Product Name

  • Name

    Indium

  • EINECS 231-180-0
  • CAS No. 7440-74-6
  • Article Data207
  • CAS DataBase
  • Density 7.30
  • Solubility insoluble
  • Melting Point 156 ºC
  • Formula In
  • Boiling Point 2000 ºC
  • Molecular Weight 114.82
  • Flash Point 2072°C
  • Transport Information UN 3089 4.1/PG 2
  • Appearance solid
  • Safety S9-16-36/37/39-26-45-28
  • Risk Codes R20/21/22;R36/37/38   
  • Molecular Structure Molecular Structure of 7440-74-6 (Indium)
  • Hazard Symbols
  • Synonyms INE 07PB;Indium element;
  • PSA 0.00000
  • LogP 0.33750

Synthetic route

indium sulfate

indium sulfate

indium
7440-74-6

indium

Conditions
ConditionsYield
In not given Electrolysis; at 60°C;for 40 min; density of current 3-6 A/dm^2; electrolyte: in the presence of K-Na-tartarate;100%
In not given Electrolysis; at 60°C;for 40 min; density of current 3-6 A/dm^2; in the presence of H2SO4;100%
In not given Electrolysis; at 60°C;for 40 min; density of current 3-6 A/dm^2; in the presence of acetic acid, Na-acetate;100%
triisobutylindium
6731-23-3

triisobutylindium

A

indium
7440-74-6

indium

B

isobutene
115-11-7

isobutene

Conditions
ConditionsYield
In decalin byproducts: isobutane; pyrolysis in decalin under dry and deoxygenated N2 (140°C, 24 h); GLC anal. of org. products;A >99
B 96%
([(2,6-i-Pr2-C6H3)NC(Me)]2CH)Ga(Et)InEt2

([(2,6-i-Pr2-C6H3)NC(Me)]2CH)Ga(Et)InEt2

A

indium
7440-74-6

indium

B

([(2,6-i-Pr2-C6H3)NC(Me)]2CH)GaEt2

([(2,6-i-Pr2-C6H3)NC(Me)]2CH)GaEt2

C

Triethylindium
923-34-2

Triethylindium

Conditions
ConditionsYield
In toluene at 20℃; for 24h; Inert atmosphere; Schlenk technique; Glovebox;A 96%
B 94%
C n/a
cobaltocene
1277-43-6

cobaltocene

indium(I) trifluoromethanesulfonate
675617-71-7

indium(I) trifluoromethanesulfonate

A

indium
7440-74-6

indium

B

[(η(5)-C5H5)2Co]O3SCF3

[(η(5)-C5H5)2Co]O3SCF3

Conditions
ConditionsYield
In dichloromethane addn. of soln. of Cp2Co in CH2Cl2 to suspn. of InOTf in CH2Cl2; pptn., filtration, rinsing of ppt. with CH2Cl2; removal of solvent in vac.; slow evapn of concd. CH2Cl2 soln.; crystn.;A n/a
B 90.1%
indium(II) bromide

indium(II) bromide

A

indium
7440-74-6

indium

B

indium tribromide
13465-09-3

indium tribromide

Conditions
ConditionsYield
With dimethyl sulfoxide In benzeneA 90%
B n/a
With [2,2]bipyridinyl In benzeneA 90%
B n/a
With triethylamine In benzeneA 90%
B n/a
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,2-di-p-tolylethane
538-39-6

1,2-di-p-tolylethane

Conditions
ConditionsYield
In xylene pyrolysis in p-xylene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 85%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,2-di-m-tolylethane
4662-96-8

1,2-di-m-tolylethane

Conditions
ConditionsYield
In m-xylene=m-xylol pyrolysis in m-xylene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 83%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,2-bis(2-methylphenyl)ethane
952-80-7

