Product Name

  • Name

    Indium chloride

  • EINECS 233-043-0
  • CAS No. 10025-82-8
  • Article Data81
  • CAS DataBase
  • Density 3.46 g/mL at 25 °C(lit.)
  • Solubility reacts with water
  • Melting Point 262 °C (dec.)(lit.)
  • Formula InCl3
  • Boiling Point 300 °C
  • Molecular Weight 221.179
  • Flash Point 300°C subl.
  • Transport Information UN 3260 8/PG 2
  • Appearance white crystalline powder
  • Safety 26-36/37/39-45
  • Risk Codes 36/37/38-34-29-22
  • Molecular Structure Molecular Structure of 10025-82-8 (Indium chloride)
  • Hazard Symbols CorrosiveC
  • Synonyms Indium trichloride;Indium(III) chloride;Trichloroindium;Indium(Ⅲ)chloride;
  • PSA 0.00000
  • LogP 2.06850

Synthetic route

indium(III) oxide

indium(III) oxide

sulfur dioxide
7446-09-5

sulfur dioxide

chlorine
7782-50-5

chlorine

A

indium sulfate

indium sulfate

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; heating from 550 to 750°C;
In neat (no solvent) on In2O3 surface; not isolated, detd. by thermal desorption (20-650°C) and mass spectroscopy;
indium(III) oxide

indium(III) oxide

thionyl chloride
7719-09-7

thionyl chloride

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) 300°C;;
In neat (no solvent) 300°C;;
indium(III) oxide

indium(III) oxide

thionyl chloride
7719-09-7

thionyl chloride

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) 300°C;;
In neat (no solvent) 300°C;;
indium(III) oxide

indium(III) oxide

tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
780-800°C in vac.; Two-fold vacuum sublimation with prior distilling off SiCl4.;
tetrachloromethane
56-23-5

tetrachloromethane

indium(III) oxide

indium(III) oxide

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
450°C;;
In neat (no solvent) chlorination of In2O3 with CCl4 at ca 450°C;
In not given react. of In2O3 with CCl4;
indium(III) oxide

indium(III) oxide

chlorine
7782-50-5

chlorine

tin(IV) chloride
7646-78-8

tin(IV) chloride

A

(indium trichloride)2

(indium trichloride)2

B

indium(III) chloride
10025-82-8

indium(III) chloride

C

tin(IV) oxide

tin(IV) oxide

Conditions
ConditionsYield
In gas Kinetics; flow method (600 - 800°C, 5 - 50 vol.% SnCl4, 20 - 120 min);
indium(III) oxide

indium(III) oxide

chlorine
7782-50-5

chlorine

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With tin(IV) chloride In neat (no solvent) byproducts: O2; chlorination of equimolar mixt. of In2O3 by Cl2/SnCl4 mixt. (4 vol % SnCl4, const. temp. in range 550-700°C, 60 min); chem. anal.;
indium(III) oxide

indium(III) oxide

chlorine
7782-50-5

chlorine

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With pyrographite heating in dry flow of Cl2;
In neat (no solvent) Kinetics; byproducts: O2; heating to 700°C;
indium(III) oxide

indium(III) oxide

chlorine
7782-50-5

chlorine

A

(indium trichloride)2

(indium trichloride)2

B

oxygen
80937-33-3

oxygen

C

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
Cl2/Ar mixt. flowing over In2O3 (const. temp. in range 500-700°C,gas flow rate 2ml/min, complete satn. of carrier gas by vapours of gase ous products, duration 3 h); monitoring by gravimetric and chem. anal.;
indium(III) oxide

indium(III) oxide

chlorine
7782-50-5

chlorine

tin(IV) oxide

tin(IV) oxide

B

indium(III) chloride
10025-82-8

indium(III) chloride

C

tin(IV) chloride
7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; byproducts: O2; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2 flow 100 ml/min); chem. anal.;
With sulfur dioxide In neat (no solvent) Kinetics; byproducts: O2, SO3, In2(SO4)3; chlorination of equimolar mixt. of In2O3/SnO2 at const. temp. in range 500-700°C (Cl2/SO2 flow 100 ml/min); chem. anal.;
hydrogenchloride
7647-01-0

