Divinyl adipate supplier | CasNO.4074-90-2

Name
ADIPIC ACID DIVINYL ESTER
EINECS
CAS No. 4074-90-2
Article Data20
CAS DataBase
Density 1.039g/cm³
Solubility
Melting Point 28 °C
Formula C10H14 O4
Boiling Point 261.1°Cat760mmHg
Molecular Weight 198.219
Flash Point 122.2°C
Transport Information
Appearance
Safety Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Adipicacid, divinyl ester (6CI,7CI,8CI); Hexanedioic acid, diethenyl ester (9CI);Divinyl adipate; Divinyl hexanedioate
PSA 52.60000
LogP 1.92020

Synthetic route

: 108-05-4
vinyl acetate

: 124-04-9
Adipic acid

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With sulfuric acid; mercury(II) diacetate for 4h; Reflux; Inert atmosphere;	52%
With mercury(II) sulfate
With sulfuric acid; mercury(II) diacetate; copper diacetate at 70℃;
With mercury(II) sulfate

: 6213-94-1
trimethylsiloxyethene

: 111-50-2
Adipic acid dichloride

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With potassium fluoride; 18-crown-6 ether In acetonitrile at 40 - 50℃; for 20h; Inert atmosphere;	48%

: 124-04-9
Adipic acid

: 74-85-1
ethene

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With trihexyl(tetradecyl)phosphonium chloride; tetrabutyl-ammonium chloride; copper diacetate; tetrahexylammonium chloride; palladium; copper dichloride In 1,4-dioxane for 21h; Catalytic behavior; High pressure;	16%

: 75-07-0
acetaldehyde

: 111-50-2
Adipic acid dichloride

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With pyridine

: 124-04-9
Adipic acid

: 74-86-2
acetylene

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With chloroacetic acid; mercury(II) oxide at 80℃;
rhenium(I) pentacarbonyl chloride In toluene at 140℃; under 15001.5 Torr; for 6h; Product distribution / selectivity;	96 %Chromat.
rhenium In toluene at 160℃; under 15001.5 Torr; for 6h; Product distribution / selectivity;

: 124-04-9
Adipic acid

: 1119-20-6
divinylmercury

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
In xylene for 1h; Heating;

: 5130-24-5
Vinyl chloroformate

disodium adipate: disodium adipate

: 4074-90-2
divinyl adipate

: C22H26O6Se2

: 4074-90-2
divinyl adipate

Conditions

Conditions	Yield
With diisopropylamine In chloroform for 12h; Reflux;	0.15 g

: 4074-90-2
divinyl adipate

: 3034-38-6
1H-4(5)-nitroimidazole

: 1-(4-nitro-imidazol-1-yl)-ethyl vinyl adipate

Conditions

Conditions	Yield
With Thermomyces lanuginosus lipase; potassium carbonate In dimethyl sulfoxide at 50℃; for 0.5h; Flow reactor; Enzymatic reaction;	99%
With D-aminoacylase from Escherichia coli (EC 3.5.1.81) In dimethyl sulfoxide at 50℃; for 96h;	95%
In various solvent(s) at 50℃; for 60h; Markovnikov's addition;	94%

: 4074-90-2
divinyl adipate

: 36791-04-5
ribavirin

: Hexanedioic acid (2R,3S,4R,5R)-5-(3-carbamoyl-[1,2,4]triazol-1-yl)-3,4-dihydroxy-tetrahydro-furan-2-ylmethyl ester vinyl ester

Conditions

Conditions	Yield
With 1-methyl-1H-imidazole; lipase acrylic resin from Candida antartica In acetone at 50℃; for 4h;	96%
With [bmim]BF4; Candida antarctica lipase acrylic resin In acetone at 50℃; for 12h;	98.5 % Chromat.