1,2-bis(2-methylphenyl)ethane

Conditions
ConditionsYield
In o-xylene=o-xylol pyrolysis in o-xylene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 72%
triisopropyl indium
17144-80-8

triisopropyl indium

A

indium
7440-74-6

indium

B

1,2-di-p-tolylethane
538-39-6

1,2-di-p-tolylethane

Conditions
ConditionsYield
In xylene pyrolysis in p-xylene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 67%
indium chloride

indium chloride

lithium pentamethylcyclopentadienide
51905-34-1

lithium pentamethylcyclopentadienide

A

indium
7440-74-6

indium

B

indiumpentamethylcyclopentadienide

indiumpentamethylcyclopentadienide

C

bis(pentamethylcyclopentadienyl)indium(III) chloride
117469-41-7

bis(pentamethylcyclopentadienyl)indium(III) chloride

D

decamethylfulvalene
69446-48-6

decamethylfulvalene

Conditions
ConditionsYield
In diethyl ether InCl added to suspension of Li(C5(CH3)5), stirred for 5h at room temp.; exclusion of air and moisture; filtered, washed four times with ether, sublimation; elem. anal.;A 21%
B 62.01%
C 5%
D 2.5%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

2,2',3,3'-tetrahydro-1H,1'H-1,1'-biindene
82721-36-6

2,2',3,3'-tetrahydro-1H,1'H-1,1'-biindene

Conditions
ConditionsYield
In further solvent(s) pyrolysis in indane under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 62%
tri-n-butylindium
15676-66-1

tri-n-butylindium

A

1-butylene
106-98-9

1-butylene

B

indium
7440-74-6

indium

Conditions
ConditionsYield
In decalin byproducts: butene; pyrolysis in decalin under dry and deoxygenated N2 (140°C, 24 h); GLC anal. of org. products;A 60%
B >99
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,2-bis(4-chlorophenyl)ethane
5216-35-3

1,2-bis(4-chlorophenyl)ethane

Conditions
ConditionsYield
In further solvent(s) pyrolysis in p-chlorotoluene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 60%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,1'-bitetralyl
1154-13-8

1,1'-bitetralyl

Conditions
ConditionsYield
In tetralin pyrolysis in tetralin under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 60%
Conditions
ConditionsYield
In ethylbenzene pyrolysis in ethylbenzene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 51%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

3,4-dimethylhexane
583-48-2

3,4-dimethylhexane

C

butene-2
107-01-7

butene-2

D

n-butane
106-97-8

n-butane

Conditions
ConditionsYield
In decalin pyrolysis in decalin under dry and deoxygenated N2 (140°C, 24 h); GLC anal. of org. products;A >99
B 10%
C 30%
D 40%
tri-sec-butylindium
101749-61-5

tri-sec-butylindium

A

indium
7440-74-6

indium

B

1,2-bis(4-methoxyphenyl)ethane
1657-55-2

1,2-bis(4-methoxyphenyl)ethane

Conditions
ConditionsYield
In further solvent(s) pyrolysis in p-methoxytoluene under dry and deoxygenated N2 (stirring; 140°C, 9 h); GLC anal. of org. products;A n/a
B 35%
K(1+)*{HIn(CH2C(CH3)3)3}(1-)=K{HIn(CH2C(CH3)3)3}
139408-74-5

K(1+)*{HIn(CH2C(CH3)3)3}(1-)=K{HIn(CH2C(CH3)3)3}

Chlorodiisopropylphosphane
40244-90-4

Chlorodiisopropylphosphane

A

indium
7440-74-6

indium

B

(((CH3)3CCH2)2In(P(CH(CH3)2)2))2
380456-91-7

(((CH3)3CCH2)2In(P(CH(CH3)2)2))2

C

((CH3)3CCH2)3In*P(H)(CH(CH3)2)2
380456-92-8

((CH3)3CCH2)3In*P(H)(CH(CH3)2)2

D

((CH3)3CCH2)3In*P2(CH(CH3)2)4
380456-93-9

((CH3)3CCH2)3In*P2(CH(CH3)2)4

Conditions
ConditionsYield
In pentane byproducts: H2, (Me3CCH2)P(i-Pr)2, KCl; under Ar, standard vac. line techniques; pentane solns. of ClP(i-Pr)2 and In compd. (molar ratio 1:1) cooled to -78°C; combined; warmed slowly to room temp.; stirred for 2 d; pentane sol. products sepd. from ppt. by extn. (8 times); solvent removed by vac. distn. at 0°C; mixt. of three In compds. obtained; P2(i-Pr)4 adduct crystd. at room temp. in drybox; detd. by (1)H and (31)P NMR spectroscopy;A n/a
B n/a
C n/a
D 33.7%
indium chloride