hydrogenchloride

indium
7440-74-6

indium

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With water starting with slightly wettened In without heating, then at 120 to 140°C, by adding more water;
byproducts: H2; wet HCl gas;
In hydrogenchloride prepn. by dissolving In in HCl according to S. V. Bleshinskii, V. F. Abramova, Chemistry of Indium (Akad. Nauk Kirg. SSR, Frunze, 1958);
indium
7440-74-6

indium

chlorine
7782-50-5

chlorine

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
in dry Cl2-flow;
Glowing to red heat, yellow-green flame.;
air removed by N2-flow, then reaction at 600°C in N2/Cl2-flow;
InCl2(1+)
29790-97-4

InCl2(1+)

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With lithium chloride In N,N-dimethyl-formamide Ar atmosphere, 25°C, ionic strength 1 M (LiClO4); not isolated; potentiometric monitoring (3 mass-% indium amalgam indicator electrode), estimation of stability const. of InCl3 in DMF;
hydrogenchloride
7647-01-0

hydrogenchloride

indium(III) hydroxide

indium(III) hydroxide

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In water In(OH)3 was dissolved in conc. HCl; evapd.;
In water drying (HCl(g) stream, 250°C), sublimation (500°C);
indium trichloride trihydrate

indium trichloride trihydrate

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With thionyl chloride In neat (no solvent) refluxing educt with dry SOCl2 for about 6 h; dried in vac. for about 2 h;
indium(II) perchlorate octahydrate

indium(II) perchlorate octahydrate

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With lithium chloride In N,N-dimethyl-formamide Ar atmosphere, 25°C, ionic strength 1 M (LiClO4); not isolated; potentiometric monitoring (3 mass-% indium amalgam indicator electrode), estimation of stability const. of InCl3 in DMF;
indium(ii) chloride

indium(ii) chloride

chlorine
7782-50-5

chlorine

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
mild heating; sublimation in CO2-flow;
at 300-350°C in CO2-containing Cl2-flow, in few hours;
mild heating; sublimation in CO2-flow;
indium sulfate

indium sulfate

sulfur dioxide
7446-09-5

sulfur dioxide

chlorine
7782-50-5

chlorine

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) Kinetics; byproducts: SO3; heating to from 550 to 750°C;
indium sulfate

indium sulfate

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With sulfur dioxide; chlorine Kinetics; byproducts: SO2;
With chlorine In solid Kinetics; byproducts: SO2, O2; at 128-800°C;
indium sulfate

indium sulfate

chlorine
7782-50-5

chlorine

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: O2; heating to above 800°C;
indium chloride

indium chloride

lithium nitrate

lithium nitrate

water
7732-18-5

water

A

indium(III) hydroxide

indium(III) hydroxide

B

ammonium chloride

ammonium chloride

C

indium(III) chloride
10025-82-8

indium(III) chloride

D

lithium chloride

lithium chloride

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
indium chloride

indium chloride

lithium nitrate

lithium nitrate

water
7732-18-5

water

A

indium(III) hydroxide

indium(III) hydroxide

B

nitrogen
7727-37-9

nitrogen

C

indium(III) chloride
10025-82-8

indium(III) chloride

D

lithium chloride

lithium chloride

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
indium chloride

indium chloride

lithium nitrate

lithium nitrate

water
7732-18-5

water

A

indium(III) hydroxide

indium(III) hydroxide

B

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

C

indium(III) chloride
10025-82-8

indium(III) chloride

D

lithium chloride

lithium chloride

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
indium chloride

indium chloride

lithium nitrate

lithium nitrate

water
7732-18-5

water

A

indium(III) hydroxide

indium(III) hydroxide

B

indium(III) chloride
10025-82-8

indium(III) chloride

C

lithium chloride

lithium chloride

D

dinitrogen monoxide
10024-97-2

dinitrogen monoxide

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
indium chloride

indium chloride

lithium nitrate

lithium nitrate

water
7732-18-5

water

A

lithium nitrite
13568-33-7

lithium nitrite

B

indium(III) hydroxide

indium(III) hydroxide

C

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In water reaction of an excess of InCl with aq. LiNO3 solns. 20°C;
indium(III) nitride