: 4074-90-2
divinyl adipate

: 94-52-0
5-nitrobenzimidazole

: C17H19N3O6

Conditions

Conditions	Yield
With Thermomyces lanuginosus lipase; potassium carbonate In dimethyl sulfoxide at 50℃; for 0.5h; Flow reactor; Enzymatic reaction;	95%

: 2589-57-3
dimethyl 2,2'-azobis(isobutyrate)

: 4074-90-2
divinyl adipate

polymer; monomer(s): divinyl adipate, 0.3 mol/l; dimethyl 2,2\-azobis(isobutyrate), 0.01 mol/l: polymer; monomer(s): divinyl adipate, 0.3 mol/l; dimethyl 2,2\-azobis(isobutyrate), 0.01 mol/l

Conditions

Conditions	Yield
In benzene at 80℃; for 4h;	93%

: 4074-90-2
divinyl adipate

: 57-50-1
Sucrose

: sucrose-6-O-vinyl adipate

Conditions

Conditions	Yield
With thermomyces lanuginosus lipase immobilized on tetramethylorthosilicate and methyltrimethoxysilane (3:1 ratio) In N,N-dimethyl-formamide at 30 - 50℃; Molecular sieve; Enzymatic reaction; regioselective reaction;	92.8%

: 4074-90-2
divinyl adipate

: 696-23-1
2-methyl-4-nitro-1H-imidazole

: C14H19N3O6

Conditions

Conditions	Yield
With Thermomyces lanuginosus lipase; potassium carbonate In dimethyl sulfoxide at 50℃; for 0.5h; Flow reactor; Enzymatic reaction;	92%

: 2589-57-3
dimethyl 2,2'-azobis(isobutyrate)

: 4074-90-2
divinyl adipate

polymer, Mn 1.68E4 g/mol by GPC, Mw/Mn 13.0; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate): polymer, Mn 1.68E4 g/mol by GPC, Mw/Mn 13.0; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate)

Conditions

Conditions	Yield
In benzene at 80℃; for 4h;	87%

: 4074-90-2
divinyl adipate

: 497-76-7
arbutin

: 681212-47-5
6-O-vinyladipoyl arbutin

Conditions

Conditions	Yield
Streptomyces sp.-derived alkaline protease In pyridine at 30℃; for 96h; Product distribution / selectivity;	85%

: 4074-90-2
divinyl adipate

: 3459-18-5
4-nitrophenyl N-acetyl-β-D-glucosaminide

: 1261582-34-6
6-O-(p-nitrophenyl 2-acetamido-2-deoxy-β-D-glucopyranosyl) vinyl adipate

Conditions

Conditions	Yield
With lipase from Candida antarctica In acetone at 45℃; for 12h; Molecular sieve; Enzymatic reaction; regioselective reaction;	83%

: 4074-90-2
divinyl adipate

: 57-50-1
Sucrose

: 359707-34-9
C20H32O14

Conditions

Conditions	Yield
Candida antarctica-derived lipase type A In DMF (N,N-dimethyl-formamide) at 30℃; for 48h; Product distribution / selectivity;	81%

: 4074-90-2
divinyl adipate

: 65-71-4
thymin

: 1038531-21-3
C15H20N2O6

Conditions

Conditions	Yield
With potassium carbonate In dimethyl sulfoxide at 80℃; for 2.5h;	80%

: 2589-57-3
dimethyl 2,2'-azobis(isobutyrate)

: 4074-90-2
divinyl adipate

polymer, Mn 1.85E4 g/mol by GPC, Mw/Mn 12.7; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate): polymer, Mn 1.85E4 g/mol by GPC, Mw/Mn 12.7; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate)

Conditions

Conditions	Yield
In benzene at 80℃; for 4h;	79%

: 4074-90-2
divinyl adipate

: 959-26-2
Bis(2-Hydroxyethyl)terephthalat

: O,O’-((terephthaloylbis(oxy))bis(ethane-2,1-diyl)) divinyl diadipate

Conditions

Conditions	Yield
With 1-butyl-3-methylimidazolium Tetrafluoroborate; 2-hydroxyresorcinol In acetone at 65℃; for 40h; Enzymatic reaction;	79%