indium chloride

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

indium(III) chloride
10025-82-8

indium(III) chloride

A

indium
7440-74-6

indium

Cl2InCH2InCl2((CH2N(CH3)2)2)2
99666-60-1

Cl2InCH2InCl2((CH2N(CH3)2)2)2

C

InCl3*0.67(CH2N(CH3)2)2*0.67CH2Cl2

InCl3*0.67(CH2N(CH3)2)2*0.67CH2Cl2

Conditions
ConditionsYield
With methylene chloride In dichloromethane; toluene equimolar amts. of InCl and InCl3 suspended in CH2Cl2-toluene (1:1, v/v) at -80°C, TMEDA added, stirred, allowed to reach room temp., further stirred for 1 h (total react. time 3-4 h); filtered, crystals deposited on standing collected and dried under vac., further crop obtained by addn. of Et2O to mother liquor and recrystn. (CH2Cl2); InCl3 solvate isolated from separate expt. by addn. of petroleum ether to react. mixt.; elem. anal.;A n/a
B 20%
C n/a
lithium tetrahydridoindanate
128448-03-3

lithium tetrahydridoindanate

quinuclidine hydrochloride
39896-06-5

quinuclidine hydrochloride

lithium bromide
7550-35-8

lithium bromide

A

indium
7440-74-6

indium

B

[H(quinuclidine)2][In5Br8(quinuclidine)4]

[H(quinuclidine)2][In5Br8(quinuclidine)4]

Conditions
ConditionsYield
In diethyl ether byproducts: H2, LiCl; quinuclidine hydrochloride added over 5 min to an in situ generated soln. of LiInH4 contg. LiBr in Et2O at -78°C, warmed to -30°C,stirred for 2 h, filtered, kept at this temp. for 72 h; evapd. (vac.), extd. (toluene), crystd. at -50°C overnight;A n/a
B 17%
indium(I) bromide

indium(I) bromide

sodium tri-tert-butylsilanide
103349-41-3

sodium tri-tert-butylsilanide

A

indium
7440-74-6

indium

B

tetrasupersilyldiindium
174809-84-8

tetrasupersilyldiindium

Conditions
ConditionsYield
In tetrahydrofuran byproducts: tBu3SiH, tBu3SiBr, (tBu3Si)2; equimolar ratio, stirring (-78°C, 12 h), warming (room temp.); volatile compds. removal (vac.), dissoln. (pentane), filtn., pptn. (1 week, -23°C); elem. anal.;A n/a
B 16.2%
In tetrahydrofuran byproducts: NaBr; equimolar ratio, stirring (-78°C, 12 h), warming (room temp.); volatile compds. removal (vac.), dissoln. (pentane), filtn., pptn. (1 week, -23°C); elem. anal.;A n/a
B 16.2%
(Cp(*)Fe(CO)2)2InI
871347-07-8

(Cp(*)Fe(CO)2)2InI

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate
79060-88-1

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

A

indium
7440-74-6

indium

B

[((η5-C5Me5)Fe(CO)2)2(μ-I)][B(C6H3(CF3)2-3,5)4]
871347-11-4

[((η5-C5Me5)Fe(CO)2)2(μ-I)][B(C6H3(CF3)2-3,5)4]

Conditions
ConditionsYield
In dichloromethane (N2 or Ar); a soln. of Fe complex added to a suspn. of B complex at -78°C, warmed to 20°C over 30 min, stirred for 3 h; filtered, layered with hexanes;A n/a
B 15%
[(C2H5)2InSb(Si(CH3)3)2]3

[(C2H5)2InSb(Si(CH3)3)2]3

A

indium
7440-74-6

indium

B

indium(III) antimonide

indium(III) antimonide

Conditions
ConditionsYield
In neat (no solvent) byproducts: ethylene, HSiMe3; heated under vac. to 400°C for 10 h;A n/a
B 13%
indium chloride

indium chloride

N,N,N,N,-tetramethylethylenediamine
110-18-9

N,N,N,N,-tetramethylethylenediamine

indium(III) chloride
10025-82-8

indium(III) chloride

A

indium
7440-74-6

indium

Cl2InCH2InCl2((CH2N(CH3)2)2)2
99666-60-1

Cl2InCH2InCl2((CH2N(CH3)2)2)2

Conditions
ConditionsYield
With methylene chloride In dichloromethane InCl and catalitic amts. of InCl3 suspended in CH2Cl2 at -80°C, TMEDA added, allowed to reach room temp. over ca. 2 h; Et2O added, ppt. collected, dried;A n/a
B 10%
dicarbonylcyclopentadienyliodoiron(II)
12078-28-3, 38979-86-1

dicarbonylcyclopentadienyliodoiron(II)