indium(III) nitride

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With hydrogenchloride byproducts: NH4Cl;
cadmium(II) selenide

cadmium(II) selenide

InSeCl

InSeCl

A

Cd2InSe3Cl

Cd2InSe3Cl

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
In neat (no solvent) mixt. of the starting materials heated in evacuated sealed quartz tubes to 500-900°C; decompn. of educts ocurrs, InCl3 sublimates off;A 0%
B n/a
indium chloride

indium chloride

A

indium
7440-74-6

indium

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With water
In water Kinetics; stirring of monohalide in H2O, disproportionation within several minutes at 20°C; products not isolated, detn. of In(III) in soln. after sepn. of solid phase (In);
With water
In dichloromethane disproportionation at temp. above -80°C;
indium chloride

indium chloride

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
by strong heating;
by strong heating;
indium chloride

indium chloride

indium(ii) chloride

indium(ii) chloride

A

indium
7440-74-6

indium

B

indium(III) chloride
10025-82-8

indium(III) chloride

Conditions
ConditionsYield
With water In hydrogenchloride formation of InCl3 and In from InCl and InCl2 in aq. HCl by addn. of H2O;;
With H2O In hydrogenchloride formation of InCl3 and In from InCl and InCl2 in aq. HCl by addn. of H2O;;
ethylmagnesium chloride
2386-64-3

ethylmagnesium chloride

indium(III) chloride
10025-82-8

indium(III) chloride

diethylindium chloride
14774-82-4

diethylindium chloride

Conditions
ConditionsYield
In diethyl ether; hexane under N2, stirring, 20 h, 25 °C; filtn.;100%
In diethyl ether; hexane under N2, stirring, 20 h, 25 °C; evapn. (vac.); redissolving (hexane); extn. (refluxing, 2 h); evapn.;80%
indium(III) chloride
10025-82-8

indium(III) chloride

diethylammonium N,N-diethyldiselenocarbamate
30634-02-7

diethylammonium N,N-diethyldiselenocarbamate

tris(diethyldiselenocarbamato)indium(III)
19400-67-0

tris(diethyldiselenocarbamato)indium(III)

Conditions
ConditionsYield
In methanol; ethanol to a soln. of (Et2NH2)(Et2dsc) in methanol a soln. of InCl3 in ethanol is added (Ar); ppt. is sucked off, washed with water and ethanol and dried, dissolved in small amount chloroform, filtration of soln. in vac., crystn.;100%
methyl methylphenylphosphinate
6389-79-3

methyl methylphenylphosphinate

indium(III) chloride
10025-82-8

indium(III) chloride

poly(indium methylphenylphosphinate)

poly(indium methylphenylphosphinate)

Conditions
ConditionsYield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;100%
nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)
158789-52-7

nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)

indium(III) chloride
10025-82-8

indium(III) chloride

((CH3)3CC8H3NN)4ReNInCl3

((CH3)3CC8H3NN)4ReNInCl3

Conditions
ConditionsYield
In tetrahydrofuran; hexane; dichloromethane Re compd. dissolved in CH2Cl2/THF/hexane and cooled to -5°C, electrophile added dropwise to this soln., stirred for 6 h at -5°C; solvent removed at -5°C, elem. anal.;100%
1-methyl-3-(propyl-3-sulfonic acid)imidazole chloride salt

1-methyl-3-(propyl-3-sulfonic acid)imidazole chloride salt

indium(III) chloride
10025-82-8

indium(III) chloride

C7H13N2O3S(1+)*Cl4In(1-)

C7H13N2O3S(1+)*Cl4In(1-)

