1,1-Dichloroethylene
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
Conditions | Yield |
---|---|
With hydrogen fluoride; SbCl5 on Carbon at 100℃; under 760.051 Torr; for 0.00277778h; | A 80% B n/a C n/a |
Conditions | Yield |
---|---|
With hydrogen fluoride at 150℃; unter Druck; | |
With antimony(III) fluoride at 150℃; unter Druck; | |
With antimony dichloride trifluoride; antimony(III) fluoride anfangs unter Kuehlung mit Eis; |
Conditions | Yield |
---|---|
With hydrogen fluoride at 65℃; | |
With hydrogen fluoride; tin(IV) chloride | |
With hydrogen fluoride Heating; | |
With hydrogen fluoride |
1,1,1-trichloroethane
A
4-chloro-6-methyl-2H-pyran-2-one
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
D
1,1-Dichloroethylene
E
3,5-dichlorophenol
Conditions | Yield |
---|---|
With sulfuric acid; hydrogen fluoride; antimonypentachloride | A 1.19 g B n/a C n/a D n/a E 0.20 g F 0.08 g |
1,1,1-trichloroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
D
1,1-Dichloroethylene
Conditions | Yield |
---|---|
With fluorinated (with SF4) γ-alumina; hydrogen fluoride for 2h; Product distribution; Ambient temperature; | |
With hydrogen fluoride; antimonypentachloride at 60℃; under 7500.6 Torr; Mechanism; var. reaction partners and temp.; | |
With chromium(III) oxide; sulfur tetrafluoride; hydrogen fluoride at 20℃; for 2h; Product distribution; Further Variations:; Reagents; |
1,1,1-trichloroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
D
Vinylidene fluoride
Conditions | Yield |
---|---|
With fluorinated Fe3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With fluorinated Co3O4 for 2h; Ambient temperature; Yields of byproduct given. Title compound not separated from byproducts; |
1,1-Dichloroethylene
A
1,1,1-Trichloro-2,2,2-trifluoroethane
B
2,2,2-trifluoroethanol
C
1-Chloro-1,1-difluoroethane
D
HCFC-141b
Conditions | Yield |
---|---|
With fluorinated Co3O4 for 2h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; |
1,1-Dichloroethylene
A
1,1,1-Trichloro-2,2,2-trifluoroethane
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
D
1,1,2-Trichloro-1,2,2-trifluoroethane
Conditions | Yield |
---|---|
With fluorinated Co3O4 for 2h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; |
1,1-Dichloroethylene
A
1-Chloro-1,1-difluoroethane
B
HCFC-141b
C
chlorotrifluoromethane
D
1,2-dichloro-1,1-difluoroethane
Conditions | Yield |
---|---|
With fluorinated Fe3O4 for 2h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; |
1,1-Dichloroethylene
A
1-Chloro-1,1-difluoroethane
B
HCFC-141b
C
1,2-dichloro-1,1-difluoroethane
D
1,1,2-Trichloro-1,2,2-trifluoroethane
Conditions | Yield |
---|---|
With fluorinated Fe3O4 for 2h; Ambient temperature; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; |
1,1,3,3-tetrachloro-1,3-difluoro-2-propanone
acetone
A
Dichlorofluoromethane
B
HCFC-141b
C
trichlorofluoromethane
D
1-chloro-1-fluoroethane
E
1,1-Dichloroethylene
F
CFC-112a
Conditions | Yield |
---|---|
With propene; sulphur hexafluoride for 0.5h; Rate constant; Ambient temperature; Irradiation; also with acetone-d6; |
1,1,1-trichloroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
D
chlorotrifluoromethane
E
1,1-Dichloroethylene
Conditions | Yield |
---|---|
With fluorinated indium(III) oxide Product distribution; Ambient temperature; further reagent: fluorinated gallium(III) oxide; |
1,1-Dichloroethylene
A
1-Chloro-1,1-difluoroethane
B
HCFC-141b
C
chlorotrifluoromethane
Conditions | Yield |
---|---|
With fluorinated gallium(III) oxide Product distribution; Ambient temperature; |
1,1,2-Trichloro-1,2,2-trifluoroethane
A
1,1,1-Trichloro-2,2,2-trifluoroethane
B
HCFC-141b
C
chlorotrifluoromethane
Conditions | Yield |
---|---|
With fluorinated gallium(III) oxide Product distribution; Ambient temperature; further reagent: fluorinated indium(III) oxide; |
1,1,1-trichloroethane
hydrogen fluoride
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
1,1,1-trichloroethane
hydrogen fluoride
antimonypentachloride
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
1,1,1-trichloroethane
antimony(III) fluoride
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
1,1,1-trichloroethane
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
HCFC-141b
1,1-Dichloroethylene
A
1-Chloro-1,1-difluoroethane
B
HCFC-141b
C
1,1,1-trichloroethane
Conditions | Yield |
---|---|
at 65℃; unter Druck; |
dichloromethane
A
pentaerythrityl tetrachloride
B
Isobutane
C
1-Chloro-1,1-difluoroethane
D
HCFC-141b
E
1,2-dichloro-1,1-difluoroethane
F
pentachloroethane
Conditions | Yield |
---|---|
With fluorinated gallium(III) oxide Product distribution; Mechanism; Ambient temperature; |
Conditions | Yield |
---|---|
With HF; TiCl4 In sulfolane; hydrogenchloride; polyethylene | |