[CH((CH3)2CN-2,6-(i)Pr2C6H3)2In]
769959-24-2

[CH((CH3)2CN-2,6-(i)Pr2C6H3)2In]

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate
79060-88-1

sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate

A

indium
7440-74-6

indium

B

[((2,6-diisopropylphenyl-NC(Me))2CH)Fe(III)(η5-cyclopentadienyl)(CO)][B(C6H3(CF3)2-3,5)4]
1036767-96-0

[((2,6-diisopropylphenyl-NC(Me))2CH)Fe(III)(η5-cyclopentadienyl)(CO)][B(C6H3(CF3)2-3,5)4]

Conditions
ConditionsYield
In tetrahydrofuran under N2 or Ar; THF added to solid mixt. of Fe complex and NaB(C6H3(CF3)2)4; THF soln. of In compd. added; volatiles removed; extd. into toluene; soln. filtered; layered with hexane; crystd. for 1 wk; elem. anal.;A n/a
B 10%
indium(III) oxide

indium(III) oxide

indium
7440-74-6

indium

Conditions
ConditionsYield
With magnesium violent but incomplete reaction;
With sodium carbonate; pyrographite in blow pipe;
With hydrogen in tube with H2-flow;
indium(III) oxide

indium(III) oxide

manganese
7439-96-5

manganese

A

indium
7440-74-6

indium

B

manganese(II) oxide

manganese(II) oxide

Conditions
ConditionsYield
In neat (no solvent) (Ar); In2O3 and Mn reacted in 1:1 or 1:2 or 2:1 molar ratio; powdered inmortar; sealed under vacuum in quartz ampoule; heated to 723 K and with 0.5 K/h to 973 K; maintained for 7 days; cooled to 0.8 K/h to 473 K; le ft standing at room temp.;
indium
7440-74-6

indium

water
7732-18-5

water

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: In2O3; at 473°K and then at 673-773°K more;100%
arsenic

arsenic

indium
7440-74-6

indium

indium arsenide

indium arsenide

Conditions
ConditionsYield
In neat (no solvent) In, As evacuated, closed in an outgassed quartz ampoule at .apprx.1E-4 Pa, heated at 580.+-.20°C, 150h;100%
In neat (no solvent) deposited at GaAs by periodic supply of As and Ga species, deposition times was 25 min;
In, As sources used on InAs substrate at 450 to 525°C;
In neat (no solvent) mixt. melting (evac. sealed quartz capsule, 7E-4 hPa); differential thermal anal.;
In neat (no solvent, solid phase) annealing (800 K, 7 d);
indium
7440-74-6

indium

antimony
7440-36-0

antimony

indium(III) antimonide

indium(III) antimonide

Conditions
ConditionsYield
In neat (no solvent) In, Sb evacuated, closed in an outgassed quartz ampoule at .apprx.1E-4 Pa, heated at 500.+-.20°C, 70h or heated at 400.+-.20°C, 110h;100%
In melt crystn. from the melt with nearly stoichiometric composition;; single crystals obtained;;
In neat (no solvent) High Pressure; 0.7 GPa, laser heating;
indium
7440-74-6

indium

2,3-naphthalenediol
92-44-4

2,3-naphthalenediol

In{OC10H6(OH)-2,3}
121581-68-8, 121581-73-5

In{OC10H6(OH)-2,3}

Conditions
ConditionsYield
With Et4NClO4 In acetonitrile byproducts: H2; Electrolysis; using indium metall anode, platinum wire cathode in soln. of Et4NClO4 and dihydroxynaphthalene (2 h, N2, 20 mA), hydrogen gas evolving at the cathode and forming product at the anode; product collected by filtration, washed with acetonitrile and Et2O, dried (vac.); elem. anal.;100%
indium
7440-74-6

indium

lanthanum
7439-91-0

lanthanum

tellurium

tellurium

cesium chloride

cesium chloride

A

CsInTe2

CsInTe2

B

Cs3LaCl6

Cs3LaCl6

Conditions
ConditionsYield
at 299.84 - 999.84℃;A 100%
B n/a
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0286Sn0286In0143Sb0143Te