Conditions
ConditionsYield
at 80℃; for 1h; Inert atmosphere;100%
indium(III) chloride
10025-82-8

indium(III) chloride

1,3-diphenylpropanedione
120-46-7

1,3-diphenylpropanedione

In(III)(dibenzoylmethanate)3

In(III)(dibenzoylmethanate)3

Conditions
ConditionsYield
With diethylamine In benzene N2; refluxed for 3h; molar ratio InCl3/ligand/base: 1/3.1/3.1;; recrystn. from dichloromethane-ethanol (1:1); elem. anal.;;99%
With ethanol; sodium isocyanate In tetrahydrofuran N2; refluxed for 3h; molar ratio InCl3/ligand/base=3.1/3.1;; recrystn. from dichloromethane-ethanol (1:1); elem. anal.;;91%
With sodium isocyanate In ethanol N2; refluxed for 3h; molar ratio InCl3/ligand/base: 1/3.1/3.1;; recrystn. from dichloromethane-ethanol (1:1); elem. anal.;;89%
With NaOAc In ethanol; water addn. of ethanolic dibenzoylmethane with stirring to aq. InCl3 buffered with NaOAc; recrystn. (acetone); elem. anal.;
potassium hydridotris(3,5-dimethylpyrazolyl)borate
17567-17-8

potassium hydridotris(3,5-dimethylpyrazolyl)borate

indium(III) chloride
10025-82-8

indium(III) chloride

(tris(3,5-dimethyl-1-pyrazolyl)hydridoborate)InCl2
112439-54-0

(tris(3,5-dimethyl-1-pyrazolyl)hydridoborate)InCl2

Conditions
ConditionsYield
In tetrahydrofuran stirring (18 h, room temp.), solvent removal (vacuum); extraction (CH2Cl2), recrystn. (MeCN);99%
indium(III) chloride
10025-82-8

indium(III) chloride

acetylacetone
123-54-6

acetylacetone

indium acetylacetonate

indium acetylacetonate

Conditions
ConditionsYield
With sodium isocyanate In ethanol byproducts: alkyl carbamate; refluxing for 3h; molar ratio of (acetylacetone)/InCl3=3.1-3.3 and (NaOCN)/(InCl3)=6.6-6.7;;99%
With sodium isocyanate In methanol byproducts: alkyl carbamate; addn. of NaOCN (120mmol) and acetylacetone (120mmol) to a soln. of InCl3 (18.1mmol) in methanol (80ml) at room temp.; refluxing at 68°C for 3h; cooling; filtration;; washing solids with benzene; distn. (solvents, acetylacetone) under reduced pressure; addn. of benzene; filtration; concg. soln. under reduced pressure; heating solid at 60-70°C in vac. for 1-2h; recrystn. from ethanol;;98.6%
With sodium isocyanate In tetrahydrofuran refluxing for 3h; molar ratio of (acetylacetone)/InCl3=3.1-3.3 and (NaOCN)/(InCl3)=6.6-6.7;;91%
indium(III) chloride
10025-82-8

indium(III) chloride

thiophenol
108-98-5

thiophenol

tris(benzenethiolato)indium(III)
1046154-90-8

tris(benzenethiolato)indium(III)

Conditions
ConditionsYield
In benzene molar ratio In/Si: 1:3, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;99%
phenylthiotrimethylsilane
4551-15-9

phenylthiotrimethylsilane

indium(III) chloride
10025-82-8

indium(III) chloride

chlorobis(phenylthio)indane

chlorobis(phenylthio)indane

Conditions
ConditionsYield
In benzene byproducts: (CH3)3SiCl; molar ratio In/Si: 1:2, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;99%
In benzene byproducts: (CH3)3SiCl; molar ratio In/Si: 1:1, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;46%
Ag[(cyclopentadienyl)tris(dimethylphosphito-P)cobalt]

Ag[(cyclopentadienyl)tris(dimethylphosphito-P)cobalt]

thallium hydrotris(1H-pyrazol-1-yl)borate

thallium hydrotris(1H-pyrazol-1-yl)borate

indium(III) chloride
10025-82-8

indium(III) chloride

[In((C5H5)Co(PO(OCH3)2)3)((C3H3N2)3BH)](1+)*InCl4(1-)=[In((C5H5)Co(PO(OCH3)2)3)((C3H3N2)3BH)](InCl4)

