 75-28-5
Isobutane

A: 110-05-4
di-tert-butyl peroxide

B: 67-64-1
acetone

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
With [5,10,15,20-tetrakis(heptafluoropropyl)porphinato]iron(II)-(3-fluoropyridine)2; oxygen In benzene at 80℃; under 6464.3 Torr; for 91h; Product distribution; Mechanism; other reagent: (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(II) bis(3-fluoropyridine) complex;	A 7.8 % Turnov. B 8.1 % Turnov. C 84 % Turnov.
With oxygen; [5,10,15,20-tetrakis(pentafluorophenyl)porphinato]iron(II)-(3-fluoropyridine)2 In benzene at 80℃; under 6464.3 Torr; for 20h; other catalyst: (5,10,15,20-tetrakis(heptafluoropropyl)porphyrinato)iron(II) bis(3-fluoropyridine) complex;	A 10.3 % Turnov. B 3.6 % Turnov. C 86 % Turnov.

...Expand

: 4444-61-5
di-tert-butylhydroperoxide

A: 110-05-4
di-tert-butyl peroxide

B: 67-64-1
acetone

C: 75-65-0
tert-butyl alcohol

Conditions

Conditions	Yield
In dichloromethane at -20.5 - 17℃; Kinetics; Mechanism; Rate constant;

...Expand

: 3141-58-0
tert-butoxy radical

A: 2229-07-4
methyl radical

B: 110-05-4
di-tert-butyl peroxide

C: 67-64-1
acetone

Conditions

Conditions	Yield
In tetrachloromethane at 295℃; Rate constant; other solvents, other temperature;

...Expand

: 7664-93-9
sulfuric acid

: 7722-84-1
dihydrogen peroxide

: 75-65-0
tert-butyl alcohol

A: 75-91-2
tert.-butylhydroperoxide

B: 110-05-4
di-tert-butyl peroxide

...Expand

: 110-05-4
di-tert-butyl peroxide

: 2C17H13Cl4N2(1-)*2Cu(1+)*C6H6

: 1215209-38-3
[Cl2NN]Cu-OtBu

Conditions

Conditions	Yield
With pyridine In fluorobenzene at 10℃; Kinetics; Temperature; Concentration;	100%

: 110-05-4
di-tert-butyl peroxide

: 20427-59-2
copper hydroxide

: copper(II) oxide

Conditions

Conditions	Yield
Stage #1: di-tert-butyl peroxide; copper hydroxide In water at 60℃; for 0.5h; Inert atmosphere; Stage #2: In water for 5h; Sonication; Inert atmosphere;	100%

: 110-05-4
di-tert-butyl peroxide

: 932-01-4
4,4-dimethyl-cyclohexanol

: 140-88-5
ethyl acrylate

: 96517-19-0
8,8-dimethyl-1-oxa-spiro[4.5]decan-2-one

Conditions

Conditions	Yield
Stage #1: di-tert-butyl peroxide; 4,4-dimethyl-cyclohexanol; ethyl acrylate at 50 - 160℃; for 4.16667h; Stage #2: With sodium hydroxide; water In tert-butyl methyl ether at 40℃; Stage #3: With sulfuric acid In tert-butyl methyl ether; water pH=1;	96.3%

...Expand

: 546-68-9
titanium(IV) isopropylate

aqueous 3N-K2 CO3: aqueous 3N-K2 CO3

: 110-05-4
di-tert-butyl peroxide

: 220038-45-9
DIPT

: 7732-18-5
water

: 150-86-7
phytol

: (2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

Conditions

Conditions	Yield
silica gel In diethyl ether; dichloromethane	95%

...Expand

: 110-05-4
di-tert-butyl peroxide

: 118-91-2
ortho-chlorobenzoic acid

: 610-96-8
methyl chlorobenzoate

Conditions

Conditions	Yield
With copper(l) chloride In chlorobenzene at 130℃; for 12h; Schlenk technique; Inert atmosphere;	95%

: 110-05-4
di-tert-butyl peroxide

: 123-11-5
4-methoxy-benzaldehyde

: 833-79-4
t-butyl 4-methoxybenzoate

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;	95%

: 109-99-9
tetrahydrofuran

: 110-05-4
di-tert-butyl peroxide

: 30806-83-8
p-ethoxycarbonylphenyl isocyanate

: ethyl 4-((tert-butoxycarbonyl)(tetrahydrofuran-2-yl)amino)benzoate

Conditions

Conditions	Yield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;	95%

...Expand

: 110-05-4
di-tert-butyl peroxide

: 57139-25-0
N-methoxy-2-methylbenzamide

: C13H17NO2

Conditions

Conditions	Yield
With palladium diacetate; trifluoroacetic acid In cyclohexane at 100℃; for 0.5h;	94%