Ge0286Sn0286In0143Sb0143Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.72Sn0.08In0067Sb0067Te

Ge0.72Sn0.08In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.24Sn0.56In0067Sb0067Te

Ge0.24Sn0.56In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.08Sn0.72In0067Sb0067Te

Ge0.08Sn0.72In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.4Sn0.4In0067Sb0067Te

Ge0.4Sn0.4In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.35Sn0.35In0.1Sb0.1Te

Ge0.35Sn0.35In0.1Sb0.1Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.5Sn0.5InSbTe4

Ge0.5Sn0.5InSbTe4

Conditions
ConditionsYield
at 550 - 950℃; for 240h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

GeSnInSbTe5

GeSnInSbTe5

Conditions
ConditionsYield
at 350 - 950℃; for 240h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Ge0.8In0067Sb0067Te

Ge0.8In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
indium
7440-74-6

indium

antimony
7440-36-0

antimony

tellurium

tellurium

Sn0.8In0067Sb0067Te

Sn0.8In0067Sb0067Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
germanium
7440-56-4

germanium

indium
7440-74-6

indium

tellurium

tellurium

Ge0.4Sn0.4In0.13Te

Ge0.4Sn0.4In0.13Te

Conditions
ConditionsYield
at 590 - 900℃; for 120h; Inert atmosphere;100%
indium
7440-74-6

indium

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

indium(III) triflate - dimethylsulfoxide (1/7)

indium(III) triflate - dimethylsulfoxide (1/7)

Conditions
ConditionsYield
With oxygen In dimethyl sulfoxide metal. In under O2 atm. treated with DMSO and triflic acid (3 equiv.) in3 portions, heated at 100°C for 22 h;99%
arsenic

arsenic

niobium

niobium

indium
7440-74-6

indium

potassium
7440-09-7

potassium

10K(1+)*NbInAs6(10-)=K10NbInAs6

10K(1+)*NbInAs6(10-)=K10NbInAs6

Conditions
ConditionsYield
In neat (no solvent) mixt. K, Nb, In, and As was sealed in Nb container, enclosed in evacuated fused-silica ampule and heated at 600°C for a week and cooled slowly; elem. anal.;99%
gadolinium

gadolinium

germanium
7440-56-4

germanium

indium
7440-74-6

indium

Gd2InGe2

Gd2InGe2

Conditions
ConditionsYield
In neat (no solvent) (Ar); a mixt. of Gd, Ge, and In sealed (vac.), heated;99%
indium
7440-74-6

indium

lanthanum
7439-91-0

lanthanum

LaAu2In4

LaAu2In4

Conditions
ConditionsYield
In melt heating lanthanum, gold and indium in molar ratio 1:2:4 to 1000 for 10 hin vac., keeping at 1000°C for 120 h; cooling to room temp. for 48 h, X-ray anal.;99%
indium
7440-74-6

indium

praseodymium

praseodymium

PrAu2In4

PrAu2In4

Conditions
ConditionsYield
In melt heating praseodymium, gold and indium in molar ratio 1:2:4 to 1000 for 10 h in vac., keeping at 1000°C for 120 h; cooing to room temp. for 48 h, X-ray anal.;99%
Conditions
ConditionsYield
In melt heating cerium, gold and indium in molar ratio 1:2:4 to 1000 for 10 h invac., keeping at 1000°C for 120 h; cooling to room temp. for 48 h, X-ray anal.;99%
tetrahydrofuran
109-99-9

tetrahydrofuran

indium
7440-74-6

indium

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bromine
7726-95-6

bromine

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide

bis(tetrahydrofuran)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In tetrahydrofuran99%
pyridine
110-86-1

pyridine

indium
7440-74-6

indium

bromopentafluorobenzene
344-04-7

bromopentafluorobenzene

bromine
7726-95-6

bromine

bis(pyridine)(pentafluorophenyl)indium dibromide

bis(pyridine)(pentafluorophenyl)indium dibromide

Conditions
ConditionsYield
In dichloromethane99%
neodymium

neodymium

indium
7440-74-6

indium

NdAu2In4

NdAu2In4

Conditions
ConditionsYield
In melt heating neodymium, gold and indium in molar ratio 1:2:4 to 1000 for 10 hin vac., keeping at 1000°C for 120 h; cooling to room temp. for 48 h, X-ray anal.;99%
indium
7440-74-6