[In((C5H5)Co(PO(OCH3)2)3)((C3H3N2)3BH)](1+)*InCl4(1-)=[In((C5H5)Co(PO(OCH3)2)3)((C3H3N2)3BH)](InCl4)

Conditions
ConditionsYield
In methanol; dichloromethane; acetone99%
trimethylsilyl cyanide
7677-24-9

trimethylsilyl cyanide

Gallium trichloride
13450-90-3

Gallium trichloride

indium(III) chloride
10025-82-8

indium(III) chloride

0.5In(3+)*0.5Ga(3+)*3CN(1-)=In0.5Ga0.5(CN)3

0.5In(3+)*0.5Ga(3+)*3CN(1-)=In0.5Ga0.5(CN)3

Conditions
ConditionsYield
In diethyl ether; hexane byproducts: Me3SiCl; N2-atmosphere; dropwise addn. of stoic. mixt. of metal salts (in ether) to Me3SiCN (in hexane), stirring for 12 h; collection (filtration), heating in hexane (several h), washing (hexane);99%
(2S)-methylbuthyl-1-magnesium bromide
35026-81-4

(2S)-methylbuthyl-1-magnesium bromide

indium(III) chloride
10025-82-8

indium(III) chloride

In((S)-2-methylbutyl)2Cl

In((S)-2-methylbutyl)2Cl

Conditions
ConditionsYield
In diethyl ether inert atmosphere; slow addn. of 2 equiv. of Mg-compd. to InCl3 suspn. at0°C, stirring overnight; solvent removal (vac.), extn. into pentane, filtration, solvent removal (vac.);99%
indium(III) chloride
10025-82-8

indium(III) chloride

N-methylpiperazinodithiocarboxylic acid, potassium salt

N-methylpiperazinodithiocarboxylic acid, potassium salt

indium(III) N-methylpiperazine dithiocarbamate
371958-47-3

indium(III) N-methylpiperazine dithiocarbamate

Conditions
ConditionsYield
In methanol to a soln. of metal salt added slowly a soln. of S compd., stirred for 3h; solvent removed (vac.), extrd. (CH2Cl2), filtered (G-3), evapd. (vac.); elem. anal., IR;99%
methanol
67-56-1

methanol

[bis(4-allyl-3-thiosemicarbazonato)acenaphthenequinone]zinc(II)

[bis(4-allyl-3-thiosemicarbazonato)acenaphthenequinone]zinc(II)

indium(III) chloride
10025-82-8

indium(III) chloride

[indium chloride bis(4-allyl-3-thiosemicarbazonate)acenaphthenequinone]*(methanol)

[indium chloride bis(4-allyl-3-thiosemicarbazonate)acenaphthenequinone]*(methanol)

Conditions
ConditionsYield
In methanol addn. of Zn compd. in MeOH to InCl3, heating under reflux for 2 h or stirring overnight;99%
In methanol addn. of Zn compd. in MeOH to InCl3, heating under reflux for 6 h; cooling to room temp., filtration, washing with Et2O, drying under vacuum, elem. anal.;27%
zinc bis(4-methyl-3-thiosemicarbazonate)acenaphthenequinone

zinc bis(4-methyl-3-thiosemicarbazonate)acenaphthenequinone

indium(III) chloride
10025-82-8

indium(III) chloride

[indium chloride bis(4-methyl-3-thiosemicarbazonate)acenaphthenequinone]*(methanol)

[indium chloride bis(4-methyl-3-thiosemicarbazonate)acenaphthenequinone]*(methanol)

Conditions
ConditionsYield
In methanol addn. of Zn compd. in MeOH to InCl3, heating under reflux for 2 h or stirring overnight;99%
In methanol addn. of Zn compd. in MeOH to InCl3, heating under reflux for 6 h; cooling to room temp., filtration, washing with Et2O, drying under vacuum, elem. anal.;62%
2K(1+)*Zr6B(13+)*15Cl(1-)=K2(Zr6B)Cl15