: 109-99-9
tetrahydrofuran

: 110-05-4
di-tert-butyl peroxide

: 1548-13-6
p-trifluoromethyl-phenylisocyanate

: tert-butyl (tetrahydrofuran-2-yl)(4-(trifluoromethyl)phenyl)carbamate

Conditions

Conditions	Yield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;	94%

...Expand

: 110-05-4
di-tert-butyl peroxide

: 10031-82-0
4-ethoxybenzaldehyde

: 1409654-77-8
C13H18O3

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;	93%

: 110-05-4
di-tert-butyl peroxide

: 873-55-2
sodium benzenesulfonate

: 3112-85-4
Methyl phenyl sulfone

Conditions

Conditions	Yield
In water at 100℃; for 12h; Sealed tube;	93%
With water at 110℃; for 12h; Temperature; Sealed tube; Green chemistry;	93%

: 110-05-4
di-tert-butyl peroxide

: 372521-42-1
[(C5HiPr4)Sm(μ-I)(THF)2]2

: 372521-43-2
(C5HiPr4)SmIOtBu(THF)

Conditions

Conditions	Yield
In toluene Sm-complex and ligand were loaded in flask, toluene was condensed at -20°C, stirred for 10 min at room temp.; toluene was removed;	92%

: 110-05-4
di-tert-butyl peroxide

: 120-14-9
3,4-dimethoxy-benzaldehyde

: 3,4-dimethoxybenzoic acid t-butyl ester

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;	92%

: 110-05-4
di-tert-butyl peroxide

: 6462-50-6
sodium 4-methoxybenzenesulfinate

: 3517-90-6
p-anisyl methyl sulfone

Conditions

Conditions	Yield
In water at 80℃; for 12h; Sealed tube;	92%
With water at 110℃; for 12h; Sealed tube; Green chemistry;	92%

: 110-05-4
di-tert-butyl peroxide

: 34176-08-4
sodium 4-bromobenzenesulfinate

: 3466-32-8
4-bromoohenyl methyl sulfone

Conditions

Conditions	Yield
With water at 110℃; for 12h; Sealed tube; Green chemistry;	92%

: 110-05-4
di-tert-butyl peroxide

: sodium 4-iodobenzenesulfinate

: 64984-08-3
1-iodo-4-(methylsulfonyl)benzene

Conditions

Conditions	Yield
With water at 110℃; for 12h; Sealed tube; Green chemistry;	92%

: 109-99-9
tetrahydrofuran

: 110-05-4
di-tert-butyl peroxide

: 49647-20-3
4-acetylphenyl isocyanate

: tert-butyl (4-acetylphenyl)(tetrahydrofuran-2-yl)carbamate

Conditions

Conditions	Yield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;	92%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 110-05-4
di-tert-butyl peroxide

: 66-99-9
β-naphthaldehyde

: 34304-74-0
tert-butyl naphthalene-2-carboperoxoate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;	92%

...Expand

: 110-05-4
di-tert-butyl peroxide

: 39515-51-0
3-Phenoxybenzaldehyde

: 98992-33-7
C17H18O3

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;	91%

: 75-91-2
tert.-butylhydroperoxide

: 110-05-4
di-tert-butyl peroxide

: 86-81-7
3,4,5-trimethoxy-benzaldehyde

: tert-butyl 3,4,5-trimethoxybenzoperoxoate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;	91%

...Expand

: 75-91-2
tert.-butylhydroperoxide

: 110-05-4
di-tert-butyl peroxide

: 3453-33-6
6-methoxynaphthalene-2-carbaldehyde

: tert-butyl 6-methoxy-naphthalene-2-carboparoxoate

Conditions

Conditions	Yield
With tetra-(n-butyl)ammonium iodide In water for 2h; Irradiation; Green chemistry;	91%

...Expand

: 110-05-4
di-tert-butyl peroxide

: 104-87-0
4-methyl-benzaldehyde

: 13756-42-8
tert-butyl 4-methylbenzoate

Conditions

Conditions	Yield
With copper(I) bromide In hexane at 50℃; for 5h; Inert atmosphere;	90%

: 110-05-4
di-tert-butyl peroxide

: 1356668-56-8
N-phenyl-N-tosylmethacrylamide

: 2-methyl-N-phenyl-2-(p-tolyl)butanamide

Conditions

Conditions	Yield
With iron(III) sulfate In fluorobenzene at 115℃; for 8h; Reagent/catalyst; Solvent; Temperature; Inert atmosphere; Sealed tube;	90%

: 110-05-4
di-tert-butyl peroxide

: 14752-66-0
sodium p-chlorobenzenesulphinate

: 98-57-7
4-chlorophenyl methyl sulfone

Conditions

Conditions	Yield
In water at 100℃; for 12h; Sealed tube;	90%
With water at 110℃; for 12h; Sealed tube; Green chemistry;	90%