indium

toluene-4-sulfonic acid
104-15-4

toluene-4-sulfonic acid

indium(III) tosylate

indium(III) tosylate

Conditions
ConditionsYield
In nitromethane at 20℃; for 1.5h; Sonication;99%
indium
7440-74-6

indium

ethanethiol
75-08-1

ethanethiol

tris(ethylthio)indane

tris(ethylthio)indane

Conditions
ConditionsYield
With oxygen; tetraethylammonium perchlorate In acetonitrile Electrolysis; bubbling O2 through a soln. of thiol in CH3CN/Et4NClO4, electrolysis (open to atmosphere): Pt cathode, In anode, 15V, 50 mA, 1.0 h react. time, at the end of electrolysis stirring for ca. 12 h; filtration, washing with CH3CN, then petroleum ether, drying in vac.; elem. anal.;98%
indium
7440-74-6

indium

trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

indium(III) triflate

indium(III) triflate

Conditions
ConditionsYield
In nitromethane at 20℃; for 0.5h; Sonication;98%

Indium History

The German chemists Ferdinand Reich and Hieronymous Theodor Richter dissolved the minerals pyrite, arsenopyrite, galena and sphalerite in hydrochloric acid and distilled the raw zinc chloride. As it was known that ores from that region sometimes contain thallium they searched for the green emission lines with spectroscopic methods. They named the element with the blue spectral line indium. Richter went on to isolate the metal in 1864.
Until 1924, only approximately a gram of Indium (CAS NO.7440-74-6) constituted the world's supply.

Indium Consensus Reports

Reported in EPA TSCA Inventory.

Indium Standards and Recommendations

OSHA PEL: TWA 0.1 mg(In)/m3
ACGIH TLV: TWA 0.1 mg(In)/m3

Indium Specification

The Indium, with the cas registry number 7440-74-6, is a kind of silver gray fusible metal. This is insoluble in water, stable chemically but incompatible with strong acids, strong oxidizing agents, sulfur. Its product categories are including Inorganics; Indium; Metal and Ceramic Science; Metals; Catalysis and Inorganic Chemistry; Chemical Synthesis; IndiumMetal and Ceramic Science; IApplication CRMs; ICP CRMs; Alphabetic; Analytical Standards; ICP-OES/-MS; ICPSpectroscopy; Spectroscopy.

The physical properties of this chemical are below: (1)#H bond acceptors: 0; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 0; (5)Exact Mass: 114.903878; (6)MonoIsotopic Mass: 114.903878; (7)Topological Polar Surface Area: 0; (8)Heavy Atom Count: 1; (9)Covalently-Bonded Unit Count: 1

The production method of this chemical is below: all kinds of waste and intermediate products from the production of lead, Zinc, antimony, tin go through the process of enriched oxidation, extraction, metathesis and electrolysis to get this chemical.

As to its usage, it is widely applied in many ways. It could be used as the doping agent in compound semiconductor and high purity semiconductor [semiconducting] material; It could also be used in producing low melting point alloy and indium; Then it could also be applied in electron electroplate industry.

When you are using this chemical, you should be very cautious. For one thing, it is irritant which may cause inflammation to the skin or other mucous membranes, and it is irritating to eyes, respiratory system and skin. For another thing, it is harmful which may cause damage to health. If by inhalation, in contact with skin and if swallowed, it will be harmful. In addition, it is highly flammable which may catch fire in contact with air, only needing brief contact with an ignition source, and it has a very low flash point or evolve highly flammable gases in contact with water. Beside all these, it is corrosive which may destroy living tissue on contact.

Due to so many dangers, you could take the different measures to deal with different cases. Wear suitable protective clothing, gloves and eye/face protection. If in case of contact with eyes, rinse immediately with plenty of water and seek medical advice, and if in case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible). Then when store it, keep container in a well-ventilated place away from sources of ignition. After contact with skin, wash immediately with plenty of soap-suds.

Additionally, you could convert the following datas into the molecular structure:
(1)Canonical SMILES: [In]
(2)InChI: InChI=1S/In
(3)InChIKey: APFVFJFRJDLVQX-UHFFFAOYSA-N 

Below are the toxicity information of this chemical:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LDLo subcutaneous 10mg/kg (10mg/kg)   "Toxicity of Industrial Metals," Browning, E., London, Butterworths, 1961Vol. -, Pg. 144, 1961.

 

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