2K(1+)*Zr6B(13+)*15Cl(1-)=K2(Zr6B)Cl15

indium(III) chloride
10025-82-8

indium(III) chloride

acetonitrile
75-05-8

acetonitrile

(Zr6B)Cl12(CH3CN)6(1+)*InCl4(1-)=(Zr6B)Cl12(CH3CN)6(InCl4)

(Zr6B)Cl12(CH3CN)6(1+)*InCl4(1-)=(Zr6B)Cl12(CH3CN)6(InCl4)

Conditions
ConditionsYield
In acetonitrile byproducts: KCl; CH3CN added to metal complex, sealed in a glass ampule, kept at 100°C for 3-4 d, filtered (Ar), treated with excess of InCl3, sealed, heated at 100°C for 12 h; evapd. slowly;99%
2,2':6,2''-terpyridine
1148-79-4

2,2':6,2''-terpyridine

sodium azide

sodium azide

indium(III) chloride
10025-82-8

indium(III) chloride

(2,2',2''-terpyridine)In(N3)3
259137-34-3

(2,2',2''-terpyridine)In(N3)3

Conditions
ConditionsYield
In tetrahydrofuran; toluene byproducts: NaCl; Ar-atmosphere; stoich. amts.; treatment of InCl3 (in PhMe) with terpy and then with NaN3 (in THF), refluxing for 5 h; filtration off of NaCl, cooling to -30°C (pptn.);98.4%
tribenzylindium
125706-16-3

tribenzylindium

indium(III) chloride
10025-82-8

indium(III) chloride

benzylindium chloride

benzylindium chloride

Conditions
ConditionsYield
In toluene a soln. of tribenzylindane and InCl3 (ratio 1:2) in toluene is heated under reflux for 8 h, cooling to room temp. (under Ar); filtn. of residue, drying in vac., elem. anal.;98%
In benzene N2 atmosphere, dry and degassed solvent, addn. of In-compd. in benzene to SnCl3, refluxing (5 h), pptn. on cooling; filtration, drying in vac.;90%
indium(III) chloride
10025-82-8

indium(III) chloride

triisopropyl indium
17144-80-8

triisopropyl indium

(i-Pr)2InCl
123241-18-9

(i-Pr)2InCl

Conditions
ConditionsYield
In toluene addn. of InCl3 to soln. of iPr3In, stirring, 6h, 80°C, filtration, washed with toluene (8x), evapn. in vac., under Ar; elem. anal.;97%
sodium N-morpholinocarbamodithioate
873-58-5

sodium N-morpholinocarbamodithioate

indium(III) chloride
10025-82-8

indium(III) chloride

bis(2-mercaptoethyl) ether disodium salt

bis(2-mercaptoethyl) ether disodium salt

(O(C2H4)S)2indium(III) morpholine dithiocarbamate
419535-68-5

(O(C2H4)S)2indium(III) morpholine dithiocarbamate

Conditions
ConditionsYield
In benzene anhydrous condns.; a soln. of metal salt and thiolate stirred for 3 h inbenzole, a metal compd. treated with carbamate, stirred for 3 h at room temp.; filtered, solvent removed (vac.); elem. anal., IR;97%
dimethylselenide
593-79-3

dimethylselenide

indium(III) chloride
10025-82-8

indium(III) chloride

[In(μ-Cl)Cl2(SeMe2)2]2
1211565-03-5

[In(μ-Cl)Cl2(SeMe2)2]2

Conditions
ConditionsYield
In neat (no solvent) (Ar); Schlenk techniques; InCl3 dissolved in Me2Se at 0°C; stirred for 1 h at room temp.; crystd. by slow diffusion of pentane; elem. anal.;97%
(ethylthio)trimethylsilane
5573-62-6