: 110-05-4
di-tert-butyl peroxide

: 15898-38-1
sodium 3-methylbenzenesulfinate

: 10355-06-3
methyl 3-methylphenyl sulfone

Conditions

Conditions	Yield
With water at 110℃; for 12h; Sealed tube; Green chemistry;	90%

: 109-99-9
tetrahydrofuran

: 110-05-4
di-tert-butyl peroxide

: 34893-92-0
3,4-dichlorophenyl isocyanate

: tert-butyl (3,5-dichlorophenyl)(tetrahydrofuran-2-yl)carbamate

Conditions

Conditions	Yield
With copper(l) chloride at 130℃; for 12h; Inert atmosphere; Schlenk technique; Glovebox;	90%

...Expand

: 109-99-9
tetrahydrofuran

: 110-05-4
di-tert-butyl peroxide

: 621-29-4
3-tolyl isocyanate

: tert-butyl (tetrahydrofuran-2-yl)(m-tolyl)carbamate

Conditions

Conditions	Yield
With copper(l) chloride at 130℃; for 12h; Catalytic behavior; Reagent/catalyst; Temperature; Inert atmosphere; Schlenk technique; Glovebox;	90%

...Expand

Di-tert-butyl peroxide Consensus Reports

Reported in EPA ISCA Inventory

Di-tert-butyl peroxide Standards and Recommendations

DFG MAK: Mild skin irritant

Di-tert-butyl peroxide Specification

The IUPAC name of tert-Butyl peroxide is 2-tert-butylperoxy-2-methylpropane. With the CAS registry number 110-05-4, it is also named as Bis(1,1-dimethylethyl)peroxide. The product's categories are Organics; Organic Peroxide; Oxidation; Synthetic Organic Chemistry. It is colourless liquid which is miscible with benzene, petroleum ether and other organic solvents, and immiscible with water. This chemical may decompose explosively if heated, subjected to shock, or treated with reducing agents. When heated to decomposition it emits acrid smoke and fumes. Additionally, it should be sealed in the container and stored in cool, ventilate and dry place.

The other characteristics of this product can be summarized as: (1)ACD/LogP: 3.19; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.19; (4)ACD/LogD (pH 7.4): 3.19; (5)ACD/BCF (pH 5.5): 157.44; (6)ACD/BCF (pH 7.4): 157.44; (7)ACD/KOC (pH 5.5): 1301.07; (8)ACD/KOC (pH 7.4): 1301.07; (9)#H bond acceptors: 2; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 3; (12)Index of Refraction: 1.405; (13)Molar Refractivity: 42.53 cm³; (14)Molar Volume: 173.4 cm³; (15)Surface Tension: 23 dyne/cm; (16)Enthalpy of Vaporization: 33.52 kJ/mol; (17)Vapour Pressure: 27.3 mmHg at 25°C; (18)Rotatable Bond Count: 3; (19)Exact Mass: 146.13068; (20)MonoIsotopic Mass: 146.13068; (21)Topological Polar Surface Area: 18.5; (22)Heavy Atom Count: 10; (23)Complexity: 80.8.

Preparation of tert-Butyl peroxide: It can be obtained by the reaction of tertiary butanol and hydrogen peroxide in concentrated sulfuric acid.

Uses of tert-Butyl peroxide: It is widely used as crosslinking agent of unsaturated polyester resins and silicone rubber, polymerization initiator of monomer, polypropylene modifiers, vulcanization agent. It also can react with 2-piperidino-acrylonitrile to get 2,3-bis-tert-butoxymethyl-2,3-di-piperidin-1-yl-succinonitrile. This reaction needs solvent benzene at temperature of 20 °C. The yield is 64%.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and may cause fire, so people should keep it away from sources of ignition. If you want to contact this product, you must ear suitable protective clothing, gloves and eye/face protection.

People can use the following data to convert to the molecule structure.
1. SMILES:O(OC(C)(C)C)C(C)(C)C
2. InChI:InChI=1/C8H18O2/c1-7(2,3)9-10-8(4,5)6/h1-6H3

The following are the toxicity data which has been tested.

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	> 4103ppm/4H (4103ppm)	BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: DYSPNEA	American Industrial Hygiene Association Journal. Vol. 19, Pg. 205, 1958.
mouse	LD50	oral	4572mg/kg (4572mg/kg)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 43, 1982.
rat	LC50	inhalation	> 4100ppm/4H (4100ppm)		ARCO Chemical Company Report. Vol. JUN1982,
rat	LD50	intraperitoneal	3210mg/kg (3210mg/kg)	BEHAVIORAL: MUSCLE WEAKNESS BEHAVIORAL: ATAXIA	American Industrial Hygiene Association Journal. Vol. 19, Pg. 205, 1958.
rat	LD50	oral	> 25gm/kg (25000mg/kg)		ARCO Chemical Company Report. Vol. JUN1982,

Product Name

Di-tert-butyl peroxide

Synthetic route

Di-tert-butyl peroxide Consensus Reports

Di-tert-butyl peroxide Standards and Recommendations

Di-tert-butyl peroxide Specification

Related Products

Hot Products