: 4074-90-2
divinyl adipate

: 59-47-2
mephenesin

: 1-O-vinyladipoyl-mephenesin

Conditions

Conditions	Yield
With Lipozyme(R) In acetone at 50℃; for 2h;	78.5%

: 51384-51-1
(RS)-metoprolol

: 4074-90-2
divinyl adipate

: 1350627-08-5
N-(5-vinyloxycarbonylpentanoyl)metoprolol

Conditions

Conditions	Yield
With Porcine pancreas lipase type II In tetrachloromethane at 50℃; for 72h; Enzymatic reaction;	74%

: 4074-90-2
divinyl adipate

: 66-22-8
uracil

: 1038531-17-7
1-(uracil-1-yl)-ethyl vinyl adipate

Conditions

Conditions	Yield
With potassium carbonate In dimethyl sulfoxide at 80℃; for 2.5h;	73%

: 4074-90-2
divinyl adipate

: 104-29-0
chlorphenesin

: 1-O-vinyladipoyl-chlorphenesin

Conditions

Conditions	Yield
With Lipozyme(R) In acetone at 50℃; for 2h;	72.5%

: 4074-90-2
divinyl adipate

: 602-41-5
thiocolchicoside

: 1261582-37-9
C35H43NO13S

Conditions

Conditions	Yield
With lipase from Candida antarctica In acetone at 45℃; for 12h; Molecular sieve; Enzymatic reaction; regioselective reaction;	72%

: 4074-90-2
divinyl adipate

: 1464-44-4
phenyl-β-D-glucopyranoside

: 1261582-29-9
6-O-(phenyl β-D-glucopyranosyl) vinyl adipate

Conditions

Conditions	Yield
With lipase from Candida antarctica In acetone at 45℃; for 12h; Molecular sieve; Enzymatic reaction; regioselective reaction;	72%

: 530-26-7
D-Mannose

: 4074-90-2
divinyl adipate

: Hexanedioic acid (2R,3S,4S,5S)-3,4,5,6-tetrahydroxy-tetrahydro-pyran-2-ylmethyl ester vinyl ester

Conditions

Conditions	Yield
With alkaline protease from Bacillus subtilis In pyridine at 50℃; for 96h;	69%

: 2589-57-3
dimethyl 2,2'-azobis(isobutyrate)

: 4074-90-2
divinyl adipate

polymer, Mn 1.71E4 g/mol by GPC, Mw/Mn 9.2; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate): polymer, Mn 1.71E4 g/mol by GPC, Mw/Mn 9.2; monomer(s): divinyl adipate; dimethyl 2,2\-azobis(isobutyrate)

Conditions

Conditions	Yield
In benzene at 80℃; for 4h;	68%

: 288-32-4
1H-imidazole

: 4074-90-2
divinyl adipate

: C13H18N2O4

Conditions

Conditions	Yield
With Thermomyces lanuginosus lipase; potassium carbonate In dimethyl sulfoxide at 50℃; for 0.5h; Flow reactor; Enzymatic reaction;	68%

: 4074-90-2
divinyl adipate

: 5370-01-4
(rac)-mexiletine hydrochloride

: 1268813-08-6
C19H27NO4

Conditions

Conditions	Yield
With sodium methylate In toluene for 12h; Inert atmosphere;	67%

: 2280-44-6
D-Glucose

: 4074-90-2
divinyl adipate

: 6-O-vinyladipoyl-D-glucopyranose

Conditions

Conditions	Yield
With alkaline protease from Streptomyces sp In N,N-dimethyl-formamide at 35℃; for 96h;	66%
With pyridine at 50℃; Enzymatic reaction;

: 4074-90-2
divinyl adipate

: 40983-58-2
methyl shikimate

: C16H22O8

Conditions

Conditions	Yield
With immobilized lipase from Mucor miehei In acetone at 30℃; for 12h;	65.1%