(ethylthio)trimethylsilane

indium(III) chloride
10025-82-8

indium(III) chloride

chlorobis(ethylthio)indane

chlorobis(ethylthio)indane

Conditions
ConditionsYield
In benzene byproducts: (CH3)3SiCl; molar ratio In/Si: 1:2, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;96%
In benzene byproducts: (CH3)3SiCl; molar ratio In/Si: 1:1, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;25%
potassium dihydrobis(pyrazol-1-yl)borate

potassium dihydrobis(pyrazol-1-yl)borate

sodium acetate
127-09-3

sodium acetate

indium(III) chloride
10025-82-8

indium(III) chloride

(acetato)bis{dihydrobis(1-pyrazolyl)borato}indium(III)

(acetato)bis{dihydrobis(1-pyrazolyl)borato}indium(III)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: KCl, NaCl; N2 atmosphere; stirring (room temp., 5 h); evapn. of solvent (vac.), extn. (benzene), filtration, removal of solvent (vac); elem. anal.;96%
(W3Se4(H2O)9)(4+)
184229-82-1, 777840-00-3

(W3Se4(H2O)9)(4+)

water
7732-18-5

water

indium(III) chloride
10025-82-8

indium(III) chloride

[(H2O)12W3Se4In](5+)

[(H2O)12W3Se4In](5+)

Conditions
ConditionsYield
With sodium tetrahydroborate In hydrogenchloride In-compd. addn. to soln. of complex, Ar atmosphere, borohydride addn. inportions, dilution by aq. HCl, sepn. on cation-exchange column (Dowex);96%
sodium N,N'-diisopropyldithiocarbamate
4092-82-4

sodium N,N'-diisopropyldithiocarbamate

indium(III) chloride
10025-82-8

indium(III) chloride

chlorobis(diisopropyldithiocarbamato)indium(III)
180607-99-2

chlorobis(diisopropyldithiocarbamato)indium(III)

Conditions
ConditionsYield
In methanol byproducts: NaCl; (N2); stirring (ca. 30°C, 3-4 h); evapn., extn. (CHCl3), filtration, removal of solvent (reduced pressure), crystn. (CH2Cl2/hexane); elem. anal.;96%
potassium 1,2-cyclobutane-3,4-dithiolate
52427-61-9

potassium 1,2-cyclobutane-3,4-dithiolate

indium(III) chloride
10025-82-8

indium(III) chloride

benzyltrimethylammonium chloride
56-93-9

benzyltrimethylammonium chloride

tris(benzyltrimethylammonium) [tris(1,2-dithioquadratato-S,S')indate(III)]

tris(benzyltrimethylammonium) [tris(1,2-dithioquadratato-S,S')indate(III)]

Conditions
ConditionsYield
In water 3-3 equiv. of K-salt and N-compd. were dissolved in H2O, 1 equiv. of InCl3 was slowly added in H2O; ppt. was filtered off, dried in an exsiccator, elem. anal.;96%
HN(CH3)Si(CH3)2N(CH3)Li

HN(CH3)Si(CH3)2N(CH3)Li

indium(III) chloride
10025-82-8

indium(III) chloride

[Li[In(HN(CH3)Si(CH3)2N(CH3))2(CH3NSi(CH3)2NCH3)]]2

[Li[In(HN(CH3)Si(CH3)2N(CH3))2(CH3NSi(CH3)2NCH3)]]2

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl, Me2Si(NHMe)2; addn. of the Li compd. in Et2O to a slurry of InCl3 in Et2O at room temp., stirring (24 h); removal of ether (vac. distn.), drying (24 h), extraction (hexane), filtration (Celite), removal of hexane (vac.); crystals may be obtained by dissoln. of the solid in hexane/Et2O (1:9) and cooling 24 h at -35°C; elem. anal.;96%
3-diethylamino-propan-1-ol
622-93-5

3-diethylamino-propan-1-ol

indium(III) chloride
10025-82-8

indium(III) chloride

[InCl3(3-diethylamino-1-propanol)]2

[InCl3(3-diethylamino-1-propanol)]2

Conditions
ConditionsYield
In dichloromethane (N2); ligand added to a suspn. of InCl3, stirred for 12 h; added to stirring pentane, filtered, dried (vac.);96%