With HF; TiCl4 In sulfolane; hydrogenchloride; polyethylene |
Conditions | Yield |
---|---|
With HF |
Conditions | Yield |
---|---|
With hydrogen fluoride In carbon dioxide |
Conditions | Yield |
---|---|
at 200℃; for 2h; Conversion of starting material; | 82% |
Conditions | Yield |
---|---|
With tris[(2-pyridylmethyl)amine]; copper(l) chloride In N,N-dimethyl-formamide at 130℃; for 14h; | 46% |
HCFC-141b
A
1-fluoroethane
B
chloroethane
C
1-chloro-1-fluoroethane
Conditions | Yield |
---|---|
With hydrogen; platinum on activated charcoal at 200℃; | A 45% B 21% C 31% |
Conditions | Yield |
---|---|
With tris[(2-pyridylmethyl)amine]; copper(l) chloride In N,N-dimethyl-formamide at 130℃; for 14h; | 45% |
Conditions | Yield |
---|---|
With tris[(2-pyridylmethyl)amine]; copper(l) chloride In N,N-dimethyl-formamide at 130℃; for 14h; | 17% |
Conditions | Yield |
---|---|
With tris[(2-pyridylmethyl)amine]; copper(l) chloride In N,N-dimethyl-formamide at 130℃; for 14h; | 15% |
HCFC-141b
1,1-Dichlorethanphosphonsaeuredichlorid
Conditions | Yield |
---|---|
With aluminium trichloride; phosphorus trichloride Behandeln des Reaktionsgemisches mit Wasser und Dichlormethan bei -20grad; |
HCFC-141b
Conditions | Yield |
---|---|
With hydroxyl Kinetics; flash-photolysis - laser-induced fluorescence; | |
With hydroxide In gaseous matrix at -23.1 - 23.9℃; under 0.06 - 0.2 Torr; Kinetics; | |
With hydroxide at 19.9℃; under 37.5 Torr; Rate constant; Thermodynamic data; ΔHR; | |
With tetrachloromethane at 24.85℃; under 40 Torr; Kinetics; Further Variations:; Temperatures; radical reaction; Photolysis; |
HCFC-141b
N-tert-butyl-α-phenylnitrone
A
benzoyl-tert-butylnitroxyl radical
B
C11H15ClNO
Conditions | Yield |
---|---|
Irradiation; Title compound not separated from byproducts; |
Conditions | Yield |
---|---|
With oxygen at -20.1 - 47.9℃; under 4 - 60 Torr; Kinetics; Mechanism; Irradiation; UV flash photolysis; formation of chloro and peroxyradicals was detected by time-resolved MS; |
HCFC-141b
A
2,2,2-trifluoroethanol
B
1-Chloro-1,1-difluoroethane
C
1-chloro-1-fluoroethane
D
1,1-Dichloroethylene
E
acetic acid
Conditions | Yield |
---|---|
fluorinated γ-alumina at 300℃; Product distribution; other temperatures; also with HCl or HF as reagents; |
Conditions | Yield |
---|---|
With hydrogen fluoride Heating; |
HCFC-141b
A
formaldehyd
B
fluorodichloromethyl
C
dichlorofluoroacetaldehyde
Conditions | Yield |
---|---|
With oxygen; nitrogen(II) oxide; chlorine at 19.9℃; under 37.5 Torr; Rate constant; Thermodynamic data; Product distribution; Irradiation; ΔHR, var. of ratios; |
HCFC-141b
Conditions | Yield |
---|---|
With air; hydrogen; ozone at 30℃; under 50 Torr; Rate constant; Irradiation; |
HCFC-141b
Conditions | Yield |
---|---|
With oxygen; chlorine; Nitrogen dioxide radical reaction; Photolysis; |
Molecular Formula: C2H3Cl2F
Molecular Weight: 116.95 g/mol
EINECS: 404-080-1
Index of Refraction: 1.386
Density: 1.302 g/cm3
Enthalpy of Vaporization: 26.88 kJ/mol
Boiling Point: 35.5 °C at 760 mmHg
Vapour Pressure: 522 mmHg at 25 °C
Melting point: -104 °C
Appearance: Colorless liquid
Structure of Dichlorofluoroethane (CAS NO.1717-00-6):
IUPAC Name: 1,1-Dichloro-1-fluoroethane
Product Category of Dichlorofluoroethane (CAS NO.1717-00-6): refrigerants
Dichlorofluoroethane (CAS NO.1717-00-6) has been used as cleaning agent and polyurethane foam.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LC50 | inhalation | 151gm/m3/2H (151000mg/m3) | BEHAVIORAL: GENERAL ANESTHETIC BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: CYANOSIS | Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 9(10), Pg. 37, 1965. |
rabbit | LD50 | skin | > 2gm/kg (2000mg/kg) | Food and Chemical Toxicology. Vol. 33, Pg. 483, 1995. | |
rat | LC50 | inhalation | 56700ppm/6H (56700ppm) | BEHAVIORAL: TREMOR BEHAVIORAL: ATAXIA | Food and Chemical Toxicology. Vol. 33, Pg. 483, 1995. |
rat | LD50 | oral | > 5gm/kg (5000mg/kg) | Food and Chemical Toxicology. Vol. 33, Pg. 483, 1995. | |
rat | LD50 | skin | > 2gm/kg (2000mg/kg) | LIVER: OTHER CHANGES | Food and Chemical Toxicology. Vol. 33, Pg. 483, 1995. |
Hazard Codes: Xi,N
Risk Statements: 59-52/53
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R59:Dangerous to the ozone layer.
Safety Statements: 23-36/37/39-61-59
S23:Do not breathe vapour.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S59:Refer to manufacturer / supplier for information on recovery / recycling.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
Dichlorofluoroethane , its cas register number is 1717-00-6. It also can be called Freon 141b ; and 1,1-Dichloro-1-fluoroethane .
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