: bis(2-hydroxyethyl)(2,2,4-trimethylhexane-1,6-diyl)dicarbamate

: 4074-90-2
divinyl adipate

: O,O’-(7,7,9-trimethyl-4,13-dioxo-3,14-dioxa-5,12-diazahexadecane-1,16-diyl) divinyl diadipate

Conditions

Conditions	Yield
With 2-hydroxyresorcinol at 65℃; for 40h; Enzymatic reaction;	65%

: 2589-57-3
dimethyl 2,2'-azobis(isobutyrate)

: 4074-90-2
divinyl adipate

polymer; monomer(s): divinyl adipate, 0.5 mol/l; dimethyl 2,2\-azobis(isobutyrate), 0.5 mol/l: polymer; monomer(s): divinyl adipate, 0.5 mol/l; dimethyl 2,2\-azobis(isobutyrate), 0.5 mol/l

Conditions

Conditions	Yield
In benzene at 80℃; for 4h;	63%

: 4074-90-2
divinyl adipate

: 652-67-5
Isosorbide

: O,O'-(hexahydrofuro[3,2-b]furan-3,6-diyl) divinyl diadipate

Conditions

Conditions	Yield
With 2-hydroxyresorcinol In acetone at 65℃; for 40h; Enzymatic reaction;	62%

: 4074-90-2
divinyl adipate

: 33069-62-4
taxol

A: 7-epipaclitaxel 2'-vinyl adipate

B: 188593-01-3
paclitaxel 2'-vinyl adipate

Conditions

Conditions	Yield
With thermolysin from Bacillus thermoproteolyticus Rokko In tert-Amyl alcohol at 35℃; for 96h;	A 18% B 60%

...Expand

: 4074-90-2
divinyl adipate

: 7085-55-4
troxerutin

: 1218941-81-1
troxerutin vinyl adipate

Conditions

Conditions	Yield
With pyridine at 55℃; for 96h; Enzymatic reaction;	60%
With pyridine; alkaline protease from Bacillus subtilis at 50℃; for 120h; Enzymatic reaction; regioselective reaction;

Divinyl adipate Chemical Properties

Hexanedioic acid diethyl ester(4074-90-2)'s molecular formula is C₁₀H₁₈O₄and its formula weight is 202.25.
The density of hexanedioic acid diethyl ester(4074-90-2) is 1.009 and it has a melting point of -18°C. Its Boiling point is 251°C and the refractive index is about 1.426-1.428.
Hexanedioic acid diethyl ester(4074-90-2) has the property of being dissolved in alcohols and ethers, it is not soluble in water.
The molecular structure of hexanedioic acid diethyl ester(4074-90-2) :

Divinyl adipate Uses

Hexanedioic acid diethyl ester(4074-90-2) is used as a plasticizer for cellulose acetate, cellulose acetate butyrate and pyroxylin. It is also used as a organic solvent or in organic synthesis.

Divinyl adipate Toxicity Data With Reference

1.	orl-rat LD50:6400 mg/kg	GISAAA Gigiena i Sanitariya. 35 (10)(1970),88.
2.	orl-mus LD50:6400 mg/kg	GISAAA Gigiena i Sanitariya. 35 (10)(1970),88.
3.	orl-gpg LD50:4300 mg/kg	GISAAA Gigiena i Sanitariya. 35 (10)(1970),88.
4.	orl-rbt LD50:4300 mg/kg	GISAAA Gigiena i Sanitariya. 35 (10)(1970),88.

Divinyl adipate Safety Profile

Low toxicity by ingestion. When heated to decomposition it emits acrid smoke and irritating vapors.

Product Name

ADIPIC ACID DIVINYL ESTER

Synthetic route

Divinyl adipate Chemical Properties

Divinyl adipate Uses

Divinyl adipate Toxicity Data With Reference

Divinyl adipate Safety Profile

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