Indium chloride Chemical Properties

Molecular Formula: InCl3
Molecular Weight: 221.18g/mol
Mol File: 10025-82-8.mol
Einecs: 233-043-0
Appearance: White flakes
Melting Point: 586 °C
Boiling point: 800 °C
Flash Point: 300 °C subl
Density: 3.46 g/mL at 25 °C(lit.)
Water Solubility: Reacts
Sensitive: Hygroscopic
Structure of Indium trichloride (CAS NO.10025-82-8):
                      
IUPAC Name: Trichloroindigane
Canonical SMILES: Cl[In](Cl)Cl
InChI: InChI=1S/3ClH.In/h3*1H;/q;;;+3/p-3
InChIKey: PSCMQHVBLHHWTO-UHFFFAOYSA-K
Product Categories of Indium trichloride(CAS NO.10025-82-8): Inorganics ; Catalysis and Inorganic Chemistry ; Chemical Synthesis ; Crystal Grade Inorganics ; Indium Salts ; IndiumMetal and Ceramic Science ;Salts;Indium .

Indium chloride Uses

  Indium trichloride (CAS NO.10025-82-8)  is  a lewis acid catalyst in organic reactions such as Friedel-Crafts acylations and Diels-Alder reactions,and it's also  the imporant materials to manufacture other indium salt.

Indium chloride Production

  Indium trichloride (CAS NO.10025-82-8) will be placed in dry metal quartz tube, which leads to a fully dry chlorine gas, heated to 150 to 300 ° C for the reactions to produce a shiny sheet metal indium trichloride, 600 ° C sublimation, the sublimation process which leads to a small amount of chlorine-containing nitrogen or carbon dioxide flow, which leads to non-final chlorine carbon dioxide, obtained by cooling. Two by three indium chloride and hydrogen chloride at 100 ° C reaction progressive derived. Four hydration from hydrochloric acid-soluble metal indium obtained after crystallization.

Indium chloride Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 4950ug/kg (4.95mg/kg)   Comptes Rendus Hebdomadaires des Seances, Academie des Sciences. Vol. 256, Pg. 1043, 1963.
mouse LD50 intravenous 11900ug/kg (11.9mg/kg)   Drugs in Japan Vol. -, Pg. 136, 1990.
mouse LDLo subcutaneous 60mg/kg (60mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo intravenous 640ug/kg (0.64mg/kg)   Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975.
rabbit LDLo subcutaneous 2mg/kg (2mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(10), Pg. 28, 1965.
rat LD50 intraperitoneal 2370ug/kg (2.37mg/kg)   Drugs in Japan Vol. -, Pg. 136, 1990.
rat LD50 intravenous 4460ug/kg (4.46mg/kg)   Drugs in Japan Vol. -, Pg. 136, 1990.
rat LDLo subcutaneous 10mg/kg (10mg/kg) SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION

SKIN AND APPENDAGES (SKIN): HAIR: OTHER
Journal of Industrial Hygiene and Toxicology. Vol. 24, Pg. 243, 1942.

Indium chloride Consensus Reports

Reported in EPA TSCA Inventory.

Indium chloride Safety Profile

A poison by subcutaneous, intraperitoneal, and intravenous routes. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl. See also INDIUM.
Hazard Codes of Indium trichloride (CAS NO.10025-82-8): C
Risk Statements: 36/37/38-34-29-22
36:  Irritating to the eyes
37:  Irritating to the respiratory system
38:  Irritating to the skin
34:  Causes burns
29:  Contact with water liberates toxic gas
22:  Harmful if swallowed
Safety Statements: 26-36/37/39-45
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36:  Wear suitable protective clothing
37:  Wear suitable gloves
39:  Wear eye/face protection
45:  In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)

Indium chloride Specification

  Indium trichloride , its cas register number is 10025-82-8. It also can be called Indium trichloride ; Indium (III) chloride ; and Indium In 111 Chloride .

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